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202'!_[ 11 29 1 -
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CHE MIS'f RY (55)

Time: 3 Hrs. (7 Pages ) Ma x. Ma rks : 70 J

General Instruction s :
- .

The question paper is divided into four sections.

(1) . Section A: Q. No. 1 contains Ten multiple choice type of questions
carrying One mark each. Only the first attempt will be
;
considered for evaluation.
Q. No. 2 contains Eight very short answer ty pe of
questfons car.ry jng One mark each.
(2) S ectio n, B: Q. No. 3 to Q. No. 14 are Twelve short answer type OJ
questions carrying Two marks each. (Attempt any Eight)
(3) Section C: Q. No. 15 to Q. No. 26 are Twelve short answer type of
questions carrying Three marks each. (Attempt any
Eight)
(4) Section D: Q. No. 27 to Q. No. 31 are Five long answer type of
questions carrying Four marks each. (Attempt any
Three)
•
(5) Use of fog table is allowed. Use <f c,alculator is not allowed.
(6) Figures to the right indicate full marks.
(7) Given: R=8 .314J.K·- 1.mol 1

NA = 6.022 x 1023
F = 96500C

IOIs Is I2 I Page 1 P.T.O.

 (vi) The 11urnl·h:r ul°p:111 ic k s p1l ' '- <· 111 11 i I .ll t ' < , · 11l1 <·d r 1JI J1< l J 1111
Ce ll is l ~1t\'

( n) l (h ) 2
(r) 3 ( d) 1

(vii) The monomer used in prcparn tion 01 tc fl on i"i

(a) E capro lactum (b) vinyl chlo ride
(c) styrene (d) Let rn 11 uo ro cl hcnc

(viii) Among the fol lowing vinylic halid e is

(a) R - CH - R (b) C il 2 = C J/ - X

(.c) (rx
*
(ix) The product of hydrolysis of propyne in the presence of
I% ·HgS04 and 40% H2 S04 is _ _
(a) methanal (b) ethanal
( c) propanal _ ( d) propanone
(x) lfunit of rate constant is mon.1m-3s- 1, the order-of reaction
would b e - -
(a) - zero (b) l
(c) 2 . - (d) 3

Q. 2. An.swer 'the fo llowing questions : 181

(i) Write the name of metal nanoparticle t~sed to remove E.coli
bacteria.from wat~r.
(ii) Write the name of reduction product form ed when ethyl
cyanide is treated with sodium an d alco hol.

'(iii) Complete the reaction : CH 3CH 2CI AgCN >?

ale.~

(iv) Calcul.at~ e~fective atomic numbe'i· of [Co (NH3) 6J. 3+ ion.

Page 3 P.T.O.
 SE CT IO N - A
wing muhiple I1OJ
Q. 1. Select and write the correct answer for the follo
choi ce type of questions :
3
(i) The spin only n1agnetic mome nt of Cr + catio n is _ _
(a) 3.742 BM (b) 3.75 58M ~
(c) 3.873 BM (d)' 3.633 BM .

(ii) The linkage present in Lactose is _ _

(a) a, P-1, 2 - glycosidic linkage
(b) a-1 , 4- glyc o~idi c linkage
(c) p~ 1, 4 - glycos idic linkage
(d) a -1 , 4 - glycosid ic linkage

,Ciii) ·The product of the foll~owing reac tion is

0
II' >?
C2H5 -C- CH 3 Hi~ Ni

(a) . CH 3 - CH 2 - ·CH 2 - CH 2 - OH
(b) ~H 3 ·-cH - CH 2 -CH3
_..... .. - . I - - -- - ~.:'.;'"- _..,,,_ .- -
oH . .

(c) C H3 _- CH 2 - CH 2 - CH3
_(d}- CH3 - .CH 2 ---: CH 2 - COO H

(iv) The pH of 0.001 M HC] solu tion is _ __,c__

(a) 10 (b) 3
(c) 2 (d) 11
name
(v) The corr ect structure of com plex having IUPAC
sodi um hexanitro cobaltate (Ill ) is
(a) Na 3 [Co( NO 2) 5]
(b) Na 4 [Co(NO 2 ) 6]
( c) Na 3 [Co( NO 2 ) 6]
(d) Na 4 [Co(NO 2 ) 5]

\ oI s I s 12 \ Page 2
 T.4 i • e to
(v ) The co mpounds of 1 ion s arc co lourle ss du
(vi) Write SI unit of mol
ar cond UC1t.1V
• •
1ty.
.
(v ii) W,rit e the sign conve n 1·
ion
· f'
wo °
rk done du rin g expansion

of gas.
t·evers e osmosis.
(viii) Write the condi tion of

SECTION - B
ns : [16)
of the fo llo wi ng questio
A tte m pt any EI G H T
pr es sio n fo r m ax im um work obtainable during
Q. 3. Derive an ex
bl e ex pa ns io n of an ideal gas from in itia l volume
isothennaI re versi
(V 1) to final volume (V2).
tion.
e in te rh al og en co m po un ds? Write. the chemical reac ~

Q. 4. What ar . .
dry slaked lime.
wh en chlorine reacts with
m at er ia l? W rite th e reac tion involved in sol-2....,el
Q. 5. What is nano .
.

process during ~ydrolysis.

e-cla ss ffi ca tio n of pr ot ein s with an example.
Q._J:_ ___ :'7rit
- ---- -· ..,.. - - --
- ~

e
~

re
--- ' ---
._.:;- ,

qu ire d to de poSJt 2·4gofCu~ when-2·0

3-A
Q. 7. Calcul ate th e tim
Cu SO4 solution;
of current passed through
1
t. m as s of C u= 63 .5 g. m oJ- )
(A
=
in es are ba sic in na tu re ? Among dimethylamine (pKb
Q. 8. Why am
hy la m in e (P ~b = 3 ·0), wh ich one is more basic?
3 ·27) and di et
r ac tio n of so di um ac etate -acetic acid buffer.
Q. 9. Explain buffe
ethyl
pr ep ar at io n of (a) di eth yl ether (b) ethyl cy anide from
Q. 10. Write I

br om ide. 3 1
is O· I 59 111 0I dm - .b ar- at 25 °C .
fo r CI 11 Br(g)
Q. 11. He nr y's co ns ta nt sure is
so lu bi li ty in w,a tc r at 25 °C , if its partial pres
Ca lcu late its
O· I 64 ha r.

\ o\ 8\ sl 2-\
 .ind n:i, 11( ' o / rrir nio ni c r o /
Q. 12. v\ 'ritt' Uw .'>It Lh ' lt 11l'

(n) Nylo11-6
( b) Natural rubber
.
W. 1caJ
Q. Lt Define Lanthan ide' co nt ractwn. nlc t11c haJancccJ chcm
•

O reacts with J 11 S.
eq ua tio ns when acidified K2Cr2 7
the
14 · De riv e the rel ati on sh ip betwee n moJar ma ss, dens ity of
Q.
.
substanc e and unit cell edge length

-SECTION - c ·
lowing qu estions : f24J
Attempt any EIGHT of the fol
mass
Ho w will you de termi ne molar
Q. 15. W ha t is osm otic pre ssure?
of sol ute fro m osm otic pre ssure?
olved in :
Q. 16. Write chemical reaction s inv
(a) Rosenmund reduction.
ion.
(b) Ga ttem1an Koch fonnylat
eth anal.
(c) Ca nn izz aro reaction ofm
thalpy of co mb ust ion ofme tha
ne , if the
Q. 17 . Ca lcu lat e the sta nd ard en
xid e an d
- sta nd ard en tha lpy of for mation of metha ne , car bo n dio
... :.: --- ----
are - 74 ·8, - 39 3 · 5 and - 28 5·8 kJmo-I- 1 res pe cti ve ly.
wa ter
l owing on ethyl bromide ?
Q. 18. Wh at is the acti on of fol (
(a) silvernitrite
(b) Mg in dry eth er
de
(c) alcoholi c sodium hy droxi

Q. 19. Fo r the reacti on A + B ➔

P.
the rate of reaction do ubled. If
If [BJ is do ub led at con stant (A],
the rate of reaction increases by
(A] is triple an d [BJ is doub led,
law eq uation.
a factor of 6. Calculate the rate

P.T.O.
I IsIs I I
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 J ?::

Q. 20. Arrange the following in the increasing order of the property

mentioned :
(i) HOC1, HCIO2 , HCIO3 , HCIO4 (aci d ic strength)
(ii) Mf, MCI, MBr, MI (ionic character)
(iii) HF, HCl, HBr, HI (thermal stability)

Q. 21. Exp lai n Wo1f- Kishner redu ction reaction. Write preparation of
propanone by using et~anoyl chloride and dimethyl cadmium.

Q. 22. ~rite postulates of Werner theory of co-ordination complexes.

Write the name of a hexadentate ligand.

, Q. 23. Define electrochemical series and write its two applicatio ns.
. .

Q. 24. Identify 'A', 'B' and 'C' in following chain reaction and rewrite
the chemical reactions: ,

CH3CH2 OH red'P'
>A . KCN >B LiAIH4 ) C
812 ale Ether

Q. 25. Define acids and bases according to Bronsted-~~"".ry t~eory.

Derive reiationship between_pH:and pOH.
. • "!t-- - .,1. •
O. 26. Write the preparation~o f potassi urr1d1chromate from chromite
- -- - --- ---- ---

:-.----------
.
ore. · -,,.. - - - · · ----~--~-~--, " ' ~ ~ , -~
1
\.

SECTION-- D
Attempt any THREE of tl}e following questions : . [12]

Q. 27. Convert the fo llowing :

(i) acetaldehyde to isopropyl alcohol.
(ii) cumene to phenol. 1

(iii) anisole to p henol.

Write two uses of neon.

IoI sIs1.2I Page 6

r ..
Q, zs . Define : (i)
l •\ rensi"<' '
111 ( / / l I,, 11, , . •
I
" ' 1 v( JH o pt •t f 1t •
(ii) f, .
soh nrrc ill 1d ;\ cJ 1.1h;11,( f l f t )( /'

Wh 'lt ·1,·,
u ( l C'/1 /y l)
l(' i,' l

. •n 11
Wri te t hc ·1! 0
< m rc 1111,nli c , •,
q/ fr ,111 1

elements.
pe o f . . r!
Q. 29 . P re d ic t the ty c l c n 1c 111 h, 1 111 1 1

cub ic la lt 1cc of n " o /1d

Ieng th o f40 0 d d ensity is 6 ·2 5 g /m
l
A . P m an
en t = 60)
( tom1c in ass o f elem
Define : Nanosci ence ilc
tion o f po ly ac r; lorn •,..
te ch e1n ic al 1·e ac ti on fo r th e p repa ra
Wri to r
fl if e period and ra te co n~ta nt
Q. JO . D er iv e th e relation between h al
.
first ord er reacti on .
du ri ng ·discharging of le ad accu mulat or
action
\Yri te the net cell re
ur e o f,p er ox ym on osulphuric ac id.
D ra w th e st ru ct of
ge o m et ry
b er o f u n p ai re d el ec tr on s an d_
e num
Q. 31. M en ti o n th
fo llo w in g co m pl ex es :
(i) [Ni (ci1;F_:_ .·
N)4]2 -
~ - ~ - £ N i -EE
ing :
C on v er t th e foll ow
to ethanal.
(a) Ethanenitr{Ie in
) C yc lo he x~ n e into ad ip ic acid.
(b
♦♦♦

Page 7

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