0% found this document useful (0 votes)
263 views24 pages

SC Thermodynamics e

The document outlines the important instructions and structure for the JEE-MAIN exam conducted by Sri Chaitanya IIT Academy on November 9, 2024. It details the marking scheme, types of questions, and the subjects covered, which include Physics, Chemistry, and Mathematics. Additionally, it specifies the rules regarding materials allowed in the examination hall and the procedure for submitting the answer sheet.

Uploaded by

b5gw48286j
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
263 views24 pages

SC Thermodynamics e

The document outlines the important instructions and structure for the JEE-MAIN exam conducted by Sri Chaitanya IIT Academy on November 9, 2024. It details the marking scheme, types of questions, and the subjects covered, which include Physics, Chemistry, and Mathematics. Additionally, it specifies the rules regarding materials allowed in the examination hall and the procedure for submitting the answer sheet.

Uploaded by

b5gw48286j
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 24

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 09-11-2024
Time: 09.00Am to 12.00Pm RPTM-13/17 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.^
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown belo w

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
09-11-2024_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee-Main_RPTM-13/17_Test Syllabus
PHYSICS : Rigid body Dynamics-2: Conservation of angular momentum ; Collision of point masses with rigid
bodies, Rolling with and without slipping, Toppling.
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)
CHEMISTRY : Thermodynamics-I: Zeroth law, first law, Internal Energy, Heat, Work Energy, Relation b/w H and
U, Application of first law in different types of processes, Polytropic process, limitations of first
law, Problems based on different type of processes & applications of 1st law
Thermodynamics-II: Carnot cycle, Clausius inequality, Entropy change in chemical reaction, third
law of thermodynamics, Gibbs free energy and its applications
Thermochemistry: Introduction, Different type of Heat of reactions, Resonance energy, Born-
Haber cycle, Kirchoff's law, relation between heat of solution and heat of hydration.
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)
MATHEMATICS : Complex Numbers
COMPLETE RPTM-13 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM13+10Q CUMULATIVE)

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 2


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A solid uniform disc of mass m rolls without slipping down a fixed inclined plane with an
acceleration a. The frictional force on the disc due to surface of the plane is:
1) 2 ma 2) 3/2 ma 3) ma 4) 1/2 ma
2. STATEMENT-1: An astronaut in an orbiting space station above the Earth experiences
weightlessness.
STATEMENT-2 : An object moving around the Earth under the influence of Earth's
gravitational force is in a state of 'free-fall
1) Statement -1 is true, Statement -2 is true; Statement -2 is a correct explanation for
Statement -1
2) Statement -1 is true, Statement -2 is true; Statement -2 is not a correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true.
3. The temperature of equal masses of three different liquids A,B and C are 120 C ,190 C and
280 C respectively. The temperature when A and B are mixed is 160 C and when B and C
are mixed is 230 C . The temperature when A and C are mixed is
1) 18.20 C 2) 220 C 3) 20.20 C 4) 25.20 C
4. Two particles of equal mass m at A and B are connected by a rigid light rod AB lying on a
smooth horizontal table. An impulse J is applied at A in the plane of the table and
perpendicular at AB. Then the velocity of particle at A is:
J J 2J
1) 2) 3) 4) Zero
2m m m
5. A uniform rod AB of length L and mass M is lying on a smooth table. A small particle of
mass m strike the rod with a velocity v0 at point C a distance x from the centre O. The
particle comes to rest after collision. The value of x, so that point A of the rod remains
stationary just after collision,:

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 3


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

1) L / 3 2) L / 6 3) L / 4 4) L / 12
6. A uniform rod of mass M is hinged at its upper end. A particle of mass m moving
horizontally strikes the rod at its mid point elastically. If the particle comes to rest after
collision find the value of M/m =?

1) 3/4 2) 4/3 3) 2/3 4) none


7. A uniform solid disc of mass 1 kg and radius 1m is kept on a rough horizontal surface. Two
forces of magnitude 2N and 4N have been applied on the disc as shown in the figure. Linear
acceleration of the centre of mass of the disc is if there is no slipping.
2N

4N

1) 4 m/s2 2) 2 m/s2 3) 1 m/s2 4) zero


8. Each situation in column I gives graph of a particle moving in circular path. The variables
 , and t represent angular speed (at any time t) , angular displacement (in time t) and time
respectively. Column II gives certain resulting interpretation. Match the graphs in column I
with Statements in column II and indicate your answer by darkening appropriate bubbles in
the 4  4 matrix given in the OMR.
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 4
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

Column-I Column-II
A) P) Angular acceleration of particle is uniform


2
B) Q) Angular acceleration of particle is non-
uniform


2 -  graph

C) R) Angular acceleration of particle is directly
proportional to t.

t
 - t graph
 Angular acceleration of particle is directly
D) S)
proportional to  .

2
t
 - t graph
2

1) A-> S, B -> P, C->P, D-> r 2) A-> P, B -> Q, C->P, D-> Q


3) A-> R, B -> P, C->Q, D-> P 4) A-> R, B -> Q, C->P, D-> Q
9. A uniform circular disc of mass m and radius a is rotating with constant angular velocity 
in a horizontal plane about the vertical axis passing through its centre and perpendicular to
a
its plane. A particle P of mass 2m is placed gently on the disc at a point, distant from the
2
centre. If the particle does not slip on the disc, find the new angular velocity of the rotating
system.
  
1)  2) 3) 4)
2 3 4
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 5
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
10. A circular platform is free to rotate in a horizontal plane about a vertical axis passing
through its centre. A tortoise is sitting at the edge of the platform. Now, the platform is given
an angular velocity 0 . When the tortoise move along a chord of the platform with a
constant velocity (w.r.t the platform), the angular velocity of the platform   t  will vary
with time t as

1) 2)

3) 4)
11. A solid cylindrical wheel of mass M and radius R is pulled by a force F applied to the centre
of the wheel at 37 above the horizontal. If the wheel is to roll without slipping, what is the
maximum value of F ?. The coefficients of static and kinetic friction are  s  0.40 and
3
 k  0.30 and sin 37 
5
1) 0.79 Mg 2) 0.98 Mg 3) 0.6 Mg 4) 0.49 Mg
12. Initial angular velocity of a circular disc of mass M is 1 . Then, two small spheres of mass

m are attached gently to two diametrically opposite points on the edge of the disc. What is

the final angular velocity of the disc?

M m M m  M   M 
1)   1 2)   1 3)   1 4)   1
 M   m   M  4m   M  2m 

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 6


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
13. A uniform rod AB of mass 3m and length 2l is lying at rest on a smooth horizontal table
with a smooth vertical axis through the end A. A particle of mass 2m moves with speed 2u
across the table and strikes the rod at is mid-point C. If the impact is perfectly elastic, then
find the speed of the particle after impact if it strikes the rod normally and comes back.
7u 2u u 4u
1) 2) 3) 4)
3 3 3 3
14. A cubical block of side 30cm is placed on a rough horizontal surface of coefficient of
friction 0.6. At what minimum height above the ground, a horizontal force must be applied
on the block so that it starts toppling before slipping?

1) h  25cm 2) h  23cm 3) h  20cm 4) h  15cm


15. In the circuit shown in figure, the charge on the 5  F capacitor will be

1) 4.5C 2) 9C 3) 15C 4) None of these


16. Assertion: A ball rolled down a rough inclined making an angle  as shown. Kinetic energy
of ball at bottom is mgh.
Reason: Work done by friction is zero

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 7


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P


1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true
17. A conducting rod AC of length 4l is rotated about a point O in a uniform magnetic field B
directed into the plane of the paper AO  l and OC  3l . Then

Bl 2 7
1) V A  VO  2) VO  V A  Bl 2
2 2
9
3) V A  VC  4 Bl 2 4) VC  VO  Bl 2
2
18. Assertion: A conical pendulum is revolving in a horizontal circle, angular momentum about
point of suspension is constant
Reason: Torque of tension about point of suspension is zero
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 8


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
3
19. In the figure shown a slab of refractive index is moved towards a stationary observer at
2
2m/s. A point ‘O’ is observed by the observer with the help of paraxial rays through the slab.
Both ‘O’ and observer lie in air. The velocity with which the image will move is

4
1) 2 m/s towards left 2)
m/s towards left
3
3) 3 m/s towards left 4) zero
20. A uniform cylinder of mass M and radius R is to be pulled over a step of height a  a  R 
by applying a force F at its centre ' O ' perpendicular to the plane through the axes of the
cylinder on the edge of the step (see figure). The minimum value of F required is:
F

O
R
a

2 2
 Ra  R  a a2
1) Mg 1    2) Mg    1 3) Mg 4) Mg 1  2
 R   Ra R R
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

21. A particle of mass 100 g is projected at time t = 0 with a speed 20ms1 at an angle 45 to
the horizontal as given in the figure. The magnitude of the angular momentum of the particle

about the starting point at time t = 2s is found to be K kgm 2 / s . The value of K is ______.

(Take g  10ms 2 )

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 9


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

22. A particle of mass ‘m’ is moving in time ‘t’ on a trajectory given by



r  10 t 2 i  5   t  5  j . Where  and  are dimensional constants. The angular

momentum of the particle becomes the same as it was for t = 0 at time t = ______ seconds.
23. A block of mass m  1kg slides with velocity v  6m / s on a frictionless horizontal surface
and collides with a uniform vertical rod and sticks to it as shown. The rod is pivoted about O
and swings as a result of the collision making angle  before momentarily coming to rest. If
n
the rod has mass M  2kg , and length l  1m , the value of cos  is approximately, then
50
n is: (take g  10m / s 2 )
O

M, l

m

m v
m

i
24. If the ratio of the intensity of two coherent sources is 4 then the value of max will be
imin

25. A ball of mass 160 g is thrown up at an angle of 60 to the horizontal at a speed of 10ms 1 .

The angular momentum of the ball ( in kg m 2 / s ) at the highest point of the trajectory with


respect to the point from which the ball is thrown is nearly g  10ms 2 
26. A disc of mass M and radius R is rolling with angular speed  on a horizontal plane as
shown in Figure. The magnitude of angular momentum of the disc about the origin O is

 x / y  MR 2 then x + y is (x any y are least possible integers)


Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 10
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
Y


M
X
O
27. Consider a body, shown in figure, consisting of two identical balls, each of mass 2 Kg
connected by a light rigid rod of length L = 1m. If an impulse J  10 N  Sec is imparted to
the body at one of its ends, what would be its angular velocity?

28. As per the given figure, two blocks each of mass 250 g are connected to a spring of spring
constant 2Nm1 . If both are given velocity v in opposite directions, then maximum
v
elongation of the spring is , then n is
n

250g 250g

29. Electric field at point P (as shown in figure) on the perpendicular bisector of a uniformly
Q
charged thin wire of length L carrying a charge Q is given by . Value of x is. The
x 0 L2
3
distance of the point P from the centre of the rod is a = L.
2

30. Two coils requires 20 minutes and 60 minutes respectively to produce same amount of heat
energy when connected separately to the same source. If they are connected in parallel
arrangement to the same source; the time required to produce same amount of heat by the
combination of coils, will be _______min.
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. The correct IUPAC name of following compound is ________.
OH

1) 2-methylhex-2-en-4-ol 2) 2-methyl-4-hydroxyhex-2-ene
3) 3-hydroxy-5-methylhex-4-ene 4) 5-methylhex-4-en-3-o1
32. Enol content order of (I), (II), (III) is
O O O

(I) (II) (III)


1) I>II>III 2) I<II<III 3) I>II<III 4) I<II>III
33.
  
O O NH NH O NH

(I) (II) (III)


Stability order of carbocations is _______
1) I>II>III 2) II>III>I 3) III>II>I 4) II>I>III
34. Consider

(I) (II)

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 12


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
A) Resonance energy of I>II
B) Resonance energy per ring of I>II
C) Number of resonating structures of I>II
D) Both I and II have same extent of delocalization of  electrons
Correct combination is ________
1) A,B,C only 2) A,B,C,D 3) A and C only 4) A,C,D only
35. A) All alkyl halides including Fluorides on reduction with zinc and dilute hydrochloric acid
give alkanes
B) Rate of reaction of halogens with alkanes is F2  Cl2  Br2  I 2

C) Rate of replacement of hydrogens of alkanes with halogens is 3  2  1


D) Fluorination of alkanes is very slow process and Iodination is too violent to be controlled
correct combination is
1) A,B,C,D 2) A,B,C 3) B,C 4) B,C,D
36.
COOH

OH

H
  CH3CO 2 O 
 A  CH3COOH

Name of the Compound ‘A’ is


1) Salol 2) Oil of winter green
3) Aspirin 4) Salicylic acid
AlH  iBu 
CN 
2  product ?
2.H 2O
37.
CN CH2-NH2
1) 2)
COOH CHO
3) 4)
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 13
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
38. Assertion (A): There is a natural asymmetry between converting work to heat & heat to
work.
Reason (R): No process is possible in which the sole result is the absorption of heat from a
reservoir and its complete conversion into work
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true
39. Assertion: Work done in a reversible isothermal expansion of an ideal gas is
v
2.303nRT log 2
v1
Reason: Work done in a reversible isothermal expansion of an ideal gas is negative
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true but R is NOT the correct explanation of A.
3) A is true but R is false
4) A is false but R is true
40. Match List – I with List – II
LIST – I LIST – II
1) Spontaneous process I) H  0
2) Process with P  0 & T  0 II) Gr , p  0

3) H reaction III) Isothermal & isobaric process


4) Exothermic process IV) Bond Energies of molecules in reactions –
Bond Energies of product molecules
1) 1  III ,2  II ,3  IV ,4  I 2) 1  II ,2  III ,3  IV ,4  I
3) 1  II ,2  III ,3  I ,4  IV 4) 1  II ,2  I ,3  III ,4  IV

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 14


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
41.

2 p 2 p
p P p
P
V0 2V0 V0 2V0

V V
work done  w1 work done  w2
1) w1  w2 2) w1  w2 3) w1  w2 4) can’t say
42. The enthalpy of combustion of H 2 , cyclohexane  C6 H12  and cyclohexene  C6 H10  are
-250, -4000 & -3800 KJmol 1 respectively. The heat of Hydrogenation of cyclohexene is
___
1) 50KJmol 1 2) 50KJmol 1 3) 100KJmol 1 4) 100KJmol 1
43. Which of the following is associated with decrease in entropy of system
1) Mixing of ideal gases at constant Temperature and pressure
2) Expansion of an ideal gas
3) Sublimation of Iodine
4) Adsorption of H 2 on Ni surface
44. Which of the following reaction is exothermic
1) CaCO3  CaO  CO2 2) PCl5  PCl3  Cl2
3) NaOH  HCl  NaCl  H 2O 4) 2 NH 3  N 2  3 H 2
45. One of the propellent systems used in rocket engines is a mixture of hydrazine (as a fuel)
and hydrogen peroxide (as oxidant). These reactants are called hypergolic, i.e they ignite on
contact. The reaction is N 2 H 4  l   2H 2O2  l   N 2  g   4 H 2O  g  . The enthalpy of above
reaction if H  f at 298K of N 2 H 4  l   12 KCal mol 1, H 2O2  l   46 KCal.mol 1 &

H 2O  g   58 KCal.mol 1
1) -314 KCal 2) -152KCal 3) +314 KCal 4) +152 KCal

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 15


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

46. 10L of a monoatomic ideal gas at OC &10atm pressure is suddenly released to 1 atm
pressure and the gas expands adiabatically against this constant pressure. The final
temperature and volume of gas respectively are _____
1) T = 175K, 64L 2) T = 110K, V=40L 3) T=153K, V=57L 4) T=165K, V=68L
47. The minimum Temperature at which below process is spontaneous is _____
N 2 F4  g   2 NF2  g 

H rxn  85 KJ and S rxn  200 JK 1

1) 152 K 2) 152 C 3) 425 C 4) 850 C

48. The Bond enthalpies of H  H , Cl  Cl and H  Cl are 435, 243 and 431 kJmol 1
respectively. The enthalpy of formation of HCl  g  is ______

1) 226KJmol 1 2) 92KJmol 1 3) 247KJmol 1 4) 626KJmol 1


49. Which of the following is true for adiabatic expansion of an ideal gas
1) U  0 2) U  0 3) U  0 4) More data required
50. For the reaction 2 H 2  g   O2  g   2 H 2O  g  , H  571KJ , Bond Energy of

H  H  435KJ & O  O  498KJ . The average Bond Energy of  O  H  bond


(in kJ) using the given data is _______
1) 484kJ 2) -484kJ 3) 271kJ 4) -271 kJ
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. Number of paramagnetic species among the following is ________

2 2  3 3
O2 , B2 , N 2 , PtCl4  ,  NiCl4  , Co  H 2O 6  , CoF6  

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 16


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
52. No. of stereo isomers possible for Co  glyc 3 is _______

glyc= H2N CH2 C O-

53. The total number of isomers (including stereo) possible for C8 H16 which contain six
membered ring is ______
54. The number of fluorides that can be used in swart’s reaction among the following is _____
AgF , Hg 2 F2 , CoF2 , SbF5 , ZnF2 , NaF , CaF2
55. Aniline is treated with NaNO2  HCl at 273  278K to form A which is hydrolysed to ‘B’
(organic) by warming with water. Total number of atoms present in one molecule of B is
______
56. The total number of extensive properties from the following is _____

Volume, molar heat capacity, molarity, E 0cell , Gibbs Free energy change, molar mass, mole
57. The number of path variables among the following is ________
Internal Energy (U), Volume (V), Heat (q), Enthalpy (H)
58. During compression of a spring the work done is 12kJ and 2kJ escaped to surroundings as
heat. The change in internal Energy U  inkJ  is _______.
59. If 10 moles of an ideal gas expands from 10L to a volume of 100L at 300K under isothermal
& reversible condition, then work w is –xJ. The value of x / 10 is _____

 log10e  2.3 & R  8.3JK 1mol 1 


60. The difference between H and U  H  U  when the combustion of one mole of
heptane (l) is carried out at a temperature T is equal to  xRT . Then x  ?

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 17


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

 z2  
61. The point in the set {Z  C : arg    } (where C denotes the set of all complex
 z  6i  2
numbers) lie on the curve which is a
1) Circle 2) Pair of lines 3) Parabola 4) Hyperbola
62. Let the set of complex number  x1, y1  ,  x2 , y2  ,  x3 , y3  ,..... denoting the points on the

complex plane satisfying  xn 1, yn 1    


3 xn  yn , 3 yn  xn for n  1,2,3,..... suppose

 x100 , y100    2,4 then the value of x1  y1 is equal to

1) 299 2) 298 3) 297 4) 296

63. Let z  x  iy be a non-zero complex number such that z 2  i z 2 , where i   1 , then z


lies on the
1) imaginary axis 2) real axis 3) line, y  x 4) line, y   x
64. Consider Z1 and Z 2 as two non-zero complex numbers such that

Z1  Z 2  Z1  Z 2

Statement 1: amp  Z1   amp  Z 2   0


Statement 2: The complex number Z1 and Z 2 are collinear with origin
1) Statement 1 is True, statement 2 is True; statement 2 is a correct explanation for
Statement 1
2) Statement 1 is True, statement 2 is True; statement 2 is not a correct explanation for
statement 1
3) Statement 1 is True, statement 2 is False
4) Statement 1 is False, statement 2 is True
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 18
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
65. Let the straight line y  2 x touch a circle with center  0,   ,   0, and radius r at a point A1 .
Let B1 be the point on the circle such that the line segment A1B1 is a diameter of the circle.
Let   r  5  5 . Match each entry in List-I to the correct entry in List-II.
List-I List-II
P)  equals 1)  2,4 
Q) r equals 2) 5
R) A1 equals 3)  2, 6 
S) B1 equals 4) 5
5)  2,4 
The correct option is
1)  P    4  Q    2  R   1 S    3

2)  P    2  Q    4  R   1 S    3

3)  P    4  Q    2  R    5  S    3 

4)  P    2  Q    4  R    3  S    5 

66. If 1  2 2i    a  ib  , where a  0, b  0, then Arg  b  ia  equals

 1   2  2
1) tan 1   2) sin 1   3) sin 1   4) tan 1 2
 2  3   5
1
67. If z  0 be a complex number such that z   2 , then the maximum value of z is
z

1) 2 2) 1 3) 2 1 4) 2 1
a b c
68. If a, b, c, a1, b1, c1 are non-zero complex number satisfying    1  i and
a1 b1 c1

a1 b1 c1 a2 b2 c2
   0 , then   is equal to
a b c a12 b12 c12
1) -2i 2) 2+2i 3) 2 4) 2-2i
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 19
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
69. Let z1  2  3i and z2  3  4i . The set

 2
S  z  C : z  z1  z  z2
2
 z1  z2
2
 represents
1) straight line with the sum of its intercepts on the coordinate axes equals – 18
2) hyperbola with eccentricity 2
3) hyperbola with the length of transverse axis 7
4) straight line with the sum of its intercepts on the coordinate axes equals 14

70. Let us define the length of a vector ai  bj  ck as a  b  c . This definition coincides

with the usual definition of length of a vector ai  bj  ck if


1) all three of a,b,c are zero only 2) atleast two of a, b and c are zero
3) any one of a, b and c is zero 4) a + b + c=0

71. Let z1 and z2 be two complex numbers such that z1  z2  5 and z13  z23  20  15i. Then

z14  z24 equals

1) 25 3 2) 75 3) 15 15 4) 30 3
72. Let A, B, C be three sets of complex numbers as defined below:

 
A   z : Im z  1 , B   z : z  2  i  3 , C  z : Re 1  i  z  2 . The number of elements in

the set A  B  C is
1) 0 2) 1 3) 2 4) Infinite
73. The least value of z where z is complex number which satisfies the inequality

  z  3 z  1 
exp  ln 2   log 2 5 7  9i , i  1 , is equal to :
 z 1 
 
1) -2 2) 5 3) 2 4) 3

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 20


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
74. Let A  z1  , B  z2  , C  z3  , D  z4  be vertices of a square, satisfy

z1  1  z2  1  z3  1  z4  1 . Then  z1  z2  z3  z4  is
1) 4 2) 64 3) 256 4) Not Defined

75. Domain of f  x   cos  sin x   log x  x , where {.} denotes the fractional part, is

 
1) [1,  ) 2)  0, 2   [1,  ) 3)  0,   1 4)  0,1
 2
76. The complex number z  1  i is rotated through an angle 3 / 2 in anti-clockwise direction
about the origin and stretched by additional 2 units, then the new complex number is

1)  2  2i 2) 2  2i 3) 2  2i 4) 2 (1-i)

77. Let a 2  b2 be two non-zero real numbers. Then the number of elements in the set

   
X  z  C : Re az 2  bz  a and Re bz 2  az  b is equal to  
1) 3 2) 0 3) 1 4) Infinite
78. If the shortest distance between the lines

L1 : r   2    i  1  3  j   3  4  k ,   R
 m
L2 : r  2 1    i  3 1    j   5    k ,   R is , where gcd  m, n   1, then the value
n
of m  n equals
1) 384 2) 387 3) 390 4) 377
  a  ib  
79. The expression tan i log    reduces to
  a  ib  
ab 2ab ab 2ab
1) 2) 3) 4)
a 2  b2 a 2  b2 a 2  b2 a 2  b2

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 21


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P
80. Let S   z  x  iy : z  1  i  z , z  2, z  i  z  1  . Then the set of all values of x, for

which w  2 x  iy  S for some y  R , is

 1   1 1  1  1 1 
1)   2, 2)   , 3)   2,  4)   ,
 2 2   2 4   2  2 2 2 
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

81. 
Let S  z  C : z 2  z  0 . Then    Re  z   Im  z   is equal to ______.
zS
x
82. Let f  x  , x  0 be a non-negative continuous function and F  x    f  t  dt , x  0 . If for
0
some c  0, f  x   cF  x  for all x  0 , then f  2024   f  2025   ____
1 z
83. Let z  a  ib, b  0 be complex numbers satisfying z 2  z  2 . Then the least value of
n
n  N , such that z n   z  1 , is equal to ________.

 
5 /4 cos x  sin x 

84. The value of the integral 3  dx is _______.
  
4   x   
 1  e 4  
85. Let ‘z’ be a complex number satisfying iz  2  3 and if the locus of the point z  i  z  3  is

a circle having center at z0 and the radius ‘r’ then the value of  z02  2r 2  is where [.]
 
represents G.I.F.
86. Let S be the set of values of  , for which the system of equations

6 x  3 y  3 z  4 2 ,
2 x  6 y  4 z  1,
3 x  2 y  3 z  

has no solution. Then 12   is equal to _______.


S
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 22
SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

87. If 3  x 2 yi and x2  y  4i are conjugate of each other, then the values of x  y , where
x, y are real, is _______
2  sin x  dy  m
88. If y  y  x  and     cos x , y  0   1, then y  / 2  is equal to , where
y  1  dx  n

G.C.D of (m,n)=1, then n m is equal to_____


a  b 
89. Let A   1  and B   1  be two 2  1 matrices with real entries such that A  XB, where
 a2   b2 

X
1 1 1
1 k 
3 
, and k  R. If a1
2
 a2
2 2 2
3
   
 b1  b22 and k 2  1 b22  2b1b2 , then the

value of k is _______.

90. If the quadratic polynomial, y   cot   x 2  2   1


sin  x  tan  ,    0, 2  , takes
2
 5 
negative values for all x  R and the value of    ,  , then the value of  is ______.
  

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 23


SRI CHAITANYA IIT ACADEMY, INDIA 09-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-13/17_Q.P

Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 24

You might also like