SC Thermodynamics e
SC Thermodynamics e
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
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strictly prohibited.
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However, the candidate are allowed to take away this Test Booklet with them.
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SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
09-11-2024_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee-Main_RPTM-13/17_Test Syllabus
PHYSICS : Rigid body Dynamics-2: Conservation of angular momentum ; Collision of point masses with rigid
bodies, Rolling with and without slipping, Toppling.
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)
CHEMISTRY : Thermodynamics-I: Zeroth law, first law, Internal Energy, Heat, Work Energy, Relation b/w H and
U, Application of first law in different types of processes, Polytropic process, limitations of first
law, Problems based on different type of processes & applications of 1st law
Thermodynamics-II: Carnot cycle, Clausius inequality, Entropy change in chemical reaction, third
law of thermodynamics, Gibbs free energy and its applications
Thermochemistry: Introduction, Different type of Heat of reactions, Resonance energy, Born-
Haber cycle, Kirchoff's law, relation between heat of solution and heat of hydration.
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)
MATHEMATICS : Complex Numbers
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)
1) L / 3 2) L / 6 3) L / 4 4) L / 12
6. A uniform rod of mass M is hinged at its upper end. A particle of mass m moving
horizontally strikes the rod at its mid point elastically. If the particle comes to rest after
collision find the value of M/m =?
4N
Column-I Column-II
A) P) Angular acceleration of particle is uniform
2
B) Q) Angular acceleration of particle is non-
uniform
2 - graph
C) R) Angular acceleration of particle is directly
proportional to t.
t
- t graph
Angular acceleration of particle is directly
D) S)
proportional to .
2
t
- t graph
2
1) 2)
3) 4)
11. A solid cylindrical wheel of mass M and radius R is pulled by a force F applied to the centre
of the wheel at 37 above the horizontal. If the wheel is to roll without slipping, what is the
maximum value of F ?. The coefficients of static and kinetic friction are s 0.40 and
3
k 0.30 and sin 37
5
1) 0.79 Mg 2) 0.98 Mg 3) 0.6 Mg 4) 0.49 Mg
12. Initial angular velocity of a circular disc of mass M is 1 . Then, two small spheres of mass
m are attached gently to two diametrically opposite points on the edge of the disc. What is
M m M m M M
1) 1 2) 1 3) 1 4) 1
M m M 4m M 2m
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true
17. A conducting rod AC of length 4l is rotated about a point O in a uniform magnetic field B
directed into the plane of the paper AO l and OC 3l . Then
Bl 2 7
1) V A VO 2) VO V A Bl 2
2 2
9
3) V A VC 4 Bl 2 4) VC VO Bl 2
2
18. Assertion: A conical pendulum is revolving in a horizontal circle, angular momentum about
point of suspension is constant
Reason: Torque of tension about point of suspension is zero
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true
4
1) 2 m/s towards left 2)
m/s towards left
3
3) 3 m/s towards left 4) zero
20. A uniform cylinder of mass M and radius R is to be pulled over a step of height a a R
by applying a force F at its centre ' O ' perpendicular to the plane through the axes of the
cylinder on the edge of the step (see figure). The minimum value of F required is:
F
O
R
a
2 2
Ra R a a2
1) Mg 1 2) Mg 1 3) Mg 4) Mg 1 2
R Ra R R
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A particle of mass 100 g is projected at time t = 0 with a speed 20ms1 at an angle 45 to
the horizontal as given in the figure. The magnitude of the angular momentum of the particle
about the starting point at time t = 2s is found to be K kgm 2 / s . The value of K is ______.
(Take g 10ms 2 )
momentum of the particle becomes the same as it was for t = 0 at time t = ______ seconds.
23. A block of mass m 1kg slides with velocity v 6m / s on a frictionless horizontal surface
and collides with a uniform vertical rod and sticks to it as shown. The rod is pivoted about O
and swings as a result of the collision making angle before momentarily coming to rest. If
n
the rod has mass M 2kg , and length l 1m , the value of cos is approximately, then
50
n is: (take g 10m / s 2 )
O
M, l
m
m v
m
i
24. If the ratio of the intensity of two coherent sources is 4 then the value of max will be
imin
25. A ball of mass 160 g is thrown up at an angle of 60 to the horizontal at a speed of 10ms 1 .
The angular momentum of the ball ( in kg m 2 / s ) at the highest point of the trajectory with
respect to the point from which the ball is thrown is nearly g 10ms 2
26. A disc of mass M and radius R is rolling with angular speed on a horizontal plane as
shown in Figure. The magnitude of angular momentum of the disc about the origin O is
M
X
O
27. Consider a body, shown in figure, consisting of two identical balls, each of mass 2 Kg
connected by a light rigid rod of length L = 1m. If an impulse J 10 N Sec is imparted to
the body at one of its ends, what would be its angular velocity?
28. As per the given figure, two blocks each of mass 250 g are connected to a spring of spring
constant 2Nm1 . If both are given velocity v in opposite directions, then maximum
v
elongation of the spring is , then n is
n
250g 250g
29. Electric field at point P (as shown in figure) on the perpendicular bisector of a uniformly
Q
charged thin wire of length L carrying a charge Q is given by . Value of x is. The
x 0 L2
3
distance of the point P from the centre of the rod is a = L.
2
30. Two coils requires 20 minutes and 60 minutes respectively to produce same amount of heat
energy when connected separately to the same source. If they are connected in parallel
arrangement to the same source; the time required to produce same amount of heat by the
combination of coils, will be _______min.
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. The correct IUPAC name of following compound is ________.
OH
1) 2-methylhex-2-en-4-ol 2) 2-methyl-4-hydroxyhex-2-ene
3) 3-hydroxy-5-methylhex-4-ene 4) 5-methylhex-4-en-3-o1
32. Enol content order of (I), (II), (III) is
O O O
(I) (II)
OH
H
CH3CO 2 O
A CH3COOH
2 p 2 p
p P p
P
V0 2V0 V0 2V0
V V
work done w1 work done w2
1) w1 w2 2) w1 w2 3) w1 w2 4) can’t say
42. The enthalpy of combustion of H 2 , cyclohexane C6 H12 and cyclohexene C6 H10 are
-250, -4000 & -3800 KJmol 1 respectively. The heat of Hydrogenation of cyclohexene is
___
1) 50KJmol 1 2) 50KJmol 1 3) 100KJmol 1 4) 100KJmol 1
43. Which of the following is associated with decrease in entropy of system
1) Mixing of ideal gases at constant Temperature and pressure
2) Expansion of an ideal gas
3) Sublimation of Iodine
4) Adsorption of H 2 on Ni surface
44. Which of the following reaction is exothermic
1) CaCO3 CaO CO2 2) PCl5 PCl3 Cl2
3) NaOH HCl NaCl H 2O 4) 2 NH 3 N 2 3 H 2
45. One of the propellent systems used in rocket engines is a mixture of hydrazine (as a fuel)
and hydrogen peroxide (as oxidant). These reactants are called hypergolic, i.e they ignite on
contact. The reaction is N 2 H 4 l 2H 2O2 l N 2 g 4 H 2O g . The enthalpy of above
reaction if H f at 298K of N 2 H 4 l 12 KCal mol 1, H 2O2 l 46 KCal.mol 1 &
H 2O g 58 KCal.mol 1
1) -314 KCal 2) -152KCal 3) +314 KCal 4) +152 KCal
46. 10L of a monoatomic ideal gas at OC &10atm pressure is suddenly released to 1 atm
pressure and the gas expands adiabatically against this constant pressure. The final
temperature and volume of gas respectively are _____
1) T = 175K, 64L 2) T = 110K, V=40L 3) T=153K, V=57L 4) T=165K, V=68L
47. The minimum Temperature at which below process is spontaneous is _____
N 2 F4 g 2 NF2 g
48. The Bond enthalpies of H H , Cl Cl and H Cl are 435, 243 and 431 kJmol 1
respectively. The enthalpy of formation of HCl g is ______
2 2 3 3
O2 , B2 , N 2 , PtCl4 , NiCl4 , Co H 2O 6 , CoF6
53. The total number of isomers (including stereo) possible for C8 H16 which contain six
membered ring is ______
54. The number of fluorides that can be used in swart’s reaction among the following is _____
AgF , Hg 2 F2 , CoF2 , SbF5 , ZnF2 , NaF , CaF2
55. Aniline is treated with NaNO2 HCl at 273 278K to form A which is hydrolysed to ‘B’
(organic) by warming with water. Total number of atoms present in one molecule of B is
______
56. The total number of extensive properties from the following is _____
Volume, molar heat capacity, molarity, E 0cell , Gibbs Free energy change, molar mass, mole
57. The number of path variables among the following is ________
Internal Energy (U), Volume (V), Heat (q), Enthalpy (H)
58. During compression of a spring the work done is 12kJ and 2kJ escaped to surroundings as
heat. The change in internal Energy U inkJ is _______.
59. If 10 moles of an ideal gas expands from 10L to a volume of 100L at 300K under isothermal
& reversible condition, then work w is –xJ. The value of x / 10 is _____
z2
61. The point in the set {Z C : arg } (where C denotes the set of all complex
z 6i 2
numbers) lie on the curve which is a
1) Circle 2) Pair of lines 3) Parabola 4) Hyperbola
62. Let the set of complex number x1, y1 , x2 , y2 , x3 , y3 ,..... denoting the points on the
Z1 Z 2 Z1 Z 2
2) P 2 Q 4 R 1 S 3
3) P 4 Q 2 R 5 S 3
4) P 2 Q 4 R 3 S 5
1 2 2
1) tan 1 2) sin 1 3) sin 1 4) tan 1 2
2 3 5
1
67. If z 0 be a complex number such that z 2 , then the maximum value of z is
z
1) 2 2) 1 3) 2 1 4) 2 1
a b c
68. If a, b, c, a1, b1, c1 are non-zero complex number satisfying 1 i and
a1 b1 c1
a1 b1 c1 a2 b2 c2
0 , then is equal to
a b c a12 b12 c12
1) -2i 2) 2+2i 3) 2 4) 2-2i
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 19
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
69. Let z1 2 3i and z2 3 4i . The set
2
S z C : z z1 z z2
2
z1 z2
2
represents
1) straight line with the sum of its intercepts on the coordinate axes equals – 18
2) hyperbola with eccentricity 2
3) hyperbola with the length of transverse axis 7
4) straight line with the sum of its intercepts on the coordinate axes equals 14
70. Let us define the length of a vector ai bj ck as a b c . This definition coincides
71. Let z1 and z2 be two complex numbers such that z1 z2 5 and z13 z23 20 15i. Then
1) 25 3 2) 75 3) 15 15 4) 30 3
72. Let A, B, C be three sets of complex numbers as defined below:
A z : Im z 1 , B z : z 2 i 3 , C z : Re 1 i z 2 . The number of elements in
the set A B C is
1) 0 2) 1 3) 2 4) Infinite
73. The least value of z where z is complex number which satisfies the inequality
z 3 z 1
exp ln 2 log 2 5 7 9i , i 1 , is equal to :
z 1
1) -2 2) 5 3) 2 4) 3
z1 1 z2 1 z3 1 z4 1 . Then z1 z2 z3 z4 is
1) 4 2) 64 3) 256 4) Not Defined
75. Domain of f x cos sin x log x x , where {.} denotes the fractional part, is
1) [1, ) 2) 0, 2 [1, ) 3) 0, 1 4) 0,1
2
76. The complex number z 1 i is rotated through an angle 3 / 2 in anti-clockwise direction
about the origin and stretched by additional 2 units, then the new complex number is
1) 2 2i 2) 2 2i 3) 2 2i 4) 2 (1-i)
77. Let a 2 b2 be two non-zero real numbers. Then the number of elements in the set
X z C : Re az 2 bz a and Re bz 2 az b is equal to
1) 3 2) 0 3) 1 4) Infinite
78. If the shortest distance between the lines
L1 : r 2 i 1 3 j 3 4 k , R
m
L2 : r 2 1 i 3 1 j 5 k , R is , where gcd m, n 1, then the value
n
of m n equals
1) 384 2) 387 3) 390 4) 377
a ib
79. The expression tan i log reduces to
a ib
ab 2ab ab 2ab
1) 2) 3) 4)
a 2 b2 a 2 b2 a 2 b2 a 2 b2
1 1 1 1 1 1
1) 2, 2) , 3) 2, 4) ,
2 2 2 4 2 2 2 2
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81.
Let S z C : z 2 z 0 . Then Re z Im z is equal to ______.
zS
x
82. Let f x , x 0 be a non-negative continuous function and F x f t dt , x 0 . If for
0
some c 0, f x cF x for all x 0 , then f 2024 f 2025 ____
1 z
83. Let z a ib, b 0 be complex numbers satisfying z 2 z 2 . Then the least value of
n
n N , such that z n z 1 , is equal to ________.
5 /4 cos x sin x
84. The value of the integral 3 dx is _______.
4 x
1 e 4
85. Let ‘z’ be a complex number satisfying iz 2 3 and if the locus of the point z i z 3 is
a circle having center at z0 and the radius ‘r’ then the value of z02 2r 2 is where [.]
represents G.I.F.
86. Let S be the set of values of , for which the system of equations
6 x 3 y 3 z 4 2 ,
2 x 6 y 4 z 1,
3 x 2 y 3 z
87. If 3 x 2 yi and x2 y 4i are conjugate of each other, then the values of x y , where
x, y are real, is _______
2 sin x dy m
88. If y y x and cos x , y 0 1, then y / 2 is equal to , where
y 1 dx n
X
1 1 1
1 k
3
, and k R. If a1
2
a2
2 2 2
3
b1 b22 and k 2 1 b22 2b1b2 , then the
value of k is _______.