Analytical chemistry 18/1/2022 3rd revision

1) Th4+ forms a complex with pyrocatechol violet has a

a) Blue b) lemon yellow c) red d) orange colour

2) EDTA molecule has:

a) Six b) five c) four d) two donation sites

3) Murexide forms with copper ion a complex of colour:

a) Red b) yellow c) orange d) green

4) The metal indicator complex must be…....than the metal -EDTA complex

a) Equal b) weaker c) stronger d) faster

5) An acidic soln of xylenol orange indicator has a colour

a) red b) lemon yellow c) blue d) orange

6) The metal complex of EBT Indicator is:

a) blue b) green c) wine red d) orange

7) At pH=12 the predominate species of EDTA is:

a) H2y-2 b) y-4 c) H4Y d) HY-3

8)50 ml of 0.03 M of Ni+2 mixed with 50 ml 0.05 EDTA, what is the conc. Ni2+ if the mixture is
buffered at pH 3 : (kabs=4.2x1018, α4=2.5 x10-11)

a) 0.015 b) 0.01 c) 1.43x10-8 d) 1.2 x 10-5

9)......... and ………..are and examples for damasking agent:

a) Acetone and formaldehyde b) KCN and NaCN c) KI and NH4F

10) 50 ml of 0.01 Ca+2 buffered at pH= 10 is titrated with EDTA, calculate pca at end point (kabs
for Cay-2 =5x1010, α4 at pH 10=0.35)

a) 9.28 b) 6.28 c) 2.28 d) 1128

11) 6.3 gram H2C2O4.2H2O was dissolved in 500 ml water, number of oxygen atoms present in
this soln is:

a) 6.023x1023 b) 3.612x1023 c) 6.023x1022 d) 4.00 atoms

12)Calculate the pH if 5 ml (1M)HCI is added to 100 ml buffer soln of (0.28M) HF and (0.6M)
NaF: (pka= 3.15)

a) 3.08 b) 3.37 c) 7 d) 6.3

13).......group acts as a chromophore and auxochrome

a)-C=O b)-CI c) –OH d) -NH2

14) What is the (H+) ion conc. of the blood if its pH 6.8:

a) 1.58 x10-7 b) 1.1x10-10 c) 1.00 d) 1.12 x10-3

15) 0.1 gram of Na2CO3, dissolved in 100 ml water gives

a)100 b) 10 c) 1000 d) 1 ppm

16) For Zn electrode containing (1x10-2 M) ZnSO4 soln., Zn(s) = Zn2++ 2e E0 = -0.77 V. The
electrode potential (E) is

a)-1075 b) -0.711 c) +0.519 d) +0.711 volt

17) 0.227 of polybasic acid (Mw=126) requires 45 ml of (0.008 N) NaOH for the end point
titration, the acid is:

a) Monobasic b) dibasic c) tribasic acid

18) Calculate pH of an acid 0.002 M with 2.3 % dissociate (ka=4.8x10-5)

a) 6.54 b) 4.33 c) 9.54 d) 2.52

19) Sulpurous acid has k1 = 1.74x10-2, k2 =6.17x10-4 so the acid is titrated as

a) Monobasic b) dibasic c) poly basic acid

20) The best indicator for titrating HCl and NH4OH is

a) Litmus b) ph.ph c) Me.O d) phenol red

21) All cations acts as

a) Lewis bases b) Lewis acids c) Bronsted acids d) Bronsted bases

22) pOH of 0.1 M HCl is

a) 13.1 b) 1.13 c) 14.0 d) 0.14

23) Which of the solutions should have the highest buffer capacity?

a) 0.02M H2PO4- + 0.02 M HPO4-2 b) 0.1 M H2PO4-

c) 0.002M H2PO4- + 0.001 M HPO4-2 d) 0.6 M HNO3

24) 2.00 cm length wire has a length by nm:

a) 2x10-7 b) 2 x1010 c) 2x107 d) 2x10-12 nm

25) We can get the highest buffer capacity if the salt to acid ratio is

a) 2:1 b)1:1 c)1:2

26) Equivalent weight of sodium azide (NaN3) is equal to

a) 65 b) 21.7 c) 32.5

27) HCO3- is an example of:

a) Conjugate acid b) conjugate base c) amphoteric ion

28) 200 ml water are added to 100 ml HCl the ratio of dilution is

a) 1:1 b) 1:2 c) 1:3

29) Which compound are used as indicator in Fagan’s method

a) Axin b) murexide c) ph.ph d) flurosine

30) Which type of medium solution is used in Volhard Method?

a) Strong acid b) Strong base d) A and B

31) End point colour in Mohr’s method is

a) Red b) white c) Yellow d) Black ppt

32) 4.00 gram NaOH was dissolved in 500 ml water, so the number of moles present in that soln
is

a) 6.023x1023 b) 1.00 c) 0.10 d) 0.2 moles

33) If the solubility product of AgCl is ksp =1.82x10-10, so the molar conc. of Ag+ ion is

a) 1.34x10-5 b) 1.1x 10-10 c) 1x 10-4 d) 0.1

34) For the reaction MnO4- +8H++ …. = Mn2+ + 4 H2O what are the number of electrons must be
written to balance the equation;

a) 3 b) 6 c) 2 d) 5 electron

35) pH of a buffer soln. containing equimolar conc of NH4OH and NH4Cl equal

a) pkb b) 5.7 c) 9.7 d) 6.7

Tor F

1) (CH2F)3N is a Lewis base.

2) Fajans method is carried out in dark.

3) In supersaturated solution, Ksp > Ip

4) KMnO4 is a primary standard substance.

5) Dilution of buffer solution changes its buffer capacity.

6) Phosphoric acid is titrated as a monobasic acid with NaOH

7) Approximately no common indicator is used to detect the end point in W A with WB titration.

8) Diphenyl amine indicator is a type of external indicators.

9) Calomel electrode has a zero standard electrode potential

10) Formal solution containing 1 mole of substance dissolved in litre of soln.

11) Approximately all indicators can be used to detect the end point in S A with SB, titration

12) I2 is insoluble in water.

13) A small piece of sand of 0.01 g is equal to 107nanogram

14) Poor solvents make leveling effect for different acids strength

15) Boric acid (ka=1.1x10-10) is more stronger than formic acid(ka=1.8 x10-4)
Analytical chemistry 18/1/2022 3rd revision

Matching

1. Iodometry A) substance which accept electron

2. Luminol B) substance which loss electrons

3. Lewis acid C) it's pH value is not affect by heating

4. Alkaline buffer D) it's pH value increases by heating

5. Acidic buffer E) specific indicator for l, titrations

6. Oxidant F) accepts a pair of electrons

7. Reductant G)involves reduction process

8. Starch H) gain electron process

9. Reduction I) involves oxidation process

10. Iodimetry J) is a fluorescence reagent for haem Fe

Matching

1) Reduction process A) is the indicator with Mohr’s methods

2) Potassium permanganate B) is equal to conc. at dilute solutions

3) Potassium chromate C) is the number of electrons lost or gained

4) Litmus soln. D) Can be used as a self-indicator

5) Ferric alum E) is a weak organic acid indicator

6) Oxidation process F) is a fluorescence indicator

7) Oxidation numbers G) is a proton donor

8) Rhodamine 6B H) is a gain of electrons

9) Activity I) is the loss of electrons.

10) Arrhenius acid J) is the indicator with Volhard method