Sec: IJR.

IIT_*COSC(MODEL-A) CAT-04 Date: 18-05-25

Time: 3 Hrs 2018_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 AB 2 BD 3 A 4 ABC 5 BC
6 BC 7 1 8 4 9 9 10 1
11 0 12 2 13 3 14 4 15 B
16 C 17 A 18 B

PHYSICS
19 ABCD 20 AD 21 BD 22 AB 23 ABC

24 AC 25 2 26 3 27 2 28 6
29 0.25 30 21.65 31 0.28 to 32 6 33 C
0.32
34 A 35 D 36 C

CHEMISTRY
37 B 38 ABC 39 ABD 40 AB 41 ABD
1.75 3.33
42 BC 43 TO 44 5 45 3 46 TO
1.77 3.34
0.70 2.30
47 10 48 3 49 TO 50 TO 51 B
0.71 2.50
52 C 53 A 54 C
Narayana IIT Academy 18-05-25_IJR.*CO-SC(A-STAR)_JEE-ADV_CAT-04_KEY&SOL
SOLUTIONS
MATHEMATICS
 r 2  2r  r 2  1 
Tr  sin 1  
1.

 r  r  1 

1 1 1 1  1  1 
Tr  sin 1  1   1  , Tr  sin 1    sin 1  
r    
2
 r 1
2
r  1 r 1 r r
 
  1  1  1 
 S n   sin 1    cos  
2  n 1   n 1
02. Given, 1900  f 1990   2000
1900 f 1990  2000 1900   f 1990    2000 
   ,    
90 90 90  90   90   90 
 f 1990    f 1990  
 21       21, or 22
 90   90 
 f  x 
Given, x  f  x   19    90 
x
 ....... 1
19   90 
1990   f 1990  
1990  f 1990   19    90  
 19   90 
19 104  90  21 1976  1890  86
 1990  f 1990    ,  1990  f 1990   
19 104  90  22 1976  1890  4
 f 1990   1904,1994
03. a f  x   sin  sin 1 x   x,  x   1,1 Which is one – one and onto
2 2
b  f  x   sin 1  sin x   x
 
The range of the function for x   1,1 is   , 
2 2
  
Which is a subset of  1,1
Hence the function is one-one but not onto. Hence not bijective
 x, x  0

 c  f  x    Sgn  x   log  e    Sgn  x   x   x, x  0
x

0, x  0

This function has the range [0, 1] which is a subset of [-1, 1]. Hence the function is into.
Also the function is many one.
 x3 , x  0

 d  f  x   x3 sgn  x    x3 , x  0 Which is many one and into
0, x  0

04. 1  sin x  cos x  2  sin x  cos x   1
11
f  x  is defined if sin 2 x  2 sin x  2
4

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1 1 1
  sin x  1 
2
 sin x  1  or sin x  1  
4 2 2
1 3
 sin x   or sin x   (which is not true)
2 2
5  25  4sin x  24 5  1  4sin x
05.  x    1  sin x  1;   4sin x  4; 3  1  4sin  5
2.1 2
0  1  4sin x  5 ,   x  is an integer  sin x  0 ,   x   3  x  

 
2
06. Given, f  x  y  1  f  x  f  y

 
2
Putting y = 0, we get f  x  1  f  x 1 ;

Putting x  0, we have f 1  1  12  22 ;

Putting x  1, f  2    2  12  32 ;

 
2
Putting x  2, f  3  f  2   1   3  1  44 and so on.
2

Proceeding in this way, we get f 9 x   x  12 .

x  x  2x  2x 
07. sin x      Number of solution  1.
2  2  5  5 
ax  b a
08. If f  x   , x  , then f  f  x    x
cx  a c
  4  4   4  4
 f  f  x    x and f  f     ,  f  f  x    f     x   4
  x  x   x  x
ax  b
09. f  f  x    x  d   a  f  x  
cx  a
f  5  5  5a  b   5c  a  .5  25c  5a 1
f 13  13  13a  b  13c  a  .13  169c  13a  2
(1) – (2), we get, a8  144c  8a  a  9c
9cx  b
a8  144c  8a  a  9c ,  f  x  
cx  a
9c
Range f  x  does not contain 9 x9
c
f  2011   2  0  1  1  16
2
10.
f 2  2001  1  6   49, f 3  2011   4  9   169
2 2

f 4  2011  1  6  9   256, f 5  2011   2  5  6   169

2 2

It is a periodic function.
 f 2 n  2011  256 and f 2 n 1  2011  169n  2
11. From the given equation, we get
x 2   x  f   4 x  3  0, where f = fractional part function such that 0  f  1
  x 2  3x  3  f  0  f  x 2  3x  3
But 0  f  1. Therefore 0  x 2  3x  3  1 i
 x  1, 1  x  1
2

12. f  g  x    2
 2 x  1, 1  x  2
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Now, f  g  x    2  x  1  2 and 2 x 2  1  2
2

1
 x  1 and x  
2
13. Given,
 
f  x    2  cos 1 ga x 2  2  cos 1   x   2  cos 1 
Clearly, graph of f (x) is parabola opening upward.
As, range of f  x  is  0,   , so discriminant = 0
 b 2  4 ac  0
 
 4  cos 1    4  2  cos 1   2  cos 1   0 
2


 4  cos 1    4 2 2   cos 1  
2 2
0
  cos 1     cos 1    2 2
2 2

 cos1     cos 1       1 (Think), Hence,     2  1  0  2  1  3

1
14. Clearly, x 2  4 x    or  x  R
3
1
 x2  4 x     0x  R
3
 1 
So, discriminant  0  16  4    0
 3
1 1  1 
4   0, ,
 ga  4   ga   4  ,
3 3  3 
Hence, minimum integral   4

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15.

16.

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17.

18.

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PHYSICS
D
19. V1   Edx  V2
0

 x3 
QA 0  x    V
 3B 
At   0

 QA 0
0
  QA 02
At x  D

 Ex
0
20. Dipole is in uniform field, so net electric force is zero.
 
Electric potential energy of a dipole U   P.E . For stable equilibrium potential energy should be
minimum

21. when switch S is open

250
V1   6000   150V
10000
250
V2   4000   100V
10000
When switch S is close circuit reduces to shown in the figure.
250
So both the voltmeters show reading V1  V2   125V
2

22.

Q 2 c
x  Independent of Q1
abc
Q1  y  x  y  Q 2  x
Q  Q2
y 1
2
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23.
24.
 
n  a  x   y 2   c  n   a  x   y 2   c
2 2
25. V
40   40  

 a  x   y 2  2  a  x   2y 2
2 2

  x  3a    y  0   2y 2
2 2

Centre of circle (3a,0)

R  2 2a
26. w1  0 as configuration of the field is same in both the cases
1
R
 q0  2 3q 02
W2    0    4r dr  
2 R /4  40 r 2  80 R
27. When S is open
Let VP3  VQ3  0
2V
 VP2  VQ2 
5
3V
VP1  VQ1 
5

Let current through voltmeter is i (small current) Resistance of voltmeter B is R 0

 Resistance of voltmeter A is 2R 0
 VQ3  3R 0i  VP2
3V 2V
 3Ri 
5 5
V
 3Ri 
5
Ri  V / 15
Reading of voltmeter A=2V/15
Reading of voltmeter B=V/15

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When S is closed
Vc  2V / 5
For A
i1
VQ3  2R 0i1  R 0 VP2
2
3V 5 2V
 R 0i1 
5 2 5

5
R 0i1  2V / 25
2

R 0i1  2V / 25
Reading in reading of voltmeter A
2V 4V 2V
  
15 25 75

28.
 
29. Ep  
4 0

2  2 , Vp 
20

2 2 
3 T 2a 2 3 8.85  1010 100
30. F .  .  3
8 0 8 8.85  1012 8
=21.65 N
31.
32. Work done required
  
   
 U1  U1  pE   pE    16 1027    12 1027   2.8  1026 J
1 1
33.
34.

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 2KP cos 
Er 
r3
R


r
q

qKPsin  2Kpq cos 2  1
2
sin   3
 cos    cos stant
R R 3
mv 2 2KPq Kpq
 sin  2
cos   cos 
R sin  R3 R3
3Kpq 3KPq sin 4  cos 
mv 2  .sin 2
cos    2

R3 M r2
1
 2 
r
1 3 KPq sin 2  cos   qKP cos  
Total energy: m2  qV   
2 2 R3  R3 
KPq 3 
 3 cos   sin 2   1  0
R 2 
1
Angular momentum: L= m  r, as    L=constant
r
Distance from dipole =R= r sin   r
35.
36.

CHEMISTRY

37. Only tetrahedral, since there is one tetrahedral voids just above the atom & one just below the atom.

38.

39. Schottky defect is only observed in ionic compound.

C2H6  2CO2 H2
43. Electrolysis
2CH3 COONa     2 Faraday charge
at anode Cathode

0.965  60  60
Electric supplied   36  103 F
96500

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3
36  10 0.0821 298
= VH2    0.44 lit; Vtotal  VC2H4  VCO2  VH2  4  0.44  1.76 lit.
2 1

44. Concentration of Ag  should be same in Both cell.

45. Conceptual
46. 6.66 1016
47. 10 m mol/L
0.1 60
48. 3
2
0.06 1
49. E  1.1  log
2 x

Cu 3  4 NH 3  Cu  NH 3  4
2r

x 2 1

1 92 1012
 10 x 
24  x 24
E  1.1  0.03 log 24 1012  0.704
50. We have to assume here that the decrease in density is not due to volume change but due to loss of
Ge atoms only. Let x be the total number of Ge atoms missing and y be the number of boron atoms
replacing germanium atoms. Assuming volume of the crystal remaining same, then 4% decrease in
density will also decrease weight of the crystal (sample) by 4%.
   
 1   x  72 .6    y  11   0.96
 N AV   N AV 

 72 .6   11 
0.04   x     y  
 N AV   N AV 

 150 N AV 
where y   6
 0.96 
 10  11 

y  11 150  0.96
or 
N AV 10 6

 72 .6   150  0.96 
0.04   x   
 N AV   10 6 

(0.04  1.44  104 ) N AV 0.04 N AV

x  
72.6 72.6
y 150 N AV  0.96  72.6
   2.376 102
x 106  11 0.04 N AV
y
 100  2.376  102 100  2.376%
x
51. Conceptual

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52. (A) Gold sol is prepared by Bredig's Arc method and it is negatively charged
(B) Purification of colloidal solution is done by dialysis.
(C) As2 S3 sol is prepared by Double decomposition reaction and it is negatively charged.
(D) Zeta potential-potential difference between stable layer and disperse layer. (Electro kinetic
potential)
(E) Casein is lyophilic Protective colloid
X Y
53. (P) (C2H5 )3 N CH3COOH  CH3COO  aq   C2H5 3 NH  aq

As CH3COOH is a weak acid, its conductivity is already less. On addition of weak base, acid-base
reaction takes place and new ions are created. So conductivity increases.
(Q) KI  0.1M  AgNO3  0.01M  AgI  ppt   KNO3  aq.

As the only reaction taking place is precipitation of AgI and in place of Ag ,K  is coming in the
solution, conductivity remain nearly constant and then increases.
(R) CH3COOH  KOH  CH3COOK  aq  H2O

OH  aq  is getting replaced by CH3COO , which has poorer conductivity. So conductivity decreases

and then after the end point, due to common ion effect, no further creation of ions take place. So,
conductivity remain nearly same.
(S) NaOH  HI  NaI  aq  H2O

As H is getting replaced by Na+ conductivity decreases and after end point, due to OH , it
increases. So answer of 39 is : (P) – (3) ; (Q) – (4) ; (R) – (2); (S) – (1). Answer is (D).

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