Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS&STERLING_BT JEE-ADVANCE‐2021-P2 Date: 26-02-2023
Time: 02.00Pm to 05.00Pm GTA-12 Max. Marks: 180
26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Syllabus

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P

JEE‐ADVANCE‐2021‐P2‐Model
Time: 3:00Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 7 – 12) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 13 – 16) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 17 – 19) +4 0 3 12
Value Type
Total 19 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 20 – 25) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 26 – 31) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 32 – 35) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 39 – 44) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 45 – 50) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 51 – 54) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P

PHYSICS Max. Marks: 60

SECTION-1(Maximum Marks: 24)
One or More Type
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
1. In the given figure a ball of mass m is connected to an elastic spring of force constant
K = mg/L through an inextensible string as shown. Now the ball is released from rest.
K=mg/L
m

L/2

A) The maximum velocity of mass m during fall is 3gL

B) The maximum velocity of mass m during fall is 2gL
C) The maximum potential energy stored in the spring during the fall is mgL 2  3 
D) The maximum potential energy stored in the spring during the fall is mgL 2  3 
2. Two thin concentric conducting shells of radii R and 2R are shown in figure. The outer
shell carries a charge +Q and inner shell is neutral. Choose the correct option(s) :-

3R
A) With switch S open, potential of inner sphere is same as that of a point at distance
2
from centre.
B) When switch S is closed, potential of inner sphere becomes zero.
 Q
C) With switch S closed charge on inner sphere is    .
 2
D) With switch S closed charge on inner sphere is (–Q).
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
3. Two point objects of masses m and 4m are at rest at an infinite separation. They move
towards each other under mutual gravitational attraction. If G is the universal gravitational
constant, then at a separation r
A) the total mechanical energy of the two objects is zero.
10Gm
B) their relative velocity is .
r
4Gm 2
C) the total kinetic energy of the system of objects is .
r
D) their relative velocity is zero.
4. Consider two light waves moving in z direction represented by two mutually
perpendicular electric field vectors (with non-zero amplitudes): Ex  Ax cos xt  x  and
E y  Ay sin  y t   y  . Their superposition will result in a plane polarized light, if
 
A) Ax  Ay , x  ,  y   B) x   y , x  ,  y  
2 2
 
C) Ax  Ay , x   y , x  ,  y   D) Ax  Ay , x   y , x  ,  y  
2 2
5. A metal cylinder of mass 0.5 kg is heated electrically by a 12 W heater in a room at 15ºC.
The cylinder temperature rises uniformly to 25ºC in 5 min and finally becomes constant at
45ºC. Assuming that the rate of heat loss is proportional to the excess temperature over the
surroundings
A) The rate of loss of heat of the cylinder to surrounding at 20ºC is 2 W
B) The rate of loss of heat of the cylinder to surrounding at 45ºC is 2 W
240
C) Specific heat capacity of metal is J/kgºC
n(3 / 2)

D) None of these
6. In a region, magnetic field along positive x axis changes with time according to the given
graph.

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A positively charged particle is projected from origin at an angle  0 with the positive x-
axis in first quadrant of x-y plane. If the time period, pitch and radius of helical path are
T0 , P0 and R0 respectively, then which of the following statement(s) is/are correct:

T0 P 
A) At t  , co-ordinates of charge are  0 , 0 ,  2 R0  .
2  2 

, co-ordinates of charge are  0 , 0 , 2 R0  .

3T0 3P
B) At t 
2  2 

C) The maximum distance of the charge from x-axis is 2R0

D) The maximum distance of the charge from x-axis is 4R0 .
SECTION-2(Maximum Marks: 12)
Paragraph with Numerical
 This section contains THREE (03) question stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-
screen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Question Stem for Question Nos. 7 and 8

Question Stem
In the circuit shown, switch K is initially open. Both the cells are ideal
and C  30 F, E1  1V, R1  2, E 2  3V, R 2  4 . At t = 0 second, the switch K is closed. A
and B are two points on circuit as shown.

7. Just after the switch K is closed, the magnitude of current in amperes through resistance
R1 is _____

8. Long after the switch K is closed, the magnitude of charge on the capacitor in steady state
is _____ C.

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
Question Stem for Question Nos. 9 and 10
Question Stem
A point object is placed on principal axis of a concave mirror ( of focal length 15 cm) at
a distance u = 61 cm from pole. A slab of thickness t = 3 cm and refractive index
  1.5 is placed with two sides perpendicular to principal axis, such that its nearest face

is x0 cm from pole. The final image of object is to be considered after refraction by slab,
reflection by mirror and final refraction by slab.
f =15cm

object
x0
t=3cm =1.5

9. If x0  30 cm , then the distance of final image from pole is _____ cm.

10. If x0  30 cm and the object is given velocity 18 m/s towards left then the speed of image at
that instant is _____m/s
Question Stem for Question Nos. 11 and 12
Question Stem
Two blocks of mass m1  10 kg and m 2  20 kg are placed on a fixed inclined surface
making an angle   37 with horizontal. One end of a light spring of spring constant
K = 100 N/m is free and other end is connected to a support S rigidly fixed to inclined
surface. The coefficient of friction between block of mass m1 and inclined plane is
1  0.5 and that between block of mass m2 and inclined plane is  2  1. At time t = 0 both

blocks are released at rest from shown position.  Take g  10 m / s 2 

8m
=1.4 m2
L m1
/m
0 0N
1
K=
S =37°

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11. At the instant the speed of block of mass m1 is maximum, the compression in the spring
is____cm :
12. At the instant speed of block of mass m1 is maximum, the speed of block of mass m2 is
____m/s:
SECTION-3(Maximum Marks: 12)
Paragraph with Single Answer Type
 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
Paragraph-I
According to quantum mechanics, stationary states of a quantum harmonic oscillator
exist only for certain discrete energy levels, the quantum states of the oscillator. The
allowed energies are given by the simple equation
 1
E n   n   h n = 1, 2, 3....
 2

Where  is the classical angular frequency and n is the quantum number.

1
Note:- The ground-state energy of the quantum harmonic oscillator is E1  h. An
2
atomic mass on a spring cannot be brought to rest. This is a consequence of the
uncertainty principle.
In most metals, the atomic ions form a regular arrangement called a crystal lattice. The
conduction electrons in the sea of electrons move through this lattice. Figure is a one-
dimensional model of a crystal lattice. The ions have mass m, charge e, and an
equilibrium separation b.

+ + +
b b
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
13. If the middle charge is displaced a very small distance ‘x’ in positive direction (towards
right and x << b) from its equilibrium position while the outer charges remain fixed.
Then the net force experienced by the middle charge is approximately:-
e2 e2 e2 e2
A) F   x B) F   x C) F   x D) F   x2
4b3  0 2b3  0 b3  0 b 4  0

14. If this crystal consists of aluminum ions of mass m and with an equilibrium spacing of b,
the energy of the second lowest vibrational states of these ions is :-
3he 4 3he 1 3he 1 3he 1
A) B) C) D)
2b mb 0 2b mb 0 b m b  0 b 8mb 0
Paragraph-I
A prism shaped styrofoam of density ρstyrofoam < ρ water is held completely submerged in
water. It lies with its base horizontal. The base of foam is at a depth h0 below water
surface and atmospheric pressure is P0 . Surface is open to atmosphere. Styrofoam prism
is held in equilibrium by the string attached
symmetrically. (Take:ρstyrofoam = ρf ;ρ water = ρ w ) .


h0
 P 90°

90° L

15. Magnitude of force on any one of the slant face of styrofoam exerted by liquid is

A) (P0  w g(h 0 – 2))L B) ( P0  w g (h0 – )) L
2
 
C) ( P0  w g (h0 – )) L D) ( P0  w g (h0 – )) L
2 2 2

16. Now string is cut and styrofoam is allowed to come to surface. A point mass m is to be
placed symmetrically on the upper surface of styrofoam such that it is in equilibrium
with its base in horizontal plane. In equilibrium position styrofoam has half of its slant
length submerged. Surface tension of water is T, contact angle is 0°. Determine the value
of mg (mass times acceleration due to gravity) to achieve equilibrium.
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
Point mass

/2

 f gL 2 3   f gL 2 3
A)  w gL 2  2T [ L  ] B)  w gL 2  2T [ L  ]
2 4 2 8
  f gL 2
3 T [ L  ]   f gL 2 3
C)  w gL 2  D)  w gL 2  2T [ L  ]
2 8 2 2 8
SECTION-4(Maximum Marks: 12)
Non-Negative Integer Answer Type
 This section contains THREE (03) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
17. A spool, initially at rest, is kept on a frictionless fixed inclined plane, making an angle
  37 with the horizontal. The mass of the spool is 2kg and it is pulled by a string as
shown with a force of T = 10N. The string connecting the spool and the pulley is initially
horizontal. Find the initial acceleration of the spool on the incline. Express your answer in
m / s2 .
m
r
R

 T

18. A radioactive sample contains two radio nuclides A and B having decay constant  hr 1
and 2 hr 1 . Initially 25% of total decay comes from A. How long (in hour) will it take
before 75% of total decay comes from A. [Take    n 3 ]
19. Hydrogen is used in a Carnot cycle as a working substance. As a result of an adiabatic
expansion the gas volume becomes 2 times. Let the efficiency of the cycle be  . Find the
value of 4 to the nearest integer.
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
CHEMISTRY Max. Marks: 60
SECTION-1(Maximum Marks: 24)
One or More Type
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
20. In winter season, ice formed on the surface of an ocean or a lake provides thermal
insulation. Which ensures the survival of the aquatic life. The reasons for maintaining
solid ice at the top and liquid water below ice is/are
A) At the top pure water crystallises
B) The freezing point of water below ice decreases
C) Due to the increase in pressure on water below ice
D) Ice is less denser than water
21. The electron affinity of nitrogen is very low which can be attributed to
A) ‘N’ atom has stable – filled p 3 configuration
B) Addition of electron to 2 p orbital increase spin paired repulsion
C) Energy released due to attraction between the nucleus and incoming electron is offset
by the inter electron repulsion by pairing
D) Due to small size also inter electron repulsions are more than the other elements in
the group
3
22. The complex in Co  CO3 3  has one absorption band in the visible region of the

spectrum at 640 nm. From this information

A) The complex is paramagnetic with magnetic moment 4.9 BM
B) It can exhibit both optical and geometrical isomerism
C) Carbonate ion is weak ligand, so  0 is small and hence it should be high spin complex
D) The complex is blue in colour.

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
23. A photon of wavelength is 4  107 m strikes on a metal surface, the work function of the
metal being 3.4  1019 J . Select the correct statements.
A) The energy of photon is 4.97  1019 J

B) The kinetic energy of the emission is 1.57  1019 J

C) The kinetic energy of the emission is 0.98ev

D) The velocity of photo electron is 5.87  105 ms 1

24. Compound (X) C4H8O decolorizes Baeyer’s reagent. It undergoes hydrolysis in

dil H 2SO 4 to give (Y) and (Z) where both Y and Z give positive iodoform test while only
‘Y’ responds to Tollens test but (Z) doesn’t. Choose the correct statements of the
following:
NaOH PCC
A) Y   CH  CH  CH  CHO B) Z 
CH Cl
Y
 3
2 2
Br
| O ,H O
3 2  Y  other product
D) X 
Br
C) X  2  Br  CH
2
 CH  O  CH CH
2 3 Zn
CCl
4
25. Polyacetylene is a conducting polymer. Which of the following statements is/are correct
regarding polyacetylene.
A) Polyacetylene prepared by the polymerization of acetylene using a Ziegler-Natta
catalyst
B) the conjugated double bonds in polyacetylene causes it to conduct electricity
C) Polyacetylene used for the magnufacture of electrodes for measuring pH
D) Polyacetylene is not a synthetic metal
SECTION-2(Maximum Marks: 12)
Paragraph with Numerical
 This section contains THREE (03) question stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-
screen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Question Stem for Question Nos. 26 and 27
Question Stem
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
In to hot concentrated solution of KOH containing 33.6 gm of KOH, chlorine gas is
passed till all the KOH is completely reacted. Evaporation of the solution gives a solid.
26. The solid is dissolved in water and treated with AgNO3 . What is the weight of precipitate
formed.
27. The solid is heated in the presence of MnO2 . What is the weight of the gas liberated
Question Stem for Question Nos. 28 and 29
Question Stem
There are some isomeric amines containing only one N atom. Each one of which forms a
chloride salt on treatment with HCl containing 32.42% chlorine. None of them decolorizes
Br2 water.
(At. Wt of Cl = 35.5)
28. How many of them can evolve N2 on reaction with HNO2? (Excluding Stereo isomers)
29. How many of them is/are not respond to carbyl amine test?
Question Stem for Question Nos. 30 and 31
Question Stem
‘A’ is a substance that converts into B, C and D by three first order parallel paths
simultaneously according to the following stoichiometry.

Path I
B

t1/ 2  86.625 min.

A  Path II
 2C


Path III
D
The partial t1/2 of A along path I and path II are 173.25 min and 346.5 min, respectively.
The energies of activation of the reaction along path I, path II and path III are 40 kJ mol–1,
60 kJ mol–1 and 80 kJ mol–1 respectively.
30. The percent distribution of C in the product mixture B, C and D at any time is equal to
____
31. The overall energy of activation in kJ mol –1 of A along all the three parallel path is equal
to _____

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
SECTION-3(Maximum Marks: 12)
Paragraph with Single Answer Type
 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

Paragraph-1:
The hydrogen bond can be defined as the attractive force which binds hydrogen atom of
one molecule with the electronegative atom (F, O or N) of another molecule. The
hydrogen bond is usually represented as X  H ........Y where X and Y are highly
electronegative atoms such as F, O and N. Note that the description of “donor” and
“acceptor” in hydrogen bond refers to the proton, in the hydrogen bond X  H ........Y , the
X  H group act as hydrogen donor to acceptor atom Y . In contrast, in a coordination bond
the donor atom is the one that bears the electron pair.
The strongest hydrogen bond resemble covalent bonds, the weakest one are like van der
waals interactions and the majority have energies lying between these two extremes.
Some non-conventional hydrogen bonds that do not conform the definition above are also
known. Hydrogen bond is universal and appear in several compounds.
32. Which of the following characteristics is/not correct for hydrogen bond.
A) Most of the hydrogen bonds X  H ........Y are unsymmetric that is hydrogen atom is
much closer to ' X ' than to ' Y '
B) Hydrogen bonds may be linear or bent
C) Linear hydrogen bonds are energetically less favorable than bent form of hydrogen
bond
D) Hydrogen bond is due to electrostatic attraction.
33. The universal appearance of hydrogen bond in several compounds is/not because of
A) small bond energy
B) ability to form inter molecular and intra molecular or both type of hydrogen bonds
C) in liquids hydrogen bonds are continuously being broken and reformed
D) there is no effect of hydrogen bond on the structure of compounds

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Paragraph-2:
The ionones are a series of closely related chemical substances that are part of a group of
compounds known as rose ketones. Ionones are aroma compounds found in a variety
of essential oils, including rose oil. β -Ionone is a significant contributor to the aroma of
roses, despite its relatively low concentration, and is an important fragrance chemical used
in perfumery. A mixture of α- and β-ionones are prepared by the acid catalysis of
pseudoionone which in turn is produced by the aldol condensation of 3,7-dimethylocta-
2,6-dienal with acetone under basic conditions. Oxidative cleavage by NaIO4-KMnO4
followed by treatment with NaOI followed by acidification and heating results in 3,3-
dimethyladipic acid incase of α-ionone and 2,2-dimethyladipic acid incase of β-ionone
(oxidize any aldehyde group if formed to acid).
34. The structure of pseudoionone is
CH3 H CH3 O

O CH3

H3 C CH3 H3C CH3

A) B)
CH3 O CH3 O

H CH3

H3 C CH3 CH3
C) D)

35. The structure of α-ionone is

CH2 O CH3 O

A) CH3 B) CH3

CH3 CH3
H3 C H3C
CH3 O CH3 O

C) CH3 D) CH3

CH3 CH3
H3C H3 C

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
SECTION-4(Maximum Marks: 12)
Non-Negative Integer Answer Type
 This section contains THREE (03) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.


36. Dissociation constant for H 3 N  CHR  COOH  H 2 N  CHR  COOH  H 

H N  CHR  COO
is 10–10 and hydrolysis constant of 2 is 10–12, then what will be the pH at
isoelectric point for amino acid H 2 N  CHR  COOH .
37. Amygdalin, a compound isolated from the pits of apricots, peaches and wild cherries.
Although it has no known therapeutic value, it has been used as unsanctioned anticancer
drug.
The number of stereogenic centers present in Amygdalin is ( x ).
The number of non bonding electrons are ( y ).
The degree of unsaturation is ( z ).
x yz
Find the value of
13

38. 10% sites of catalyst bed have absorbed by H 2 . On heating H 2 gas is evolved from sites
and collected at 0.03 atm and 300 K in a small vessel of 2.46 cm3. Number of sites
available is 5.4 1017 per cm2 and surface area is 100cm2. Find out the no. of surface sites
occupied per molecule of H 2 . (Given N A  6 1023 )

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P

MATHEMATICS Max. Marks: 60

SECTION-1(Maximum Marks: 24)
One or More Type
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.

39. Let y  f  x be the solution of differential equation x 2  2 x7  5  dydx  x 1. Such that
7

7
f 1  then
5
1
A) the equation e x  f  1  has exactly one real solution
4
1
B) the equation e x  f  1  has no real solution
4
C) f 1  f  1
D) f  x is an odd function
40. Let a function ' f ' is continuous and differentiable with f  0  1 and f 1  2. Then, for
n  N , there exists atleast one c  0,1 such that :

A) f '  c  f  c  B) f '  c  f  c 
n 1 n 1
 2n 1  2n 1

C) f '  c  f  c  D) f '  c  f  c  
n 1 n 1
1 1

x 2  y  b
2

41. Consider an ellipse 2   1 resting on a plane ground where a and b are functions of
a b2

time t (in seconds) given by a  4  2t , b  1  t. There is a long rod one end of which is
hinged at (10, 0). It rests freely on the ellipse with the other end in air. then which of the
following is NOT true
A) Eccentricity of ellipse attains a maxima after some time t1  0
B) At time t  4 seconds rod is still in contact with the ellipse
C) Locus of the free end of the rod will be an arc of a circle
D) Value of t for which rod breaks off contact from the ellipse is independent of its length

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P

42. Consider f  x 

x e ex x
  2 , x  0 identify which of the following statement (s) is/are
2x
correct
A) f  x has no critical points
B) f  x has exactly two critical points
C) f  x has exactly one point of inflection
D) f  x is concave downward in  , 0 and concave upward in  0, 
x 1 y  2 z  3 x  1 y  2 3  z  3 x 1 y  2 z  3
43. Let L1 :   , L2 :   and L3 :   be three lines. A
2 1 3 1 3 5 32 19 15
plane intersecting these lines at A, B and C respectively such that PA= 2, PB = 3 and
PC = 6 where P = (1, 2, 3). If V is the volume of the tetrahedron PABC and d is the
perpendicular distance of the plane from the point P then
A) V = 18 cubic units B) V = 6 cubic units
6
C) d  units D) d =7 units
14

44. Let S  n, k  denote the number of ways in which n distinct balls can be put into k identical
boxes such that no box remains empty  k  n . Which of the following is/are correct?
A) S  5,3  25
B) S  6,3  S  5,3  S  5, 2
C) S  6,3  3S  5,3  S  5, 2
D) The number of onto function from 6 element set to 3 element set is 3! S  6,3
SECTION-2(Maximum Marks: 12)
Paragraph with Numerical
 This section contains THREE (03) question stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-
screen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
Question Stem for Question Nos. 45 and 46
Question Stem
Consider the function f :  4,8  R   0 having a continuous derivative in it’s domain. If
 f '  x
8 2
1 1
  f  x 4
dx  1 with f  4  , f  8  .
4
4 2
8
f '  x
45. The value of   f  x
4
2
dx is

1
46. The value of is
f  6
Question Stem for Question Nos. 47 and 48
Question Stem
If the graph of the function y  2ax 2  bx  c  a  0; b, c  R is intersected by each of the
following lines at most once (tangential cases are to be considered as inter section at one
point)
y  ax  b, y  bx  a, y  bx  c, y  cx  b, y  cx  a, y  ax  c then
a
47. Find maximum value of
b
c
48. Find maximum value of
a
Question Stem for Question Nos. 49 and 50
Question Stem

A person has to reach from corner A to corner B in the above grid and he is allowed to
walk only east or north along the grid avoiding the 4 junctions marked with X.
49. The number of ways of travelling from A to B if he has to definitely cross the junction C
is
50. The number of ways of travelling from A to B is
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
SECTION-3(Maximum Marks: 12)
Paragraph with Single Answer Type
 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
Paragraph-1:
Six members of IMO team are S1 , S2 , S3 , S4 , S5 , S6 and for them there are six reserved seats
R1 , R2 , R3 , R4 , R5 & R6 arranged in a row. Initially seat Ri is given to student Si , i  1, 2,...., 6. But

on the examination day, six students are randomly allotted the six seats.
51. The probability that, on the examination day, the student S1 gets R1 and S2 gets R6 and none
of the remaining gets the seat previously allotted to them is P. Then P is
11 12 18 24
A) B) C) D)
720 720 720 720
52. Let Ei denote the event that Si & Si 1 sit adjacent to each other on the day of examination.
Then the probability that the event  E1  E3  E5  occurs is
1 1 7 1
A) B) C) D)
10 15 60 5
Paragraph-II:
Let a , b , c be 3 vectors whose magnitudes are a, b, c respectively and c  a  b . If a  b and
c divides angle between the two vectors a and b in the ratio 1:  then answer the

following (Assume angle between no two vectors is an integral multiple of )
6
53. For the value   2, which is correct ?
a 2  b2 a 2  b2 a 2  b2 a 2  b2
A) c  B) c  C) c  D) c 
b 2b a 2a
54. For the value   3, which is correct ?

A) c 
 a  b ab
B) c 
 a  b ab
b b

C) c 
 a  b ab
D) c 
 a  b ab
a 2 b
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 Sri Chaitanya IIT Academy 26-02-2023_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2021-P2)_GTA-12_Q.P
SECTION-4(Maximum Marks: 12)
Non-Negative Integer Answer Type
 This section contains THREE (03) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
55. Let R1 and R2 be relations on the set 1, 2,...,50 such that

R1   p, p  : p is a prime and n  0is an integer and

n

R2   p, p  : p is a prime and n  0 or1.

n

Then, the number of elements in R1  R2 is _______.

 4044 
  an 
56. Let 100nan  100  n  2 an 1  1 and a0  0 for n  1 then  n 0  , (where [ ] denotes greatest
5
integer less than or equal to x ) is equal to ?
57. A construction company has three different sites located in the city. Analysis of the daily
wages paid to the labourers in the three sites are as follows.
Site 1 Site 2 Site 3
No. of labourers 20 25 40
Average daily wages (Rs) 305 300 340
Standard deviation (Rs) 50 40 45
p
If the standard deviation of the wages of all the 85 labourers in the city is given by Rs ,
q

p 
where p, q  N , H .C.F  p, q   1, then find the value of   2362 
q 
(where [.] denotes the greatest integer function)

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