Class : XII_R_ IIT_PCM Dt : Sun Jun 15 2025, 2:00 pm

XII_R_ IIT_PCM_ JUMBO Test - 10_15.06.2025 - Keys

Duration : 3.0Hrs Test ID : 7212 Marks : 300

(1) : a (16) : d (31) : a (46) : 92 (61) : d

(2) : c (17) : c (32) : a (47) : 8 (62) : b
(3) : a (18) : d (33) : c (48) : 18 (63) : d
(4) : b (19) : b (34) : c (49) : 25 (64) : a
(5) : b (20) : c (35) : a (50) : 4 (65) : b
(6) : b (21) : 2.5 (36) : b (51) : a (66) : b
(7) : d (22) : 400 (37) : d (52) : a (67) : c
(8) : d (23) : 21 (38) : a (53) : b (68) : c
(9) : a (24) : 20 (39) : d (54) : a (69) : a
(10) : a (25) : 3600 (40) : c (55) : d (70) : d
(11) : d (26) : d (41) : b (56) : a (71) : 24
(12) : b (27) : b (42) : b (57) : c (72) : 4
(13) : b (28) : a (43) : b (58) : c (73) : 36
(14) : b (29) : a (44) : c (59) : a (74) : 0
(15) : d (30) : d (45) : d (60) : b (75) : 4
FC
D

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 1/1
 Class : XII_R_ IIT_PCM Dt : Sun Jun 15 2025, 2:00 pm
XII_R_ IIT_PCM_ JUMBO Test - 10_15.06.2025 - Solutions
Duration : 3.0Hrs Test ID : 7212 Marks : 300

(1) : a (4) : b
Explanation : Explanation :
∘
2
Y πr ΔL 2s cos θ 2×0.06×cos 0
Stretching force, F =
L
H =
rρg
=
0.5×10
−3 3
×10 ×9.8

where the symbols have their usual meanings. = 2.44 × 10

−2
m = 2.44 cm

Both the wires are of same material, so Y will be equal, (5) : b

extension in both the wires is same, so ΔL will be equal. Explanation : Given : Surface tension,
2
r −2
∴ F ∝
L
T = 2.5 × 10 , diameter, d
N /m = 1 cm

Work done to blow a soap bubble = 2

2
′ (2r) T × A = T × 4πr × 2
F K ′
∴ = × 2
= 8 or F = 8F . . . . (i)
F (L/2) r −2 −2 2
W = 2.5 × 10 × 4 × 3.14 × (0.5 × 10 ) × 2
Work done in stretching a wire, W
1
= × F × ΔL −5
2 W = 1.57 × 10 J.
For same extension, W ∝ F
′ ′
(6) : b
W F
∴ = = 8 . . . [Using (i)]
W F Explanation :
′
W = 8W = 8 × 2 J = 16 J

(2) : c
Explanation :
Variation of density with pressure is given by
′
ρ (7) : d
ρ =
[1−
ΔP
] Explanation : Degree of freedom of polyatomic gas
K
FC
Here, ΔP = nP0 − P0 = (n − 1)P0
Here, no of translational dof = 3,
′
ρ ρK no of rotational dof = 3
∴ ρ = =
and no of vibrational dof = 2 × 2 = 4
(n−1)P
0 K−(n−1)P0
1−
K

(3) : a Therefore, total no of dof

Explanation : f = 3 + 3 + 4 = 10

Consider the equilibrium of the plane BB′ . β = CP /CV = 1 + (2/f )= 1 + (2/10)

β = 12/10 = 1.2
D

(8) : d
Explanation : The translational kinetic energy & rotational kinetic
energy both obey Maxwell’s distribution independent of each
other.
T.K.E. of diatomic molecules = (3/2) kT [3 translational D.O.F.]
A force F must be acting on this plane making an angle R.K.E. of diatomic molecules = (2/2) kT = [2 rotational D.O.F.]
(90 − θ) with the normal ON . Resolving F into two
∘
So statement I is true but statement II is false.
components, along the plane and normal to the plane. (9) : a
Component of force F along the plane, Fp = F cos θ Explanation : Based on kinetic theory of gases, molecules suffer
Component of force F normal to the plane, change in momentum when impinge on the walls of container.
FN = F cos(90
∘
− θ) = F sin θ Due to this they exert a force resulting in exerting pressure on
Let the area of the face BB′ be A′ . Then A
′
sin θ the walls of the container.
A

′ A
∴ A =
sin θ

∴ Tensile stress = F sin θ

′
=
F 2
sin θ
A A

Shearing stress = F sin θ

′
=
F
cos θ sin θ =
F sin 2θ

2A
A A

Their corresponding ratio is

Tensile stress F 2
= sin θ×
Shearing stress A

A
= tan θ
F sin θ cos θ

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 1/6
(10) : a (16) : d
Explanation : Applying Wien’s law, we get Explanation :
b
λm =
T
−3
b 2.89×10
⇒ T = = −10
= 7225 K ≈ 7000K
λm 4000×10

(11) : d
Explanation : According to Wien’s law, λm T = constant
∴ (λm T )s = (λm T )m

Ts (λm ) −4
10
or
m
= = −6
= 200
Tm (λm ) 0.5×10
s

(12) : b
Explanation :
2 2 2 −1
V = V + 2gh = (2) + 2 × 1000 × 5.1 × 10 = 1024
2 1

V2 = 32cm/s.

(13) : b (17) : c
Explanation : Explanation :
2
r g
(ρ − σ)
9η

(18) : d
Explanation :
Q = A. v

= A. √2gh

(14) : b
FC −6
= 2 × 10 × √2 × 10 × 2
Explanation : −6
= 2 × 10 × √40

−6
= 2 × 10 × 6

−6 3
= 12 × 10 m /s

(19) : b
Explanation :
Increase in length ΔL = L0 αΔθ
D

−6
= 10 × 10 × 10 × (100 − 0)

= 10
−2
m = 1.0 cm
(15) : d
Explanation : (20) : c
Explanation :
L − L0 (1 + αΔθ)

L1 1+α(Δθ)
2
∴ =
L2 1+α(Δθ)
2

−6
10 1+11×10 ×20
∴ = −6
L2 1+11×10 ×19

∴ L2 = 9.99989

∴ Length is shorten by,

−5
10 − 9.99989 = 0.00011 = 11 × 10 cm

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 2/6
(21) : 2.5 (28) : a
Explanation :
CH3 − CH3 have pure single bond and CH2 = CH2 have
pure double bond so βis minimum.
γ

Due to resonance in CH2 = CH − CH = CH2 ,γ get partial

double bond character.
(29) : a
Explanation :
Explanation : 171
(30) : d
Explanation : −3.1∘ C
(31) : a
Explanation : M gCl2 > KCl > Glucose
(32) : a
(22) : 400 Explanation : 400, 600
Explanation : Vrms = √(3RT1 /M0 ) (33) : c
200 = √(3R × 300/M0 ) . . . (1)
Explanation : I, II and III

Also, x/√3 = √(3R × 400/M0 ) . . . (2)

(34) : c
(1) ÷ (2)
Explanation :
200/(x/√3) = √(300)/400 = √(3/4)
(35) : a
⇒ x = 400 m/s.
Explanation :
FC
(23) : 21
Explanation :
(24) : 20
Explanation : (36) : b
1
mv
2
=
1
× F × Δl Explanation :
2 2

mv
2
=
Y AΔl
× Δl
(37) : d
l

Y AΔl
2
Explanation :
v = √
D

2ml
(38) : a
8 −6

v = √
5×10 ×10
−3
× 2 × 10
−2
Explanation :
5×10 ×0.1
The standard free energy change of a reaction
v = 20 m/s
o
ΔG = 2.303 RT log Kp
(25) : 3600 3
−115 × 10 = 2.3003 RT log kp
Explanation : ΔKE = ΔU 3
115×10
log Kp =
ΔU = nCV ΔT 2.303×8.134×298

2 log Kp = 20.16
1/2 mv = (3/2) nRΔT
2
mv /3nR = ΔT (39) : d
2
4 × (30) /3 × 1 × R = ΔT Explanation :
2 [Salt]
ΔT = 4 × (30) /3 × 1 × R
pOH = pHb + log10
x/3R = 1200/R [Base]

x = 3600. [Cation]
= pKb + log
(26) : d 10
[Base]

Explanation : [N H
+
] = 2 × moleof (N H4 )2 SO4
4

−\ddot{N}H2 is an electron donating group (EDG) because it 2

contains lone pair on it. Therefore it shows +M effect. pOH = 5 + log
10
1
= 5.3010

(27) : b pH = 8.6990

Explanation : As double bond character increases bond strength (40) : c

1
increases and B.S ∝
Bond Length
Explanation :
∴ As bond strength increases, bond length decreases.
Order will bea > c > b > d .

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 3/6
(41) : b (47) : 8
Explanation : Explanation :
To determine the number of intensive properties among the
+2 2− 2−
Ksp (SrCO3 ) [Sr ][CO ] [CO ]
3 3
= 2
= 2
Ksp (SrF2 )
given list, we first need to understand the definitions of intensive
+2 − −
[Sr ][F ] [F ]

(42) : b and extensive properties:

Explanation : - Intensive Properties: These are properties that do not
1
ΔH = Δf H
o
(CO2 ) − [Δf H
o
(CO) + Δf H
o
(O2 )]
depend on the amount of substance present. They remain the
2
same regardless of the size or mass of the sample.
= −94.0 − (−26.4) = −67.6 kcal.
- Extensive Properties: These properties depend on the
(43) : b amount of substance present. They change when the size or
Explanation : mass of the sample changes.
78 g of benzene on combustion produces heat =3264.6 kJ Now, let's analyze each property listed in the question:
3264.6
∴ 39 g of benzene will produce = 2
= 1632.3 kJ . 1. Temperature: Intensive property (does not depend on mass).
(44) : c 2. Pressure: Intensive property (does not depend on mass).
Explanation : 3. Volume: Extensive property (depends on mass; if you halve
ΔU = q + w the sample, the volume is halved).
∴ w = ΔU − q = 250 − 730 4. Heat Capacity: Extensive property (depends on mass; larger
= −480 kJ
samples have greater heat capacity).
(45) : d 5. Density: Intensive property (mass cancels out; it is mass per
Explanation : unit volume).
The bond enthalpy of reaction = 6. pH of a solution: Intensive property (does not depend on the
FC
[Sum of bond enthalpies of reactants] – [Sum of bond enthalpies amount of solution).
of products] 7. EMF of a cell: Intensive property (does not depend on the
−50 = [
1
× 380 +
3
× Y − Y ] − 3 × 150
size of the cell).
2 2

=
3
(Y − Y ) − 260
8. Entropy: Extensive property (depends on mass; larger
2
210×2 systems have greater entropy).
Y − Y = = 140
3
9. Free Energy (Gibbs Free Energy): Extensive property
(46) : 92
(depends on mass; changes with the amount of substance).
Explanation : undefined
10. Enthalpy: Extensive property (depends on mass; larger
D

systems have greater enthalpy).

11. Surface Tension: Intensive property (does not depend on
the amount of liquid).
12. Viscosity: Intensive property (does not depend on the
amount of liquid).
13. Boiling Point: Intensive property (does not depend on the
amount of substance).
Now, let's count the intensive properties:
- Intensive Properties: Temperature, Pressure, Density, pH,
EMF, Surface Tension, Viscosity, Boiling Point.
Total Intensive Properties = 8
Final Answer:
The number of intensive properties among the given list is 8

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 4/6
(48) : 18 (52) : a
Explanation : Explanation : In a 7 digits number formed by using 1, 2 and 3
Molarity of CH3 COOH solution = mass of acetic acid/molar suppose that 1 appears x times, 2 appears y times and 3
mass)/volume of solution in litre appears ztimes. Then
Acetic acid is monobasic. x + 2y + 3z = 10 and x + y + z = 7

0.042 = W/(60×0.05) ⇒ y + 2z = 3

W = 0.042×60×0.05 = 0.126 g ⇒ y + 1, z = 1 or y = 3, z = 0

Amount of acetic acid actually adsorbed = 0.180-0.126 = 54mg ⇒ x = 5, y = 1, z = 1 or x = 4, y = 3, z = 0

Amount of charcoal available = 3 g Therefore, the total number is

So amount of acetic acid adsorbed per gram of charcoal = 7!
+
7!
= 42 + 35 = 77 .
5! 4!3!

54mg×1g/3.0g = 18 mg (53) : b
(49) : 25 Explanation :
Explanation : μ = e × d
(54) : a
−18
μ 1.2 D 1.2×10 esu cm
∴ e =
d
=
1.0 A
=
1.0×10
−08
cm
Explanation :
−10 2
= 1.2 × 10 esu (2cos 2x − 1) + 6 = 7 cos 2x

Percentage of electronic charge On putting cos 2x = t ,

−10 2
1.2×10 esu 2t − 1 + 6 = 7t
= −10
× 100 = 25
4.8×10 esu

(50) : 4 2
2t − 7t + 5 = 0
−1
Explanation : P Cl5 , I3 , SF4 , BrF5
(2t − 5)(t − 1) = 0
(51) : a t =
5
,1
2
FC
Explanation : 5
t = , (notpossible)
2
θ 2
1−tan θ/2 2 tan
2
( 2
) − 2( ) = 1 t = 1 ⇒ cos 2x = 1 ⇒ 2x = 2nπ
2 θ
1+tan θ/2 1+tan
2
⇒ x = nπ
Let tan θ
= t
2
2
The roots in [0,314] are
4−4t −6t
= 1
1+t
2
(55) : d
2 2
4 − 4t − 6t = 1 + t Explanation :
2
⇒ 5t + 6t − 3 = 0 (56) : a
D

⇒ t =
−6+√36−4(5)(−3)
Explanation :
2(5)

−6±√96
(57) : c
=
10
Explanation : One dictionary out of 3 can occupy middle place in
−6±4√6
=
10
3
P1 = 3 ways.
6

t =
−3+2√6
4 novels out of 6 can be arranged in four places in P4 ways.
5

2√6−3
2
∴ the required number of ways
2
1−( )
5
1−t 6
cos θ = = = 3 × P4 = 3 × 6 × 5 × 3 × 3 = 1080
2
1+t 2√6−3
1+( )
5
(58) : c
24+9−12√6
1−(
25
)
Explanation :
=
24+9−12√6
1+( )
25

25−33+12√6 12√6−8 6√6−4 29+6√6

= = = ×
25+33−12√6 58−12√6 29−6√6 29+6√6

100+150√6 4+6√6 4−6√6

= = ×
625 25
4−6√6

−200 −8 4
= = = .
25(4−6√6) 4−6√6 3√6−2

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 5/6
(59) : a (67) : c
Explanation : Explanation :
2 2 2
(60) : b 2(1) + 3(2) + 4(3) +. . . . . . . . . . upto 10 terms
Explanation : 10
2
10
3
10
2
= ∑ (r + 1) r = ∑ r + ∑ r
(61) : d r=1 r=1 r=1

Explanation : = 3410

(62) : b (68) : c
Explanation : Explanation :
a, b, c are the roots of x
3
+ 4x + 1 = 0

∴ a + b + c = 0 . . . (1)

ab + bc + ca = 4 . . . (2)

abc = −1 . . . . (3)
−1 −1 −1
(a + b) + (b + c) + (c + a)
1 1 1 1 1 1
= + + = − − −
a+b b+c c+a c a b

ab+bc+ca 4
= −[ ] = −[ ] = 4
abc −1

(63) : d (69) : a
Explanation : Explanation :
(64) : a α + β = −a, αβ = 1
2 2 2
Explanation : (α − β) = (α + β) − 4αβ= a − 4

0
a = 1 b = 3, ∠c = 60 ∴ (α − β) < √5
2 2 2
FC 2
a +b −c ∴ (α − β) < 5
cos C =
2ab 2
2 2 2 ∴ a − 4 < 5
a +c −b
Now, cos B =
2ac
2
∴ a < 9
2
1 1+9−c 2
⇒ = ⇒ 3 = 10 − c ∴ −3 < a < 3
2 2(1)(3)

c
2
= 7. ...(1) (70) : d
Explanation :
2 2 2
a +b +c
Now, cos B =
2ac
1+7−9 y (−4) = 16 − 24 − 4 = −12
cos B =
D

2(1)√7
y (3) = 9 + 18 − 4 = 23
−1
cos B =
2√7

2 1
cos B = 2

2
(2) (7)
So range is [−13, 23]
2
∴ sin B = 1 − cos B
1 27
= 1 − = .
28 28

(65) : b (71) : 24
Explanation : Explanation :
(log2 x)
2
= log2 x − (log2 x)
2
+ 1 (72) : 4
2(log x)
2
− log x − 1 = 0 Explanation :
2 2

log x = 1 or log x = −
1 (73) : 36
2 2 2

1
Explanation :
x = 2 or x = − (Not possible)
√2 (74) : 0
(66) : b Explanation :
Explanation : (75) : 4
Explanation :

DFC, Plot. No. 31, Kranti Chowk Police Station Road, Nutan Colony, Chh. Sambhajinagar, Mobile: 9225318727 Page 6/6