Revison Date 31/10/2017 Revison Issue 1

SAFETY DATA SHEET

KG1 - H.D. Cleaner & Degreaser

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name KG1 - H.D. Cleaner & Degreaser

Product number 656264IP

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Heavy Duty, Alkaline Liquid Hard Surface Cleaner.

1.3. Details of the supplier of the safety data sheet

Supplier Reza Chemical Industries
P.O. Box 1555
Jeddah 21425
Alireza Tower
Madina Road
Tel: Head Office 012 657 2877
Fax: Head Office 012 657 2832
Tel: Factory 012 637 3910
Fax: Factory 012 637 3876
E-Mail: [email protected]

1.4. Emergency telephone number

Emergency telephone Techincal Advice +966 12 637 3910 Ext. 2451/2452
(Office hours only: 7:30am to 4:30pm Sun to Thurs)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318

Environmental hazards Not Classified

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H314 Causes severe skin burns and eye damage.

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Precautionary statements P102 Keep out of reach of children.

P260 Do not breathe spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P315 Get immediate medical advice/ attention.
P501 Dispose of contents/ container in accordance with local regulations.

Contains SODIUM METASILICATE, SODIUM HYDROXIDE

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM DODECYL BENZENE SULPHONATE 3-5%

CAS number: 68411-30-3 EC number: 270-115-0

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Chronic 3 - H412

SODIUM METASILICATE 3-5%

CAS number: —

Classification
Skin Corr. 1B - H314
Eye Dam. 1 - H318

2-BUTOXYETHANOL 3-5%
CAS number: 111-76-2 EC number: 203-905-0

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319

SODIUM CUMENE SULPHONATE 3-5%

CAS number: 15763-76-5 EC number: 239-854-6

Classification
Eye Irrit. 2 - H319

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SODIUM HYDROXIDE 0.1-1%

CAS number: 1310-73-2 EC number: 215-185-5 REACH registration number: 01-
2119457892-27-xxxx
Spec Conc Limits :- Skin Corr. 1A (H314) >= 5 %, Skin Corr. 1B (H314) >=2% <5 %, Skin Irrit. 2 (H315) >=0.5%<2%, Eye
Irrit. 2 (H319) >=0.5% <2%

Classification
Met. Corr. 1 - H290
Skin Corr. 1A - H314
Eye Dam. 1 - H318

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Unlikely route of exposure as the product does not contain volatile substances. If spray/mist
has been inhaled, proceed as follows. Move affected person to fresh air and keep warm and
at rest in a position comfortable for breathing.

Ingestion Do not induce vomiting. Give plenty of water to drink. Get medical attention immediately.

Skin contact Wash with plenty of water. Get medical attention promptly if symptoms occur after washing.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Get medical attention immediately. Continue to rinse.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Irritation of nose, throat and airway.

Ingestion May cause chemical burns in mouth and throat.

Skin contact Burning pain and severe corrosive skin damage. May cause serious chemical burns to the
skin.

Eye contact Severe irritation, burning and tearing. Prolonged contact causes serious eye and tissue
damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Thermal decomposition or combustion products may include the following substances:
Irritating gases or vapours.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing, gloves, eye and face protection. For personal protection, see
Section 8.

6.2. Environmental precautions

Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the
Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Small Spillages: Flush away spillage with plenty of water. Large Spillages: Contain and
absorb spillage with sand, earth or other non-combustible material. Collect and place in
suitable waste disposal containers and seal securely.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Wear protective clothing, gloves, eye and face protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep only in the original container in a cool, well-ventilated place. Store away from the
following materials: Oxidising materials.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

Usage description See Product Information Sheet & Label for detailed use of this product.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
2-BUTOXYETHANOL
Long-term exposure limit (8-hour TWA): WEL 25 ppm 123 mg/m³
Short-term exposure limit (15-minute): WEL 50 ppm 246 mg/m³
Sk
SODIUM HYDROXIDE
Short-term exposure limit (15-minute): WEL 2 mg/m³
WEL = Workplace Exposure Limit
Sk = Can be absorbed through skin.

8.2. Exposure controls

Protective equipment

Appropriate engineering Not relevant.

controls

Eye/face protection The following protection should be worn: Chemical splash goggles or face shield.

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Hand protection Wear protective gloves. (Household rubber gloves.)

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Respiratory protection Respiratory protection not required.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Clear. Yellow.

Odour Faint Solvent.

pH pH (concentrated solution): 13.45

Melting point -2°C

Initial boiling point and range 102°C @ 760 mm Hg

Flash point Boils without flashing.

Relative density 1.084 @ 20°C

Solubility(ies) Soluble in water.

9.2. Other information

Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Reactions with the following materials may generate heat: Strong acids.

10.2. Chemical stability

Stability No particular stability concerns.

10.3. Possibility of hazardous reactions

Possibility of hazardous See sections 10.1,10.4 & 10.5
reactions

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid Strong acids. Aluminium, Tin, Zinc and their alloys.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects We have not carried out any animal testing for this product. Any ATE figures quoted below are
from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate)
Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer.

Acute toxicity - oral

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Notes (oral LD₅₀) Based on available data the classification criteria are not met.

ATE oral (mg/kg) 14,391.37

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

ATE dermal (mg/kg) 27,312.72

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

ATE inhalation (vapours mg/l) 275.58

SECTION 12: Ecological Information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Toxicity We have not carried out any Aquatic testing, therefore we have no Aquatic Toxicity Data
specifically for this product. The Aquatic Toxicity Data, where provided by the raw material
manufacturer for ingredients with aquatic toxicity, can be made available on request.

12.2. Persistence and degradability

Persistence and degradability Sequestrant is readily degraded during biological effluent treatment processes.

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil

Mobility Not known.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Discharge used solutions to drain. Small amounts (less than 5 Litres) of unwanted product
may be flushed with water to sewer. Larger volumes must be sent for disposal by approved
waste contractor. Rinse out empty container with water and consign to normal waste.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3266

UN No. (IMDG) 3266

UN No. (ICAO) 3266

14.2. UN proper shipping name

Proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (disodium trioxosilicate)
(ADR/RID)

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Proper shipping name (IMDG) CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (disodium trioxosilicate)

Proper shipping name (ICAO) CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (disodium trioxosilicate)

14.3. Transport hazard class(es)

ADR/RID class Class 8: Corrosive substance.

ADR/RID label 8

IMDG class Class 8: Corrosive substances.

ICAO class/division Class 8: Corrosive substances.

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

EmS F-A, S-B

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not relevant. for a packaged product.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Safety Data Sheet prepared in accordance with REACH Commission Regulation (EU) No
2015/830 (which amends Regulation (EC) No 453/2010 & 1907/2006).
The product is as classified under GHS/CLP- Regulation (EC) No 1272/2008 classification,
labelling & packaging of substances & mixtures.
Ingredients are listed with classification under GHS/CLP - Regulation (EC) No 1272/2008
classification, labelling & packaging of substances & mixtures.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out as not applicable as this product is a mixture.

SECTION 16: Other information

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Abbreviations and acronyms PBT: Persistent, Bioaccumulative and Toxic substance.

used in the safety data sheet vPvB: Very Persistent and Very Bioaccumulative.
ATE: Acute Toxicity Estimate.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
IMDG: International Maritime Dangerous Goods.
ICAO-TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
GHS: Globally Harmonized System.
Spec Conc Limits = Specific Concentration Limits.

Classification abbreviations Acute Tox. = Acute toxicity

and acronyms Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Eye Dam. = Serious eye damage
Eye Irrit. = Eye irritation
Met. Corr. = Corrosive to metals
Skin Corr. = Skin corrosion
Skin Irrit. = Skin irritation

Key literature references and Material Safety Data Sheet, Miscellaneous manufacturers. CLP Class - Table 3.1 List of
sources for data harmonised classification and labeling of hazardous substances. ECHA - C&L Inventory
database.

Classification procedures Calculation Method.

according to Regulation (EC)
1272/2008

Revision comments Safety Data Sheet amended in accordance with REACH Commission Regulation (EU) No
2015/830 amendment. (Changes to Sections 2,3,15&16)

Revision date 31/10/2017

Revision Issue 1

SDS status The Hazard Statements listed below in this Section No 16 relate to the Raw Materials
(Ingredients) in the Product (as listed in Section 3) and NOT the product itself. For the Hazard
Statements relating to this Product see Section 2.

Hazard statements in full H290 May be corrosive to metals.

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.

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