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Crw36333 Corrosion Inhibitor Crw36333 Egypt English Oic-Eh Oilfield 1101549

The CRW36333 Corrosion Inhibitor is a flammable liquid with multiple health hazards including acute toxicity and reproductive toxicity, supplied by Baker Hughes. It requires careful handling, protective equipment, and adherence to safety precautions to prevent exposure and environmental contamination. In case of an emergency, specific first aid measures and emergency contacts are provided for immediate assistance.

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0% found this document useful (0 votes)
12 views12 pages

Crw36333 Corrosion Inhibitor Crw36333 Egypt English Oic-Eh Oilfield 1101549

The CRW36333 Corrosion Inhibitor is a flammable liquid with multiple health hazards including acute toxicity and reproductive toxicity, supplied by Baker Hughes. It requires careful handling, protective equipment, and adherence to safety precautions to prevent exposure and environmental contamination. In case of an emergency, specific first aid measures and emergency contacts are provided for immediate assistance.

Uploaded by

ch.m.gamal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 12

SAFETY DATA SHEET

Version
1.02
CRW36333 CORROSION INHIBITOR

Section 1. Identification
Product name : CRW36333 CORROSION INHIBITOR
Product code : CRW36333
Product type : Liquid.

Recommended use : Corrosion inhibitor.

Supplier's details : Baker Hughes


Stockpit Road,
Knowsley Industrial Park,
Liverpool,
L33 7TQ, UK

Tel: +44 (0)151 545 3899


Fax: +44 (0)151 548 0094
e-mail address of person : [email protected]
responsible for this SDS
Emergency telephone : CHEMTREC Emergency Telephone within UK: 0870 820 0418
number CHEMTREC Emergency Telephone outside UK: +44 870 820 0418

Section 2. Hazard identification


Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 3
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
SKIN SENSITISATION - Category 1
REPRODUCTIVE TOXICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 2

GHS label elements


Hazard pictograms :

GHS02 GHS06 GHS05 GHS08


Signal word : Danger
Hazard statements : Highly flammable liquid and vapour.
Toxic if swallowed, in contact with skin or if inhaled.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes damage to organs.
May cause damage to organs through prolonged or repeated exposure. (heart, liver)
Toxic to aquatic life.
Precautionary statements

Date of issue/Date of revision : 4 November Date of previous issue : 23 January 2024 Version : 1.02 1/12
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CRW36333 CORROSION INHIBITOR

Section 2. Hazard identification


Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves: > 8 hours (breakthrough
time): Nitrile gloves.. Wear protective clothing. Wear eye or face protection. Wear
hearing protection. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use only outdoors or in a well-ventilated area.
Avoid release to the environment. Do not breathe vapour. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Contaminated
work clothing should not be allowed out of the workplace.
Response : IF exposed or concerned: Call a POISON CENTER or doctor. IF INHALED:
Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. IF ON SKIN: Call a POISON CENTER or doctor if
you feel unwell. Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazard statements : H225, H301 + H311 + H331, H315, H317, H318, H361, H370, H373, H401
(Code)
Precautionary statements : P201, P202, P280, P210, P271, P273, P260, P270, P264, P272, P308 + P311,
(Code) P304 + P340, P311, P301 + P310, P330, P303 + P361 + P353, P302 + P312, P352,
P333 + P313, P305 + P351 + P338, P310, P405, P501

Other hazards which do not : None known.


result in classification
Additional information
Mixing of chemicals may create a reaction hazardous to one’s health, to the environment, or a potential fire
hazard.

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

Ingredient name % CAS number


methanol ≥50 - ≤75 67-56-1

Fatty acids, tall-oil, reaction products with diethylenetriamine, acetates ≤5 68153-60-6

2-mercaptoethanol <2.5 60-24-2

1,2-Ethanediamine, N1-(2-aminoethyl)-, ethoxylated propoxylated ≤3 68910-19-0

benzododecinium chloride ≤2.6 139-07-1

miristalkonium chloride <1 139-08-2

cetalkonium chloride ≤0.3 122-18-9


There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

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CRW36333 CORROSION INHIBITOR

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Check for and remove any contact lenses. Chemical burns must
be treated promptly by a physician.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to
an unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled. Causes damage to organs following a single exposure if inhaled.
Skin contact : Toxic in contact with skin. Causes damage to organs following a single exposure in
contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Toxic if swallowed. Causes damage to organs following a single exposure if
swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations
Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in
foetal deaths,skeletal malformations
Ingestion : Adverse symptoms may include the following:,stomach pains,reduced foetal weight,
increase in foetal deaths,skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

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Section 5. Firefighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion
from the chemical hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. The vapour/gas is heavier than air
and will spread along the ground. Vapours may accumulate in low or confined areas
or travel a considerable distance to a source of ignition and flash back. This
material is toxic to aquatic life. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides,halogenated
decomposition products compounds

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

Methods and material for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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CRW36333 CORROSION INHIBITOR

Section 6. Accidental release measures


Reference to other sections : See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before use.
Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not
breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10). Store in original container, protected from direct sunlight.
Store locked up. Eliminate all ignition sources. Separate from oxidising materials.
Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before
handling or use.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
methanol EU OEL (Europe, 1/2022). Absorbed through skin.
TWA: 200 ppm 8 hours.
TWA: 260 mg/m³ 8 hours.
Biological exposure indices
No exposure indices known.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

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CRW36333 CORROSION INHIBITOR

Section 8. Exposure controls/personal protection


Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in
addition to chemical safety goggles. If inhalation hazards exist, a full-face respirator
may be required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. Recommended: > 8 hours
(breakthrough time): Nitrile gloves.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Recommended: If necessary half-face mask and organic vapour
filter (Type A)

Section 9. Physical and chemical properties and safety


characteristics
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Information on basic physical and chemical properties


Appearance
Physical state : Liquid. [Clear.]
Colour : Yellow.
Odour : Mercaptan

Odour threshold : Not available.


pH : 6
Melting point/freezing : ≥65°C
point
Boiling point, initial : Not available.
boiling point, and boiling
range
Flash point : Closed cup: 12.2°C (54°F) [TCC]
Evaporation rate : Not available.
Flammability (solid, gas) : May be combustible at high temperature.
Lower and upper : Not available.
explosion limit/
flammability limit

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CRW36333 CORROSION INHIBITOR

Section 9. Physical and chemical properties and safety


characteristics
Vapour pressure : 49.6 kPa (372.3 mm Hg) at 54.44°C
Relative vapour density : >1 [Air = 1]
Relative density : 0.883 to 0.953 (15.6°C)
Solubility(ies) :

Media Result
cold water Partially soluble
hot water Soluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition : Not available.
temperature
Viscosity : Dynamic (15.6°C): 5 cP

Explosive properties : Not available.


Oxidising properties : Not available.

Other information
Pour point : -40°C (-40°F)

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapour to accumulate in low or confined areas.
Incompatible materials : Reactive or incompatible with the following materials: oxidising materials.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
methanol LC50 Inhalation Vapour Rat 128.2 mg/l 4 hours
LD50 Dermal Rabbit 17100 mg/kg -
LD50 Oral Rat ≥2528 mg/kg -
2-mercaptoethanol LC50 Inhalation Vapour Rat 2 mg/l 4 hours
LD50 Dermal Rabbit 112 to 224 mg/ -
kg
LD50 Oral Rat 131 mg/kg -
benzododecinium chloride LD50 Oral Rat 400 mg/kg -
Conclusion/Summary : May be toxic if inhaled. May be toxic by skin absorption. May be toxic if ingested.
Can cause target organ damage. Adverse health effects could include the following:
central nervous system depression
Irritation/Corrosion
Skin : May cause skin irritation.
Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury.

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CRW36333 CORROSION INHIBITOR

Section 11. Toxicological information


Respiratory : No known significant effects or critical hazards.
Sensitisation
Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction
may occur when subsequently exposed to very low levels.
Respiratory : No known significant effects or critical hazards.
Mutagenicity
Not available.
Conclusion/Summary : No known significant effects or critical hazards.
Carcinogenicity
Not available.

Conclusion/Summary : No known significant effects or critical hazards.


Reproductive toxicity
Not available.
Conclusion/Summary : No known significant effects or critical hazards.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
methanol Category 1 - -
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
2-mercaptoethanol Category 2 oral heart, liver
Aspiration hazard
Not available.

Information on likely routes : Not available.


of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled. Causes damage to organs following a single exposure if inhaled.
Skin contact : Toxic in contact with skin. Causes damage to organs following a single exposure in
contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Toxic if swallowed. Causes damage to organs following a single exposure if
swallowed.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations
Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in
foetal deaths,skeletal malformations
Ingestion : Adverse symptoms may include the following:,stomach pains,reduced foetal weight,
increase in foetal deaths,skeletal malformations

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure

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CRW36333 CORROSION INHIBITOR

Section 11. Toxicological information


Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very
low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : Suspected of damaging fertility or the unborn child.

Numerical measures of toxicity


Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)
CRW36333 CORROSION INHIBITOR 191.7 526.9 N/A 5.7 N/A
methanol 100 300 N/A 3 N/A
2-mercaptoethanol 131 112 N/A 3 N/A
benzododecinium chloride 400 1100 N/A N/A N/A
miristalkonium chloride 500 1100 N/A N/A N/A
cetalkonium chloride 500 1100 N/A N/A N/A

Section 12. Ecological information


Toxicity : This material is toxic to aquatic life.
Product/ingredient name Result Species Exposure
methanol Acute EC50 >10000 mg/l Fresh water Daphnia 48 hours
Acute LC50 15400 mg/l Fresh water Fish 96 hours
2-mercaptoethanol Acute EC50 19 mg/l Fresh water Algae 72 hours
Acute EC50 0.4 mg/l Fresh water Daphnia 48 hours
Acute LC50 37 mg/l Fresh water Fish 96 hours
benzododecinium chloride Acute LC50 100 to 500 μg/l Crustaceans - Echinogammarus 48 hours
olivii

Persistence and degradability


Product/ingredient name Test Result Dose Inoculum
2-mercaptoethanol OECD 306 24 % - Not readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability


2-mercaptoethanol - - Not readily

Bioaccumulative potential

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Section 12. Ecological information


Product/ingredient name LogPow BCF Potential
methanol -0.77 - Low
2-mercaptoethanol -0.056 - Low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste packaging should be recycled. Incineration or landfill should only
be considered when recycling is not feasible. This material and its container must
be disposed of in a safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Vapour from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers.

Section 14. Transport information


International transport regulations
Regulatory UN number Proper shipping name Transport PG* Label
information hazard class(es)
ADR/RID Class UN1992 FLAMMABLE LIQUID, TOXIC, 3 (6.1) II
N.O.S.(Methanol solution)

IMDG Class UN1992 FLAMMABLE LIQUID, TOXIC, 3 (6.1) II


N.O.S.(Methanol solution)

IATA Class UN1992 FLAMMABLE LIQUID, TOXIC, 3 (6.1) II


N.O.S.(Methanol solution)

PG* : Packing group

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Section 14. Transport information


Regulatory Environmental Additional information
information hazards
ADR/RID Class No. Tunnel code
(D/E)

Hazchem code
3WE
IMDG Class No. -

IATA Class No. -

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.


to IMO instruments

Section 15. Regulatory information


International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Additional information : Shelf life: 2 years

Section 16. Other information


National Fire Protection :
Association (U.S.A.)

3 Flammability
Health 3 0 Instability
Special

History
Date of issue/Date of : 4 November 2024
revision
Date of previous issue : 23 January 2024
Version : 1.02

Date of issue/Date of revision : 4 November Date of previous issue : 23 January 2024 Version : 1.02 11/12
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Section 16. Other information


Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
ACUTE TOXICITY (oral) - Category 3 Calculation method
ACUTE TOXICITY (dermal) - Category 3 Calculation method
ACUTE TOXICITY (inhalation) - Category 3 Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1 Calculation method
SKIN SENSITISATION - Category 1 Calculation method
REPRODUCTIVE TOXICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2 Calculation method
SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 2 Calculation method
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.

Date of issue/Date of revision : 4 November Date of previous issue : 23 January 2024 Version : 1.02 12/12
2024

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