MATERIAL SAFETY DATA SHEEET
PRODUCT : SEETULN 68
PRODUCT CODE : 49 450
MSDS NO. : 1-175-5
DATE OF ISSUE : OCTOBER 1995
STATUS : NEW
HINDUSTAN PETROLEUM CORPORATION LIMITED
17, JAMSHED JI TATA ROAD,
BOMBAY,
INDIA - 400 020
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients present at or above 0.1 wt % (classified as toxic or very toxic) or 1 wt % (classified as harmful,
irritant or corrosive).
HAZARDOUS INGREDIENT APPROXIMATE CONCENTRATION
None
The chemical identity of some or all of the ingredients is confidential business information and is being
withheld. In the event of a medical emergency, compositional information will be provided to medical
staff.
3. HAZARD IDENTIFICATION
This product contains a highly refined base oil.
It is of low oral and dermal toxicity and under normal conditions of use should present no significant health
hazards. However, in common with most mineral oils, prolonged and repeated skin contact may cause
dermatitis.
Handling precautions should be strictly observed.
4. FIRST AID
INHALATION :
At ambient/normal handling temperatures, inhalation of vapors is normally not a problem. If overexposed
to oil mist, remove from further exposure. Administer artificial respiration if breathing is irregular or has
stopped. Get prompt medical attention.
SKIN CONTACT :
No adverse effect due to skin contact are expected.
EYE CONTACT :
Rinse immediately with plenty of water until irritation subsides. If irritation persists, obtain medical advice.
INGESTION :
If swallowed, DO NOT induce vomiting; keep at rest and call a physician
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA :
Foam, dry chemical powder, carbon dioxide.
FIRE AND EXPLOSION HAZARDS :
Combustible material, low hazard. The product can form flammable mixtures or can burn only on heating
above the flash point. However, minor contamination by hydrocarbons of higher volatility may increase
the hazard.
SPECIAL FIRE-FIGHTING PROCEDURES :
Water fog or spray, to cool fire-exposed surface (e.g. containers) and to protect personnel, should be used
by personnel trained in fire fighting.
Cut off "fuel" ; depending on circumstances, either allow the fire to burn out under controlled conditions or
use foam or dry chemical powder to extinguish the fire.
Respiratory and eye protection equipment required for fire fighting personnel exposed to fumes or smoke.
HAZARDOUS COMBUSTION PRODUCTS :
Smoke, and carbon monoxide may be formed in the event of incomplete combustion.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS : See Section 8.
LAND SPILL :
Shut off source taking normal safety precautions. Prevent liquid from entering sewers, water course of low
lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. Take measures to
minimize the effects on ground water.
Recover by skimming or pumping using explosion-proof equipment, or contain spilled liquid with booms,
sand, or other suitable absorbent and remove mechanically into containers.
If necessary, dispose of adsorbed residues as direct in Section 13.
WATER SPILL
Confine the spill immediately with booms. Warn other shipping. Notify port and other relevant
authorities.
Remove from the surface by skimming or with suitable absorbents. Disperse the residue in unconfined
waters, if permitted by local authorities and environmental agencies.
7. HANDLING AND STORAGE
Storage the product in cool, well ventilated surroundings, well away from source of ignition.
Provide suitable mechanical equipment for the safe handling of drums and heavy packages.
Electrical equipment and fitting must comply with local regulations regarding fire prevention with this
class of product.
LOAD/UNLOAD TEMPERATURE, o C : Ambient to max. 60oC
STORAGE TEMPERATURE, o C : Ambient to max. 60oC
SPECIAL PRECAUTIONS :
Keep containers closed when not in use
Prevent small spills and leakages to avoid slip hazard.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMIT :
5 mg/m3 for oil mists (TWA, 8h - workday) recommended based upon the ACGIH TLV (Analyses
according to US NIOSH Method 5026, NIOSH Manual of Analytical Methods, 3rd Ed.).
PERSONAL PROTECTION :
In open systems where contact is likely, wear safety goggles, chemical-resistant overalls, and chemically
impervious gloves.
Where only incidental contact is likely, wear safety glasses with side shields. No other special precautions
are necessary provided skin/eye contact is avoided.
When concentration in air exceed the occupational exposure limit, and where engineering, work practices,
or other means of exposure reduction are not adequate, approved respirators may be required.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE / ODOUR : CLEAR GOLDEN LIQUID, MILD
PETROLEUM ODOUR.
DENSITY @ 29.5oC, g/ml (Average) : 0.885
BOILING RANGE : IBP 340oC (TYPICAL)
VISCOSITY, KINEMATIC @ 40oC, CST : 62.0 - 68.0
VAPOUR DENSITY : GREATER THAN AIR
EVAPORATION RATE :SLOWER THAN N-BUTYL ACETATE
SOLUBILITY : SOLUBLE IN HYDROCARBON SOLVENTS, INSOLUBLE IN WATER
: SOLUBLE IN HYDROCARBON SOLVENTS, INSOLUBLE IN WATER
pH : NOT APPLICABLE : NOT APPLICABLE
FLASH POINT, oC (COC) : 170 MINIMUM
AUTI-IGNITION TEMPERATURE : DATA NOT AVAILABLE
PARTITION COEFFICIENT n-octanol/water : DATA NOT AVAILABLE
10. STABILITY AND REACTIVITY
STABILITY (THERMAL, LIGHT, ETC) : Stable
CONDITIONS TO AVOID :
Keep away from heat source, open flames and other sources of ignition
INCOMPATIBLE MATERIALS :
Avoid contact with strong oxidants such as liquid chlorine and concentrated oxygen.
HAZARDOUS DECOMPOSITION PRODUCTS :
Product does not decompose at ambient temperature.
11. TOXICOLOGICAL INFORMATION
EFFECTS OF OVER EXPOSURE :
INHALATION :
Negligible hazard at ambient/normal handling temperatures.
Elevated temperatures or mechanical action may form vapours, mists, or fumes which may be irritating to
the eyes, nose, throat, and lungs.
Avoid breathing vapours, mists, or fumes.
SKIN CONTACT :
Low order of acute toxicity.
Prolonged or repeated contact may lead to mild skin irritation,
EYE CONTACT :
Slightly irritating, but does not injure eye tissue.
INGESTION :
Low order of acute/systemic toxicity.
CHRONIC :
Contains lubricating oil base stocks. Base oils of similar composition and refining history have exhibited
no carcinogenic activity in laboratory animals.
TOXICITY DATA :
ACUTE :
No test data are available for this product. The potential health hazards were therefore derived from what is
known of the toxicity of base oils in general. The general effects of base oils of this type are well known
and are described in numerous publications including CONCAWE Report 5/87 "Health Aspects of
Lubricants".
CHRONIC :
Although there is no specific test data on the oil components, the base oils would not be expected to exhibit
carcinogenic potential based upon what is known of the toxicity of base oils in general.
12. ECOLOGICAL INFORMATION
In the absence of specific environmental data for this product, this assessment is based on information for
general hydrocarbon components found in lubricant mineral oils. Lubricant mineral oils, immediately
following a release into the environment, will remain largely on the soil surface, and in water, will remain
largely on the water surface. Based on chemical/physical information from the literature for this product
category, no harmful effects to terrestrial or aquatic habitats would be expected. This product is expected
to be resistant to biodegradation and to persist in the environment.
13. DISPOSAL CONSIDERATIONS
Collect and dispose of waste product at an authorised facility, in conformance with national and local
regulations, and in accordance with EEC Directives on the disposal of waste oil.
14. TRANSPORT INFORMATION
USUAL SHIPPING CONTAINERS : Rail cars, tank trucks, drums.
TRANSPORT TEMPERATURE, oC : Ambient to max.60 C
15. REGULATORY INFORMATION
EC DANGEROUS SUBSTANCES/PREPARATIONS CLASSIFICATION :
Not Regulated
Refer to national legislation implementing the EC Directive 91/155/EC.
16. OTHER INFORMATION
PRODUCT TYPE / USES :
Lubricating oil for lubrication of refrigeration compressors.
SOURCE OF KEY DATA :
The recommendations presented in this Material Safety Data Sheet were compiled from actual test data
(when available), comparison with similar products, component information from suppliers and from
recognised codes of goods practice.
The information and recommendations contained herein, to the best of knowledge of Hindustan Petroleum
Corporation Limited are brief, accurate and reliable as of the date issued, but are offered without guarantee
or warranty. They relate to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Conditions of use of the material are under the
control of the user; therefore, it is the user's responsibility to satisfy himself as to the suitability and
completeness of such information for his particular use.
