Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super-60 & All Jee-Main Date:06-06-2021
Time: 10.15Am to 01.15 GTM-27 Max.Marks:300
Key Sheet
PHYSICS
1 4 2 3 3 2 4 1 5 3
6 2 7 4 8 3 9 4 10 3
11 3 12 3 13 3 14 2 15 1
16 3 17 4 18 4 19 3 20 1
46.09 to
21 2.00 22 12.00 23 2.00 24 48.00 25 46.50
26 20.00 27 24.00 28 7.50 29 80.00 30 80.00

CHEMISTRY
31 1 32 3 33 1 34 2 35 1
36 3 37 1 38 2 39 3 40 2
41 4 42 2 43 2 44 1 45 2
46 1 47 4 48 3 49 1 50 1
51 4.00 52 3.00 53 8.00 54 2.00 55 4.00
56 4.00 57 6.00 58 5.00 59 5 60 5

MATHEMATICS
61 1 62 1 63 4 64 1 65 2
66 1 67 4 68 2 69 3 70 1
71 3 72 4 73 1 74 2 75 3
76 1 77 2 78 1 79 2 80 4
81 18 82 1 83 2 84 9 85 2
86 2 87 9 88 6 89 0 90 2
Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

SOLUTIONS
PHYSICS
 
1.  
F  I l 
2. For a diamagnetic substance, magnetic susceptibility is independent of temperature.
3. Apply Ampere’s circuital law.
r 2
For r  a, B 2r  0 .I B  r
a 2
1
For a  r  b, B 
r
For r > c, B = 0
1 d2
4. x  D 2  d 2  D 
2D
1 d2 
For destructive interference =  2n  1
2D 2
d2
 (Odd multiplier in denominator)
 2n  1 D
5. Given logic gate represents OR gate
6. Let R be the resistance of portion DP. Then resistance of portion PC = 2 – R.
As B and P are at same potential,
 2  R  1  2  R
 
1 2  R 
2R
  2R
3 R
 2  R  6  3R  R 2  2R
 R 2  2R  4  0
 R  5 1
7. Based on theory
8. V  2x 2
dv
  4x
dx
vdx
a   2x 2 .4x  8x 3  64 m / s 2
dx
3/2
 dW   3xy.dy   3.y .dy
9.
y5/2 6 5/ 2 32  6 192
 3.   4  
5/2 5 5 5
10. By conservation of linear momentum along horizontal
mv0 sin 300   6m  v '
v0
 v' 
12
1 2 1
Loss in K.E. =   6m  v'  mv02
2 2
2
 v  1
=   3m   0   mv02
 144  2
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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

= mv20
3  72  23mv02
144 48
11.

Hemisphere
Ncos   Ma ......(i)
mg  Nsin   ma cot 
mg
a
M tan   m cot 
12. Conceptual
13. A uniform string of length 20m is suspended from a rigid support. Such that the time
taken to reach the support.
mgx
T
I
mgx
So, velocity at point P  I
m/I

v  gx
dx
 gx
dt
20 dxt t
0   gdt
x 0
20
 2 x   10t
 0
2
20  10t
t  2 2s
14. Consider cavity as negative mass and apply superposition of gravitational potential.
Consider the cavity formed in a solid sphere as shown in figure. V     0

Sec: Sr.Super-60 & All Page 3

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

According to the question, we can write potential at an internal point P due to the
complete solid sphere.
2
GM  2  R  
Vs   3R    
2R 3   2  
GM  2 R 2 
 3R  
2R 3  4 
GM 11R 2  11GM
 
2R 3  4  8R
Mass of removed part,
3
M 4 R M
=    
4
 R 3 3  2  8
3
Potential at point P due to removed part
3 GM / 8 11GM  3GM 
Vc     
2 R 8R  8R 
Thus, potential due to remaining part at point P,
11GM  3GM 
Vp  Vs  Vc   
8R  8R 
 11  3 GM   GM
8R R
15. Q  Q1  Q2
n1  n 2 n n
 1  2
Ym  1 Y1  1 Y2  1
Ym  3 / 2
16. PA  PB
P0  d1g R  cos   sin    P0  d 2 R  cos   sin  
d1 cos   sin  1  tan 
  
d 2 cos   sin  1  tan 
17. Conceptual
18. Conceptual
19. Efficiency
Tsink
  1
Tsource
Tsink
Now, 0.4  1 
500K

Sec: Sr.Super-60 & All Page 4

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
 Tsin k  0.6  500K
 300K
300K
Thus, 0.6  1 
T'source
300K
T 'source 
0.4
= 750 K
20. Twill be maximum temperature where product of pV is maximum

Equation of line AB, we have

y 2  y1
y1  y 2   x  x1 
x 2  x1
2p  p
 p  p0  0 0  V  2V0 
V0  2V0
p
p  p0  0  V  2V0 
V0
p
p  0 V 2  3p 0 V
v0
p
nRT  0 V 2  3p0 V
v0
1   p0V 2 
T   3p 0 V 
nR  v 0 
For maximum temperature
T
0
V
p0
 2V   3p0
V0
V = 3 / 2V0
(Condition for maximum temperature)
Thus, the maximum temperature of the gas during the process will be
1  p 0 9 2 3 
Tmax    V0  3p0  V0 
nR  V0 4 2 
1  9 9  9 p 0 V0
   p 0 V0  p 0 V0  
nR  4 2  4 nR
21.

Sec: Sr.Super-60 & All Page 5

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

dB 1 3
22.  .A  a a.2
dt 2 2
2 3 2
 a
4
 a2
V 
3 2 3
B
23. tan   2
B1

0 M
2
3
sin 
tan   4 r
0 M
cos 
4 r 3
tan   2tan 
20  30
24. v1   60 cm
 20  30 
u for mirror = 60 + 10 =70 cm
v for mirror = 70 cm
 u for lens (again) = 70 + 10 =80 cm
80  30
 v2   48cm
80  30 
1
25. E  13.6  4 1    51eV
 16 
Vstopping  51  45  46.50 eV
2 5
26.  3   x2  x 
2
2
 5 
9 2  x 2    x 
 2 
25 2
9 2    5x
4

Sec: Sr.Super-60 & All Page 6

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
11 2
  5x
4
11
x 
20
2
27. 1H  21 H  2 He4  Energy
E  4  7.1  4 1.1
 24MeV
hc
28. KE max  

29. Vrx  4 m / s
Vry  8m / s
Vr  42  82  80 m / s
30. T  5  11  16
2u
  u  80 m / s
10

CHEMISTRY
3 2
31. In sp d hybridisation the d-orbitals participated in hybridization are d x  y and d z
2 2 2

32. Due to greater repulsion

33. Addition Elimination Mechanism
34. Acid base reaction with phenol derivative
35. Stability of carbocation
36. More pie bond more stable
37.
OH OH COOH COOH

Cl CH3
(I) (II) (III) (IV)
pKa=9.98 pKa = 9.38 pKa = 4.17 pKa = 4.37
Decreasing order of acidic strength III > IV > II > I
38. boric acid is white ppt
39. Go through structure
40. Salt of Pb(II) gives these observation.
41. The equation is
5NaHSO 3  2NaIO 3  2Na 2SO 4  3NaHSO4  H 2O  I 2
Hence 520 g NaHSO 3 per mole of I2.
a
42. When is large attractive interaction among molecules is large
b
 Vapour pressure will be low
(i.e., non volatile) liquid B
43. apply radius formula for single electron
44. Heat  nCp T

Sec: Sr.Super-60 & All Page 7

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
12.7
128.7   Cp 110
63.5
C p  5.85cal mol 1 K 1
3
45. NH 2  CN s  O 2 g  N 2 g   CO 2 g  H 2O1
2
n  2  1.5  0.5; H  U   n  RT
0.5  8.314  298
H  742.7 kJ 
1000
  742.7  1.239  kJ
 ~ 741.5 kJ mol1 .
46. Molar mass 2  65  130g
Molar mass of PCl5  208.5 g mol1
If  is the degree of dissociation, 130 1  
 1 208
130   205.5  130   78.5
78.5
   0.6
130
47. T1/ 2  C10 n , in the case T1/ 2 C 0 .
 n= 0
6.37  7.84  c  6.02 155
48. 
40 4
155 40 0
c   A
4 6.34  7.84  6.02
0
 5.18A  518pm
49. Zeolite
50. At Concentration less than CMC soap behave as true solutiion
51. Benzyne is also sp hybridized
52. 1, 4, 5
CH3 CH2SH CH2SH CH3

H2N * NH * COOH H 2N * NH * COOH

O O
53.
54. The compound should be [Pt(NH3)4] [PtCl4] which contain only two ions and cannot
give ppt with AgNO3 as Cl- is in coordination sphere. It has two coordination isomers.
55. 2 Na2 S 2O3  I 2  Na2 S 4O6  2 NaI
O O
: ONa
NaO S:
S S
: S:
O O
The four sulphur atoms are in sp3 hybridization.
56. K 4 Fe CN 6   6 H 2 SO4  6 H 2O  2 K 2 SO4  FeSO4  3NH 4 2 SO4  6CO

Sec: Sr.Super-60 & All Page 8

Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
1 1
57. Theortical mole fraction of solute = 
x 1   x  1
1.25 1
Now 
1.25   x  1 5
6.25 = 1.25 + (x – 1)
x=6
ratio= vanthoff’s factor=6/5
58. w  It
w
 It  1=I  0.20 or I=5 amp .
z
59.
NH3 NH3
H2 N NH2 H2 N O
H2C CH2 H2C CO
Co Co
OC CO OC CH2
O O O NH2
NH3 NH3
H2 O
C H2
C C
OC H2 C O
NH2 OC NH2
O NH3 H2 N NH3
O NH3

Co Co Co

O NH3 H2 N NH3 NH3

H2 N

OC C H2 C H2 C
NH3 C O C O
H2 O O

60. Only for Cu2+/Cu, the SRP is positive.

MATHEMATICS
61. Points of intersection y  m1 x  k and y  m2 x  k is  0, k 
1 3
Hence k 
3 2
62. Let x  y  z  w  k
pqrs  k
Now  r 2  k  a 2  k
(r – radius of circle, a = side of the square )
r 1
 r 2  a 2  
a 

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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
63. p1 : x  y  z  1 ……..(i)
p 2 : x  y  z  1 ……..(ii)
p 3 : x  3y  3z  2 ……..(iii)
From (i) and (ii) x = 0 z = 1 + y not satisfying eq.(iii)
 S2 is true clearly L1 , L 2 and L 3 are parallel pair wise,
 S1 is falls
64. To be an equivalence with relation, the relation must be all reflexive, symmetric and
transitive.
T   x, y  : x  y  Z  is
1) Reflexive for  x, x   Z , i.e.x  x  0  Z
2) Symmetric for  x, y   Z  x  y  Z
 y  x  Z , i.e. y, x   Z
3) Transitive for  x, y   Z and  y, w   Z  x  y  Z and y  w  Z , giving
x  w  Z , i.e. x, w   Z
S   x, y  : y  x  1and 0  x  2 is not reflexive, for  x, x   S would imply x  x  1
 0  1 impossible 
Thus, S is not an equivalence relation.
65. Key:2
Because the 42 roots of the equations are symmetrically distributed in the complex
plane, assume a = 1, without loss of generality, Now
2
1  b  1  cos   i sin   2  2cos   2  3 , as given
2

3 
 cos   or  
2 6
2K  42
Because b  1,  is of the form  where 1  K    i.e., 1  K  3
42  12 
6
So, there are 2  3  6 such angles and hence the probability 0.14
41
66. Key:1

The graph of f  x  is showing by shaded line. Clearly f  x  is non-differentiable at two

points x = 1, 2
67. Key:4
Sol : APB  900
So, circum centre is the midpoint Q of AB
Let Q  h, k 
OQA  900 , AOQ  450
Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

Now OQ  cos 450  1

OA 2
2 2
 h  50    k  100  1
 
10 2
2 2
  h  50    k  100   50
2 2
 locus of circum centre of PAB is  x  50    y  100   50
68. Key :2
 2 2
Sol: D  2 3 5 D   82  for  2
4  6
5 2 2
D1  8 3 5 = 5[18 – 10] – 2 [ 48 – 50] + 2 (16 – 30]
10 2 6
= 40 + 4 – 28  0
No solutions for  2
dy x  2  y sin x   y cos x 1  e 
sin x

69. Key :3 
dx esin x  x cos x
 esin x  x cos x  dy  x  2  y sin x  dx  y cos x 1  esin x  dx
esin x dy  y cos xesin x dx  2 xdx  x cos xdy  xy sin xdx  y cos xdx
 d  ye    sxdx   d  xy cos x 
sin x

yeh sin x  x 2  xy cos x  c,sin cef (0)  0  c  0

x2 x2
y  f ( x ) 
esin x  x cos x esin x  x cos x
2
 f   
 1
70. Key :1
Sol: , b  1 3 6  ......  2022
a  1 12 4  ....  1
 
2
Equation : x  2023x  2022  0
71. Key: 3
Sol: The median is the value of 5th item when items are arranged in increasing or decreasing
order  median is unchanged.
72. Key :4
~  ~ p  ~ q   ~ ~ p  ~ q    ~ q  ~ p 
Sol: S–I:

 ~  p ~ q   q ~ p 
 ~ p  q   ~ q  p 
p  q   p  q   q  p    ~ p  q    ~ q  p 
But
S – I is false

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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

~ p  ~ q  ~ p  ~ q   ~ q  ~ p   p  ~ q   q  ~ p 
S – II :
S –II is true
73. Key :1
1 
 f  2021 x   f  2021  f  2020 x   f 
lim 
 
 1  f  2021  x   f  2021 x x0 x  1 f  2020  x   f  2020  

Sol: L  lim   e
x 0  1  f  2020  x   f  2020  
 

 
lim  f ' 2021 x  f ' 2020 x 
0
e x0
 e 1
74. Key:2
Sol: C3  C3  C2 , C 2  C2  C1 Given det values D=0
75. Key:3
Let       
cos      cos       cos       cos      cos      cos    
 cos   cos   sin   sin   2
x2  4
lim 2
x 2 x2  x  2
76. Key:1
 1, x 1
Sol: f 1  x    2
 3 x , x  1
 In 1,   f is increasing in  ,1 f is decreasing  f has min. at x  1
 f 1   f 1   a  1  1  1  0
  a  1  0  a  1
77 key : 2
Sol : Equation of normal to y2  4x is
y  mx  2m  m 3 it is passing through P  h, k  .
m 3  m  2  h   k  0 …………..(i)
m1  m 2  m 3  0
m1m 2  m 2 m3  m3m1  2  h
m1m 2 m 3   k
k
 m 3   it satisfy Eq.(i)

Locus y2   2 x  2 2  3
Comparing with y 2  4x
2
78. Key :2
 2 

  sin   0,   cos   0 and  cot    1  x  y infinitely many solutions.
Sol.   2 , 3
 
7
And   ,   sin   1,   cos   0 and  cot   0  x  0, y  0 unique solution.
 6 
2 2
79. Key :2 Here,  2 cos   11cos     5 cos   10 cos   and
2 2
 2sin   11sin     5sin   10sin  
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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
cos     25
Adding these two, 
cos      11
80. key : 4
 k   k 
Sol :  k  cos    i sin  ,
 1010   1010 
 2k   2k 
 k  cos    i sin  ,
 2020   2020 
 k , k  1, 2,3,....2020 are the vertices of regular polygon having 2020 sides
504

 4k  2   4k
504
k 1
63
= 8
63

k 1
4k 3   4k 1

81. ANS:18

Sol: a  b  3i  3 j

c. a  b  3 2
2      2  c . c  a  b  18  c  18
ab
 
82. ANS:1
Sol: Let e x  t , t   0,  
Given equation will be t 4  t 3  4t 2  t  1  0
1 1  1   1
Divide by t 2 to get t 2  t  4   2  0   t 2  2    t    4  0
t t  t   t
1 1
Let t    ,   2,    t 2  2   2  2
t t
So, the equation will be   2     4  0
2

 2    6  0    3,2
   2,   ,we get   2  e x  e x  2
So, x  0 only solution
83. key:2
Sol : Let f  x   x 3  x 2   x  1 ,   
f  0   1  0, f  1      0
 root x 0 lies between - 1 and 0
 1 
 x 0  0  tan 1      cot 1  x 0 
 x0 
 1 
 tan 1  x 0   tan 1     / 2
 x0 
15
r 1
84. ANS;9 N    1 .15 Cr .17 r  C15
r 1

 C1. C15  C2 .34 C15 15 C3 .51C15  ..... 15 C15 .1517 C15  1715
15 17 15

Ten’s digit is 9
85. key;2
Sol: Curve is rectangular hyperbola

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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s

n  n2 1
Perpendicular distance , d n 
2
n n 1 1
lim  n.d n   lim n 2  1  n  lim 
n  n  n  2
2 2 n 1  n 2 2
86. ANS:2
 
2
G.I .  e x x.e x  c    x   xe x   '  x   e x  x  1   min    1  m  1 / e
  1 / m  2
1
87. ANS:9 V   r 2
3
 1 r2 
2 4 6 d 2 2
V2 
9
 r r 
dr
 V  0r 
3
1 
2

2
 3 3  2  3 6  
  1
3
 a  3
a  b  9
b  6
88. ANS;6 f  x   g  x 
 x  1  1
 x  1 x  1
 x x  2   0
x  0, x  2  0, so  x  0
 x 1
x=0,1,2,3,4,5
89. ANS:0
Since A and B are orthogonal
AA T  I  BBT
This also tells us that A,B are invertible
Given that
det(A) + det(B) = 0
det(A) = - det(B)
which gives us
det  A   det  B   1  det  AB 
A  B  AI  BI
 ABBT  BAA T

= A BT  A T B 
det  A  B   det  A  BT  A T  B 
 det  A  .det  BT  AT  .det  B
T
 det  AB  .det  B  A  
 
= - det  A  B

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Sri Chaitanya IIT Academy 06-06-2021_Sr.Super60 & All_Jee-Main_GTM-27_Key & Sol’s
2 det  A  B   0
det  A  B   0
90. ANS;2
Given , fofox(x)+f(x)=2 ………(1)
Replace f(x) by x
 fof  x   x  2
 ff  x   2  x ……..(2)
Now from equation 91) and (2), we get f  f  f  x     2  f  x 
 f 2  x  2  f  x
2 1
M   f  x  dx    f  x   f  2  x   dx  2
1 0

Sec: Sr.Super-60 & All Page 15