Safety Data Sheet
Page 1 of 9
LOCTITE UR 8418 1KG MSDS-No. : 477225
V001.5
Revision: 11.09.2015
printing date: 22.10.2015
Section 1. Identification of the substance/preparation and of the company/undertaking
Product name: LOCTITE UR 8418 1KG
Other means of identification: LOCTITE UR 8418 1KG
Product code: IDH2049106
Recommended use of the chemical and restrictions on use
Intended use: Water based adhesive
Identification of manufacturer, importer or distributor
Manufacturer: PT. Henkel Adhesive Technologies
Jl.Rembang Industri Raya no 26 PIER Pasuruan 67152,
Jawa Timur - INDONESIA
Telp : +62 343 740251 Fax : +62 343 740250
responsible for Safety Data
Sheet:
Emergency information: Emergency number +6234 3740251 (office hour only)
Section 2. Hazards identification
GHS Classification:
Hazard Class Hazard Category Route of Exposure Target organ
Acute toxicity Category 4 Inhalation
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Respiratory sensitizer Category 1
Skin sensitizer Category 1
Carcinogenicity Category 2
Specific target organ toxicity - Category 3 respiratory tract irritation
single exposure
Specific target organ toxicity - Category 2
repeated exposure
GHS label elements:
Hazard pictogram:
Signal word: Danger
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V001.5 LOCTITE UR 8418 1KG
Hazard statement: H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Precaution:
Prevention: P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P285 In case of inadequate ventilation wear respiratory protection.
Response: P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
Storage: P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal: P501 Dispose of contents/container to an appropriate treatment and disposal facility in
accordance with applicable laws and regulations, and product characteristics at time of
disposal.
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V001.5 LOCTITE UR 8418 1KG
Section 3. Composition / information on ingredients
Substance or Mixture:
Mixture
Declaration of hazardous chemical:
Hazard component CAS-No. Content GHS Classification
Isocyanic acid, polymethylenepolyphenylene ester 30- 60 % Acute toxicity 4; Inhalation
9016-87-9 H332
Skin corrosion/irritation 2
H315
Serious eye damage/eye irritation 2A
H319
Respiratory sensitizer 1
H334
Skin sensitizer 1
H317
Carcinogenicity 2
H351
Specific target organ toxicity - single exposure 3
H335
Specific target organ toxicity - repeated exposure 2
H373
Isocyanates, reaction product of polyol with 30- 60 % Acute toxicity 4; Inhalation
methylenediphenyl diisocyanate~ H332
Skin corrosion/irritation 2
H315
Serious eye damage/eye irritation 2A
H319
Respiratory sensitizer 1
H334
Skin sensitizer 1
H317
Specific target organ toxicity - single exposure 3
H335
Ethyl acetate 10- 30 % Flammable liquids 2
141-78-6 H225
Serious eye damage/eye irritation 2A
H319
Specific target organ toxicity - single exposure 3
H336
Section 4. First aid measures
Inhalation: Move to fresh air.
If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel.
Get immediate medical attention.
Skin contact: Rinse with running water and soap.
Get medical attention if irritation persists.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes,
and seek immediate medical attention.
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V001.5 LOCTITE UR 8418 1KG
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person.
If individual is conscious, wash out mouth with water.
If symptoms develop and persist, get medical attention.
Section 5. Fire fighting measures
Suitable extinguishing media: Use media appropriate for surrounding material.
Specific hazards arising from the Pressure build-up.
chemical:
Special protection equipment and Wear self-contained breathing apparatus.
precautions for firefighters: Wear full protective clothing.
Hazardous combustion products: carbon oxides.
nitrogen oxides
Hydrocarbons
HCN
Section 6. Accidental release measures
Personal precautions: Keep unprotected persons away.
Don't breathe vapours or aerosole.
Wear protective equipment.
Environmental precautions: Do not empty into drains / surface water / ground water.
Clean-up methods: Wipe up using absorbent material.
Dispose in suitable waste container.
Wash away residue with plenty of water.
Section 7. Handling and storage
Handling: Do not get in eyes.
Do not get on skin or clothing.
Wash thoroughly after handling.
Avoid breathing vapors or mists of this product.
Ensure adequate ventilation.
Storage: Store in tightly closed containers, cool and dry.
Do not let moisture contaminate this material. Product reacts with water to release carbon
dioxide, which could build up pressure in closed containers and lead to bursting. Do not
reseal if moisture contamination is suspected.
Storage at 10 to 35°C is recommended.
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V001.5 LOCTITE UR 8418 1KG
Section 8. Exposure controls / personal protection
Components with specific control parameters for workplace:
METHYLENE BISPHENYL Value type Time Weighted Average (TWA):
ISOCYANATE (MDI)
9016-87-9
ppm 0.005
Remarks ACGIH
Isocyanic acid, polymethylenepolyphenylene Value type Time Weighted Average (TWA):
ester
9016-87-9
ppm 0.005
Remarks ID NAB
ETHYL ACETATE Value type Time Weighted Average (TWA):
141-78-6
ppm 400
Remarks ACGIH
Ethyl acetate Value type Time Weighted Average (TWA):
141-78-6
ppm 400
Remarks ID NAB
Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of vapor/mist/fume/dust,
appropriate NIOSH/MSHA respiratory protection must be provided.
Hand protection: Appropriate chemical resistant gloves.
Butyl rubber gloves
PVA gloves
Polyethylene gloves
Protective gloves made of PVC.
Neoprene gloves
Nitrile gloves.
Please note that in practice the working life of chemical resistant gloves may be
considerably reduced as a result of many influencing factors (e.g. temperature). Suitable
risk assessment should be carried out by the end user. If signs of wear and tear are noticed
then the gloves should be replaced.
Eye protection: Wear chemical goggles; face shield (if splashing is possible).
Body protection: Suitable protective clothing
Engineering controls: Ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust
generated from the handling of this product.
General protection and hygiene Eyewash fountains and emergency showers are required. Launder contaminated clothing
measures: before reuse.
Hygienic measures: When using do not eat or drink. When using do not smoke. Wash hands before work
breaks and after finishing work.
Section 9. Physical and chemical properties
Appearance: liquid
Odor: slightly, Musty
Odor threshold (CA): No data available.
pH: No data available.
Melting point / freezing point: Not available.
Specific gravity: No data available.
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V001.5 LOCTITE UR 8418 1KG
Boiling point: > 300 °C (> 572 °F)
Flash point: 66 °C (150.8 °F)
(Open cup)
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Lower explosive limit: No data available.
Upper explosive limit: No data available.
Vapor pressure:
Not available.
Vapor density: No data available.
Density: No data available.
Solubility: No data available.
Partition coefficient: n- No data available.
octanol/water:
Auto ignition: 600 °C
Decomposition temperature:
Viscosity: 8 - 11 poise
(; 25 °C (77 °F); Method:
Supplier method)
VOC content: No data available.
Section 10. Stability and reactivity
Reactivity/Incompatible Water
materials: Reaction with alcohols
Reaction with amines
Acids.
Bases
Conditions to avoid: High temperatures.
Hazardous decomposition carbon oxides.
products: nitrogen oxides
hydrocarbons
Hydrogen cyanide.
Section 11. Toxicological information
Inhalative toxicity: Acute toxicity estimate (ATE) : 12.64 mg/l
Exposure time: 4 h
Test atmosphere: Vapor.
Method: Calculation method
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V001.5 LOCTITE UR 8418 1KG
Health Effects:
Ingestion: No information available.
Skin: Causes skin irritation.
May cause skin sensitization.
Eyes: Causes eye irritation.
Inhalation: Harmful by inhalation.
May cause sensitization by inhalation.
May cause respiratory irritation.
Symptoms of Overexposure: None known.
Acute oral toxicity:
Isocyanic acid, Value type LD50
polymethylenepolyphenylene ester Value > 10,000 mg/kg
9016-87-9 Species rat
Method OECD Guideline 401 (Acute Oral Toxicity)
Ethyl acetate Value type LD50
141-78-6 Value 6,100 mg/kg
Species rat
Method
Acute inhalative toxicity:
Ethyl acetate Value type LC50
141-78-6 Value 200 mg/l
Exposure time 1h
Species rat
Method
Acute dermal toxicity:
Isocyanic acid, Value type LD50
polymethylenepolyphenylene ester Value > 9,400 mg/kg
9016-87-9 Species rat
Method OECD Guideline 402 (Acute Dermal Toxicity)
Ethyl acetate Value type LD50
141-78-6 Value > 18,000 mg/kg
Species rabbit
Method Draize Test
Skin corrosion/irritation:
Ethyl acetate Result not irritating
141-78-6 Exposure time 24 h
Species rabbit
Method
Serious eye damage/irritation:
Ethyl acetate Result slightly irritating
141-78-6 Exposure time
Species rabbit
Method OECD Guideline 405 (Acute Eye Irritation / Corrosion)
Respiratory or skin sensitization:
Ethyl acetate Result not sensitising
141-78-6 Test type Guinea pig maximisation test
Species guinea pig
Method OECD Guideline 406 (Skin Sensitisation)
Germ cell mutagenicity:
Ethyl acetate Result negative
141-78-6 Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test)
Metabolic activation / Exposure time with and without
Method Ames Test
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V001.5 LOCTITE UR 8418 1KG
Repeated dose toxicity:
Isocyanic acid, Result NOAEL=0,2 mg/m³
polymethylenepolyphenylene Route of application inhalation: aerosol
ester Exposure time / Frequency of treatment 2 y6 h per d, 5 d per week
9016-87-9 Species rat
Method OECD Guideline 453 (Combined Chronic Toxicity /
Carcinogenicity Studies)
Ethyl acetate Result NOAEL=900 mg/kg
141-78-6 Route of application oral: gavage
Exposure time / Frequency of treatment 90 ddaily
Species rat
Method EPA Guideline
Ethyl acetate Result LOAEL=3,600 mg/kg
141-78-6 Route of application oral: gavage
Exposure time / Frequency of treatment 90 ddaily
Species rat
Method EPA Guideline
Ethyl acetate Result NOAEL=0.002 mg/l
141-78-6 Route of application inhalation
Exposure time / Frequency of treatment 90 dcontinuous
Species rat
Method
Section 12. Ecological information
Toxicity:
Isocyanic acid, Value type LC50
polymethylenepolyphenylene ester Value > 1,000 mg/l
9016-87-9 Acute Toxicity Study Fish
Exposure time 96 h
Species Danio rerio
Method OECD Guideline 203 (Fish, Acute Toxicity Test)
Ethyl acetate Value type LC50
141-78-6 Value 270 mg/l
Acute Toxicity Study Fish
Exposure time 48 h
Species Leuciscus idus melanotus
Method DIN 38412-15
Ethyl acetate Value type EC50
141-78-6 Value 164 mg/l
Acute Toxicity Study Daphnia
Exposure time 48 h
Species Daphnia cucullata
Method OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test)
Ethyl acetate Value type EC50
141-78-6 Value > 2,000 mg/l
Acute Toxicity Study Algae
Exposure time 96 h
Species Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata)
Method OECD Guideline 201 (Alga, Growth Inhibition Test)
Value type NOEC
Value 2,000 mg/l
Acute Toxicity Study Algae
Exposure time 96 h
Species Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata)
Method OECD Guideline 201 (Alga, Growth Inhibition Test)
Ethyl acetate Value type EC10
141-78-6 Value 2,900 mg/l
Acute Toxicity Study Bacteria
Exposure time 18 h
Species
Method
Persistence and degradability:
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V001.5 LOCTITE UR 8418 1KG
Ethyl acetate Result readily biodegradable
141-78-6 Route of application aerobic
Degradability 100 %
Method OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test)
Bioaccumulative potential / Mobility in soil:
Ethyl acetate LogKow 0.6
141-78-6 Temperature
Method OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake
Flask Method)
Section 13. Disposal considerations
Product
Method of disposal: Dispose of in accordance with local and national regulations.
Packaging
Disposal of uncleaned packages: Packaging that cannot be cleaned are to be disposed of in the same manner as the product.
Section 14. Transport information
General information:
Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.
Section 15. Regulatory information
Regulatory Information: Decree of Minister of Industry No. 23/M-IND/PER/4/2013 concerning the Revision of Decree of
Minister of Industry No.87/M-IND/PER/9/2009 concerning Globally Harmonized System of
Classification and Labelling of Chemicals
Decree of Minister of Industry No. 87/M-IND/PER/9/2009 concerning Globally Harmonized
System of Classification and Labelling of Chemicals
Section 16. Other information
Disclaimer: This information is based on our current level of knowledge and relates to the product in
the state in which it is delivered. It is intended to describe our products from the point of
view of safety requirements and is not intended to guarantee any particular properties.
