Sec: JR MPC STAR JEE - MAINS DATE: 19-07-2025

Time: 03:00 Hrs. WTM-01 Max Marks: 300

IMPORTANT INSTRUCTIONS: -
JEE MAINS MODEL
MATHEMATICS:
+Ve - Ve No.of
Section Question Type Total marks
Marks Marks Q’S
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 25) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S Marks
Sec – I(Q.N : 26 – 45) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 46 – 50) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100
CHEMISTRY:
+Ve - Ve No.of
Section Question Type Total marks
Mark Marks Q’S
Sec – I(Q.N : 51 – 70) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 71 – 75) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100

Syllabus:
MATHS : Compound angles and multiple, submultiple (70%), cumulative (30%)
PHYSICS : Relative motion in 1D & 2D (Rain -man, Aeroplane- wind, river-boat,
Shortest distance of approach in 2D motion) - Full chapter. (70%)
Cumulative (30%)
CHEMISTRY : Chemical bonding complete (70%) Cumulative (30%)

QUESTION PAPER ANALYSIS

SUBJECT EASY MODERATE DIFFICULT

MATHS 11 11 3
PHYSICS 5 15 5
CHEMISTRY 8 14 3
TOTAL 24 40 11
 MATHS Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. If sin x  sin 2 x  1 then the value of cos12 x  3cos10 x  3cos8 x  cos 6 x  2 is equal to
A) 0 B) 1 C) -1 D) 2
 
2. Let    0,  and t1  (tan ) tan  , t2  (tan ) cot  , t3  (cot ) tan  , t4  (cot ) cot  then
 4
A) t1 >t 2 >t 3 >t 4 B) t 4 >t 3 >t 1 >t 2 C) t 3 >t1 >t 2 >t 4 D) t 2 >t 3 >t 1 >t 4
  
3. For 0     / 2, if x   cos 2 n , y   sin 2 n and z   cos 2 n sin 2 n  then xyz 
n 0 n 0 n 0

A) xy B) x  yz C) x  y  z D) xz  y
4. If the inequality sin x  a cos x  a  1  cos x , holds for any x  R, then the largest
2 2

negative integral value of a is

A) -4 B) -3 C) -2 D) -1
3 1  cos  1  cos 
5. If     then  is equal to
2 1  cos  1  cos 
2 2 1 1
A) B)  C) D) 
sin  sin  sin  sin 
6. Ina  PQR if 3sin P  4cos Q  6 and 4sin Q  3cos P  1 then the angle R equal to
5   3
A) B) C) D)
4 6 4 4
       
7. If tan      tan      a then tan 3      tan 3     
4  4  4  4 
A) 0 B) a C) 3a D) a 3  3a
27 cosec6   8sec 6 
8. If 10sin 4   15cos 4   6 , then the value of is :
16sec8 
2 3 3 1
A) (b) (c) (d)
5 4 5 5
9. The value of 36  4cos 9  1 4cos 27  1  4cos 81  1 4cos 243  1 is
2  2  2  2

A) 54 B) 18 C) 27 D) 36
m 1
10. If tan   and tan   , then    
m 1 2m  1
  
A) B) C) D) None of these
3 4 6

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 1 3
11.  =
sin10 cos10
A) 0 B) 1 C) 2 D) 4
3  A   5A 
12. If cos A  , then 32 sin   sin   
4 2  2 
A) 7 B) 8 C) 11 D) None of these
 3 5 7
13. cos 4  cos 4  cos 4  cos 4 
8 8 8 8
A) 1 B) 1 C) 3
D) 3
2 4 2 4

14. If a tan   b , then a cos 2  b sin 2 

A) a B) b C) a D) b
sin 2 A cos A
15. . 
1  cos 2 A 1  cos A
A A A A
A) tan B) cot C) sec D) cosec
2 2 2 2
16. The value of tan 90  tan 270  tan 630  tan810 is __________
A) 1 B) 3 C) 4 D) -3
17. Let A be a 3  3 invertible matrix. If | adj  24 A | ∣adj∣(3adj (2 A))∣, then | A |2 is
equal to :
A) 6 6 B) 212 C) 2 6 D) 1
18. If the system of equation; 2 x  y  3z  5;3x  2 y  z  7;4 x  5 y  z  9 has
infinitely many solutions, then   2  2 ) is equal to :
A) 22 B) 18 C) 26 D) 30
1 0 0 
19. Let A   0 1 1  . Then A2025  A2020 is equal to:
1 0 0 
 
A) A  A
6
B) A5 C) A5  A D) A6
20. If A is a symmetric matrix and B is a skew-symmetrix matrix such that
2 3 
A B    , then AB is equal to:
 5 1
 4 1  4 2   4 2   4 2 
A)   B)   C)   D)  
 1 4   1 4  1 4   1 4

JR MPC STAR_JEE MAIN WTM - 01 Page 3

 SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.
21. The value of cos52  cos 68  cos172 is_________
22. If A  35 , B  15 and C  40 then tan A  tan B  tan B tan C  tan C tan A =__________
tan x tan y tan z 38
23. If   , x  y  z   and tan 2 x  tan 2 y  tan 2 z  then K  ________
2 3 5 K
24. The minimum value of the function
sin x cos x tan x cot x
f ( x)     whenever it is defined
1  cos 2 x 1  sin 2 x sec 2 x  1 cosec2 x  1
is k than 4+k = ______
1
0
89
25. Let f () 
1  (cot ) 2
and S  
1
f (). Then the value of 2 S  8  _______

PHYSICS Max Marks: 100

SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. Raindrops are falling vertically with a velocity 10 m / s . To a cyclist moving on a

straight road the rain drops appear to be coming with a velocity of 20 m / s . The
velocity of cyclist is:-
A) 10 m / s B) 10 3 m / s C) 20 m / s D) 20 3 m / s
27. A man travelling at 10.8 kmph in topless car on a rainy day. He holds an umbrella

at angle of 37 with the vertical so that he does not wet. If rain drops falls
vertically downwards what is rain velocity.
A) 1 m/s B) 2 m / s C) 3 m / s D) 4 m / s .
28. A man can row a boat in still water with a velocity of 8 kmph. Water is flowing in
a river with a velocity of 4 kmph. At what angle should he row the boat so as to
reach the exact opposite point
 
A) 150 to flow of water B) 120 to flow of water.
 
C) 30 to flow of water. D) 90 to flow of water.
29. A stone is dropped from a height h. Simultaneously, stone is thrown up from the
ground which reaches a height 4h. The two stones cross each other after time
h 8gh h
A) B) C) 2gh D)
8g 2h

JR MPC STAR_JEE MAIN WTM - 01 Page 4

 30. Two bodies are thrown simultancously from a tower with same initial velocity v0
: one vertically upwards, the other vertically downwards. The distance between
the two bodies after time t is
1 1
A) 2v0t  gt 2 B) 2v0t C) v0t  gt 2 D) v0t
2 2
31. Two trains, each 50 m long are travelling in opposite direction with velocity
10 m / s and 15 m / s . The time of crossing is

A) 2 s B) 4 s C) 2 3s D) 4 3 s
32. Particle A moves along X -axis with a uniform velocity of magnitude 10 m / s .
Particle B moves with uniform velocity 20 m / s along a direction making an angle

of 60 with the positive direction of X -axis as shown in figure. The relative
velocity of B with respect to that of A is

A) 10 m / s along X -axis
B) 10 3 m / s along Y -axis (perpendicular to X -axis)
C) 10 5 along the bisection of the velocity of A and B
D) 30 m / s along negative X -axis
33. A boat crosses a river from port A to port B, which are just on the opposite side.
The speed of the water is VW and that of boat is VB relative to still water. Assume
VB  2VW . What is the time taken by the boat, if it has to cross the river directly on
the AB line where AB = D
2D 3D D D 2
A) B) C) D)
VB 3 2VB VB 2 VB
34. Two cars A and B are moving with same speed of 45 km / hr along same direction.
If a third car C coming from the opposite direction with a speed of 36 km / hr
meets two cars in an interval of 5 minutes, the distance of separation of two cars
A and B should be (in km )
A) 6.75 B) 7.25 C) 5.55 D) 8.35
1
35. A train is moving slowly on a straight track with a constant speed of 2 ms . A
1
passenger in that train starts walking at a steady speed of 2 ms to the back of the
train in the opposite direction of the motion of the train. So to an observer
standing on the platform directly in front of that passenger, the velocity of the
passenger appears to be
1 1
A) 4 ms B) 2 ms

JR MPC STAR_JEE MAIN WTM - 01 Page 5

 C) 2 ms1 in the opposite direction of the train D) Zero
36. Two trains are moving with equal speed in opposite directions along two parallel
railway tracks. If the wind is blowing with speed u along the track so that the
relative velocities of the trains with respect to the wind are in the ratio 1: 2 , then
the speed of each train must be
A) 3u B) 2u C) 5u D) 4u
37. A train is moving towards east and a car is along north, both with same speed.
The observed direction of car to the passenger in the train is
A) East-north direction B) West-north direction
C) South-east direction D) None of these
38. A boat is moving with a velocity 3i  4 j with respect to ground. The water in the
river is moving with a velocity 3i  4 j with respect to ground. The relative
velocity of the boat with respect to water is
A) 8 j B) 6i  8 j C) 6i  8 j D) 5 2
39. A particle when thrown, vertically up moves such that it passes from same height
at 2s and 10s, the height is
A) g B) 2g C) 5g D) 10 g
40. A body freely falling from the rest has a velocity ' v ' after it falls through a height '
h'. The distance it has to fall down for its velocity to become double, is
A) 2h B) 4h C) 6h D) 8 h
41. Two trains A and B,100 m and 60 m long, are moving in opposite directions on
parallel tracks. The velocity of the shorter train is 3 times that of the longer one. If
the trains take 4s to cross each other, the velocities of the trains are
A) vA  10 ms , ve  30 ms B) vA  2.5 ms , vB  7.5 ms
1 1 1 1

C) v A  20 ms ,vB  60 ms D) vA  5 ms ,vB  15 ms
1 1 1 1

42. Out of the following four cases of projection where components along horizontal
and vertical are given the maximum range is for:

A) B) C) D)
43. The equations of motion of a projectile thrown in x-y plane from origin are
x  8t , y  6t  10t 2 then the angle of projection is -
A) tan 1 (3 / 4) B) tan 1 (4 / 3) C) sin 1 (3 / 4) D) cos1 (3 / 4)

44. A particle is projected with speed 20 m / s at an angle 30 with horizontal. After
how much time the angle between velocity and acceleration will be 90 


A) 1 sec B) 2 sec C) 1.5 sec D) 2.5 sec

JR MPC STAR_JEE MAIN WTM - 01 Page 6
 
45. A body is thrown from a point with speed 50 m / s at an angle 37 with horizontal.
When it has moved a horizontal distance of 80 m then it's distance from point of
projection is
A) 40 m (B) 40 2 (C) 40 5 (D) none of these

SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

46. A boat is sent across a river with a velocity of 8 km / hr . If the resultant velocity of
boat is 10 km / hr , then velocity of the river in km/hr______
1
47. A ship A is moving Westwards with a speed of 10kmh and a ship B 100 km
1
South of A, is moving Northwards with a speed of 10kmh . The time after which
the distance between them becomes shortest, is___________hr
48. Two particles A and B are thrown vertically upward with velocity, 5 m / s and
10 m / s respectively ( g  10ms ) Find separation in meters between them after
2

one second.

49. Two parallel rail tracks run from North to south. Train A move north with speed
54 kmph and train B moves south with speed of 90 kmph. What is velocity of a
monkey running on the roof of the train A against its motion (with its velocity of
18 km / h with respect to the train A) as observed by a man standing on the
ground in kmph is _______(along north)
50. A particle starts from the origin at time t  0 and moves along the positive
x  axis . The graph of velocity with respect to time is shown in figure. What is the
position of the particle in meters at time t  5 sec

JR MPC STAR_JEE MAIN WTM - 01 Page 7

 CHEMISTRY Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

51. If the principal quantum number n=6, the correct sequence of filling of electrons will be :
A) ns  (n  2) f  np  ( n  1) d B) ns  ( n  2) f  (n  1) d  np
C) ns  np  (n  1)d  (n  2) f D) ns  (n  1)d  (n  2) f  np.
52. Non-zero dipole moment is shown by:

A) CCl 4 B) CO 2 C) H 2O D)
53. The charge/size ratio of a cation determines its polarising power. Which one of the
following sequences represents the increasing order of the polarising power of the
 2 2 2
cationic species K ,Ca ,Mg ,Be ?
A) Ca  Mg  Be  K B) Mg  Be  K  Ca
2 2 2  2 2  2

C) Be  K  Ca  Mg 2 D) K  Ca  Mg  Be
2  2  2 2 2

54. Which of the following shapes of SF4 is more stable and why?

A) (i) is more stable due to three lone pair-bond pair repulsions at 90
B) (ii) is more stable due to two lone pair-bond pair repulsions
C) Both are equally stable
D) Both are unstable
55. Molecular shapes of SF4 ,CF4 and XeF4 are :
A) the same with 2,0 and 1 lone pair of electrons
B) the same with 1,1 and 1 lone pair of electrons
C) different with 0,1 and 2 lone pair of electrons
D) different with 1, 0 and 2 lone pair of electrons
56. The correct decreasing order of bond angles is :
A) ClF3  PF3  NF3  BF3 B) BF3  PF3  NF3  ClF3
C) BF3  NF3  PF3  ClF3 D) BF3  ClF3  PF3  NF3
57. The orbital angular momentum for an electron revolving in an orbit is given by
h
l (l  1)  . This momentum for an s-electron will be given by
2

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 h h 1 h
A) zero B) C) 2 D)  
2 2 2 2
58. The de-Broglie's wavelength of electron present in first Bohr orbit of ' H ' atom is:
0.529
A) 4  0.529Å B) 2  0.529Å C) Å D) 0.529Å
2
59. The percentage of s -character in the hybrid orbitals sp, sp and sp follows the pattern :
2 3

A) sp  sp  sp B) sp  sp  sp C) sp  sp  sp D) sp  sp  sp
3 2 2 3 2 3 2 3

60. Arrange the following in increasing order of their bond order : O2 ,O2 ,O2 and O22
2     2   2 2  
A) O2 ,O2 ,O2 ,O2 B) O2 ,O2 ,O2 ,O2 C) O2 ,O2 ,O2 ,O2 D) O2 ,O2 ,O2 ,O2

61. In the compound the bond is of the type:

A) sp  sp B) sp  sp C) sp  sp D) sp  sp
2 3 3 3 2 3

62. Select the correct code for the following repulsive forces, according to VSEPR theory :
(i) lone pair - lone pair > lone pair - bond pair
(ii) lone pair - bond pair > bond pair - bond pair
(iii)lone pair - lone pair > bond pair - bond pair
(iv)lone pair - bond pair > lone pair - lone pair
A) (i), (ii) and (iii) B) (ii) and (iv) C) (i), (iii) and (iv) D) (i) and (iv)

63. Hybridisation of CH3 and CH 3 are :
2 2 2
A) sp and sp respectively B) sp and sp respectively
2 3 3 3
C) sp and sp respectively D) sp and sp respectively
64. Among LiCl,BeCl2 ,BCl3 and CCl 4 , the covalent bond character follows the order :
A) LiCl  BeCl 2  BCl3  CCl4 B) LiCl  BeCl 2  BCl3  CCl 4
C) LiCl  BeCl 2  BCl3  CCl4 D) LiCl  BeCl 2  BCl3  CCl 4
65. Which one of the following arrangements of molecules is correct on the basis of their
dipole moments?
A) BF3  NH 3  NF3 B) BF3  NF3  NH 3
C) NH 3  BF3  NF3 D) NH 3  NF3  BF3
66. Which of the following is correct?
A) The number of electrons present in the valence shell in SF6 is 12
B) The rates of ionic compounds are very slow
C) According to VSEPR, SnCl 2 is a linear molecule
 2
D) The correct order of ability to form ionic compounds among Na ,Mg and Al3 is
Al3  Mg 2  Na 
   
67. Out of N 2O,SO2 ,I3 ,I3 ,H 2O, NO2 , N 3 , the linear species are :
       
A) NO2 ,I3 ,H 2O B) N 2O,I3 , N3 C) N 2O,I3 , N3 D) N3 ,I3 ,SO2
68. Which of the following statement is incorrect?
A) Lithium and magnesium exhibit diagonal relationship.
JR MPC STAR_JEE MAIN WTM - 01 Page 9
 B) Elements of groups 1,2,13,14,15,16 and 17 are known as representative elements.
C) In 5th period, the orbitals 5s 4 f 4d 6 p are filled.
D) General electronic configuration of f-block elements is (n  2) f (n  1)d 0,1ns 2
114

69. Increasing order of electron gain enthalpy is :

A) N  O  Cl  Al B) O  N  Al  Cl
B) N  Al  O  Cl D) Cl  N  O  Al
70. The electronic configuration of transition elements is exhibited by:
C) ns (n  1)d
2 5 2 10
A) ns1 B) ns np D) (n  1)d 19 ns 02
SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

71. The number of incorrect statement/s about the black body from the following is_________
1. Emit or absorb energy in the form of electromagnetic radiation.
2. Frequency distribution of the emitted radiation depends on temperature.
3. At a given temperature intensity vs frequency curve passes through a maximum
value.
4. The maximum of the intensity vs frequency cure at a higher frequency at higher
temperature compared to that at lower temperature activation energy.
72. The successive ionisation values for an element ' X ' are given below:
i H1 410 kJ mol1 i H 2 820 kJ mol1
i H 31100 kJ mol 1 i H 41500 kJ mol1
i H 5 3200 kJ mol1
The number of valence electrons for the element ' X '._______________
73. The dipole moment of HBr is 2.6  1030 cm and the interatomic spacing is 1.41Å . The
percentage of ionic character is x/2 x is________
74. The ratio of  to  -bonds in mesitylene is :________

75. Total number of bond pairs and lone pairs around the central atom in the I3 ion
are:________

***

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 JR MPC STAR JEE MAINS WTM-01 KEY SHEET

DATE: 19-07-2025

MATHS KEY:

1) C 2) B 3) C 4) B 5) B 6) B 7) D 8) A 9) D 10) B

11) D 12) C 13) C 14) A 15) A 16) C 17) C 18) C 19) A 20) B

21) 0 22) 1 23) 3 24) 2 25) 9

PHYSICS KEY:

26) B 27) D 28) B 29) A 30) B 31) B 32) B 33) A 34) A 35) D

36) A 37) B 38) C 39) D 40) B 41) A 42) B 43) A 44) A 45) C

46) 6 47) 5 48) 5 49) 36 50) 9

CHEMISTRY KEY:

51) B 52) C 53) D 54) B 55) D 56) C 57) A 58) B 59) A 60) D

61) D 62) A 63) C 64) A 65) D 66) A 67) C 68) C 69) C 70) D

71) 0 72) 4 73) 23 74) 7 75) 5

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 MATHS SOLUTIONS
1. Sol. C
Sin x  cos 2 x
cos12 x  3cos10 x  3cos8 x  cos 6 x  2  sin 6 x  3sin 5 x  3sin 4 x  sin 3 x  2

2. Sol. B
 
In  0,  , tan   1 and cot   1
 4
 (cot )cot   (cot ) tan   (tan ) tan   (tan )cot 
 t 4  t3  t1  t 2

3. Sol. C
1 xy

1 xy  1
1
xy

1
z   cos 2 n  sin 2 n  
n 0 1  cos  sin 2 
2

4. Sol. B
sin 2 x  acos x  a 2  1  cos x . Putting x  0 , we have a  a 2  2 or a 2  a  2  0
or ( a  2)( a  1)  0 or a  2 or a  1 .
Therefore, the largest negative integral value of a is -3
5. Sol. B
1  cos  1  cos  1  cos   1  cos 
 
1  cos  1  cos  1  cos 2 
2 2
   (     3 / 2)
| sin x |  sin 

6. Sol. B
3sin P  4cos Q  6.(i )
 4sin Q  3cos P  1..(i)
1  5
Squaring and adding (i) and (ii) we get sin( P  Q )   P  Q  or
2 6 6
11
 3sin P  4cos Q  , which is not possible
2

So R 
6

7. Sol. D
   
tan 3      tan 3      a 3  3(1)a  a 3  3a
4  4 
 u sing A  B  ( A  B)3  3 AB( A  B) 
3 3

8. Sol. A
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    15 1  sin 2    0
2 2
Given, 10 sin 2 
Let sin   t  10t  15(1  t )  6
2 2 2

10t 2  15  30t  15t 2  6  (5t  3) 2  0

125 125
27  8
3 2 27 8  250  2
sin 2   and cos 2   ;
125  5 5
4
5 5 5
16  
2
9. Sol. D
sin 3
4cos 2   1  4 1  sin 2    1  3  4sin 2   So, given expression can be
sin 
written as
sin 27  sin81 sin 243 sin 729
 36    
sin 9 sin 27  sin 81 sin 243
sin 729
 36   36
sin 9

10. Sol. B
1 1
As    is independent of m, therefore put m  1, then tan   and tan   .
2 3
(1 / 2)  (1 / 3) 
Therefore, tan (  )   1. Hence     .
1  (1 / 6) 4
(Also check for other values of m).
11. Sol. D
1 3
(d) 
sin10 cos10
1 3 
2  cos10o  sin10o 
 2 2 
2  cos10  3 sin10
o o

 sin10 o
cos10 o

2 sin10o cos10o 
4sin (30o  10o ) 4sin 20o
   4.
sin 20o sin 20o

12. Sol. C
A 5A
32sin sin  16(cos 2 A  cos3 A)
2 2
 16(2cos2 A  1  4cos3 A  3cos A)
 9 27 3
 16  2   1  4   3    11 .
 16 64 4

13. Sol. C
 3 5 7  3 3 
cos 4  cos 4  cos 4  cos 4  cos 4  cos 4  cos 4  cos 4
8 8 8 8 8 8 8 8
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   3 
 2  cos 4  cos 4 
 8 8 
 2  2 3 
2
2  2 3

 2  cos  cos   2cos cos 
 8 8  8 8
 1   3      3 
 2 1   2cos2  2cos 2    2  1  cos 1  cos 
 2 8  8   4  4 
   
 2   1  cos 1  cos 
 4  4
   1 1 3
 2  1  cos 2   2  1    2  
 4  2 2 2

14. Sol. A

tan   b tan   b / a a cos 2  b sin 2

 1  tan  
2
(2 tan ) a 1  b 2 / a 2   2b  b / a
 a  b 
 1  tan   1  tan  1  b2 / a 2
2 2


a 2  b 2  2b 2 a 2  b 2
a
a 2
 b2 
a a a 2  b2
a
15. Sol. A
2sin A cos A cos A
.
2cos 2 A 2cos 2 A
2
 tan A
2
16. Sol. C
Given, tan 9  tan 27   tan 63  tan 81
 tan 9  cot 9  (tan 27  cot 27 )
tan   cot   2cosec 
2 2 2 4 2 4
 
 
  4
sin18 sin 54 5 1 5 1
17. Sol. C
(c)Given|adj(24A)|=|adj3(adj2A)|
| 24 A |2 | 3adj(2 A) |2
  243 | A |   33 | adj(2 A) |   36 | 2 A |2 
2 2 2

 246 | A |2   243 | A |  36  212 | A |4

2

246
| A |2   64  26
3 2
6 12

18. Sol. C

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 2  3
(c) For Infinitely many solutions,   0  3 2 1  0
4 5 
 2(2  5)  ( 4  3)  3(7)  0
 4  3  4  31  0
2  5
3  0  3 2 7  0
4 5 9
 2(17)  (1)  5(7)  0
   1
Similarly,  2  1  0
From equation (i) ,
4  3  4  31  0    5  2   2  26
19. Sol. A
1 0 0  1 0 0
A  0 1 1  A  1
  2
1 1
   
1 0 0  1 0 0 
1 0 0 1 0 0  1 0 0
A3   2 1 1   A4  3 1 1   An   n  1 1 1 
     
1 0 0 1 0 0   1 0 0 
 1 0 0  1 0 0
A2025  A2020   2024 1 1    2019 1 1 
   
 1 0 0   1 0 0 

20. Sol. B
a c  0 d  a c  d  2 3 
(b) Let A    and B   d Then, A  B   
c b   0  c  d b   5 1
On comparing each term,
a  2, b  1, c  d  5, c  d  3  a  2, b  1, c  4, d  1
 2 4   0 1  4 2 
Now, AB     
 4 1 1 0   1 4 
21. Sol. 0

22. Sol. 1
A  B  C  900
  tan A tan B  1

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23. Sol. 3
tan x  2t , tan y  3t , tan z  5t
Also x  y  z  
 tan x  tan y  tan z  tan x tan y tan z
1
 t2   tan 2 x  tan 2 y  tan 2 z  t 2 (4  9  25)  38t 2 ,
3
K  3
24. Sol. 2
sin x cos x tan x cot x
f ( x)    
1  cos x 1  sin x
2
2
sec x  1
2
cosec 2 x  1
sin x cos x tan x cot x
   
| sin x | | cos x | | tan x | | cot x |
4, x 1 st quadrant
2, x  2 nd quadrant

 ; f ( x) min  2
 0, x  3 rd quadrant
2, x  4 th quadrant
25. Sol. 9
1 sin 2 
f ()    sin 2 
r  cot 2  sin 2   cos 2 
89
S   f ()  sin 2 i  sin 2 2    sin 2 89
1

  sin 2 i  sin 2 89    sin 2 2  sin 2 88     sin 2 45

1
 44   89 / 2 25  8
2
89
 7 8  81 9
2
PHYSICS SOLUTIONS
26. Sol. B
VRC  VR  VC ; VC  202  10 2  300 ms 1
27. Sol. D
VM
VRM  VR  VM   37  , tan 37 
VR
28. Sol. B

VMW sin   VW
V 4 1
sin   W      30
VMW 8 2
Total angle    90
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29. Sol. A
1 2 1
For first stone, u  0, h1  gt , for 2nd stone, u  8 gh , h2  ( 8gh )t  gt 2
2 2
h  h1  h2
30. Sol. B
S  Vrel  t 
31. Sol. B
Total length 50  50 100
Time     4sec
Relative velocity 10  15 25
32. Sol. B  
VBA  VB  VA
 
 20  cos 600 iˆ  20sin 600 ˆj  10iˆ  10 3 ˆj
33. Sol. A

VB sin   VW
Vw 1
sin       30 VB  2VW 
VB 2
D
Time taken to cross the river, t 
VB cos 
34. Sol. A
Distance b / w the cars A and B remains constant. Let the distance be ' x '
Velocity of C w.r.t. A and B V  45  36  81Km / h Distance
5
 81   6.75Km.
60
35. Sol. D
Vt  2 m / s V pt  2 m / s
Vp  Vt  2
So the velocity of train  0
36. Sol. A
Let the speed of trains be x
xu 1
   2 x  2u  x  u  x  3u.
xu 2
37. Sol. B

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   
vct  vc  vt
  
 
vct  vc  vi
Velocity of car w.r.t. train  vct  is towards West - North.
38. Sol. C
Relative velocity  (3i  4 j )  (3i  4 j )  6i  8 j.
Hence velocity of monkey will be 36 km / hr towards north.
39. Sol. D
If t1 and t 2 are the time, when body is at the same height then,
1 1
h  gt1t2   g  2  10  10 g .
2 2
40. Sol. B

(b) Let at point A initial velocity of body is equal to zero.

For path AB : v 2  0  2 gh for path AC : (2v) 2  0  2 gx
4v 2  2 gx
Solving (i) and (ii), x  4h
41. Sol. A
3v A  vB ; vm   v A  vB
I I
t  A B ; s1  s2   vA  vB  t
vm
42. Sol. B
Conceptual
43. Sol. A
ux  8  u cos u y  6
u 6
 u sin  tan   y  
ux 8
44. Sol. A

Usin 30 20
t   1sec.
g 2  10

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45. Sol. C

4
x  80 m U x  50cos37  50   40 m / s
5
3
U y  50sin 37  50   30 m / s
5
2U xU y 2  40  30 2  40  30
Range R     240 m
g g 10
x 80
t   2 second
U x 40
1 1
So y  U y t  gt 2  30  2   10  42  60  20  40 m.
2 2
OP  (80)  (40)  1600  5  40 5
2 2

46. Sol. 6


Given AB  Velocity of boat  8 km / hr

AC  Resultant velocity of boat
 10
 km / hr
BC  Velocity of river
 AC 2  AB 2
47. Sol. 5

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 Distance OB  100cos 45  50 2 km
Time taken to each the shortest distance between
OB 50 2
A and B    5h
VBA 10 2
48. Sol. 5
S  Vrel  t 
49. Sol. 36
Solution
Taking south direction as positive
vmonkey, ground  vmg
  
vm , g  vm , A  v Ag  18  54  36 km / hr
50. Sol. 9
S  Area under graph
1 
   2  2   (2  2)  (3  1)  9m
2 

CHEMISTRY SOLUTIONS
51. B
Conceptual
52. C
[Hint : H 2O is not a linear molecule but angular in shape. Thus, it shows
dipole moment.]
53. D

54. B
[Hint : The shape (ii) has minimum repulsion.]
55. D
Conceptual
56. C

57. A
Conceptual
58. B
2r  n

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59. A
Conceptual
60. D
Conceptual
61. D
Conceptual
62. A
Conceptual
63. C
Conceptual
64. A
Conceptual
65. D
Conceptual
66. A
[Hint : S forms six covalent bonds with six F atoms, i.e., 12 electrons are
involved. According to VSEPR, it has octahedral configuration.]
67. C
Conceptual
68. C Conceptual
69. C Conceptual
70. D Conceptual
71. 0 Conceptual
72. 4
Sudden jump in the ionisation enthalpy occurs from 4th to 5th value.
73. 23

74. 7

75. 5
Conceptual

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