product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90

7060071XBR
Review Date: May 31 (Apr.) 2013
Page 1 of 10

_____________________________________________________________________________________________________________________

SAFETY DATA SHEET OF

CHEMICAL PRODUCTS (SDS)
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

According to the revision date above, this Safety Data Sheet is in accordance with Brazilian regulations.

Product
product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
Product description: Base oil and Additives
DGN:7060071XBR
Product code: 20203010E010, 550715
Intended use: Gear oil

Company Identification
Supplier Cosan Lubricants and Specialties S. A.
RIBEIRA BEACH, 1
GOVERNOR'S ISLAND - RIO DE JANEIRO - RJ ZIP CODE 21930-080 Brazil
24-hour Health Emergency +55 21 3386-2329/ +55 19 3403-2091/ 0800 644 1562
Technical Information about the product +55 21 3386-2329/ +55 19 3403-2091/ 0800 644 1562
E-Mail [email protected]
FAX +55 21 3386-2197

SECTION 2 HAZARD IDENTIFICATION

This material is not hazardous according to regulatory guidelines (see Section 15 of this Safety Data Sheet).

Other risk information:

PHYSICAL / CHEMICAL HAZARDS

Without significant risks

Health Risks
High-pressure injection under the skin can cause serious damage. Excessive exposure can result in irritation.
of the eyes, skin, and respiratory system.

ENVIRONMENTAL RISKS
Without significant risks

IDENTITY OF Health: 0 Flammability: 1 Reactivity: 0

RISK ISSUED FROM
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (Apr.) 2013
Page 2 of 10

BY NFPA:

NOTE: This material should not be used for any purpose other than for which the product was intended.
manufactured, described in Section 1, without consulting an expert. Health studies have shown that exposure to
Chemical products can pose health risks.

SECTION 3 COMPOSITION AND INFORMATION ABOUT THE INGREDIENTS

This material is defined as a mixture.

Dangerous Substance(s) or Complex Substance(s) requiring disclosure

Name CAS# Concentration* GHS Hazard Codes

Catalytically Paraffinic Oil 64742-71-8 5 - 10% H304
DEPARAFFINIZED (PETROLEUM)
OLEFIN SULFIDE 5 - 10% H227
HEAVY PARAFFIN DISTILLATE EXTRACTED BY 64742-65-0 30 - 40% H304
SOLVENT AND FREE OF WAXES.

All concentrations are in weight percentage, unless the ingredient is a gas. The concentrations
two gases are in volumetric percentage.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove the product immediately to avoid further exposure. For those assisting, avoid exposing yourself.
and let others expose themselves. Use appropriate respiratory protection. If irritation occurs in the device
respiratory, dizziness, nausea, or unconsciousness, seek medical assistance immediately. If cardiac arrest occurs
in breathing, apply ventilation with a mechanical device or use mouth-to-mouth breathing.

CONTACT WITH THE SKIN

Wash the contact areas with water and soap. If the product is injected into or under the skin, or
into any part of the body, regardless of the appearance of the wound or its size, the
The individual should be assessed immediately by a doctor as a surgical emergency case. Even if
the initial symptoms of high-pressure injection may be minimal or absent, early surgery, within the
the first hours can greatly reduce the extent of the damage.

EYE CONTACT
Wash very well with water. If irritation occurs, seek medical assistance.

INGESTION
Normally, first aid is not necessary. Seek medical assistance if any occurs.
discomfort.

SECTION 5 FIRE FIGHTING MEASURES

MEANS OF EXTINCTION
 Product Name: TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (April) 2013
Page 3 of 10

Suitable Method for Extinguishing: Use water mist, foam, chemical powder, or carbon dioxide (CO2)
to extinguish the flames.

Improper means for extinction: Direct jets of water

FIRE EXTINGUISHING
Fire Extinguishing Instructions: Promote the evacuation of the area. Avoid using water on
fire control or those resulting from dilution reach the streams, sewers, or water supplies
drinkable. Firefighters must use standard personal protective equipment when they are in
closed spaces and use self-contained breathing apparatus. Use water spraying to cool the
surfaces exposed to fire and to protect workers.

Hazardous Combustion Products: Smoke, Fumes, Aldehydes, Sulfur Oxides, Products of

Incomplete combustion, Carbon oxides

Flammability Properties
Flash point [Method]: >165ºC (329ºF) [ASTM D-92]
Inflammability Limits (approximate % of volume in air): LEL: 0.9 7.0
Auto-Ignition Temperature: N/A

SECTION 6 CONTROL MEASURES FOR SPILLING OR

LEAK

NOTIFICATION PROCEDURES
In the case of an accidental spill, please notify the authorities, in accordance with the regulations that apply.
apply.

PROTECTIVE MEASURES
Avoid contact with the spilled material. See Section 5 for Firefighting Measures. See Section 2.
for Hazard Identification. See Section 4 for First Aid Measures. See Section 8 for Control
of Exposure and Individual Protection. Additional protective measures may be necessary, depending on the
specific circumstances and/or the opinion of emergency response experts.

For those responsible for emergency response: Respiratory protection: respiratory protection will be
necessary only in special cases, for example, the formation of fogs. Semi-face or face mask
complete with dust/organic vapor filter(s) or self-contained breathing apparatus can be used,
depending on the size of the spill and the potential level of exposure. If exposure cannot be
completely characterized or an atmosphere deficient in oxygen is possible or foreseeable, the use
autonomous breathing apparatus is recommended.
Work gloves resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA)
they are not water-resistant and are not suitable for emergency use. Protective goggles against products
chemicals splash or contact with the eyes are possible. Small spills: Work clothes
Common anti-static garments are usually suitable. Large spills: full-body resistant overalls.
Chemical products and anti-static material are recommended.

SPILL MANAGEMENT
Spill on Earth: Stop the leak if you can do so without risking yourself. Recover through
by pumping or with an appropriate absorbent.

Water spill: Stop the leak if you can do so without risking yourself. Contain the spill.
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (April) 2013
Page 4 of 10

_____________________________________________________________________________________________________________________
immediately with containment barriers. Notify other carriers. Remove the top of the
surface or use appropriate absorbent agents. Consult a specialist before using dispersants.

The recommendations for when there are spills in water and on land are based on the highest possibility of
occurrence for this material. However, the geographical conditions, the wind, the temperature, (in case of
water spill) waves, and the direction and speed of ocean currents can greatly influence
scale and appropriate actions must be taken. For this reason, local specialists must be
consulted. Note: Local regulations should specify the actions to be taken.

PRECAUTIONS FOR THE ENVIRONMENT

Large spills: Place the spilled liquid in dikes for recovery and subsequent disposal. Prevent the
entry into water resources, sewage, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Prevent small spills and leaks to avoid slippery surfaces. Material can accumulate.
static charges that can cause an electrical spark (source of ignition). When the material is handled
In bulk, an electric spark can ignite any flammable vapors from liquids or residues that
may be present (for example, during the transition of loading operations). Use
appropriate connection and/or grounding procedures. However, connectors and grounding cannot
eliminate the risk of static buildup. Consult the applicable local standards for guidance. References
additional include the American Petroleum Institute 2003 (Protection against Static Electricity-Induced Ignition,
Lightning and Surge Protection or National Fire Protection Agency 77 (Recommended Practices on )
Static Electricity) or CENELEC CLC / TR 50404 (Electrostatics - Code of practices to avoid risks
due to static electricity).

Static accumulator: This material is a static accumulator.

STORAGE
The choice of storage container can affect the accumulation or dissipation of static. Do not store
in open containers or unlabeled. Keep away from incompatible materials.

SECTION 8 EXPOSURE CONTROL AND PERSONAL PROTECTION

Exposure Limit Values

Exposure limits / standards (Note: the exposure limits are not for the additives)

Name of the substance Form Limit / Standard Source Note

PARAFFIN OIL Mist TWA 5 mg/m3 N/A OSHA Z1
CATALYTICALLY
DEPARAFFINATED (PETROLEUM)
PARAFFINIC OIL Fraction that TWA 5 mg/m3 N/A ACGIH
catalytically can be
DEPARAFFINATED (PETROLEUM) Finalized
PARAFFIN OIL Fog TWA 5 mg/m3 N/A ACGIH
catalytically
DEPARAFFINIZED (PETROLEUM)
HEAVY PARAFFINIC DISTILLATE Mist TWA 5 mg/m3 N/A OSHA Z1
EXTRACTED BY SOLVENT AND
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (April) 2013
Page 5 of 10

EXEMPT FROM WAX.

HEAVY PARAFFINIC DISTILLATE TWA 2000 500 ppm N/A OSHA Z1
EXTRACTED BY SOLVENT AND mg/m3
FREE OF WAX.
HEAVY PARAFFINIC DISTILLATE Fraction that TWA 5 mg/m3 N/A ACGIH
EXTRACTED BY SOLVENT AND it can be
WAX FREE. inalada
HEAVY PARAFFINIC DISTILLATE Fog TWA 5 mg/m3 N/A ACGIH
EXTRACTED BY SOLVENT AND
WAX FREE.

Limits for exposure / standards for materials that can be formed when handling this product:
When mists or aerosols may occur, the following is recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5
mg/m³ OSHA PEL.

Note: The limits / standards are just a guideline. Follow the applicable regulations.

Engineering Controls

The level of protection and types of controls needed will vary depending on the conditions and the potential of
exhibition. Consider control measures:
No special requirements, under normal usage conditions and with adequate ventilation.

Personal Protection

The selection of personal protective equipment varies depending on the conditions of exposure such as
application practices, handling, concentration and ventilation. Information about the selection of equipment
The protection information for the use of this material is provided below and is based on its normal use.

Respiratory Protection: If the controls carried out by the local engineering do not maintain the
concentrations of air contaminants at a level that is adequate to protect the health of the worker,
it may be appropriate to use an approved respirator. The selection of the respirator to be used, and its
maintenance must comply with the required regulations, if applicable. Types of respirators
they must be considered inclusive for this material.
No special requirements, under normal usage conditions and with adequate ventilation.

For high concentrations of air, use an approved air-supplied respirator, operated so that
the pressure is positive. Respirators with air supply with escape cylinders can be used when the
oxygen levels are inadequate, or there is a risk of gas/vapor formation, or if the capacity of
filter purification is excessive.

Protection for the hands: Any specific information about gloves is provided based on the literature
published and in the data from glove manufacturers. The suitable type of gloves and their durability will differ
depending on the specific usage conditions. Contact the glove manufacturer for more information
specific information about glove selection and durability. Inspect and replace worn gloves or
damaged. The types of gloves considered for this product include:
Usually, no protection is necessary under normal usage conditions.

Eye/face protection: If there is a possibility of contact, it is recommended to use glasses.

security with side protection.

Skin and body protection: Any specific information about the clothing is based on
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Revision Date: May 31 (Apr.) 2013
Page 6 of 10

_____________________________________________________________________________________________________________________
published literature and data provided by manufacturers. The types of clothing to be considered
for this material include:
According to good industrial hygiene practices, precautionary measures must be taken.
to avoid contact with the skin. No protection is usually required for the skin,
under normal conditions of use.

Specific hygiene measures: Always observe good personal hygiene measures, such as washing yourself.
after working with the material and before eating, drinking and/or smoking. Routinely wash the clothes of
work and protective equipment to remove contaminants. Discard clothing and shoes
contaminated that could not be cleaned. Practice good hygiene and cleaning habits.

ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharges to air, water, and soil. Protect the
environment through the application of adequate control measures to avoid or limit emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: The physical and chemical properties are provided for safety, health, and consideration only.
environment, and may not fully represent the product specifications. Contact the supplier
for additional information.

GENERAL INFORMATION
Physical condition: Liquid
Brown
Characteristic
Odor threshold: N/A

IMPORTANT INFORMATION ABOUT HEALTH, SAFETY, AND THE ENVIRONMENT

Relative Density (at 15 ºC): 0.891
N/A
Flash Point [Method]: 165°C (329°F) [ASTM D-92]
Flammability limits (approximate % of volume in air): 0.9 7.0
Auto-ignition temperature: N/A
Range: N/A
Decomposition temperature: N/A
Vapor density (Air = 1): 2 to 101 Kpa
Vapor pressure: Less than 0.013 kPa (0.1 mm Hg) at 20ºC
Evaporation rate (n-butyl acetate = 1): N/A
N/A
Log. of Electrical Energy [Pow] (n-Octanol / Water Partition Coefficient): 3.5
Solubility in water: Negligible
74.86 cSt (74.86 mm2/sec) at 40ºC | 14.25 cSt (14.25 mm2/sec) at 100ºC
Oxidizing Properties: See Risk Identification Section.

OTHER INFORMATION
Freezing point: N/A
Melting point: N/A
Flow Point: -32°C (-26°F)
DMSO extracted (only mineral oil), IP-346: < 3 % weight
 Product name: TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31, 2013
Page 7 of 10

_____________________________________________________________________________________________________________________
SECTION 10 STABILITY AND REACTIVITY

STABILITY: The material is stable under normal conditions.

CONDITIONS TO BE AVOIDED: Excessive heat. High sources of ignition energy.

INCOMPATIBLE MATERIALS AND SUBSTANCES: Strong Oxidants

DANGEROUS PRODUCTS OF DECOMPOSITION: The material does not decompose at room temperature.

POSSIBILITY OF DANGEROUS REACTIONS: Dangerous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
EXHIBITION ROUTE Conclusion / Observations
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for materials.
of a similar structure.
Irritation: No end point data available Negligible risk when handled at room temperatures
for the material. the normals. Based on the evaluation of the components.

Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for materials
of a similar structure.

Pele
LD50 > 5000 Minimally Toxic. Based on test data for materials
mg/kg of similar structure.
Irritation (Rabbit): Available data. Negligible skin irritation at room temperature. Based on
in test data for materials of similar structure.

Eye
Irritation (Rabbit): Available data. It may cause mild discomfort in the eyes, of short duration.
Based on test data for structural materials
similar.

OTHER SHORT AND LONG-TERM HEALTH EFFECTS OF EXPOSURE

Effects on health are expected from sub-chronic, chronic respiratory or skin sensitization.
mutagenicity, reproductive toxicity, carcinogenicity, target organ toxicity (single or repeated exposure)
aspiration toxicity and other effects based on human experience and/or experimental data.

For the product itself:

Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory system.
Contains:
Severely refined base oil: Did not cause cancer in tested animals. The portion that represented the
material passed the IP-346 test, Ames Modified, nor in other selection tests. Studies on the skin
Inhalation studies showed minimal effects. Dermal and inhalation studies showed minimal effects;
nonspecific infiltration in immune cells of the lungs, oil deposition and minimal granuloma formation.
Non-sensitive in animal testing.
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (April) 2013
Page 8 of 10

translatedText

The following ingredients are mentioned in the lists below: None.

--REGULATORY LISTS RESEARCHED--

1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information provided is based on available data about the material, about the components of the material, and
about similar materials.

ECOTOXICITY
Material -- It is not expected to be harmful to aquatic organisms.

MOBILITY
Basic oil components -- Material has low solubility and will float and is expected to migrate
from water to land. Possibility of causing division in sediments and in solids of sewage.

PERSISTENCE AND DEGRADABILITY

Biodegradation
Components of base oil -- Possibility of being inherently biodegradable

POTENTIAL FOR BIOLOGICAL ACCUMULATION

Basic oil components -- It has the potential to be bioaccumulative; however, the metabolism or
Physical properties can reduce bioconcentration or limits of bioavailability.

SECTION 13 CONSIDERATIONS ON TREATMENT AND DISPOSAL

The disposal recommendations are based on the type and method provided for the material. The disposal must be of
in accordance with current applicable laws and regulations, and with the characteristics of the material at the time of disposal.

RECOMMENDATIONS FOR DISPOSAL

The product can be burned in a closed and controlled incinerator for value fuels or can
to be incinerated under supervision, at high temperatures to prevent the formation of products
undesirable in combustion. Protect the environment. Dispose of used oil in appropriate places. Minimize the
Contact with skin. Do not mix with used oils, solvents, brake fluids or cooling fluids.

Warning about PackagingTEXT OF THE CAUTION LABEL: Empty containers may retain residues and
they can be dangerous. DO NOT PRESSURIZE, CUT, MELT, PUT IN FIRE, PIERCE, GRIND, OR
 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (Apr.) 2013
Page 9 of 10

EXPOSE SUCH RECIPIENTS TO HEAT, FLAMES, SPARKS, STATIC ELECTRICITY, OR OTHERS

IGNITION SOURCES; THEY CAN EXPLODE AND CAUSE SERIOUS INJURIES OR DEATH. Do not promote the
repackaging or cleaning of the container without the residue having been completely removed. Empty drums must be
completely drained, dried and properly returned to a drum reconditioner. All containers
must be disposed of according to current environmental and governmental regulations.

SECTION 14 TRANSPORTATION INFORMATION

LAND: Not Regulated for Land Transport

ANTT No. 420 and its updates (National Agency for Land Transport).

MARITIME (IMDG): It is not regulated for marine transportation according to the IMDG code.
International Maritime Dangerous Goods Code (IMDG Code);

Standard 5 of the DPC (Department of Ports and Coasts of the Ministry of the Navy);
ANTAQ (National Agency of Waterway Transportation).

Marine Pollution: No

AIR (IATA): Not Regulated for Air Transport

Dangerous Goods Regulation (DGR IATA);
DAC - Department of Civil Aviation of the Ministry of Aeronautics.

SECTION 15 REGULATIONS

This material is not hazardous as defined by NBR 14725-2 / Risk Classification System.

Meets the requirements of the following national/regional chemical inventory: AICS, ENCS
IECSC, KECI, PICCS, TSCA
Special Cases.

Inventory Status
NDSL Applicability restrictions

SECTION 16 OTHER INFORMATION

Not Determined

KEY FOR THE H CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):

H227: Flammable Liquid: Flammable Liquid, Cat 4

H304: May be fatal if swallowed or enters airways; Aspiration, Cat 1

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

 product_name TOYOTA GENUINE GEAR OIL SUPER 75W-90
7060071XBR
Review Date: May 31 (Abr.) 2013
Page 10 of 10

_____________________________________________________________________________________________________________________
Updates made in accordance with the implementation of the GHS requirements
.
-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained in this document express what ExxonMobil has to offer at its best.
knowledge about this subject on this date. You can contact ExxonMobil to ensure that this
The document is the most recent and available by ExxonMobil. The information and recommendations are provided for the
analysis and consideration of the user, being their responsibility to verify if they meet the requirements
necessary requirements for your private use. If the buyer repackages this product, it will be their responsibility
The user should ensure that the product remains within its safety and health properties and others.
necessary information including that of the packaging. The appropriate procedures for the safe handling of this
product, must be communicated to all people who have operational contact with it up to the end user. The
any alteration to the statements in this document is expressly prohibited. Except as established by law,
Republication or retransmission of this document in whole or in part is not permitted. The term ExxonMobil is
used generically for convenience, and may include one or more companies within the ExxonMobil organization
Chemistry or the corporation ExxonMobil or any affiliate where there is a direct or indirect interest in this matter.

-----------------------------------------------------------------------------------------------------------------------------------------------------

For internal use only

0B, 0B, 0, 0, 0, 0 PPEC: A

DGN: 7060071XBR (1010627)

-----------------------------------------------------------------------------------------------------------------------------------------------------
Editorial rights 2002 Exxon Mobil Corporation, All rights reserved.