Application of An Enhanced RBI Method For Petrochemical Equipments Lee2006
Application of An Enhanced RBI Method For Petrochemical Equipments Lee2006
Journal of Pressure Vessel Technology Copyright © 2006 by ASME AUGUST 2006, Vol. 128 / 445
line. To incorporate the characteristics of all materials, the mole Characteristics of ASME Code. The concepts of API and
fraction of materials extracted from material balance table 共MBT兲 ASME methodologies are similar because both of them suggest
in the process and flow diagram 共PFD兲 is considered. progression from the qualitative risk ranking approach to the
quantitative approach. When adopting the quantitative risk rank-
2 Representative RBI Methodologies ing procedures, requiring a great deal of effort, it is possible to
calculate the risk value by multiplying the probability and the
Characteristics of API Code. The risk is an effective index to consequence cost. However, although the risk itself may be math-
evaluate structural integrity of equipment. In the API RBI meth- ematically precise, risk tolerance is not. Besides, certain param-
odology, it is utilized as a technical basis for prioritizing and man- eters in ASME RBI methodology—operating temperatures and
aging an appropriate inspection. The RBI methodology defines the various material properties and so on—may enter into calculations
risks of operating equipments as combination of two separate as time dependent distributions. In this case, failure probability
terms: increases due to aging or accumulated damage and decreases by
Risks = LOFs ⫻ COFs 共1兲 adequate repair or replacement activities.
This risk-based methodology groups or ranks systems and com-
where the subscript s means the scenario number, LOF is the
likelihood of failure for scenario and COF is the consequence of ponents after considering their specific features. In the case of
failure for scenario. qualitative risk analysis, the resultant risks are represented as one
The RBI methodology can be applied as qualitative, quantita- of 16 areas and used mainly for screening. On the other hand,
tive, or in combinational forms. All approaches provide a system- quantitative risk analysis measures or estimates the risk numeri-
atic way to screen the risks, identify areas of potential concern, cally. So, the corresponding risk values can be used for identifying
and develop a prioritized list for in-depth inspection or analysis. the best time of inspection or replacement as well as a variety of
The primary difference between the qualitative and quantitative financial calculation. Figure 2 shows the RBI process based on
approaches is the level of resolution. The qualitative approach ASME code in which the use of operating experience database
requires less detailed information regarding the facility and, con- and analytical damage models are recommended 关12兴.
sequently, its discriminative ability is quite limited. The qualita-
tive approach is normally used to rank operating facilities or ma- Characteristics of RIMAP. Since RIMAP is the ongoing
jor equipments of them to determine priorities for further project to develop a European RBI guideline, here, tentative re-
quantitative RBI. The quantitative RBI analysis, on the other sults are summarized. In this methodology, risk is defined as the
hand, provides specific risk values for each equipment and subdi- combination of probability of failure 共PoF兲 and consequence of
vided parts, etc. In accordance with the amount of information, a failure 共CoF兲 for a given scenario. RIMAP distinguishes between
level of comprehensive inspection plan can be established for the two types of scenario—worst case scenario and expected
process facilities. Figure 1 shows the risk evaluation process of scenario—and recommends use of the expected scenario in analy-
the qualitative, semi-quantitative, and quantitative RBI ap- ses. With respect to equipments of petrochemical, chemical,
proaches based on API codes 关9,10兴. power, and steel works industries, enormous efforts are being fo-
cused on analyzing the PoF and CoF. However, as same to the API rather than LOF. Therefore, with respect to likelihood analysis of
and ASME methodologies, the scenario of RBI and RBM starts petrochemical equipment, the procedure described in API 581
from active degradation mechanisms and leads to consequences. code can be used without modification.
The guidance to assess the PoF of equipment is being con- In the view point of materials, making up the oil refinery equip-
ceived for continuous degradation mechanism and systematic in- ment, it is possible to estimate the COF with a representative
spection program 关18兴. Also, to analyze the CoF, a set of require- material described in API 581 code based on NBP. In a petro-
ments is being formulated with respect to four aspects: safety, chemical plant, however, there are relatively larger numbers of
health, environment, and business 关19兴. For passive equipment materials per equipment related to various heat and chemical re-
like a pressure vessel, the failure scenario is usually loss of con- action processes. When using representative material according to
tainment. The loss of containment of flammable or toxic sub- current RBI guidelines, the calculated COF would not be accurate
stances will lead to safety, health, and environment consequences, and lead to in appropriate risk calculation. So, in this paper, prin-
as well as business consequence. The failure mode of active cipal efforts are devoted to develop an enhanced consequence
equipment is usually the loss of a particular function although loss analysis procedure. All the available materials of ethylene facili-
of containment may occur as well. In the case of the loss of ties, listed in Table 1, are used for prototypal risk assessment and
function failure mode the consequence is belong to business con- the number of them is 25 and over.
sequence.
Modified COF Evaluation Procedure. Representative RBI
3 Enhanced RBI Methodology methodologies based on API 580/ 581 codes, ASME code,
RIMAP, and so on are useful guidelines to assess the risk ranking
Characteristics of Enhanced RBI. The role of refinery plant is and design the appropriate inspection plan in oil refinery, petro-
to separate various liquid mixtures of hydrocarbons—liquefied pe- chemical, and nuclear power plants. Especially, the API 580/ 581
troleum gas 共LPG兲, gasoline, kerosene, gas oil, and so on—from a guideline has been utilized in evaluating the risk of equipments in
crude oil using differences of their normal boiling points 共NBPs兲.
While, the main function of petrochemical plant is to manufacture
basic raw materials—ethylene, propylene, butadiene, benzene,
toluene, and xylene—by cracking naphtha produced in oil refinery Table 1 Material list of ethylene facilities
plant. The main role of petrochemical plants is to produce plastics,
synthetic fiber, and synthetic rubber such as polyethylene, poly- Material Name Material Name
propylene, polystylene, purified terephthalic acid 共PTA兲, etc.
There are several raw material treatment processes in refineries H2 Hydrogen C 5H 6 1-pentene-3-yne
and petrochemical plants. For example, heating is a common pro- CO Carbon monoxide C 5H 8 1-pentyne
CO2 Carbon dioxide C5H10 1-pentene
cess in both types of plants while various chemical reaction pro-
H 2S Hydrogen sulfide C5H12 n-pentane
cesses are necessary only in petrochemical plant. The refinery
CH4 Methane C 6H 6 Benzene
plant requires relatively fewer types of equipment such as heat Acetylene Cyclohexane
C 2H 2 C6H12
exchanger, heater, and crude distillation unit 共CDU兲, etc. On the Ethylene Toluene
C 2H 4 C 7H 8
contrary, the petrochemical plant is comprised of more complex Ethane 1-heptene
C 2H 6 C7H14
equipment such as heat exchanger, heater, hydrotreater, reformer, C 3H 4 Propadiene C 8H 8 Styrene
fractionator column, extractor column and drum, etc. 关20兴. In spite C 3H 6 Propylene C8H10 Ethylbenzene/O-xylene
of the differences, since the mechanical characteristics of some C 3H 8 Propane C8H16 1-octene
equipments in both plants are alike, it is permitted to adopt iden- C 4H 6 1,3-Butadiene C9-205C n-paraffin
tical generic failure frequency if specific equipment modification C 4H 8 1-Butene H 2O Water
and management system evaluation factors are considered. In ad- C4H10 n-Butane
dition, perception of risk is often strongly influenced by the COF
gas, refinery, and petrochemical plants. Generally, the plant safety timation of realistic COF reflecting all material characteristics, a
and availability can be improved by application of RBI with ap- database to manage the specific information in MBT—molecular
propriate plant management practices. weight, density, NBP, and so on—was developed. Figure 4 shows
In accordance with industrial experience, for realistic conse- the initial screen of interface program between the material man-
quence analysis of petrochemical equipment, the characteristics of agement database and enhanced RBI program.
all materials in the mixture should be reflected. The characteristics
of each material to be considered are flammability, toxicity, and Development of Enhanced RBI Program. A RBI program
the degree of influence on failure. Figure 3 shows the proposed adopting the proposed COF estimation procedure for the sake of
procedure to estimate COF by the semi-quantitative approach. In
order to substitute the characteristics of all materials, the mole
fraction which is a good parameter to complement the conserva-
tiveness of API 581 code was used in this procedure. Also, the
mathematical expression for ideal heat capacity at constant pres-
sure 共C p兲 represented to the third degree of temperature 共T兲 in API
581 code was altered to the fourth degree of temperature in this
procedure as follows 关21兴
C p = A + BT + CT2 + DT3 + ET4 共2兲
where A, B, C, D, and E are ideal gas constants. In addition, Eq.
共7.1兲 described in API 581 was corrected as follows
Q L = C dA 冑
2⌬P
gc
144
共3兲
petrochemical plant has been developed. Microsoft Visual C⫹⫹ required. For instance to determine total TMSFs, each damage
6.0, Microsoft Visual Basic 6.0, and Microsoft Access 2000 were mechanism such as thinning, stress corrosion cracking 共SCC兲,
used as a toolkit. Thereby, it becomes possible to perform a real- high temperature hydroattack 共HTHA兲, and brittle fracture phe-
istic risk analysis of equipment and to compare the evaluation nomena was evaluated and added, then the LOFs of columns and
results to those by the traditional API 581 method. The developed vessels were calculated. In the case of quantitative likelihood
program consists of a graphic user interface, evaluation, and da- analysis, the information of the number of nozzles, planned or
tabase layers. In the database layer, basic information such as unplanned shutdown, stability ranking, relief valve 共RV兲 mainte-
operating conditions, equipment geometries, construction mate- nance, etc., were additionally considered to obtain mechanical and
rial, fluid material, inspection, and mechanical damage data are process subfactors.
archived. On the other hand, in the evaluation layer, the basic
information is assessed and the results are represented in terms of Risk Assessment of Columns. In order to verify the applica-
risk matrix, total technical module subfactor 共TMSF兲, likelihood bility, the developed RBI program has been applied to evaluate
of failure, consequence of failure and financial risk. Figure 5 the risks of major equipment. The columns of ethylene facilities
shows the three-tier structure of the proposed RBI program which were subdivided into bottom 共BTM兲 and top 共TOP兲 parts, and the
is widely accepted in window-based evaluation systems. resultant total of 30 parts is listed in Table 3 with corresponding
The proposed risk assessment program possesses all the quali- information extracted from piping and instrumentation diagram
tative, semi-quantitative, and quantitative risk evaluation modules. 共P&ID兲.
As one of key features, the semi-quantitative and quantitative risk Figures 8共a兲 and 8共b兲 represent the risk assessment results of
evaluation modules can provide risk evaluation results based on columns obtained by the semi-quantitative RBI module in which
both the proposed and API COF estimation procedures. Toxic ma- the risk is defined as one of high, medium high, medium, and low
terials as well as representative materials are determined automati- level. As shown in the figure, by using the proposed method, risk
cally for comparison to those getting from the existing guideline. distributions were moved to lower risk area. The percentage of
Also, several material management functions such as to input the risk ranking above medium high according to traditional API 581
mole fraction, etc., were added. Figure 6 depicts the result screens method was 33% while that obtained by the proposed method was
of qualitative, semi-quantitative, and quantitative RBI programs, 26%. Also, from the assessment results using the quantitative RBI
respectively, as an example. module, it was found that the risks estimated by the proposed
method were significantly lower compared to those evaluated by
4 Application Of the Enhanced RBI Program the API 581 method even though there were a few exceptional
cases to show disparities from the general trend. On the other
Equipment Selection and LOF Calculation. The petrochemi- hand, to find out the root causes of high risk parts, a comparison
cal plant can be defined by a series of processes such as pyrolysis, between individual risk 共RiskA兲 and mean risk 共RiskM兲 of all col-
quench, gas compression, acid gas removal, drying, caustic, pro- umns was performed. As shown in Fig. 8共c兲, relatively high risk
pylene purification, refrigeration, etc. Even though each process parts of columns are operated under high pressure conditions or
has lots of its own equipment to attain its intended function, there possess acid and toxic materials.
are several major equipment common to most of the processes.
From integrity evaluation point of view, as shown in Fig. 7, col- Risk Assessment of Vessels. Similar risk assessment was car-
umn and vessel which deal with pressurized chemical materials ried out for vessels, such as drum, accumulator, and reactor, of
were chosen for prototypal risk assessment. which integrity should be maintained sufficiently to store petro-
For likelihood analysis of columns and vessels, as mentioned chemicals and to prevent the backward flow in pipelines. Both the
previously, the procedure described in API 581 code was used semi-quantitative and quantitative RBI assessment was conducted
without modification. Table 2 represents an example of the input for 18 vessels as represented in Table 4. Figure 9共a兲 depicts the
conditions used in the LOF calculation by semi-quantitative and output from semi-quantitative RBI module adopting the tradi-
quantitative RBI approaches. In the case of semi-quantitative like- tional API 581 method and Fig. 9共b兲 illustrates those obtained by
lihood analysis, equipment data related to design and operating the proposed method. As illustrated in the figure, the resultant risk
conditions, geometry data, construction material, and TMSF are matrices from the two RBI methods were alike even though the
Part No.
Equipment identification 共TOP, BTM兲 Description Construction material
Table 4 Vessel list considered in prototypal assessment PGC: process gas compressor
Equipment
identification Part No. Description Construction material