:

Dear students, morning to all. Note that last class we LS coupling Now we JJ
coupling This is heavier atom JJ coupling is like as heavier atom This is very
important because in JJ coupling Arrays is heavier atom Spin-spin interaction
similarly, orbit-orbit interaction will but spin-orbit magnetic interaction will be
strong so JJ coupling means it arrives the heavier atom Similarly, spin orbit
magnetic interaction will strong Spin orbit 19 interaction will very strong for
note this J-J coupling is heavier atom here spin-spin interaction and orbit-orbit
interaction are weak but spin-orbit-magnet interaction is strong same way LS
coupling is opposite LS coupling is in lighter atom J-J coupling is in heavier
atom LS coupling is spin-spin orbit-orbit The interaction between orbital 90
momentum and spin 90 momentum of single electron is much greater than the
interaction between orbital and spin momentum of orbital and spin momentum of
single electron is much greater than interaction between orbital momentum of
different electron or spin momentum of different electrons The interaction between
orbital and spin momentum of single electron is much greater than orbital and spin
momentum of single electron is greater than interaction between orbital momentum of
different electron or spin momentum of different electron. The spin orbit
interaction is strong. Spin orbit interaction is strong. Very very important.
Similarly, have residual electrostatic interaction, which orbit-orbit. orbital-
orbital interaction is residual electrostatic interaction. Spin-spin interaction is
weak. Residual electrostatic interaction is also as orbital-orbital interaction and
also spin-spin interaction. Both are very weak. Next we will strong spin-orbital
interaction. Let's spin-orbit interaction swing angular moment vector orbital
angular moment vector orbital angular moment vector L swing angular moment vector
L of each individual electron are strong coupled together to form resultant total
angular moment vector J so the magnitude number is total angular moment J equal to
h cross root of J into J plus 1 J can take the half integral values J can take
the half integral values is very important We like this because what will of S is
plus or minus 1 by 2 right? J equals L plus or minus S J equals L plus half and
minus half J have the half integral values, see this is very important Note it
Next residual electrostatic interaction and spin-spin interaction. the weak
interaction. weak means residual electrostatic interaction orbital-orbital spin-
spin this is weak interaction this concept number 2 concept number 1 is strong
spin-orbit interaction this is first topic we are to one is strong spin-orbit
interaction another is weak Now we the resultant angular moment vector j of
individual electrons are less strongly coupled with one another to form the total
angular moment vector j Note that the resultant angular momentum vector J of
individual electrons are less strongly coupled with one another to form the total
angular momentum vector J. individual small j and total capital J. So what saying
is the resultant angular momentum vector J of individual electrons are less
strongly coupled with one another to form the total angular momentum. So total
angular momentum we find is J equal to First we can J1 J2. This is minimum value
comma Next J1 and J2. minimum we can plus 1 etc. So maximum value for J1 plus J2
will We add it this formula is very important for Please note Okay, the total
angular momentum. Okay? the total angular momentum. Did you Next we will an
example of electron configuration 4P and 4D We know as SPTF, yellow value is 0, 1,
2, 3 P is L and 1 for P-electrons. We the electron spin by S1. When we add we get
maximum value. If difference between we 1 by 2. If we increase by we 3 by 2. If L
and S we 3 by 2. actually we have got 1 by 2, 3 by 2, 3 by 2 we have and got 1 by
2, 3 by 2 ok? so we P electrons for P orbitals similarly we got 2 L orbitals for so
we 2 and half for if difference for will first 3 by 2 if 1 we 5 by 2 If you add you
5 by 8. So J2's value is... We have already the formula for J1 J2 First, J1 J2.
This is minimum value. comma We add plus 1 Finally we J1 and J2 directly. So we
this value when So we two values and two values So what J1 is this and this. Now 1
by 2, 3 by 2. Next 1 by 2, 5 by 2. Next we this 3 by 2 with this 3 by 2. next it
5x2 so 3x2, 3x2, 3x2, 5x2 so we 4 combinations 4 possible combinations of j1 and j2
values total 4 combinations are so how many combinations are there are 4
combinations we can the combinations of the number f's we ok? note it next we see
the configuration we 4f as usual we the f as 0,1,2,3 so f is the value of and is
off So, we can take the difference between 5 by 2 if plus 1 we 7 by 2 if we add we
7 by 2 according to that rule we j first we get 5 by 2 next we 5 by 2 and we get 7
by 2 7 so we can 5 by 2 7 by 2 for j value ok? so we can j value giving an
electronic configuration like this. According to the JJ coupling, possible value of
the by combination. According to the JJ coupling the possible value of J for the
combination Now we have 1x2, 3x2, J1 is to 1x2, J2 is to 3x2 So when we the
difference we 1, when we plus 1 we get 2, if we add we 3, so J's value is 1,2 So by
a combination like we J value in 1,2 So we have use calculate have this formula,
modulus of J1 minus J2 minimum comma modulus of j1-j2 minimum plus 1 comma etc j1
plus j2 so when apply this we 3 values 1 comma 2 comma 2 we will repeat it add this
is one the important questions we have 3 one more questions pure jj coupling is
number error If pure JJ coupling is not it possible. Next is selection rule for JJ
coupling. one electron, the value is 1 by 2. Sorry, plus or minus 1. If we two
electrons, the of plus or minus 1. If two electrons, L value is del L1 is plus or
minus 1 L2 is 0 plus or minus 2 this is 2 electron note 1 electron sister del L
value is plus or minus 1 for 2 electron sister L1 is plus or minus 1 L2 is 0 plus
or minus 2 note this generally if this I forgot to this Generally, JJ coupling
selection tools, generally... JJ coupling selection rule, first spin del s is
equal to 0. For orbital, del L is equal 0, plus or minus 1. Total angular momentum
del J is equal to 0, plus or minus 1. For LS coupling and JJ coupling, almost same
selection rule. Ok guys. So in J, 0 to 0 transition is not possible. the selection
rule clearly. It is very important Next, to find the electronic structure of atom
or molecules find the electronic structure of atom or molecules, what coupling we
is JJ coupling is very very important, have already TRB to find the electronic
structure of atom or molecule by using the LS coupling LS coupling because JJ is
not pure JJ effect so we are not to find the electronic structure of atom or
molecule by using LS coupling very very important similarly you JJ selection rule
clearly We one more question. Please see clearly. We JJ coupling. Please prepare
well. Next we are to about the stork effect. The splitting of spectral line due to
electric field is called stork effect. Let's see about that. Study well, the best.
Dear students, morning to all.