Patents

Geopolymer-based Crack Injection Material Composition

Abstract translated from Korean

KR101067891B1
South Korea
The present invention relates to a crack repair stiffener composition of a geopolymer-based
concrete structure exhibiting excellent workability and easy penetration into fine cracks as well as
excellent exponential properties in crack repair of concrete structures. Geopolymer 70-90 1% by Download PDF Find Prior Art Similar
weight of water, 1-20% by weight, caustic alkali, 1-% by weight, 3-8% by weight of high softening
agent, 2-5% by weight of MgO, 0.1-2% by weight of antifoaming agent, and 0.1-2% by weight of
Other languages: Korean
waterproofing agent. The crack injection material composition of the concrete structure of the
present invention composed of 10% by weight, 30-70% by weight silicate, 1-10% by weight of silane, Inventor: 김태현, 신동구, 정재운
and 5-30% by weight of the liquid resin may be formed by physical and chemical environmental
conditions. Used for repairing cracks in structures, applied to all cracks in structures regardless of
Worldwide applications
crack width, increases adhesion of new / old concrete, enhances durability by crack repair
reinforcement, Because the main raw material used in the cost is cheaper compared to traditional 2011 KR
epoxy injection method. In addition, since the geopolymer crack injection material of the present
invention has essentially the same physical properties as concrete, there is no additional stress or
Application KR1020110066587A events
cracking caused by dry shrinkage or thermal expansion, thereby improving durability, and in case of
fire, fire resistance does not decrease. It is expected that it may be usefully used in the art because 2011-07-05 Application filed by 리플래시기술 주식회사, (주)
of its ease of handling and excellent workability. 디오

2011-07-05 Priority to KR1020110066587A

2011-09-28 Application granted

Classifications
2011-09-28 Publication of KR101067891B1
C04B28/006 Compositions of mortars, concrete or artificial stone, containing inorganic
binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate
cements containing mineral polymers, e.g. geopolymers of the Davidovits type Info: Patent citations (4), Cited by (17), Legal events, Similar
documents, Priority and Related Applications
View 5 more classifications
External links: Espacenet, Global Dossier, Discuss

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Chemical & Material Sciences

Engineering & Computer Science

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Claims (8) Hide Dependent

translated from Korean

Powder phase consisting of 70-90% by weight of geopolymer, 3-8% by high fluidizing agent, 2-5% by weight of MgO, 0.1-2% by weight of antifoaming agent, and 0.1-2% by weight of
waterproofing agent, and 1-20% by weight of water , 1-10% by weight caustic alkali, 30-70% by weight silicate, 1-10% by weight of silane, and 5-30% by weight of the liquid resin
crack injection material composition. The method of claim 1,
The mixing ratio of the powder phase and liquid phase is 1: 0.3 ~ 0.8 crack injection material composition of the concrete structure, characterized in that. The method of claim 1,
The geopolymer is a crack injection material composition of a concrete structure, characterized in that at least one selected from the group consisting of blast furnace slag, fly ash,
and metakaolin. The method of claim 1,
The geopolymer is a crack injection material composition of a concrete structure, characterized in that the powder is 8,000 cm 2 / g or more. The method of claim 1,
The caustic alkali is a crack injection material composition of a concrete structure, characterized in that at least one selected from the group consisting of KOH, NaOH, and LiOH.
The method of claim 1,
The silicate is crack injection material composition of a concrete structure, characterized in that at least one selected from the group consisting of lithium silicate, sodium silicate,
and potassium silicate. The method of claim 1,
The silane is selected from the group consisting of n-octyltriethoxysilane, n-octylethoxysilane, isooctylmethoxysilane, and aminosilane, the crack injection material composition of a
concrete structure. The method of claim 1,
The liquid resin is a crack injection material composition of a concrete structure, characterized in that at least one selected from the group consisting of SB (Styrene-Butadiene)
latex, PAE emulsion, EVA emulsion, epoxy resin, acrylic resin, and polyester.

Description translated from Korean

Geopolymer-based crack injection material composition {CRACK REPAIRING COMPOSITION OF CONCRETE STRUCTURE USING GEOPOLYMER}

The present invention relates to a crack repair stiffener composition of a concrete structure using a geopolymer, and more specifically, using a geopolymer, such as blast
furnace slag, fly ash, metakaolin in powder form, MOH type caustic alkali and R 2 in the liquid phase O. (n) SiO 2 type silicate is used as alkali activator, silane is added, it is

excellent in workability and easily penetrates into minute cracks, and it is excellent in exponential property so that it is easily applied to repair and reinforcement of wet
surface. It relates to crack injection materials of possible concrete structures.

Civil construction using concrete plays an important role in the national economy as a national infrastructure. Therefore, these concrete structures must be able to be
maintained and managed for a long time. However, these concrete structures have large and small cracks after construction due to poor physical and chemical
environmental conditions, which inevitably leads to significant economic loss due to the inevitable major repair or reconstruction in the middle of the target year.
The most widely used material for crack repair of concrete structures is epoxy resin. Epoxy has high compressive strength and tensile strength, can be manufactured
with various viscosities, and is widely used as a crack repair and reinforcing material for structures because of its early strength and excellent adhesion.

However, epoxy exhibits a large adhesive strength at the beginning of construction, but has a heterogeneous property with concrete such as shrinkage and thermal
expansion due to drying, and thus, in the long term, adhesive performance is deteriorated, resulting in a dropout in the new / old concrete bonding surface.

In addition, handling is somewhat complicated and proper temperature management is required, and there is a problem in fire resistance in case of fire, and in case of
wet surface, it is hard to be hardened, so adhesion strength may be reduced, and dry shrinkage rate, elastic modulus, thermal expansion coefficient and Due to the
difference in physical properties such as strength, there is a problem that additional stress or cracking may occur. In addition, the unit price is expensive and in the case
of a specific epoxy may be harmful to the human body has a very difficult disadvantage of handling.

On the other hand, conventionally, the Portland cement system is usually used as a crack injection material, but since Portland cement has a large maximum particle
diameter of about 0.1 mm, cracks that can be repaired by using a normal Portland cement are limited.

In other words, the relationship between the crack width and the maximum particle diameter of the injectable injection material in the crack repair of rock or concrete
structures, JK Michel suggests that the maximum particle diameter of the injection material should be less than one third of the crack width. The minimum width of
cracks that can be repaired with cement is about 0.3 mm.

However, considering that the cracks that require repair are generally 0.4 mm or more in terms of durability and 0.2 mm or more in terms of water resistance,
conventional ordinary Portland cement-based crack injection materials may be satisfactory in terms of durability but are inadequate in terms of water resistance. There is
this.

The present invention is to solve the above problems, the problem to be solved in the present invention is applied to all cracks generated in the structure, regardless of
crack width, including geopolymer eco-friendly binder consisting of ultra-fine particles, It is to provide a concrete crack injecting material containing a geopolymer that
can increase the adhesive strength, enhance the durability due to crack repair reinforcement, and can be restored to prevent the occurrence of rework.

In order to solve the above problems,

The present invention is a powder form consisting of 70-90% by weight of the geopolymer, 3-8% by weight of the high fluidizing agent, 2-5% by weight of MgO, 0.1-2% by
weight of the defoaming agent, and 0.1-2% by weight of the waterproofing agent, and water 1- It provides a crack injection material composition of a concrete structure
consisting of 20% by weight, 1-10% by weight caustic alkali, 30-70% by weight silicate, 1-10% by weight silane, and 5-30% by weight liquid resin.

It is preferable that the mixing ratio of the said powder form and a liquid phase is 1: 0.3-0.8.

The geopolymer is preferably selected from the group consisting of blast furnace slag, fly ash, and metakaolin.

The geopolymer is preferably a powder of 8,000 cm 2 / g or more.

Preferably, the caustic alkali is selected from the group consisting of KOH, NaOH, and LiOH.

The silicate is preferably selected from the group consisting of lithium silicate, sodium silicate, and potassium silicate.

The silane is preferably one or more selected from the group consisting of n-octyltriethoxysilane, n-octylethoxysilane, isooctylmethoxysilane, and aminosilane.

The liquid resin is preferably selected from the group consisting of SB (Styrene-Butadiene) latex, PAE emulsion, EVA emulsion, epoxy resin, acrylic resin, and polyester.

As described above, the geopolymer crack injection material according to the present invention is easily penetrated into fine cracks, and thus, the crack of the concrete
structure can be more easily repaired and reinforced, and the industrial by-products are used as the main raw materials. Compared with the low cost, it is advantageous
for cost reduction.

In addition, since the geopolymer crack injection material of the present invention has essentially the same physical properties as concrete, there is no additional stress
or crack caused by dry shrinkage or thermal expansion, thereby improving durability, improving adhesion to the concrete structure, and its adhesion performance. You
can keep it for a long time.

In addition, the present invention has the advantage that the fly ash is used as the main raw material, the fire resistance is not lowered at the time of fire occurrence, the
handling is easy, and the workability is excellent.

In addition, the present invention has excellent repair / reinforcement effect, it can be used as the injection material when repairing and reinforcing cracks of damaged
bridges, tunnels, covering structures and other reinforced concrete structures for civil construction.

EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

The composition of the present invention is a powder form consisting of 70-90% by weight of the geopolymer, 3-8% by weight of the high fluidizing agent, 2-5% by weight
of MgO, 0.1-2% by weight of the antifoaming agent, and 0.1-2% by weight of the waterproofing agent, and water 1-20% by weight, caustic alkali 1-10% by weight, silicate
30-70% by weight, silane 1-10% by weight, and 5-30% by weight of the liquid resin, so as to injectability, adhesion strength, index characteristics, etc. This improved crack
injector material can be produced.

The crack injection material is divided into a powder phase and a liquid phase, and the powder phase is composed of a geopolymer, a high fluidizing agent, MgO, an
antifoaming agent, a waterproofing agent, and the liquid phase is composed of water, caustic alkali, silicate, silane, and liquid resin. It is preferable that the use ratio of
powder form and liquid phase is 1: 0.3-0.8 by volume ratio. If the liquid content is less than 0.3, it is difficult to inject into the crack because the solid content is too high,
and there is a problem of slow strength expression due to the low reactivity, and if it exceeds 0.8, the crack injection property is good due to the high solid content, There
is a problem that the intensity is expressed low.

Geopolymers such as blast furnace slag, fly ash, metakaolin, etc., which are used in the form of crack injection material, are chemically based on silico-aluminates and
are also referred to as poly (sialate). Sialate stands for silicon-oxo-aluminate M n- (SiO 2 ) Z -AlO 2 n · wH 2 O, where M is a cation such as potassium, sodium, or calcium,

n is the degree of polycondensation, z is 1 , 2, or 3.

The geopolymer was used as a main component of the crack repair material composition of the concrete structure as a material having excellent initial strength,

chemical resistance, freeze-thaw resistance, heat resistance, and the like as compared with cement. The geopolymer preferably has a powder degree of 8,000 cm 2 / g or

more, and less than 8,000 cm 2 / g has a problem in that injection into a crack width of 0.2 mm or less is difficult.

The geopolymer is contained in 70 to 90% by weight of the powder phase, if the content is less than 70% by weight because of the high amount of water used has a
problem of poor crack repair due to a decrease in the volume of the crack injection material, exceeding 90% by weight In this case, there is a problem that the injection
property is poor because the amount of the powder component is too high.
The high fluidizing agent disperses the geopolymer particles to enable a reduction in the amount of water used, and serves to increase the strength and shorten the
curing time. Melamine-based, naphthalene-based, polycarboxy-clock and lignosulfate-based are used. The MgO was added to suppress cracking.

The high fluidizing agent is contained in 3 to 8% by weight of the powder phase, if the content is less than 3% by weight, there is a problem in that the injection is poor due
to the lack of fluidity of the crack injection material, if the content exceeds 8% by weight of the crack injection material The fluidity no longer improves and there is a
problem that the strength is lowered. In addition, the MgO is contained in a powder form of 2 to 5% by weight, when the content is less than 2% by weight because the
shrinkage of the crack injection material occurs during the curing process, there is a problem that the filling effect of the crack is insufficient and the injection effect is
low. If it exceeds 5% by weight, there is a problem that expansion of the crack injection material occurs.

The antifoaming agent serves to lower the surface tension of the interface to extinguish air bubbles entrained in the crack injection material, and the waterproofing agent
serves to enhance the exponential property, and a product used as a general cement antifoaming agent and waterproofing agent is used.

The antifoaming agent is contained in a powder form of 0.1 to 2% by weight, if the content is less than 0.1% by weight, the defoaming effect is too low, there is a problem
that the air amount increases in the crack injection material, if the content exceeds 2% by weight of the crack injection material There is a problem that the defoaming
effect no longer improves. In addition, the waterproofing agent is contained in the powder phase of 0.1 to 2% by weight, when the content is less than 0.1% by weight
there is a problem that the waterproof effect is not sufficient, when the content exceeds 2% by weight delay the hydration reaction of the geopolymer There is a problem
that the strength expression does not occur sufficiently.

An alkali activator may be included in the liquid phase of the crack injection material. Alkali activators are caustic alkalis in the form of MOH and silicates in the form of R

2 O. (n) SiO 2 . Caustic alkalis and silicates are used in combination but may be used alone. M of the caustic alkali is an alkali metal ion such as Na, K, and Li, and the

silicate is selected from the group consisting of lithium silicate, sodium silicate and potassium silicate.

The caustic alkali is contained in 1 to 10% by weight in the liquid phase, if the content is less than 1% by weight because the hydration reaction of the powder phase of
the geopolymer is not sufficiently proceeded, there is a problem that the strength is not achieved, 10 wt. If it exceeds% there is a problem that the workability is poor
because the hydration reaction rate is too fast. In addition, the silicate is contained in 30 to 70% by weight in the liquid phase, when the content is less than 30% by
weight, the content of the silicate is too low to proceed the geopolymer reaction sufficiently, if the content exceeds 70% by weight There is a problem that the crack
injection is insufficient due to the rapid polymerizing effect of the geopolymer.

The silanes are selected from the group consisting of n-octyl triethoxy silane, n-octyl ethoxy silane, isooctyl methoxy silane and aminosilane.

Silane is a compound represented by the formula R 1 Si (OR) 3 , wherein R 1 is an organic functional group that reacts with various polymers. OR means a hydrolyzable

alkoxy group at the other end of the silane molecule. Silane is a very useful material because it has a very low interfacial tension, so it is fast to absorb and changes the
crack surface of the structure hydrophobicly, but the water repellency is low and does not adversely affect the geopolymer bond.

When the content of the silane in the liquid phase is 1 to 10% by weight, the effect is insufficient when the content is less than 1% by weight, and when the content
exceeds 10% by weight, the crack surface of the structure is changed to hydrophobic so that the water repellency is high. There is a problem of delaying the polymer
curing reaction.

The liquid resin is characterized in that any one of SB (Styrene-Butadiene) latex, PAE emulsion, EVA emulsion, epoxy resin, acrylic resin and polyester.

The content of the liquid resin is used in 5 to 30% by weight of the liquid, when the content is less than 5% by weight does not improve the absorbency of the geopolymer
has a problem of poor waterproofness, if the content exceeds 30% by weight geopolymer There is a problem in that the coating film is formed on the surface of the
hydration product to make the hydration reaction poor.

Hereinafter, the present invention will be described in more detail with reference to Examples.

<Examples>

In order to confirm the performance of the present invention, a crack injection material was prepared using the composition of the present invention, and injected into the
crack of the concrete structure specimen in which the crack had already occurred to repair the crack, and then KS F 4042 "Polymer cement for repairing the concrete
structure. The performance test was carried out according to the "mortar" test method. The results are shown in [Table 1].

The crack injection material is 90% by weight of the geopolymer, 5% by weight of the high fluidizing agent, 3% by weight of MgO, 1% by weight of the antifoaming agent,
1% by weight of the waterproofing agent and 15% by weight of water, caustic alkali 10%, silicate 55%, It consists of 5% by weight of silane and 15% by weight of liquid
resin.

The above description is merely illustrative of the technical spirit of the present patent, and those skilled in the art to which the present patent belongs may make various
modifications and changes without departing from the essential characteristics of the present patent.

In addition, the embodiments disclosed in the present patent are not intended to limit the technical spirit of the present patent but to describe the technical spirit of the
present patent.

Therefore, the protection scope of the present patent should be interpreted by the following claims, and all technical ideas within the equivalent scope should be
interpreted as being included in the scope of the present patent.
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KR101303136B1 2013-06-18 2013-09-09 여용득 Acrylic copolymer injecting materials and repairing method of concrete
structure by using cementitious acrylic copolymer injecting materials

CN103553538A * 2013-10-28 2014-02-05 河南阳光防水科技有限公司 Non-destructive waterproof agent for architectural indoor deep
penetration curing

KR101373754B1 2013-06-10 2014-03-13 쌍용양회공업(주) Sprayable geopolymer repair mortar formulation using lithium chloride
and colemanite for concrete repair

KR101415342B1 2012-02-22 2014-07-07 씨캠 주식회사 Paint composition

KR101418310B1 2014-04-22 2014-07-10 부림산업개발(주) Injecting apparatus for crack repair and crack repairing methods of
concrete structure using the same

KR101478755B1 * 2014-03-31 2015-01-02 주식회사 이에스피소재 Compositions water stop for concrete structures and manufacturing
method and waterproof and repair method for concrete structures using
the same

EP2837608A1 2013-08-15 2015-02-18 Dow Global Technologies LLC Epoxy-multilayer polymer rdp geopolymer compositions and methods of
making and using the same

KR101555207B1 2013-10-30 2015-09-23 (주)포스코건설 Floor layer material of parking lot and method for producing and
constructing the smae

KR101820350B1 * 2017-06-19 2018-01-22 (주)주은건설 Mortar composition for repairing concrete using geopolymer and method
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Concepts

machine-extracted
Download Filter table

Name Image Sections Count Query match

injection title,claims,abstract,description 40 0.000

injection title,claims,abstract,description 40 0.000

material title,claims,abstract,description 39 0.000

geopolymer title,claims,abstract,description 31 0.000

mixture title,claims,abstract,description 16 0.000

concrete claims,abstract,description 29 0.000

chemical substances by application claims,abstract,description 16 0.000

alkali claims,abstract,description 14 0.000

Silane claims,abstract,description 13 0.000

caustics claims,abstract,description 13 0.000

silane claims,abstract,description 13 0.000

Orthosilicate claims,abstract,description 12 0.000

liquid claims,abstract,description 12 0.000

water claims,abstract,description 12 0.000

resin claims,abstract,description 10 0.000

resin claims,abstract,description 10 0.000

antifoaming agent claims,abstract,description 9 0.000

method claims,abstract,description 9 0.000

waterproofing claims,abstract,description 9 0.000

powder claims,description 19 0.000

liquid phase claims,description 10 0.000

phase claims,description 8 0.000

Potassium hydroxide claims,description 6 0.000

Sodium hydroxide claims,description 6 0.000

Styrene-butadiene claims,description 6 0.000

butadiene-styrene rubber claims,description 6 0.000

emulsion claims,description 6 0.000

styrene butadiene claims,description 6 0.000

styrene butadiene rubber claims,description 6 0.000

 fly ash claims,description 5 0.000

Lithium hydroxide claims,description 4 0.000

epoxy resin claims,description 4 0.000

kaolin claims,description 4 0.000

polyepoxide claims,description 4 0.000

slag claims,description 4 0.000

Acrylic resin claims,description 3 0.000

Acrylic resin claims,description 3 0.000

Potassium silicate claims,description 3 0.000

Sodium Silicate claims,description 3 0.000

ethoxy(octyl)silane claims,description 3 0.000

latex claims,description 3 0.000

latex claims,description 3 0.000

lithium metasilicate claims,description 3 0.000

lithium silicate claims,description 3 0.000

methoxy(6-methylheptyl)silane claims,description 3 0.000

octyltriethoxysilane claims,description 3 0.000

polyester claims,description 3 0.000

potassium silicate claims,description 3 0.000

potassium silicate claims,description 3 0.000

potassium silicate claims,description 3 0.000

silanamine claims,description 3 0.000

sodium silicate claims,description 3 0.000

sodium silicate claims,description 3 0.000

mixing claims,description 2 0.000

repair process abstract,description 15 0.000

Epoxy abstract,description 4 0.000

reinforcement abstract,description 4 0.000

cracking abstract,description 3 0.000

physical effect abstract,description 3 0.000

raw material abstract,description 3 0.000

substance abstract,description 3 0.000

environmental effect abstract,description 2 0.000

stiffener abstract,description 2 0.000

1-20% by weight abstract 1 0.000

Softening Agent abstract 1 0.000

exhibiting effect abstract 1 0.000

penetration abstract 1 0.000

Show all concepts from the description section

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