AAVISHKAR INSTITUTE

Chapter: 5 Std 11 : Chemistry Date : 10/10/24

Marks: 65 E11C5 Time: 2hour
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [62]

1. What will be the change in enthalpy (DH) for endothermic reaction ?

(A) Zero (B) –ve (C) +ve (D) (B) and (C) both
2. Which of the following has maximum neutralization enthalpy ?
(A) NH4OH and CH3COOH (B) NH4OH and HCl
(C) NaOH and CH3COOH (D) NaOH and HCl

3. Combustion enthalpy of carbon, Hydrogen and Methane at 25°C temperature are –395.5 kJ mol–1, –284.8
kJ mol–1 and –890.4 kJ mol–1 respectively. Calculate the standard enthalpy of formation of methane for the
same temperature.
(A) 890.4 kJ mol–1 (B) –298.8 kJ mol–1 (C) –74.7 kJ mol–1 (D) –107.7 kJ mol–1
4. Change in entropy for one mole water from liquid from to vapour at 373 K is .......... Joule/Kelvin.
(DHvap = 2.257 kJ/gm)

5.
(A) 105.9 (B) 107.9
....... is not an extensive property. EL (C) 108.9 (D) 109.9
AT
mass
(A) mass (B) volume (C) (D) Enthalpy
volume
6. For the reaction :
TP

C3H8(g) + 5O2(g) ® 3CO2(g) + 4H2O(l) DH – DU = ..........

(A) RT (B) –3RT (C) 3RT (D) –RT
7. .......... has given DG = DH – TDS.
GI

(A) Faraday (B) Kirchof (C) Einstein (D) Gibs helm holtz
8. Change in entropy during adsorption of gas on the solid substance is ...........
AN

(A) increasing (B) decreasing (C) constant (D) infinite

9. When 1 mole Zn powder is reacted with 1 mole sulphuric acid in bomb calourimeter (closed isolated
system), ...........
(A) DU < 0, w = 0 (B) DU > 0, w = 0 (C) DU < 0, w < 0 (D) DU > 0, w > 0
10. If K < 1, DG° = ..........
(A) +ve (B) –ve (C) Zero (D) 1
11. Change in enthalpy during neutralization reaction of one mole HCl with dilute KOH at 298 K is .......... kJ.
(A) 68 (B) 56 (C) 50 (D) 65
12. Which of the following statement is correct for the spontaneous reaction ?
(A) Entropy of the system is always increased.
(B) Free energy of the system is always increased.
(C) Total entropy change is always negative.
(D) Total entropy change is always positive.

13. 723 kJ mol–1 heat is released when 1 mole methanol combustions in present of O2. What amount of heat is
enlisted of one mole of O2 is used ?
(A) 241 kJ (B) 723 kJ (C) 482 kJ (D) 924 kJ

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14. Hess’s law of integrate enthalpy is related to ...........
(A) change in enthalpy of reaction. (B) rate of reaction.
(C) equilibriums constant. (D) effect of pressure an the volume of gas.
15. For a reaction DH = 3 kJ and DS =10 J/Kelvin at what temperature the reaction will be spontaneous ?
(A) 300 K (B) 200 K (C) 273 K (D) 373 K
16. Which one of the following is related to thermodynamic equilibrium ?
(A) All of above (B) Thermal equilibrium
(C) equilibriums of pressure (D) Chemical equilibrium
17. Which one of the following is the isobaric process ?
(A) DH = 0 (B) DE = 0 (C) DP = 0 (D) DQ = 0
18. For the spontaneous reaction at each temperature ...........
(A) DG –ve; DH +ve and DS +ve (B) DG +ve; DH –ve and DS +ve
(C) DG –ve; DH –ve and DS –ve (D) DG –ve; DH –ve and DS +ve
19. Which one of the following has maximum entropy ?
(A) Hg (B) Diamond (C) N2(l) (D) H2(g)

20. An exothermic reaction is spontaneous reaction ............ is correct from the following.
(A) DG > 0 (B) DS < 0 (C) DS > 0 (D) DH < 0
21.
(A) zero (B) +ve EL
What will be the value of DG for the ice at 8oC temperature ?
(C) –ve (D) one
AT
22. Ice cube is melting at the room temperature this reaction belongs to which law of ?
(A) Zeroth Law (B) Third Law (C) First Law (D) Second Law
23. Combustion enthalpies of methane and ethane are –210 K cal mol–1 and –368 K cal mol–1. Combustion
TP

enthalpy of Decane is ......... .

(A) –158 K cal (B) –1632 K cal
(C) –1700 K cal (D) given mettre is not complete
GI

24. For the gaseous reaction, at 300 K temperature, value of DH – DU = –4.98 kJ., Then Dn(g) = ..........
(A) 1 (B) 2 (C) –2 (D) 0
AN

25. For the reaction 298 K A(g) + B(g) ® C(g) at 298 K, DU = –5 cal and DS = –10 cal K–1. DG = ........... cal.
(A) 2612 (B) 2379 (C) 261.2 (D) –2612
26. According to the first law of thermodynamics, which of the following shows change in state function ?
(A) qrev (B) qrev – wrev (C) qrev / wrev (D) qrev + wrev

27. Standard entropies of x 2 , y 2 and xy 3 are 60, 40 and 50 J / K mol –1 respectively for the reaction
1 3
x 2 + y 2 ® xy 3 ; DH = –30 kJ to be at equilibrium the temperature should be.
2 2
(A) 500 K (B) 750 K (C) 1000 K (D) 1250 K
28. When water freezed to ice, entropy .......... .
(A) Increases (B) Decreases (C) Constant (D) Zero
29. Standard enthalpy of formation is zero for ........... from following.
(A) F2(g) (B) F(g) (C) HF(aq) (D) F–(aq)

30. Thermodynamically stable form of C is .........

(A) Graphite (B) Diamond (C) Fulerenl (D) Cock
31. Work done is .......... when 3 moles of ideal gas is expand in vacuum.
(A) +ve (B) –ve (C) zero (D) can not cecide

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32. .......... is not an extensive property.
(A) Molar conductivily (B) Electro motive force (C) Resistance (D) Heat capacity
33. Calculate the work, when 1 mole ideal gas defuse to 1 atm from 10 atm at 300 K temperature.
(A) 5744.1 J (B) 6257.2 J (C) 4938.8 J (D) 4138.8 J
34. At 300 K one mole ideal gas is expand freely to 100 liter from 10 liter. If DU = 0, then DH = ..........
(A) 20 kJ (B) 200 kJ (C) –200 kJ (D) 0
35. Dissociation enthalpy of biatomic molecules XY, X2 and Y2 are too in the ratio of 1:1:0.5 the value. Enthalpy
of formation of XY. Df H = –200 kJ mol–1. Final the dissociation enthalpy of X2 ?
(A) 200 kJ mol–1 (B) 300 kJ mol–1 (C) 400 kJ mol–1 (D) 800 kJ mol–1
36. Which of the following is not correct ?
DGsystem Vf DH o – TDSo o/RT
(A) = –T (B) wrev. = –nRT ln (C) ln K = (D) K = e–DG
DStotal Vi RT
37. Standard enthalpy of formation of H2(g) , Cl2(g) and HCl(g) are 218, 121.68 and –92.31 kJ/mole respectively.
1 1
Calculate the change in standard enthalpy for the reaction. H 2(g) + Cl(g) ® HCl(g)
2 2
(A) +431.99 kJ (B) –262.14 kJ (C) –431.99 kJ (D) +247.37 kJ
38. .......... is done, when 50 gm of Fe is reacted with HCl in open vessel at 25oC temperature.
(A) zero (B) –2.2 kJ (C) 2.2 kJ (D) 0.22 kJ

39. EL
Same volume of two monoatomic gases A and B is mixed at same temperature. .......... is
Cp
Cv
= ..........
AT
(A) 0.83 (B) 1.67 (C) 3.3 (D) 3.30
40. Which of the following reaction is incorrect according to thermodynamics ?
(A) DG° = – nFE° (B) DH = DE + PDV (C) K = e–DG/RT (D) DG = DH + TDS
TP

41. What will be value of DG° for ice at 298 K temperature ?

(A) –ve (B) 0 (C) +ve (D) (A) & (B)
GI

42. Which of the following option is correct for the given equation ?
4NH3(g) + 5O2(g) ® 4NO(g) + 6H2O(g)
(A) DH = DU (B) DH < DU (C) DH > DU (D) DH ¹ DU
AN

43. If the change in entropy at 353 K is 0.087 kJ mol–1 for benzene. Then calculate the heat of
vapourisation.
(A) – 6.96 kJ mol–1 (B) 6.96 kJ mol–1 (C) – 30.711 kJ mol–1 (D) 30.711 kJ mol–1
44. The change in free energy during working of pencil cell is –1372.58 cal. Calculate the equilibrium
constant of the cell under standard condition (R = 2 cal mol–1 K–1)
(A) 1.00 ´ 105 (B) 1.00 ´ 102 (C) 1.00 ´ 1010 (D) 1.00 ´ 101
45. For which reaction DS can be maximum if it is occuring at constant volume ?
(A) N2(g) + O2(g) ® 2NO(g) (B) CaCO3(s) ® CaO(s) + CO2(g)
1
(C) C(s) + O2(g) ® CO2(g) (D) Mg(s) + O ® MgO(s)
2 2(g)
46. There is change in volume of an ideal gas when pressure is changed at constant temperature. The
change in free energy associated with this can be calculated by which of the following equation ?
P2 P2
(A) DG = –RT ln (B) DG = –2.303 RT log P
P1 1

V2 P2
(C) DG = nRT ln V (D) DG = nRT ln
1 P1

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47. A system receives 100 Joule heat and does work of 50 Joule. Calculate the change in the internal
energy ?
(A) –150 Joule (B) 50 Joule (C) –50 Joule (D) 150 Joule
48. In which phenomenon Entropy decreases ?
(A) Melting of ice (B) Crystallisation of salt (C) Evaporation of liquid (D) Diffusion
49. If substance is completely pure crystalline at 273 K, which of the following state function will be zero
at 273 K ?
(A) Free energy (B) Entropy (C) Enthalpy (D) All the given
50. Which of the following property is extensive property ?
(A) Boiling point (B) Elevation in boiling point
(C) Density (D) Fluidity

51. For a reaction value of Kc is 7.105 ´ 10–5, what will be the change in free energy ?
(A) DG > 0 (B) DG < 0 (C) DG = 0 (D) DG = 1
52. Joule K–1 gm–1 is the unit of....
(A) Entropy (B) Enthalpy
(C) Specific heat capacity (D) All the given
53. For the given equation 4NH 3(g) + 502(g) ƒ 4NO(g) + 6H2O(l) Select the correct option for change in
Enthalpy.
(A) DU + RT (B) DU + 5RT EL
(C) DU – RT (D) DU – 5RT
AT
54. By mixing aqueous solutions of silver nitrate and ammonium chloride in a test tube, white precipi-
tates are formed. In this process, test tube is ...... .
(A) universe (B) surrounding
TP

(C) borderline of the system (D) system

55. What will be the value of K and DG° for the process of transformation of ice into water at room
temperature ?
GI

(A) K = 1, DG° zero (B) K < 1, DG° positive (C) K > 1, DG° positive (D) K > 1,DG° negative
56. Which law of thermodynamics gives information about exact entropy of a substance ?
AN

(A) Zeroth Law (B) Second Law (C) Third Law (D) First Law
57. The level of thermal energy in a substance is known as ...... .
(A) Entropy (B) Temperature (C) Heat energy (D) Quantity of Heat
58. Which of the following statements is correct for absolute entropy of a substance ?
(A) It is shown as S°.
(B) It is the entropy of 1 mole of substance at constant temperature and standard state.
(C) Its unit is Joule Kelvin Mole–1.
(D) It is the entropy of 1 mole of substance.
59. Water always flows from higher level to lower level on its own. Which of the following statement is
correct for this phenomena ?
(A) Free energy increases (B) Entropy decreases
(C) Free energy decreases (D) Entropy increases

60. If the values of Df H° for H2O2 and H2O are –188 and –286 kJ mol–1, then the value of DH° = ........
kJ for the following reaction – 2H2O2(l) ® 2H2O(l) + O2(g)
(A) – 494 (B) – 196 (C) – 98 (D) +196
61. What will be the work done by the system when one mole of an ideal gas expands in vacuum ?
(A) Zero (B) 1 Joule (C) 2 Joule (D) 3 Joule
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 What will be the work done by the system when one mole of an ideal gas expands in vacuum ?
(A) Zero (B) 1 Joule (C) 2 Joule (D) 3 Joule
62. Heat of vaporization of benzene is 7350 cal K–1 mol–1. Calculate the change in entropy for converting
1 mole gaseous benzene to liquid benzene at 77 °C.
(A) 21 calorie K–1 mol–1 (B) –21 calorie K–1 mol–1 (C) –21 calorie K–1 (D) 21 calorie K–1

EL
AT
TP
GI
AN

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 AAVISHKAR INSTITUTE
Chapter: 5 Std 11 : Chemistry Date : 10/10/24
Marks: 65 E11C5 Time: 2hour

Section [ A ] : 1 Marks Questions

No Ans Chap Sec Que Universal_QueId

1. C Chap 5 (23-24) S6 1 QP23P11B1112_P1C5S6Q1
2. D Chap 5 (23-24) S6 2 QP23P11B1112_P1C5S6Q2
3. C Chap 5 (23-24) S6 3 QP23P11B1112_P1C5S6Q3
4. C Chap 5 (23-24) S6 4 QP23P11B1112_P1C5S6Q4
5. C Chap 5 (23-24) S6 5 QP23P11B1112_P1C5S6Q5
6. B Chap 5 (23-24) S6 6 QP23P11B1112_P1C5S6Q6
7. D Chap 5 (23-24) S6 7 QP23P11B1112_P1C5S6Q7
8. B Chap 5 (23-24) S6 8 QP23P11B1112_P1C5S6Q8
9. A Chap 5 (23-24) S6 9 QP23P11B1112_P1C5S6Q9
10. A Chap 5 (23-24) S6 10 QP23P11B1112_P1C5S6Q10
11. B Chap 5 (23-24) S6 11 QP23P11B1112_P1C5S6Q11
12. D Chap 5 (23-24) S6 12 QP23P11B1112_P1C5S6Q12
13. C Chap 5 (23-24) S6 13 QP23P11B1112_P1C5S6Q13
14. A Chap 5 (23-24) S6 14 QP23P11B1112_P1C5S6Q14
15. D Chap 5 (23-24) S6 15 QP23P11B1112_P1C5S6Q15
16. B Chap 5 (23-24) S6 16 QP23P11B1112_P1C5S6Q16
17. C Chap 5 (23-24) S6 17 QP23P11B1112_P1C5S6Q17
18. D Chap 5 (23-24) S6 18 QP23P11B1112_P1C5S6Q18
19. D Chap 5 (23-24) S6 20 QP23P11B1112_P1C5S6Q20
20. C Chap 5 (23-24) S6 21 QP23P11B1112_P1C5S6Q21
21. C Chap 5 (23-24) S6 22 QP23P11B1112_P1C5S6Q22
22. C Chap 5 (23-24) S6 23 QP23P11B1112_P1C5S6Q23
23. B Chap 5 (23-24) S6 24 QP23P11B1112_P1C5S6Q24
24. C Chap 5 (23-24) S6 25 QP23P11B1112_P1C5S6Q25
25. B Chap 5 (23-24) S6 26 QP23P11B1112_P1C5S6Q26
26. D Chap 5 (23-24) S6 27 QP23P11B1112_P1C5S6Q27
27. B Chap 5 (23-24) S6 28 QP23P11B1112_P1C5S6Q28
28. B Chap 5 (23-24) S6 29 QP23P11B1112_P1C5S6Q29
29. A Chap 5 (23-24) S6 30 QP23P11B1112_P1C5S6Q30
30. A Chap 5 (23-24) S6 31 QP23P11B1112_P1C5S6Q31
31. C Chap 5 (23-24) S6 33 QP23P11B1112_P1C5S6Q33
32. B Chap 5 (23-24) S6 34 QP23P11B1112_P1C5S6Q34

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33. A Chap 5 (23-24) S6 35 QP23P11B1112_P1C5S6Q35
34. D Chap 5 (23-24) S6 36 QP23P11B1112_P1C5S6Q36
35. D Chap 5 (23-24) S6 37 QP23P11B1112_P1C5S6Q37
36. C Chap 5 (23-24) S6 38 QP23P11B1112_P1C5S6Q38
37. B Chap 5 (23-24) S6 39 QP23P11B1112_P1C5S6Q39
38. B Chap 5 (23-24) S6 40 QP23P11B1112_P1C5S6Q40
39. B Chap 5 (23-24) S6 42 QP23P11B1112_P1C5S6Q42
40. D Chap 5 (23-24) S7 1 QP23P11B1112_P1C5S7Q1
41. A Chap 5 (23-24) S7 2 QP23P11B1112_P1C5S7Q2
42. C Chap 5 (23-24) S7 3 QP23P11B1112_P1C5S7Q3
43. D Chap 5 (23-24) S7 4 QP23P11B1112_P1C5S7Q4
44. D Chap 5 (23-24) S7 5 QP23P11B1112_P1C5S7Q5
45. B Chap 5 (23-24) S7 6 QP23P11B1112_P1C5S7Q6
46. D Chap 5 (23-24) S7 7 QP23P11B1112_P1C5S7Q7
47. B Chap 5 (23-24) S7 8 QP23P11B1112_P1C5S7Q8
48. B Chap 5 (23-24) S7 9 QP23P11B1112_P1C5S7Q9
49. B Chap 5 (23-24) S7 10 QP23P11B1112_P1C5S7Q10
50. B Chap 5 (23-24) S7 11 QP23P11B1112_P1C5S7Q11
51. A Chap 5 (23-24) S7 12 QP23P11B1112_P1C5S7Q12
52. C Chap 5 (23-24) S7 13 QP23P11B1112_P1C5S7Q13
53. D Chap 5 (23-24) S7 14 QP23P11B1112_P1C5S7Q14
54. C Chap 5 (23-24) S7 15 QP23P11B1112_P1C5S7Q15
55. D Chap 5 (23-24) S7 16 QP23P11B1112_P1C5S7Q16
56. B Chap 5 (23-24) S7 17 QP23P11B1112_P1C5S7Q17
57. B Chap 5 (23-24) S7 18 QP23P11B1112_P1C5S7Q18
58. B Chap 5 (23-24) S7 19 QP23P11B1112_P1C5S7Q19
59. C Chap 5 (23-24) S7 20 QP23P11B1112_P1C5S7Q20
60. B Chap 5 (23-24) S7 21 QP23P11B1112_P1C5S7Q21
61. A Chap 5 (23-24) S7 22 QP23P11B1112_P1C5S7Q22
62. B Chap 5 (23-24) S7 26 QP23P11B1112_P1C5S7Q26

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