Sec: SR.

IIT _*CO-SC(MODEL-A) Date: 27-07-25

Time: 3 Hrs Max. Marks: 180
27-07-25_SR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_RTA-23_SYLLABUS

MATHEMATICS: 100% CUMULATIVE SYLLABUS:

SYLLABUS COVERED FROM 04-04-24 TO 26-07-25

PHYSICS: 100% CUMULATIVE SYLLABUS:

SYLLABUS COVERED FROM 04-04-24 TO 26-07-25

CHEMISTRY: 100% CUMULATIVE SYLLABUS:

SYLLABUS COVERED FROM 04-04-24 TO 26-07-25

Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 5 – 8) (partial marking scheme) (+1,0)
+4 -2 4 16
Questions with Numerical Value Type
Sec – III (Q.N : 9 – 16) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +4 0 8 32
‐127.30)
Total 16 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 17 – 20) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 21 – 24) (partial marking scheme) (+1,0)
+4 -2 4 16
Questions with Numerical Value Type
Sec – III (Q.N : 25 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +4 0 8 32
‐127.30)
Total 16 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 33 – 36) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 37 – 40) (partial marking scheme) (+1,0)
+4 -2 4 16
Questions with Numerical Value Type
Sec – III (Q.N : 41 – 48) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +4 0 8 32
‐127.30)
Total 16 60

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
MATHEMATICS MAX.MARKS: 60
SECTION–I (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. If Z  x  iy, x,y   , i  1, such that Z  1 , then the maximum value of Z 3  Z  2 is?

(A) 2 (B) 4 (C) 17 (D) 13

2. If E1 ,E2 ,E3 , ,E12 are distinct number of edges of a cube, then the number of un-ordered
pairs Ei ,E j  where 1  i, j  12 that determine a plane is?

(A) 38 (B) 42 (C) 36 (D) 12

1000
p 1000 Ci
3. If 1    2020
, where p, q are coprime, then p+q is equal to?
q i 0 Ci

(A) 3020 (B) 1510 (C) 2021 (D) 2025


4
tan2 x
4. If I   dx, then the value of I is
0 x  tan x  2x tanx  3x  3 tanx  2
2 2

1 16  2  16  2  1
(A) ln2 (B)  ln   (C) ln   (D)  ln2
2  12     12    2

SECTION - II (Maximum Marks : 16)

This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1
1
5. I  
dx, then
0
1x 2

 
(A) I  ln 2 (B) I  ln 2 (C) I  (D) I 
4 4

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
1 3
6. Let     i , and S denote the set of all complex numbers in the Argand plane of the
2 2

form a  b  c2 , where a,b,c [0,1] , then :

(A) the length of perimeter of region traced by S is 3 units

3 3
(B) area of the region traced by S is units square.
2

(C) length of perimeter of region traced by S is 6 unit

 3
(D) area of the region traced by S is sq. units.
2

7. The roots ,  of the quadratic equation ax 2  bx  c  0, a  0 lie in the interval [0, 1],
then?

(a  b)(2a  b)
(A) the maximum value of is 3
a(a  b  c)

(a  b)(2a  b)
(B) the minimum value of is 2
a(a  b  c)

(a  b)(2a  b)
(C) if is at its maximum value, then 2  2 can be 2.
a(a  b  c)

(a  b)(2a  b)
(D) if is at its maximum value, then 2  2 can be 1.
a(a  b  c)

8. Let a1 ,a2 ,a3 , ,an be a sequence of real numbers which satisfies the relation an1  an2  1
for all nN. Suppose that there exists a positive integer number such that a2n  3an , then 0 0

2an
(A) lim 2
n
n  2020
r

(B) if
Tr   an2 , then min T1 , T2 , , Tr   1
n 1

(C) m nlim

 an1  an  n1/2  2

1 49
8 
(D) 
2
   6, where
8a  7 
2
x represents the greatest integer less than or equal to x.
 n 1 n

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
SECTION-III (Maximum Marks : 32)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
k r 
i   
3 2
4 2019
e
9. Find the minimum value of  
k 0 r 0
Z
1010
, where Z is any complex number

10. Let f :    be a differentiable function satisfying

 1
2(f(x))2 f(x)  (f(2x  1))2 f(2x  1), f     1
 8
2
and f(6)=2, find the value of
(f(1))3
2 2
The total number of real solutions of 4  6  5  5 is/are ……………
x x x x
11.
12. Out of 10 tokens, numbered from {1,2, ,10}, first person X chooses a token then person
Y chooses the token (without replacement in both cases). A person is winner if he gets a
prime number and in the next draw other person gets a non-prime. If both get prime in
successive draw, game is a draw. Game continues till someone wins or game is drawn. If
P(x) is the probability of X winning, P(y) is the probability of Y winning and P(d) is the
probability of a draw, then the value of 21P(x) + 126 P(y) –7P(d) is ______.
y

13. Find the maximum value of 

0
x 4  (y(3  y))2 dx, where 0  y  3 .

14. Let f(x)  x 6  2x 3  8 and g(x)  x 2  2x  4 . Let 1 , 2 ,,  6 are the roots of the equation
f(x)=0, find g  1   g   2  g   6 

15. The total number of functions f : A  B where A  a1 ,a2 ,a3 ,a4 ,a5 ,a6  and B  {1,2,3, ,9}

such that f  ai1   f  ai   i  N and f  ai   i is

  
16. Let a,b and c be three non-coplanar vectors, and d be a non-zero vector, which is
         
perpendicular to (a  b  c). If d  sinx(a  b) + cos y(b  c)  2(c  a), then the minimum value
2
of x 2  y2 is equal to , where  is equal to ________________.
4

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
PHYSICS MAX.MARKS: 60
SECTION–I (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
17. Consider three statements :

(i) In photo electric effect, even for monochromatic incident radiation, the
photoelectrons are emitted with a spread of velocities.

(ii) Photoelectrons are emitted without delay once the incident light reaches the surface
of the emitter.

(iii) Frequency of monochromatic light (well above the cutoff frequency), that is
incident on a emitter in a photoelectric effect, is increased while keeping the intensity
constant. It results in decrease in stopping potential.

Correct order of the true/false for the above statements is

(A) T T F (B) F T T (C) TFT (D) F F T

18. A Young's double slit experiment is conducted in water  1  as shown in the figure, and
a glass plate of thickness t and refractive index 2 is placed in the path of S2. The
magnitude of the phase difference at O is: (Assume that '  ' is the wavelength of light in
air)

  2   2
(A)  2  1  t (B)  1  1  t
 1    2  

2 2
(C) ∣   2  1  t∣ (D)  2  1  t
 

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
19. A motor running at full load on a 220 V line develops a back emf (induced emf) of 200V
and draws a current of 10A through the armature. Then, neglecting frictional losses,

(i) the mechanical power output of the motor is 2.2 kW

(ii) the mechanical power output of the motor is 2 kW

(iii) the armature resistance is 2

(iv) the armature resistance is 20

(A) (i) & (iv) are correct (B) (ii) & (iii) are correct

(C) (i) & (iii) are correct (D) (iii) & (iv) are correct

20. In figure (a) a solenoid produces a magnetic field whose strength increases into the plane
of the page. An induced emf is established in a conduction loop surrounding the
solenoid, and this emf lights bulbs A and B. In figure (b) point P and Q are shorted.
After the short is inserted

(A) Bulb A goes out bulb B gets brighter

(B) Bulb B goes out bulb A gets brighter

(C) Bulb A goes out bulb B gets dimmer

(D) Bulb B goes out bulb A gets dimmer

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
SECTION - II (Maximum Marks : 16)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
21. Charge is sprayed onto a large non conducting belt above the left hand roller. The belt
carries charge with a uniform surface charge density s, as it moves with a speed v
between the rollers as shown. The charge is removed by a wiper at right hand roller. For
a point just above the sheet, mark the correct option/s.

 0 v
(A) magnetic field is , out of the plane of the page, parallel to axis of roller.
2

(B) magnetic field is 0 , out of the plane of the page, perpendicular to axis
0 
(C) electric field is perpendicular to the plane of sheet
2
(D) If an electron moves parallel to V just above the sheet it will experience an upward
magnetic force.
22. A parallel plate capacitor of capacitance 10 F is connected to a cell of emf 10 Volt and
fully charged. Now a dielectric slab (k = 3) of thickness equal to the gap between the
plates, is completely filled in the gap, quasistatically keeping the cell connected. During
the filling process:
(A) The increase in charge on the capacitor is 200 C.
(B) The heat produced is zero.
(C) Energy supplied by the cell = increase in stored potential energy + work done on the
person who is filling the dielectric slab.
(D) Energy supplied by the cell = increase in stored potential energy + work done by the
person who is filling the dielectric slab + heat produced.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
23. In the circuit shown in figure, E1 and E2 are two ideal sources of unknown emfs. Some
currents are shown. Potential difference appearing across 6Ω resistance is VA – VB = 10
V.

(A) The current in the 4.00  resistor is 5 A.

(B) The unknown emf E1 is 36 V.

(C) The unknown emf E2 is 54 V.

(D) The resistance R is equal to 9  .

24. Two large conducting plates having surface charge densities  and  , respectively,
are fixed ' d ' distance apart. A small, non-conducting sphere having charge q and mass
m is attached to two identical, non-conducting springs as shown in the adjacent figure.
The charge q is now released from rest with springs in natural length. Then q will
[neglect gravity]

2K
(A) perform SHM with angular frequency
m

q
(B) perform SHM with amplitude
2k0

(C) might not perform SHM, but can have a periodic motion

(D) may become stationary after sometime.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
SECTION-III (Maximum Marks : 32)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. A particle moves along y-axis according to the equation
y (incm)  3sin100t  8 sin2 50 t  6

If the particle does not perform SHM, write your answer as 1. If it does perform SHM,
find the amplitude of the particle's oscillation in cm.
7 4
26. Two moles of O2     at temperature T0 and 3 moles of CO2     at temperature 2T0
5  3  
are allowed to mix together in a closed adiabatic vessel. The resulting mixture finally
comes in thermal equilibrium. Then, if the adiabatic exponent    of the mixture formed
is 'm' and the final temperature of the mixture is nTo, write (m+n) as your answer.
27. A point source of sound is located somewhere along the x-axis. Experiments show that
the same wave front simultaneously reaches listeners at x = –8 m and x = +2.0 m.
A third listener is positioned along the positive y-axis. What is her y -coordinate (in m)
if the same wave front reaches her at the same instant as it does the first two listeners?
28. We would like to increase the length of a 15 cm long copper rod of cross-section 4 mm2
by 1 mm. The energy absorbed by the rod if it is heated is E1. The energy absorbed by
the rod if it is stretched slowly is E2. Then find E1/E2.
[Various parameters of Copper are: Density = 9  103 kg/m3 , Thermal coefficient of linear
expansion  16  10 6 K 1 , Young's modulus = 135 × 1011 Pa, Specific heat = 400 J/kg-K]
29. Two objects of equal volume V = 1m3 and different densities d1 = 500 kg/m3 and
d2 = 1000 kg/m3 are glued to each other so that their contact surface is flat and has an
area A = 0.1 m2.

When the objects are submerged in a certain liquid, they float in stable liquid (see the
diagram). How deep (H in meters) can the contact surface be in the liquid so that the
objects are not torn apart? The maximum force that the glue can withstand is F = 250 N.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
30. A thin metal plate is being bombarded by a perpendicular beam of gas particles from
both sides. The mass of these particles is m0, their velocity before striking is v0 and there
are n particles/vol in each beam. Each beam has an area A and the collisions are elastic.
What force (in N) is needed to move the plate with a constant velocity u. Take m = 10–27
kg, n = 1026 per m3, A = 1m2, v0 = 10 m/s, u = 2 m/s.

31. A window (of weight w) is supported by two strings passing over two smooth pulleys in
the frame of the window in which window just fits in, the other ends of the string being
attached to weights each equal to half the weight of the window. One thread breaks and
the window moves down. Find acceleration of the window if  is the coefficient of
friction, and a is the height and b the breadth of the window. Express your answer in
 g 
multiple of   . (Take a=b,  =0.5)
 42 

32. Two equal heavy masses are situated at a separation r0. One of them is imparted a
Gm
velocity v 0  perpendicular to the line joining them. Treating motion only under
r0

mutual gravitational force find the ratio of maximum and minimum separation between
them.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
CHEMISTRY MAX.MARKS: 60
SECTION–I (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
33. Consider the following unbalanced reaction:
RCONH2  Br2  NaOH 
 RNH2  Na2CO3  H2O  NaBr

The incorrect statement regarding this reaction is

(A) The mechanism of this reaction involves migration of R to electron deficient
nitrogen
(B) 4-methoxybenzamide is more reactive than benzamide towards this reaction.
(C) The coefficient of NaOH in the simple balanced equation of this reaction is 4.
(D) When a mixture of MeCONH2 and PhCO*NH2 is subjected to this reaction, a mixture
of
MeNH2, Me*NH2 , PhNH2 and Ph*NH2 is obtained
34. Two rigid adiabatic vessels A and B which initially, contain two gases at different
temperature are connected by pipe line with valve of negligible volume. The vessel 'A'
5
contain 2 moles Ne gas  Cp, m  R  at 300 K, vessel ‘B’ contain 3 moles of SO2 gas
 2 
C p,m  4R  at 400 K.

The volume of A and B vessel is 4 and 6 litre respectively.

The final total pressure (in atm) when valve is opened and 15 Kcal heat supplied through
it to vessels.

[Use : R = 2cal/mol. K and R = 0.08 L. atm/mol K as per desire]

(A) 10 atm (B) 20 atm (C) 40 atm (D) 60 atm

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
35. A compound NpSq has cubic close packing (ccp) arrangement of S. N is present at
alternative tetrahedral voids. If all the atoms along one body diagonal are removed, the
empirical formula of the compound is:

(A) N5S14 (B) N4S5 (C) NS2 (D) NS

36. Given: Enthalpy of formation of H2O I and OH  aq.  are –285 kJ/mol and –227.3
kJ/mol respectively.

Enthalpy of neutralization of CH3COOH with NaOH = –55 kJ/mol

The enthalpy of dissociation of CH3COOH is:

(A) 2.3 kJ/mol (B) 2.7 kJ/mol (C) 1.3 kJ/mol (D) 1.7 kJ/mol

SECTION - II (Maximum Marks : 16)

This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
37. Consider the following reactions (unbalanced)

Cu  conc.HNO3 
 K  L  M

K  KCN(excess) 
 T  S  KNO3

Choose the correct option(s)

(A) The oxidation state of Cu in T is +2.

(B) ‘S’ has 4 bonds.

(C) ‘L’ is brown gas.

(D) ‘T’ on reaction with H2S does not give precipitate of CuS.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
38. In Baeyer's process (extraction for aluminium metal), bauxite ore is first digested with
reagent 'Q' to form 'R'. The solution of 'R' is then neutralized by passing gas 'S' and 'T' is
precipitated out.

Choose the correct option(s)

(A) 'Q' is NaOH (B) 'R' is Na[Al(OH)4]

(C) Bauxite ore is Al(OH)3 (D) 'S' is CO2 gas

39. Choose the correct option(s) for the following reaction sequence:

(A) The compound ‘P’ gives 2,4-DNP test.

(B) The compound ‘Q’ gives effervescence of CO2 with NaHCO3.

(C) The conversion of ‘P’ to ‘Q’ is a type of electrophilic substitution reaction.

(D) The compound ‘P’ is soluble in NaOH.

40. In an evacuated vessel of capacity 49.2 L, 4 moles of Ar(g) and 5 moles of PCl5(g) were
introduced and the temperature is maintained at 240 K (assume that at this temperature
decomposition of PCl5 takes place). At equilibrium, the total pressure of the mixture was
found to be 4.8 atm.

(Given R = 0.082 atm L mol–1 K–1). Correct statement(s) is/are

(A) The degree of dissociation of PCl5(g) into PCl3(g) and Cl2(g) is 0.6.

(B) KP for the reaction PCl5 ( g)  PCl3 ( g)  Cl2 ( g) is 2.7 atm.

(C) At equilibrium total moles of gases are 12.

(D) On removing Ar(g) from the equilibrium mixture at constant pressure and
temperature, the extent of dissociation of PCl5 will increase.

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
SECTION-III (Maximum Marks : 32)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
41. Among PbS , AgI , NiS , CdS , PbI 2 , HgS , PbCrO4 , Ag 2CrO4 the total number of yellow
colour compounds is/are____

42. With respect to their Boiling points the number of correct statements:

43. How many of the following species are attracted by a positively charged rod

O3 ,CO2 ,NO2 ,N2 O,CH4 ,CFCl3 ,XeF2 ,ClF3

44. How many transition states are formed during the following reaction?

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Narayana IIT Academy 27-07-25_SR.STAR CO-SC(MODEL-A)_JEE-ADV_RTA-23_QP
45. Among the following how many gives NaHSO3 addition reaction

46. A cell Cu|Cu2 | | Ag  | Ag initially contained 2M Ag+ and 2M Cu2+ions in 1 L solution

each. The magnitude of change in cell potential after it has supplied 1A current for
96500 seconds was found to be x 102 V. Here ‘ x ’ is : (in nearest integer)

2.303RT
(Take:  0.06,log  5  0.7 )
F

47. The solubility of AgCN in a buffer solution is 1.58  10 5 mol litre–1.

Given Ksp of AgCN  1.2  1016 and Ka for HCN is 4.8  10 10 . The pH of the Buffer
is____(in nearest integer)

(Take: log  2   0.3;log 1.58   0.2 )

48. In how many of the following compounds the anion oxidizes the cation on heating?

NH 4 NO 3 , NH 4 NO 2 ,  NH 4 2 Cr2O 7 , NH 4ClO 4 ,Fe  ClO 4 2 , Mg  ClO 4 2 , NH 4Cl

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