Gray Urethane Mil-Prf-85285f Amdt 1, Type I, Class H, Part A 31115apx-T1 SDS 5-27-2025
Gray Urethane Mil-Prf-85285f Amdt 1, Type I, Class H, Part A 31115apx-T1 SDS 5-27-2025
1. Identification
Product Information:
31115APX-T1
Product Name: 26307 GRAY URETHANE, MIL-PRF-85285F AMDT 1,TYPE I,CLASS H,PART A
2. Hazards Identification
EMERGENCY OVERVIEW: No hazards to be specially mentioned.
GHS Classification
Acute Tox. 4 Inhalation, Carc. 2, Eye Irrit. 2A, Flam. Liq. 2, STOT SE 3 NE
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
25.7% of the mixture consists of ingredients of unknown acute toxicity
GHS HAZARD STATEMENTS
Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Eye Irritation, category 2A H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Carcinogenicity, category 2 H351 Suspected of causing cancer.
GHS LABEL PRECAUTIONARY STATEMENTS
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash exposed skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with soap
and water [or shower].
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
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P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P317 If eye irritation persists: Get medical help.
P370+P378 In case of fire: Use CO2, dry chemical, or foam to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store in accordance with local regulations.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
GHS SDS PRECAUTIONARY STATEMENTS
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
METHYL ACETATE 79-20-9 25-50 GHS02-GHS07 H225-319-336
METHYL AMYL KETONE 110-43-0 10-25 GHS02-GHS07 H226-302+H332
POLYCAPROLACTONE TRIOL POLYESTER RESIN 37625-56-2 10-25 No Information No Information
TITANIUM DIOXIDE 13463-67-7 10-25 GHS08 H351
SYNTHETIC AMORPHOUS SILICA (PRECIPITATED) 112926-00-8 2.5-10 No Information No Information
ACETYLACETONE 123-54-6 2.5-10 GHS02-GHS06 H226-302-311
METHYL ETHYL KETONE 78-93-3 1.0-2.5 GHS02-GHS07 H225-319-332-336
BUTYL ACETATE 123-86-4 1.0-2.5 GHS02-GHS07 H226-336
XYLENE(PURE) 1330-20-7 0.1-1.0 GHS02-GHS07 H226-315
CARBON BLACK 1333-86-4 0.1-1.0 GHS07 H332
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - GENERAL ADVICE: Show this safety data sheet to the doctor in attendance. Call 911 or emergency medical service.
Do not delay care and transport of a seriously injured person. Effects should disappear after individual has been exposed to fresh air
for approximately 10 minutes. Remove and isolate contaminated clothing and shoes. Consult a physician. Do not breathe vapors,
mist or gas. Do not breathe dust. Move out of dangerous area. Use personal protective equipment. Remove all sources of ignition.
Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of contamination. See section 8 for more
information. Ensure adequate ventilation.
FIRST AID - INHALATION: Apply artificial respiration if victim is not breathing. Move victim to fresh air. Keep victim warm and quiet.
If unconscious, place in recovery position and seek medical advice. Artificial respiration and/or oxygen may be necessary.
Administer oxygen if breathing is difficult. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Get
medical attention immediately if symptoms occur.
FIRST AID - INGESTION: Rinse mouth with water. Consult a physician if necessary. Do NOT induce vomiting. Rinse mouth. Never
give anything by mouth to an unconscious person. Do not induce vomiting without medical advice. Call a poison control center or
doctor for treatment advice.
FIRST AID - SKIN CONTACT: Take off contaminated clothing and shoes immediately. In the case of skin irritation or allergic
reactions see a physician. For minor skin contact, avoid spreading material on unaffected skin. In case of contact with substance,
keep exposed skin areas immersed in water or covered with wet bandages until medical attention is received. Remove material from
skin immediately. Do not remove clothing if adhering to skin. Wash contaminated clothing before reuse.
FIRST AID - EYE CONTACT: Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists.
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. May produce an
allergic reaction. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Do not
rub affected area. Get medical attention immediately if symptoms occur.
NOTES TO PHYSICIAN: Treat symptomatically. Keep victim warm and quiet. Symptoms may be delayed.
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5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable liquid and vapor. The product causes irritation of eyes, skin
and mucous membranes. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas
(sewers, basements, tanks). Runoff may pollute waterways. Runoff to sewer may create fire or explosion hazard. Vapor explosion
hazard indoors, outdoors or in sewers. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and
flash back. Will be easily ignited by heat, sparks or flames. Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations. Cool drums with water spray. Fire will produce dense black smoke containing
hazardous combustion products (see section 10). Incomplete combustion and thermolysis may produce gases of varying toxicity
such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled in
confined spaces or at high concentration. Container may explode in heat of fire.
SPECIAL FIREFIGHTING PROCEDURES: No Information
EXTINGUISHING MEDIA: Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
HANDLING: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use
spark-proof tools and explosion-proof equipment. Wear personal protective equipment. Remove and wash contaminated clothing
before re-use. Take precautionary measures against static discharges. Do not breathe vapors or spray mist. Take necessary action
to avoid static electricity discharge (which might cause ignition of organic vapors). In case of insufficient ventilation, wear suitable
respiratory equipment. Ensure adequate ventilation. To avoid ignition of vapors by static electricity discharge, all metal parts of the
equipment must be grounded. Wash thoroughly after handling. Never pierce, drill, grind, cut, saw or weld any empty container.
Provide sufficient air exchange and/or exhaust in work rooms. Vapors may form explosive mixtures with air. Prevent the creation of
flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the occupational exposure limits.
Keep product and empty container away from heat and sources of ignition. Electrical equipment should be protected to the
appropriate standard. Keep container closed when not in use. Ground and bond containers when transferring material.
STORAGE: Keep in properly labeled containers. Keep container tightly closed. Keep out of the reach of children. Store in
accordance with the particular national regulations. Store in accordance with local regulations. Store in a well-ventilated place. Keep
cool. Ensure all equipment is electrically grounded before beginning transfer operations. Use spark-proof tools and explosion-proof
equipment. Keep locked up or in an area accessible only to qualified or authorized persons. To avoid ignition of vapors by static
electricity discharge, all metal parts of the equipment must be grounded. Store between 41 and 77 °F (5 - 25° C) in a dry, well
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ventilated place away from sources of heat, ignition and direct sunlight. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
Personal Protection
RESPIRATORY PROTECTION: If exposure limits are exceeded or irritation is experienced, ventilation and evacuation
may be required. In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations
above the exposure limit they must use appropriate certified respirators.
SKIN PROTECTION: The selected protective gloves have to satisfy the specifications of EU Regulation (EU) 2016/425
and the standard EN 374 derived from it. Solvent-resistant gloves. Protective gloves. Please observe the instructions
regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Follow
the skin protection plan. Wear protective gloves/ protective clothing. Wear suitable protective clothing.
EYE PROTECTION: Tightly fitting safety goggles. If splashes are likely to occur, wear:Face-shield.
HYGIENIC PRACTICES: Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing
and gloves, including the inside, before re-use. Handle in accordance with good industrial hygiene and safety practice.
Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin, eyes and clothing.
Wash hands before breaks and at the end of workday. Regular cleaning of equipment, work area and clothing is
recommended.
ENGINEERING CONTROLS: Ensure that eyewash stations and safety showers are close to the workstation location.
Ensure adequate ventilation. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Where reasonably
practicable this should be achieved by the use of local exhaust ventilation.
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Practical Experiences
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Legend:
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Confirmed Animal Carcinogen
A4 - Not Classifiable as a Human Carcinogen
IARC (International Agency for Research on Cancer)
Group 2B - Possibly carcinogenic to humans
Group 3 - Unclassifiable as to carcinogenicity in humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
N.I. = No Information
Ecotoxicity
Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other
aquatic invertebrates
LC50 96 h Pimephales
METHYL ACETATE EC50 72 h Desmodesmus promelas 295 - 348 mg/L, EC50 48 h Daphnia magna
79-20-9 subspicatus >120 mg/L LC50 96 h Brachydanio rerio 1026.7 mg/L
250 - 350 mg/L
METHYL AMYL KETONE LC50 96 h Pimephales
No Information No Information
110-43-0 promelas 126 - 137 mg/L
LC50 96 h Pimephales
promelas 98.3 - 110 mg/L,
ACETYLACETONE LC50 96 h Lepomis EC50 48 h Daphnia magna
No Information
123-54-6 macrochirus 50.3 - 71.8 mg/L, 34.4 mg/L
LC50 96 h Oncorhynchus
mykiss 64.1 - 80.1 mg/L
EC50 48 h Daphnia magna
>520 mg/L, EC50 48 h
METHYL ETHYL KETONE LC50 96 h Pimephales
No Information Daphnia magna 5091 mg/L,
78-93-3 promelas 3130 - 3320 mg/L
EC50 48 h Daphnia magna
4025 - 6440 mg/L
LC50 96 h Lepomis
BUTYL ACETATE EC50 72 h Desmodesmus macrochirus 100 mg/L, LC50
No Information
123-86-4 subspicatus 674.7 mg/L 96 h Pimephales promelas 17 -
19 mg/L
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LC50 96 h Pimephales
promelas 13.4 mg/L, LC50 96
h Oncorhynchus mykiss 2.661
- 4.093 mg/L, LC50 96 h
Oncorhynchus mykiss 13.5 -
17.3 mg/L, LC50 96 h Lepomis
macrochirus 13.1 - 16.5 mg/L,
LC50 96 h Lepomis EC50 48 h water flea 3.82 mg/
XYLENE(PURE)
No Information macrochirus 19 mg/L, LC50 96 L, LC50 48 h Gammarus
1330-20-7
h Lepomis macrochirus 7.711 - lacustris 0.6 mg/L
9.591 mg/L, LC50 96 h
Pimephales promelas 23.53 -
29.97 mg/L, LC50 96 h
Cyprinus carpio 780 mg/L,
LC50 96 h Cyprinus carpio
>780 mg/L, LC50 96 h Poecilia
reticulata 30.26 - 40.
Product
DISPOSAL INFORMATION: Disposal should be in accordance with applicable regional, national and local laws and regulations.
Dispose of contents/container to an approved waste disposal plant.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain spilled material. Transfer to secure containers.
Where necessary, collect using absorbent media. In the event of an uncontrolled release of this material, the user should determine if
the release is reportable under applicable laws and regulations. Water spray may reduce vapor; but may not prevent ignition in
closed spaces. Dispose of material in accordance with all federal, state and local regulations.
CONTAMINATED PACKAGING: Do not re-use empty containers.
This product contains one or more substances that are listed with the State of California as a hazardous waste:
Chemical Name CAS-No.
METHYL ACETATE 79-20-9
METHYL AMYL KETONE 110-43-0
METHYL ETHYL KETONE 78-93-3
BUTYL ACETATE 123-86-4
XYLENE(PURE) 1330-20-7
CARBON BLACK 1333-86-4
DOT
UN No UN1263
Proper Shipping Name: Paint
Hazard Class: 3
Hazard Subclass: N/A
Packing Group: II
IMDG
UN No UN1263
IMDG/GGVSee Class: 3
EmS-No: F-E, S-E
Packing Group: II
Proper Shipping Name: Paint
Primary Shipping Hazard: No Information
Marine Pollutant: Not Applicable
Shipping Hazard(Marine Pollutant): No Information
IATA
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UN No UN1263
ICAO/IATA Class: 3
Packing Group: II
Proper Shipping Name: Paint
Primary Shipping Hazard: No Information
MEX
UN No UN1263
Proper Shipping Name: Paint
Hazard Class: 3
Hazard Subclass: N/A
Packing Group: II
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TITANIUM DIOXIDE X X X X
SYNTHETIC AMORPHOUS
X X X X
SILICA (PRECIPITATED)
ACETYLACETONE X X X X
METHYL ETHYL KETONE X X X X X
BUTYL ACETATE X X X X
XYLENE(PURE) X X X X X
CARBON BLACK X X X X X
Hexanoic acid, 2-ethyl-, tin(2+)
X
salt
ETHYLBENZENE X X X X
ISOBUTYL ALCOHOL X X X
CRYSTALLINE SILICA
X X X
(QUARTZ)
CUMENE X X X X
TOLUENE X X X X
WARNING
The following ingredients present in the product are known to the state of California to cause Cancer:
Chemical Name CAS-No.
TITANIUM DIOXIDE 13463-67-7
CARBON BLACK 1333-86-4
WARNING
The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
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Legend:
TSCA United States Toxic Substances Control Act Section 8(b) Inventory
DSL Canadian Domestic Substances List
DSL/NDSL Canadian Domestic Substances List/Canadian Non-Domestic Substances List
EINECS/ELINCS European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS Japan Existing and New Chemical Substances
IECSC China Inventory of Existing Chemical Substances
KECL Korean Existing and Evaluated Chemical Substances
PICCS Philippines Inventory of Chemicals and Chemical Substances
AICS Australian Inventory of Chemical Substances
NZIoC New Zealand Inventory of Chemicals
TCSI Taiwan Chemical Substance Inventory
NFPA Rating:
HMIS Ratings:
Health: 2* Flammability: 3 Reactivity: 0 Personal Protection: X
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
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The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific
properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the
handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and
recommendations are not followed.
ObjectId: 180725 91166 180727
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