Vijay Education

Physical chemistry DPP-01(Electrochemistry)

By Jeetu Sir
Electrolytes and Electrolysis

1. Which of the following will not conduct electricity in 1. tyh; foy;u esa fuEufyf[kr es ls dkSu fo|qr /kkjk dks izokfgr
aqueous solution ugha djsxk
(a) Copper sulphate (b) Sugar (a) dkWij lYQsV (b) 'kôj
(c) Common salt (d) None of these (c) lk/kkj.k yo.k (d) buesa ls dksbZ ugha

2. Strong electrolytes are those which 2. izcy fo|qr&vi?kV~; os gSa tks

(a) Dissolve readily in water (a) ty esa 'kh?kzrk ls ?kqyrs gSa
(b) Conduct electricity (b) fo|qr dk pkyu djrs gSa
(c) Dissociate into ions at high dilution (c) mPp ruqrk ij vk;uksa esa fo;ksftr gks tkrs gSa
(d) Completely dissociate into ions at all dilutions (d) lHkh ruqrkvksa ij vk;uksa esa fo;ksftr gks tkrs gSa

3. Electrolyte can conduct electricity because 3. fo|qr&vi?kV~; fo|qr /kkjk ds pkyd gksrs gSa D;ksfa d
(a) Their molecules contain unpaired electrons, (a) buds v.kqvksa es v;qfXer bysDVªkWu gksrs gSa tks pyk;eku
which are mobile gksrs gSa
(b) Their molecules contain loosely held electrons (b) buds v.kqvksa esa f'kfFkyh; bysDVªkWu gksrs gSa tks oksYVst ds
which get free under the influence of voltage izHkko esa eqä gks tkrs gSaA
(c) The molecules break up into ions when a voltage (c) tc oksYVst iz;ksx djrs gSa rks v.kq vk;uksa esa VwV tkrs gSa
is applied (d) v.kq vk;uksa esa VwV tkrs gSa tc fo|qr&vi?kV~; dks xfyr
(d) The molecules are broken up into ions when the djrs gSa ;k foyk;d esa ?kksyrs gSa
electrolyte is fused or is dissolved in the solvent
4. fo|qr&vi?kVu esa Øe'k% vkWDlhdj.k ,oa vip;u gksrk gS
4. Electrolysis involves oxidation and reduction (a) ,uksM ,oa dSFkksM ij (b) dSFkksM ,oa ,uksM ij
respectively at (c) nksuksa bysDVªksMksa ij (d) buesa ls dksbZ ugha
(a) Anode and cathode (b) Cathode and anode
(c) At both the electrodes (d) None of the above 5. fo|qr vi?kVuh lsy esa bysDVªkWuksa dk izokg gksrk gS
(a) foy;u esa dSFkksM ls ,uksM dh vksj
5. In the electrolytic cell, flow of electrons is from
(b) ckgjh ifjiFk esa dSFkksM ls ,uksM dh vksj
(a) Cathode to anode in solution
(c) vkarfjd ifjiFk esa dSFkksM ls ,uksM dh vksj
(b) Cathode to anode through external supply
(d) vkarfjd ifjiFk esa ,uksM ls dSFkksM dh vksj
(c) Cathode to anode through internal supply
(d) Anode to cathode through internal supply
6. fuf"Ø; bysDVªksM dks iz;ksx djrs gq, lksfM;e lYQsV ds tyh;
6. A solution of sodium sulphate in water is
foy;u dk fo|qr vi?kVu fd;k x;k rks dSFkksM ,oa ,uksM ij
electrolysed using inert electrodes. The products at mRikn Øe'k% gSa
the cathode and anode are respectively
(a) H 2 , O 2 (b) O 2 , H 2
(a) H 2 , O 2 (b) O 2 , H 2
(c) O 2 , Na (d) O 2 , SO 2
(c) O 2 , Na (d) O 2 , SO 2

7. IysfVue bysDVªksM dks ysdj ruq H 2 SO 4 ds foy;u dk fo|qr

7. On electrolysing a solution of dilute H 2 SO 4 between
vi?kVu fd;k x;k rks ,uksM ij mRiUu gksus okyh xSl gksxh
platinum electrodes, the gas evolved at the anode is
(a) SO 2 (b) SO 3
(a) SO 2 (b) SO 3
(c) O 2 (d) H 2
(c) O 2 (d) H 2

8. xfyr NaCl ds fo|qr&vi?kVu ds le; ,uksM ij dkSulh

8. During the electrolysis of fused NaCl , which vfHkfØ;k gksxh
reaction occurs at anode (a) DyksjkbM vk;u vkWDlhd`r gksrs gSa
(a) Chloride ions are oxidized
(b) DyksjkbM vk;u vipf;r gksrs gSa
(b) Chloride ions are reduced
(c) lksfM;e vk;u vkWDlhd`r gksrs gSa
(c) Sodium ions are oxidised
(d)Sodium ions are reduced (d) lksfM;e vk;u vipf;r gksrs gSa
 Vijay Education
Physical chemistry DPP-01(Electrochemistry)
By Jeetu Sir
9. Electrolysis of aqueous HCl solution produces 9. tyh; HCl foy;u ds fo|qr&vi?kVu ls mRiUu gksrh gS
(a) H 2 gas at the anode (a) ,uksM ij H 2 xSl
(b) H 2 gas at the cathode (b) dSFkksM ij H 2 xSl
(c) Cl 2 gas at the cathode (c) dSFkksM ij Cl 2 xSl
(d) Cl 2 and O 2 gases both at the anode (d) ,uksM ij Cl 2 o O 2 nksuksa xSl

10. Which of the following is non-electrolytes 10. fuEu esa ls dkSu fo|qr vuvi?kV~; gS
(a) NaCl (b) CaCl2 (a) NaCl (b) CaCl2
(c) C12 H 22 O11 (d) CH 3 COOH (c) C12 H 22 O11 (d) CH 3 COOH

11. During electrolysis, the species discharged at 11. fo|qr vi?kVu ds nkSjku dSFkksM ij eqä gksrs gSa
cathode are (a) vk;u (b) /kuk;u
(a) Ions (b) Cation (c) _.kk;u (d) lHkh
(c) Anion (d) All of these

Answer Key

1 B 2 D 3 D 4 A 5 D
6 A 7 C 8 A 9 B 10 C
11 B
 Vijay Education
Physical chemistry DPP-01(Electrochemistry)
By Jeetu Sir
Faraday's law of electrolysis
1. When 9.65 coulombs of electricity is passed through a 1. tc 9.65 dwykWEc dh fo|qr /kkjk dks AgNO 3 ds foy;u ( Ag
solution of silver nitrate (atomic weight of dk ijek.kq Hkkj =107.87 ftls 108 fy;k x;k gS) esa izokfgr
Ag = 107 .87 taking as 108) the amount of silver fd;k tkrk gS rc pk¡nh dh fdruh ek=k tek gksxh
deposited is (a) 10.8 feyh xzke (b) 5.4 feyh xzke
(a) 10.8 mg (b) 5.4 mg (c) 16.2 feyh xzke (d) 21.2 feyh xzke
(c) 16.2 mg (d) 21.2 mg
2. vk;ju (II) czksekbM ds tyh; foy;u esa 3 QSjkMs dh fo|qr
2. Three faradays electricity was passed through an /kkjk izokfgr dh x;hA dSFkksM ij fdruh ek=k (xzke es)a esa
aqueous solution of iron (II) bromide. The weight of vk;ju /kkrq (ijek.kq Hkkj =56) tek gksxh
iron metal (at. wt. = 56) deposited at the cathode (in (a) 56 (b) 84
gm) is (c) 112 (d) 168
(a) 56 (b) 84
(c) 112 (d) 168
3. ,Y;wehfu;e dk ijek.kq Hkkj 27 gS ;fn 5 QSjkMs fo|qr /kkjk
3. The atomic weight of Al is 27. When a current of 5 Al + + + vk;u ;qä foy;u esa izokfgr dh tkrh gS rks tek gksus
Faradays is passed through a solution of Al + + + ions, okys ,Y;wehfu;e dh ek=k gksxh
the weight of Al deposited is (a) 27 xzke (b) 36 xzke
(a) 27 gm (b) 36 gm (c) 45 xzke (d) 39 xzke
(c) 45 gm (d) 39 gm
4. fo|qr jklk;fud rqY;kad dh bdkbZ gS
4. The unit of electrochemical equivalent is (a) xzke (b) xzke@,Eih;j
(a) Gram (b) Gram/ampere (c) xzke@dwykWEc (d) dwykWEc@xzke
(c) Gram/coulomb (d) Coulomb/gram
5. D;wfizd yo.k ds foy;u ls 2 QSjkMs fo|qr xqtkjus ij dkWij
5. What weight of copper will be deposited by passing dk fdruk Hkkj fu{ksfir gksxk (Cu dk ijek.kq Hkkj =63.5)
2 Faradays of electricity through a cupric salt
(Atomic weight of Cu = 63.5) (a) 2.0 xzke (b) 3.175 xzke
(a) 2.0 gm (b) 3.175 gm (c) 63.5 xzke (d) 127.0 xzke
(c) 63.5 gm (d) 127.0 gm

6. On passing 0.1 Faraday of electricity through 6. ,Y;wehfu;e DyksjkbM esa 0.1 QSjkMs fo|qr izokfgr djus ij
aluminium chloride, the amount of aluminium metal dSFkksM ij tek gksus okys Al /kkrq dh ek=k gksxh ( Al = 27 )
deposited on cathode is ( Al = 27 ) (a) 0.9 xzke (b) 0.3 xzke
(a) 0.9 gm (b) 0.3 gm (c) 0.27 xzke (d) 2.7 xzke
(c) 0.27 gm (d) 2.7 gm
7. 5 ,Eih;j dh /kkjk ZnSO 4 foy;u esa 40 feuV rd izokfgr
7. 5 amperes is passed through a solution of zinc dh xbZA dSFkksM ij Zn dh tek ek=k gksxh
sulphate for 40 minutes. Find the amount of zinc (a) 40.65 xzke (b) 4.065 xzke
deposited at the cathode (c) 0.4065 xzke (d) 65.04 xzke
(a) 40.65 gm (b) 4.065 gm
(c) 0.4065 gm (d) 65.04 gm
8. 3 ,Eih;j dh fo|qr /kkjk 50 feuV rd izokfgr djus ij ,d
8. On passing 3 ampere of electricity for 50 minutes, 1.8 /kkrq ds 1.8 xzke tek gksrs gSaA /kkrq dk rqY;kad nzO;eku fuEu
gram metal deposits. The equivalent mass of metal is gS
(a) 20.5 (b) 25.8 (a) 20.5 (b) 25.8
(c) 19.3 (d) 30.7 (c) 19.3 (d) 30.7
 Vijay Education
Physical chemistry DPP-01(Electrochemistry)
By Jeetu Sir
9. On passing C ampere of electricity through a 9. fdlh fo|qr&vi?kV~; ds foy;u esa C ,Eih;j fo|qr /kkjk t
electrolyte solution for t second, m gram metal lsd.M rd izokfgr djus ij /kkrq ds m xzke dSFkksM ij tek
deposits on cathode. The equivalent weight E of the gksrs gksa rks /kkrq dk rqY;kadh Hkkj E gksxk
metal is Ct C m
Ct C m (a) E = (b) E =
(a) E = (b) E = m  96500 t  96500
m  96500 t  96500 96500  m C  t  96500
96500  m C  t  96500 (c) E = (d) E =
(c) E = (d) E = Ct m
Ct m
10. MgCl 2 ls ,d xzke eSXuhf'k;e ijek.kq mRiUu djus ds fy;s
10. How many Faradays are required to generate one
vko';d QSjkMs gksx
a s
gram atom of magnesium from MgCl 2
(a) 1 (b) 2
(a) 1 (b) 2
(c) 3 (d) 4
(c) 3 (d) 4
11. Js.khØe es tqMs AgNO 3 rFkk D;wfizd yo.k foy;u esa /kkjk dh
11. A certain quantity of electricity is passed through an
aqueous solution of AgNO 3 and cupric salt solution ,d fuf'pr ek=k izokfgr dh x;h rks Ag dh 1.08 xzke ek=k tek
connected in series. The amount of Ag deposited is
gqbZ gks rks dkWij dh ,df=r ek=k gksxh (Cu dk ijek.kq Hkkj =63.5;
Ag = 108)
1 .08 gm , the amount of copper deposited is (atomic
(a) 0.6454 xzke (b) 6.354 xzke
weight of Cu = 63.5; Ag = 108)
(c) 0.3177 xzke (d) 3.177 xzke
(a) 0.6454 g (b) 6.354 g
(c) 0.3177 g (d) 3.177 g
12. xfyr ,Y;wehfu;e DyksjkbM ls fo|qr /kkjk izokfgr djus ij
12. On passing electric current through molten NTP ij ,uksM ij 11.2 yhVj Cl 2 fudkyrh gSA dSFkksM ij
aluminium chloride, 11.2 litre of Cl 2 is liberated at
tek ,Y;wehfu;e dh ek=k gS (Al dk ijek.kq Hkkj =27)
NTP at anode. The quantity of aluminium deposited
(a) 9 xzke (b) 18 xzke
at cathode is (at. wt. of Al = 27)
(a) 9 g (b) 18 g (c) 27 xzke (d) 36 xzke
(c) 27 g (d) 36 g

Answer Key

1 A 2 B 3 C 4 C 5 C
6 A 7 B 8 C 9 C 10 B
11 C 12 A