Sec: JR MPC JEE - MAINS DATE: 05-07-2025

Time: 03:00 Hrs. WTM-03 Max Marks: 300

IMPORTANT INSTRUCTIONS: -
JEE MAINS MODEL
MATHEMATICS:
+Ve - Ve No.of
Section Question Type Total marks
Marks Marks Q’S
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 25) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S Marks
Sec – I(Q.N : 26 – 45) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 46 – 50) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100
CHEMISTRY:
+Ve - Ve No.of
Section Question Type Total marks
Mark Marks Q’S
Sec – I(Q.N : 51 – 70) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 71 – 75) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100

Syllabus:
MATHS : Rank of a matrix, System of linear equations (60℅), Cumulative (40℅)

PHYSICS : Component & Resolution of Vectors, Scalar product of Two vectors,

Vector product of two vectors (70%) + Cumulative (30 %)
CHEMISTRY : Periodic classification complete (70%) Atomic structure (30%)
QUESTION PAPER ANALYSIS

SUBJECT EASY MODERATE DIFFICULT

MATHS 15 6 4
PHYSICS 18 5 2
CHEMISTRY 12 11 2
TOTAL 45 22 8
 MATHS Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. Let P and Q be 3  3 matrices with P  Q . If P 3  Q 3 and P 2Q  Q 2 P , then determinant of

 P 2  Q 2  is equal to
A) 0 B) -1 C) -2 D) 1
2 3 
2. If A is a symmetric matrix and B is a skew symmetric matrix such that A  B   ,
 5 1
then AB 
 4 2   4 2  4 2   4 2 
A)  B)  C)  D) 
1 4   1 4 

 1 4 
 
 1 4 
3. The system of equations x  2 y  3 z  5, 2 x  2 y  z  0,  x  2 y  3 z  6 has
A) infinitely many solutions B) exactly two solutions
C) unique solution D) no solution
4. The system of equations kx  y  z  1, x  ky  z  k and x  y  zk  k 2 has no solution if k
is equal to
A) -2 B) 1 C) 0 D) -1
a1 b1 c1
5. Consider the system of equations ai x  bi y  ci z  0 (where i  1, 2, 3 ), if a2 b2 c2  0 ,
a3 b3 c3
then the system has
A) only one solution B) one solution  0, 0, 0  and more solution
C) no solution D) infinite solutions
6. In a square matrix, the elements of a column are 2, 5k + 1, 3 and the cofactors of an
other column are 1 – 5k, 2, 4k – 2, then the value of k is ____
1 1
A) –6 B)  C) 6 D)
6 6
 1 2 5 
7. The rank of the matrix  2 4 a  4  is

 1 2 a  1 
A) 1 if a = 6 B) 3 if a = 1 C) 3 if a = 2 D) 1 if a = - 6
8. The system of equations (3x + 2y + z) = 6, (3x + 4y + 3z) = 14 and (6x + 10y + 8z) = a
has infinite numbers of solutions if a =
A) 8 B) 12 C) 24 D) 36
9. If the system of linear equations (x + 2y + 3z) =  x , (3x + y + 2z) = y,
(2x + 3y + z) =  z has non trivial solutions then  =
A) 6 B) 7 C) 8 D) 5

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 ai bi  
10. If Ai   i  and if | a |  1,| b |  1 , then
ai 
 det( A ) is equal to
i
b i 1

a2 b2 a2  b 2 a2 b2 a2 b2
  
A) (1  a)2
(1  b )2 B) (1  a 2 )(1  b 2 ) C) (1  a)2
(1  b )2 D) (1  a)2 (1  b)2

11. For the system of equations x  y  z  6 , x  2 y  az  10 , x  3 y  5 z  b , which one

of the following is NOT true?
A) System has infinitely many solutions for a  3, b  14
B) System has no solutions a  3, b  24
C) System has unique solutions a  3, b  14
D) System has unique solutions a  3, b  14

12. The number of values of K, for which the system of equations (k  1) x  8y  4k,
kx  (k  3)y  3k  1 has no solution is

A) 1 B) 2 C) 3 D) Infinite
13. The value of a third order determinant is 11 then the value of the square of the
determinant formed by the cofactors will be
A) 14641 B) 1331 C) 121 D) 11
14. The system of the equations 2 x  3 y  z  5 , x  ay  3 z  4 , 3 x  y  bz  7 has infinite
many solutions 13ab is equal to
A) 1110 B) 1120 C) 1210 D) 1220
cos α  sin α 0
15. If A   sin α cos α 0  then (adjA)1  ____
 0 0 1 
A) I B) A C)  A D) 0
16. If x   , y   and z   is the unique solution of the system of equations
(2x + y + z) = 1, (x – 2y – 3z) = 1, (3x + 2y + 4z) = 5 then the value of  3  4  5  =

A) 1 B) 2 C) 3 D) 4
3 3
1 
2 2
17. The values of  , for which 1 1
1   0, lie in the interval
3 3
2  3 3  1 0

C)   , 
3 3
A)  2,1 B)  3,0  D)  0,3
 2 2

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 1 2 3 0
2 4 3 2 
18. If the matrix A   is of rank 3, then  
3 2 1 3
 
6 8 7 
A) -5 B) 5 C) 4 D) -4

19. If x, y, z not all zeros and the equations x  y  z  0, 1  a  x   2  a  y  8z  0

x  1  a  y   2  a  z  0 have non-trivial solution then a 
A) 2  15 B) 3  15 C) 15 D) 5  2 2

20. The equations x  y  z  6 , x  2 y  3z  10, x  2 y  mz  n give infinite number of values

of the triplet  x, y, z  if:
A) m  3, n  R B) m  3, n  10 C) m  3, n  10 D) m  3, n  3

SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.
2 1 1 
21. The rank of 0 3 1 is ____
1 1 1 

1 x x 1
22. If f  x   2x x  x  1  x  1 x then the value of f  2025 is _________
3x  x  1 x  x  1 x  2   x  1 x  x  1

23. If a  b  c  1 and the system ax  y  z  0, x  by  z  0, x  y  cz  0 have non trivial

solutions then a  b  c  abc  ______
 0 pq p  r
24. det  q  p 0 q  r   ________
 r  p rq 0 

25. Let P be a matrix of order 3  3 such that all the entries in P are from set 1, 0,1 . Then
the maximum possible values of the determinant of P is _________

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 PHYSICS Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. The resultant of the three vectors OA, OB and OC has magnitude
(R = Radius of the circle)

A) 2R B) 1  2  R C)  
2 1 R D) 2R
27. If a car covers 2/5th of the total distance with v1 speed and 3/5th distance with v2 then
average speed is
1 v1  v2 2v1v2 5v1v2
A) v1v2 B) C) D)
2 2 v1  v2 3v1  2v2

28. A person travels along a straight road for half the distance with velocity v1 and the
remaining half distance with velocity v2 the average velocity is given by
2
v  v1  v2
2v1v2
A) v1v2 B)  2  C) D)
 v1  v1  v2
2
     
   
29. If A  B is perpendicular to B and A  2 B is perpendicular to A , then

A) A  2 B B) A  2 B C) 2 A  B D) A  B
30. If P  2i  3 j  4k and Q  5i  2 j  4k find the angle between the two vectors.
A) 30 0 B) 450 C) 600 D) 90 0
     
31. A  B  2 iˆ and A  B  4 iˆ the angle between A and B is
A) 180 0 B) 1430 C) 530 D) 37 0
   
32. The component of A along B is 3 times that of the component of B along A . Then
A : B is
A) 1: 3 B) 3 :1 C) 2 : 3 D) 3 : 2

33. The projection of a vector r  3iˆ  ˆj  2kˆ on the x  y plane has magnitude
A) 3 B) 4 C) 14 D) 10
34. Find the component (projection) of  i  j  in the direction of i
A) -1 B) -2 C) 1 D) 2

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 35. Projection of the vector 2iˆ  3 ˆj  2kˆ on the vector iˆ  2 ˆj  3kˆ is
2 1 3 3
A) B) C) D)
14 14 17 14
  
 projection of a onb
36. If a  2iˆ  3 ˆj  6kˆ and b  3iˆ  4 ˆj , then  
projection of b on a
7 5 4
A) B) C) D) None
5 7 9
37. The cross product of the vectors  2i  3 j  4k  and  i  4 j  5k  is
A) iˆ  14 ˆj  11kˆ B) iˆ  14 ˆj  11kˆ C) iˆ  14 ˆj  11kˆ D) iˆ  14 ˆj  5kˆ
38. What is the condition for the vectors 2i  3 j  4k and 3i  aj  bk to be parallel?
9 9
A) a  , b  6 B) a  6, b  C) a  4, b  5 D) a  8, b  2
2 2
   2  2
39. If A  4, B  3 the value of A  B  A.B 
A) 5 B) 25 C) 144 D) 169
40. The angle between  A  B  and  B  A  is (in radian)
 
A) B)  C) D) Zero
2 4
  
41. If P  iˆ  ˆj and Q  2iˆ  kˆ are two vectors which when added to R gives a unit vector

along Z-axis direction. Then R is
A) 3iˆ  ˆj  2kˆ B) 3iˆ  ˆj  2kˆ C) k̂ D) k̂

42. The position vector of a moving particle at ‘t’ sec is given by r  3iˆ  4t 2 ˆj  t 3 kˆ . Its
displacement during an interval of t  1s to 3 sec is
A) ĵ  kˆ B) 3iˆ  4 ˆj  kˆ C) 9iˆ  36 ˆj  27 kˆ D) 32 ˆj  26kˆ
   
43. The angle between a and b is 00 then angle between 2a and 3b is
 
A) B)  C) D) None of these
3 6
    
44. Given c  a  b . The angle which a makes with c is
A) 00 B) 450 C) 900 D) 1800
     
45. If a  2, b  5 and a  b  8 then a. b is equal to
A) 6 B) 4 C) 3 D) 5

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 SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.
 
46. If the vectors P  aiˆ  ajˆ  3kˆ and Q  aiˆ  2 ˆj  kˆ are perpendicular to each other then the
positive value of ‘a’ is ______
47. If the vectors 2iˆ  3 ˆj  ckˆ and 3iˆ  6kˆ are orthogonal, the value of ‘c’ is _______
5 p
48. The angle between the vectors  i  j  k  and  i  j  k  is sin 1 then p is _____
p
 n
49. If A  2i  3 j and B  2 j  3k the component of B along A is then ‘n’ is ______
2n  1

50. A body freely falling from a height ‘h’ describes 7h/16 in the last second of its fall.
The height ‘h’ is _____  g  10 ms 2  (in m)

CHEMISTRY Max Marks: 100

SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

51. M 3 has electronic configuration as  Ar  3d 10 4s 2 , hence it lies in

A) s-block B) p-block C) d-block D) f-block

52. Three elements, X, Y and Z belong to the same period. Their oxides are acidic,
amphoteric and basic respectively. The order of electronegativity of these elements in
the periodic table is
A) X < Y < Z B) Y < Z < X C) X< Z< Y D) Z< Y< X
53. Which of the following order of radii is correct?
A) Li  Be  Mg B) H   Li   H  C) O  F  Ne D) Na   F   O 2
54. Which of the following is not isoelectronic series?
A) Cl , P , Ar B) N , Ne, Mg C) B , He, Li D) N ,S , Cl
55. The lanthanides contraction refers to
A) radius of the series B) valence electrons of the series
C) the density of the series D) electronegativity of the series
56. Which of the following orders is not correct for the size?
A) Al3  Mg 2  Na   F B) O2  O  O  O 

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 C) Fe3  Fe2  Fe4 D) Mg  Al  Si  P
57. With an increase in the extent of penetration of valence electrons, ionisation energy
A) Decreases B) Increases
C) Remains constant D) Both are not related
58. Which of the following oxide is amphoteric?
A) CrO B) Cr2O3 C) CrO3 D) CrO5
59. Electron affinity is
A) Energy required to take out an electron from an isolated gaseous atom
B) The tendency of an atom to attract an electron towards itself
C) Energy absorbed when an electron is added to an isolated atom in gaseous state
D) Energy released when an electron is added to an isolated atom in the gaseous state
60. Correct relation among XA , XB and  , where XA and XB are the electronegativities of
elements A and B.
A) X A  X B  0.208  B) X A  X B  0.208  

C) X A  X B  0.208  D) X A  X B  0.208  
61. The polarising power of which of the following pair is similar
A) Li, Mg B) Li  , Mg 2 C) Li 2 , Mg 2 D) Li  , Mg 
62. Diagonal relationship is present between the lighter elements of periods
A) Second, third C) Third, fourth B) Second, fourth D) Third, fifth
63. Increasing order of acidic character is
A) SO3  N2O5  CO2  SiO2 B) SO3  N2O5  CO2  SiO2
C) SO3  N2O5  CO2  SiO2 D) SO3  N2O5  CO2  SiO2

64. I1 of an element X is 899 kJ mole1 and that of another element Y is 801 kJ mole1 . Then
X and Y may be
A) Li , Be B) Be, B C) B, C D) C, N
65. Considering the elements F, Cl, O and S, the correct order of their electron affinity
values is:
A) F  Cl  O  S B) F  O  Cl  S C) Cl  F  S  O D) O  F  S  Cl
66. For H-atom, the energy required for the removal of electron from various sub-shells is
given as under:

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 The order of the energies would be:
A) E1 > E2 > E3 B) E3 > E2 > E1 C) E1 = E2 = E3 D) None of these
67. The possible set of quantum numbers for the unpaired electron of chlorine is
n  m n  m
A) 2 1 0 B) 2 1 1
C) 3 1 1 D) 3 0 0
68. If 1 and  2 denote the de-Broglie wavelength of two particles with same masses but
charges in the ratio of 1 : 2 after they are accelerated from rest through the same
potential difference, then

A) 1   2 B) 1   2 C) 1   2 D) None of these.
69. Given that the mass of electron is 9.1  10 31 kg and velocity of electron is 2.2  10 6 ms 1. If

the uncertainty in its velocity is 0.1% the uncertainty in position would be

A) 26 nm B) 32 nm C) 48 nm D) 50 nm
70. 3py orbital has.......... plane as nodal plane
A) XY B) YZ C) ZX D) All of these
SECTION-B
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

71. The I. E. and E. A of an element are 13.0 eV and 3.8 eV respectively. Its
electronegativity is ___ (Mulliken scale)
72. What is the atomic number of ununquadium _____
73. Liquid non-metallic element is present in ______ period of long form of periodic
table.
74. How many of the following have spin only magnetic moment as 1.73 BM?
Cu2 , Ti 3 ,Sc 2 , Zn2 ,Cu ,Mn2
75. Light of wavelength 400 nm falls on a metal with work function 2.0 eV. Then the
velocity of ejected photoelectrons are 6.22 × 10n m/s. Then value of n is….

***
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 JR-MPC JEE MAINS WTM-03 KEY SHEET

DATE: 05-07-2025

MATHS KEY:

1) A 2) C 3) D 4) A 5) D 6) D 7) D 8) D 9) A 10) B

11) D 12) A 13) A 14) B 15) B 16) A 17) B 18) B 19) D 20) C

21) 2 22) 0 23) 2 24) 0 25) 4

PHYSICS KEY:

26) B 27) D 28) D 29) A 30) D 31) A 32) B 33) D 34) A 35) A

36) A 37) C 38) A 39) C 40) B 41) A 42) D 43) B 44) C 45) A

46) 3 47) 1 48) 3 49) 6 50) 80

CHEMISTRY KEY:

51) B 52) D 53) B 54) D 55) A 56) C 57) B 58) B 59) D 60) C

61) B 62) A 63) A 64) B 65) C 66) C 67) C 68) C 69) A 70) C

71) 3 72) 114 73) 4 74) 3 75) 5

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 MATHS SOLUTIONS
1. 𝑃 = 𝑄 ,𝑃 𝑄 = 𝑄 𝑃 ⇒ 𝑃 − 𝑃 𝑄 + 𝑄 𝑃 − 𝑄 = 𝑂
⇒ 𝑃 (𝑃 − 𝑄) + 𝑄 (𝑃 − 𝑄) = 𝑂 ⇒ (𝑃 − 𝑄)(𝑃 + 𝑄 ) = 𝑂

If 𝑃 + 𝑄 is nonsingular then 𝑃 − 𝑄 = 𝑂 ⇒ 𝑃 = 𝑄, which is contradiction ∴ 𝑃 + 𝑄 is singular

⇒ det(𝑃 + 𝑄 ) = 0.

2. 𝐴 is a symmetric matrix ⇒ 𝐴 = 𝐴. 𝐵 is a skew symmetric matrix ⇒ 𝐵 = −𝐵

2 3 2 5 2 5
Given 𝐴 + 𝐵 = ⇒ (𝐴 + 𝐵) = ⇒𝐴−𝐵 =
5 −1 3 −1 3 −1
4 8 0 −2 2 4 0 −1
⇒ 2𝐴 = , 2𝐵 = ⇒𝐴= ,𝐵 =
8 −2 2 0 4 −1 1 0
2 4 0 −1 0 + 4 −2 + 0 4 −2
∴ 𝐴𝐵 = = =
4 −1 1 0 0 − 1 −4 − 0 −1 −4

3. 1 −2 3 5 𝑅 − 2𝑅 1 −2 3 5
Augmented matrix [𝐴 𝐵] = 2 −2 1 0 𝑅 +𝑅 0 2 −5 −10
−1 2 −3 6 ∼ 0 0 0 11

⇒ rank𝐴 = 2, rank[𝐴, 𝐵] = 3. ∴ Given system of equations has no solution.

4. 𝑘 1 1 1 𝑘𝑅 − 𝑅 𝑘 1 1 1
Augmented matrix = 1 𝑘 ⋅ 1 𝑘 0 𝑘 −1 𝑘−1 𝑘 −1 ⎤
𝑘𝑅 − 𝑅 ⎥
1 1⋅𝑘 𝑘 0 𝑘−1 𝑘 −1 𝑘 −1 ⎥
𝑘 1 ⋅ 1 ⎥
𝑘−1 𝑘 −1
(𝑘 + 1)𝑅 − 𝑅 0 𝑘 − 1 ⋅ (𝑘 − 1) − (𝑘 − 1) ⎥
(𝑘 − 1) − 1 (𝑘 + 1) ⎦
0 0 ⋅ 1

Given system has no solution ⇒ (𝑘 − 1)[(𝑘 + 1) − 1] = 0, (𝑘 + 1)(𝑘 − 1) − (𝑘 − 1) ≠ 0

⇒ (𝑘 − 1)(𝑘 + 2𝑘) = 0, (𝑘 − 1)(𝑘 + 𝑘) ≠ 0 ⇒ 𝑘 = 1,0, −2, 𝑘 ≠ 1, −1,0 ⇒ 𝑘 = −2.

5. Conceptual
6. The sum of the products of the elements of any column of a square matrix with the cofactors of the
corresponding elements of any other column is zero
2(1 – 5k) + (5k + 1)2 + 3(4k – 2) = 0
7. 𝑅 → 𝑅 + 2𝑅
Apply
𝑅 →𝑅 +𝑅

8. Apply Gauss – Jordan Method

9. Take A  0 and apply C1   C1  C2  C3 

10. ai bi
| Ai |  i
ai
= (a )  (b ) , | a |  1,| b |  1
b i 2 i 2

| A |  (a
i1
i
2
 b 2 )  (a 4  b 4 )
 (a 6  b 6 )  .......

 (a 2  a 4  a 6  ......)  (b 2  b 4  b 6  .......)

a2 b2 a 2  a 2b 2  b 2  a 2 b 2 a2  b 2
   2 2

1a 2
1b 2 (1  a )(1  b ) (1  a 2 )(1  b 2 )

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11. Crammer’s rule
12. a1 b1 c1
 
a2 b2 c2
k k  3 3k  1
 
k 1 8 4k
k 2  4k  3  0 k 2  3k  2  0
k  1,3 k  1, 2
∴𝑘=1
13. |adj𝐴| = |cofactors|
|𝐴| = 11
|adj𝐴| = |𝐴|
𝑛=3
|adj𝐴| = |𝐴|2
= (11)
|adj𝐴| = 121
|(adj𝐴)| = (121)
14641
14. Δ = 0; Δ = 0

−16
𝑎 = −70; 𝑏 =
13
−16
13𝑎𝑏 = 18 × −70 ×
13
= 1120

15. adj(adj𝐴)
(Adj𝐴) =
|adj𝐴|

|𝐴| ⋅ adj𝐴
=
|𝐴|

adj𝐴
(adj𝐴) =
1𝐴
cos 𝛼 −sin 𝛼 0
|𝐴| = 1 adj𝐴 = sin 𝛼 cos 𝛼 0 =𝐴
0 0 1
16. Use Cramer’s rule

17. 𝑅 →𝑅 −𝑅

(3𝛼 + 1) + 𝛼(2𝛼 + 3) = 0
2𝛼 + 3𝛼 + 3𝛼 + 1 = 0
2𝛼 + 6𝛼 + 1 = 0
−3 + √7
𝛼=
2
−3 + √7 −3 − √7
𝛼= ,
2 2
−0.2, −2.8
(−3,0)

18. 𝑅 → 𝑅 − (𝑅 + 𝑅 + 𝑅 )
𝛼−5=0
𝛼=5
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19. Δ=0

𝑎 + 10𝑎 + 17 = 0
−10 ± √32
𝑎=
2
0 ± 4√2
𝑎=−
2
𝑎 = −5 ± 2√2

20. 1 1 1
1 2 3 =0
1 2 𝑚
𝑚=3

6 1 1
10 2 3  0
n 2 3

n  10

21. 2 1 1 2 1 1 2 1 1
0 3 −1
𝑅 → 2𝑅 − 𝑅
0 3 −1 𝑅 → 𝑅 + 𝑅 0 3 −1 . ∴ rank = 2
= 0 0 0
1 −1 1 0 −3 1 =

22. 1 1 1
𝑥(𝑥 + 1)(𝑥 − 1) 2𝑥 𝑥−1 𝑥
3𝑥 𝑥−2 𝑥

𝑓(2025) = 0

23. a 1 1
1 b 1 0
1 1 c
24. Determinant of odd order skew-symmetric matrix is zero.

25. −1 1 1
1 −1 1
1 1 −1
−1(1 − 1) − 1(−1 − 1) + 1(1 + 1)
0+2+2=4

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 PHYSICS SOLUTIONS
26. Resultant = √OA + OC + OB

√2𝑅 + 𝑅 = (√2 + 1)𝑅

27. s s 5V V
⟨V⟩ = = =
t +t + 2V +3V

28.
𝑑 𝑑
total displacement + 𝑑 2𝑉1 𝑉2
(𝑉) = = 2 2 = =
total time 𝑡1 + 𝑡2 𝑑
+
𝑑 𝑉1 + 𝑉2
2𝑉1 2𝑉2

29. A⃗ + B⃗ perpendicular to B⃗ ⇒ 𝐴⃗ + 𝐵⃗ ⋅ 𝐵⃗ = 0 ⇒ 𝐴⃗ ⋅ 𝐵⃗ + 𝐵 = 0 (1)

and (𝐴⃗ + 2𝐵⃗) perpendicular to 𝐴⃗
⇒ 𝐴⃗ + 2𝐵⃗ ⋅ 𝐴⃗ = 0 ⇒ 𝐴 + 2𝐵⃗ ⋅ 𝐴⃗ = 0 (2)

From (1) and (2), 𝐴 = 2𝐵 ⇒ 𝐴 = √2𝐵

30. 𝑃⃗ = 2𝚤ˆ + 3𝚥ˆ − 4𝑘ˆ ; 𝑄⃗ = 5𝚤ˆ + 2𝚥ˆ + 4𝑘ˆ

P⃗ ⋅ Q⃗ 10 + 6 − 16
cos 𝜃 = ⇒ cos 𝜃 = = 0 ∴ 𝜃 = 90∘
PQ √29 ⋅ √45

31. A⃗ + B⃗ = 2ı̂; A⃗ − B⃗ = 4ı̂; A⃗ = 3ı̂; B⃗ = −ı̂ So angle between 𝐴⃗ and 𝐵⃗ is 𝜋

32. Given component of A⃗ along B⃗ ⇒ √3 component of B⃗ along

𝐴⃗ ⋅ 𝐵⃗ 𝐴⃗ ⋅ 𝐵⃗ 𝐴
𝐴⃗ ⇒ = √3 ⇒ = √3
𝐵 𝐴 𝐵

33. 𝑟⃗ = 3𝚤ˆ + 𝚥ˆ + 2𝑘ˆ projection of 𝑟⃗ on 𝑥 − 𝑦 plane = √10

34. Let 𝑎⃗ = −𝚤ˆ + 𝚥ˆ; 𝑏⃗ = 𝚤ˆ component of 𝑎⃗ along 𝑏⃗ is =
⃗⋅ ⃗
= −1
| ⃗|

35. Let 𝑎⃗ = 2𝚤ˆ + 3𝚥ˆ + 2𝑘ˆ and 𝑏⃗ = 𝚤ˆ − 2𝚥ˆ + 3𝑘ˆ

⃗⋅ ⃗
Projection of 𝑎⃗ on 𝑏⃗ = = =
| ⃗| √ √

36. projection of ⃗ on ⃗ ( ⃗⋅ ⃗ )/
𝑎⃗ = 2𝚤ˆ + 3𝚥ˆ + 6𝑘ˆ, 𝑏⃗ = 3𝚤ˆ + 4𝚥ˆ = = =
projection of ⃗ on ⃗ ( ⃗⋅ ⃗ )/
37. 𝚤ˆ 𝚥ˆ 𝑘ˆ
Let 𝑎⃗ = 2𝚤ˆ − 3𝚥ˆ + 4𝑘ˆ ; 𝑏⃗ = 𝚤ˆ + 4𝚥ˆ − 5𝑘ˆ ; 𝑎⃗ × 𝑏⃗ = 2 −3 4 = −𝚤ˆ + 14𝚥ˆ + 11𝑘ˆ
1 4 −5

38. Let 𝑎⃗ = 2𝚤ˆ + 3𝚥ˆ − 4𝑘ˆ and 𝑏⃗ = 3𝚤ˆ − 𝑎𝚥ˆ + 𝑏𝑘ˆ

For a⃗ to be parallel to b⃗ = = = ⇒a= and b = −6

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39. |𝐴⃗| = 4, |𝐵⃗| = 3; |𝐴⃗ × 𝐵⃗| + |𝐴⃗ ⋅ 𝐵⃗|
= (𝐴𝐵) sin 𝜃 + (𝐴𝐵) cos 𝜃
= (𝐴𝐵) = (12) = 144

40. A⃗ × B⃗ = −(B⃗ × A⃗)

∴ Angle between A⃗ × B⃗ and B⃗ × A⃗ is 𝜋
41. 𝑃⃗ = 𝚤ˆ + 𝚥ˆ; 𝑄⃗ = 2𝚤ˆ − 𝑘ˆ; given 𝑃⃗ + 𝑄⃗ + 𝑅⃗ = 𝑘ˆ
𝑅⃗ = 𝑘ˆ − (𝑃⃗ + 𝑄⃗) = 𝑘ˆ − (3𝚤ˆ + 𝚥ˆ − 𝑘ˆ ) = −3𝚤ˆ − 𝚥ˆ + 2𝑘ˆ

42. 𝑟⃗ = 3𝚤ˆ + 4𝑡 𝚥ˆ − 𝑡 𝑘ˆ
t = 1 s is r ⃗ = 3ı̂ + 4ȷ̂ − k̂
t = 3 s is r ⃗ = 3ı̂ + 36ȷ̂ − 27k̂
s⃗ = r⃗ − r⃗ = 32ȷ̂ − 26k̂

43. If angle between 𝑎⃗ and 𝑏⃗ is 𝑂∘ . Then angle between 2𝑎⃗ and −3𝑏⃗ is 𝜋
44. Vector 𝑐⃗ is perpendicular to the plane containing 𝑎⃗ as well as 𝑏⃗, that's why 𝑐⃗ ⋅ 𝑎⃗ = 0.
45. |𝑎⃗| = 2, |𝑏⃗| = 5
|a⃗ × b⃗| = |a⃗||b⃗|sin 𝜃 = ±8
4
sin 𝜃 = ±
5
∴ 𝑎⃗ ⋅ 𝑏 = |𝑎⃗||𝑏⃗|cos 𝜃
⃗
3
= 10. ± = ±6
5
|a⃗ ⋅ b⃗| = 6

46. 𝑃⃗ = 𝑎𝚤ˆ + 𝑎𝚥ˆ + 3𝑘ˆ ; 𝑄⃗ = 𝑎𝚤ˆ − 2𝚥ˆ − 𝑘ˆ ; 𝑃⃗ perpendicular to Q⃗ a − 2a − 3 = 0 ⇒ a = 3 (or) a = −1

47. Let 𝑎⃗ = 2𝚤ˆ + 3𝚥ˆ + 𝑐𝑘ˆ and 𝑏⃗ = −3𝚤ˆ + 6𝑘ˆ Given 𝑎⃗ perpendicular to 𝑏⃗ ⇒ 𝑎⃗ ⋅ 𝑏⃗ = 0
⇒ −6 + 6𝐶 = 0 ⇒ 𝐶 = 1

48. Let 𝑎⃗ = 𝚤ˆ + 𝚥ˆ + 𝑘ˆ ; 𝑏⃗ = 𝚤ˆ − 𝚥ˆ − 𝑘ˆ

𝑎⃗ ⋅ 𝑏⃗ |−1−|
cos 𝜃 = =
|𝑎⃗||𝑏⃗| √3 ⋅ √3
−1 √8
𝜃 = cos = sin
3 3
Compare p = 3

49. 𝐴⃗ = 2𝚤ˆ + 3𝚥ˆ, 𝐵⃗ = 2𝚥ˆ + 3𝑘ˆ

⃗⋅ ⃗
Component of 𝐵⃗ along 𝐴⃗ = ⃗
=
√

∴n=6

50. 2𝑛 − 1 7
= ⇒ 𝑛 = 4sec
𝑛 16
1 1
h = gt = × 10 × 16 = 80 m
2 2

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 CHEMISTRY SOLUTIONS
51. 𝑀 → [𝐴𝑟]3𝑑 4𝑠 4𝑝

52. Acidic oxides elements are more electronegative than amphoteric than basic

53. Anion size > neutral atom size > cation size for isoelectronic species

54. Conceptual
55. Steady decrease of lanthanide elements from left to right due to imperfect screaning effect is called
lanthanide constraction
56. More positive charge

Less size

57. Extent of penetration  ionization energy

58. Conceptual

59. Electron affinity is energy releases when an electron is added to an isolated atom is the gaseous state
60. Conceptual

61. Li  , Mg 2 shows diagonal relationship.

62. Second and third periods elements show diagonal relationship

63. More number of oxygen atom per central atom is more acidic and more electro negative central atom
is more acidic

64.   
Due to completely filled 2s orbital, Be has more I1 899 kJmol 1 then B. 801 kJmol 1 
65. Due to small size, electron – electron repulsion is more for F than C . Hence E.A order C   F
Similary, S  O . Down the group, E.A decreases. Hence C  F  S  O
66. For single electron system line ‘H’ energy depends only on ‘n’ and independent of ‘  ’

67. C 17  :1s 2 2s 2 2 p6 3s 2 3 p5

l  1; n  3
m  1, 0, 1

68.
ℎ 𝜆 𝑞 2
𝜆= = = ⇒ √2 = 1.414
2𝑚 ⋅ 𝑞 ⋅ 𝑉 𝜆 𝑞 1
⇒𝜆 >𝜆

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69. 0.1 2.26
Δ𝑣 = 2.2 × 10 × =
100 2.2 × 10 m/s
6.625 × 10
Δ𝑥 ⋅ 𝑚Δ𝑣 =
4 × 3.14
6.625 × 10
Δ𝑥 =
4 × 3.14 × 9.1 × 10 × 2.2 × 10
6.625
= × 10
4 × 3.14 × 9.1 × 2.2
= 0.026 × 10 m = 0.026 × 10 × 10 nm
= 26 nm

70.

71. 𝑙𝐸 + 𝐸𝐴 13.0 + 3.8

𝐸𝑁 = =
5.6 5.6
16.8
= = 3.
5.6

72. un  1; un  1 quad-4 ununquadium: 114

73. liquid non-metal is bromine, it is in 4th period.

74. √3 = 𝑛(𝑛 + 2)
⇒𝑛=1

𝐶𝑢 = [𝐴𝑟]3𝑑
𝑇𝑖 = [𝐴𝑟]3𝑑
𝑆𝐶 = [𝐴𝑟]3𝑑
2𝑛 = [𝐴𝑟]3𝑑
𝑀𝑛 = [𝐴𝑟]3𝑑

75. 𝐾 ⋅ 𝐸 = ℎ𝜈 − 𝜔
1
𝑚𝑣 = ℎ𝜈 − 𝜔
2
6.625 × 10 × 3 × 10
=
400 × 10 × 1.6 × 10
= 3.1 − 2
= 1.1ev

1
× 9.1 × 10 × 𝑣 = 1.1 × 1.6 × 10
2
1.1 × 1.6 × 10
𝑣 = ×2
9.1 × 10
= 0.386 × 10
𝑣 = 38.6 × 10
𝑣 = 621 × 10

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