Sri Chaitanya Narayana IIT Academy

(Sri Sarvani Educational Society)

Common Central Office-Madhapur-Hyd
Jr.COIPL Date: 01-02-14
Time : 3 Hours Max Marks : 360
JEE-MAIN_2011 MODEL
IMPORTANT INSTRUCTIONS:
There are three parts in the question paper A, B, C consisting of Physics, Maths & Chemistry having
30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct
response.
Candidates will be awarded marks as stated above in instruction for correct response of each
question. 1/4 (one fourth) marks will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is indicated for an item in the answer
sheet.
There is only one correct response for each question. Filling up more than one response in each
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction
JR.COIPL_JEE-MAIN_WTM-35_SYLLABUS

Physics:
Refraction at plane surface,TIR and Prism,Refraction at curved surface,Experiments: (i) Plot of angle

of deviation vs angle of incidence for a triangular prism,(ii) Refractive index of a glass slab using a

travelling microscope(100%)

Mathematics:
Complete 3D - Geometry , Mathematical Induction, Heights and Distances(100%)
Chemistry:

Alynes: Preparations, properties and reactions; Benzene: Preparations and reactions of benzene and
alkyl benzenes,Eletrophilic aromatic substitution, mechanism of halogenations, nitration, sulphonation,
nitrosation, alkylation and acylation,Reactivity and orientation towards electrophilic aromatic
substitutions(100%)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

PHYSICS
1. Let X-Y plane be the boundary between two transparent media. Medium (1) in Z  O

has refractive index of 2 and medium (2) with Z<0 has refractive index of K 3. A


ray of light in medium (1) given by the vector A  6 3  8 3 ˆj 10kˆ is incident on the

plane of separation . The angle of refraction on in the medium (2) is

1) 750 2) 300 3) 450 4) 600

2. An observer can see through a pin-hole the top end of a thin rod of height h, placed as

shown in the figure. The beaker height is 3h and its radius h. When the beaker is filled

with a liquid up to height 2h, he can see the lower end of the rod. Then the refractive

index of the liquid is :

5 5 3 3
1) 2) 3) 4)
2 2 2 2

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3. A light ray is incident perpendicular to one face of a 900 prism and is totally internally
reflected at the glass-air interface. If the angle of reflection is 450 ,we conclude that the
refractive index n:

1 1
1) n  2) n  2 3) n  4) n  2
2 2
4. A fish looking up through the water sees the outside world, contained in a circular
4
horizon. If the refractive index of water is and the fish is 12 cm below the water
3
surface, the radius of this circle in cm is;
36
1) 36 7 2) 3) 36 5 4) 4 5
7
2
5. A transparent solid cylindrical rod has a refractive index of . It is surrounded by air,
3
A light ray is incident at the mid-point of one end of the rod as shown in the figure
.The incident angle  for which the light ray grazes along the wall of the rod is :

 3   2   1   1
1) sin1   2) sin1   3) sin1   4) sin1  

 2  3 
  3 
  2

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

6. An air bubble is inside water. The refractive index of water is 4/3. At what distance
from the air bubble should a point object be placed so as to form a real image at the
same distance from the bubble ?
1) 2R 2) 3R
3) 4R 4) The air bubble cannot form a real image.
7. A ray of light is incident at the glass-water interface at an angle i, it emerges finally
parallel to the surface of water, then the value of  g would be:

 4 1 4
1)   sin i 2) 3) 4) l
 3 sin i 3
8.

A plane mirror is placed at the bottom of a tank containing a liquid of refractive index
 . P is a small object at a height h above the mirror. An observer O-vertically above P,
outside the liquid-sees P and its image in the mirror. The apparent distance between
these two will be
2h 2h  1 
1) 2h 2) 3) 4) h 1 
  1   

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9. A ray of light incident on a slab of transparent material is partly reflected from the
surface and partly refracted into the slab. The reflected and refracted rays are mutually
perpendicular. The incident ray makes an angle i with the normal to the slab. The
refractive index of the slab is
1) tan 1 i  2) cot 1 i  3) sin1 i  4) cos1 i
10. A ray of light travels from an optically denser to rarer medium. The critical angle for
the two media is c. The maximum possible deviation of the ray will be
1)   c 2)   2c 3) 2c 4)  / 2  c
sin i
11. In the figure shown is equal to :
sin r

22 3 3 1 1
1) 2) 3) 4)
3 1 1 22 3
12. An insect starts moving up in a liquid from point O of variable refractive index
  0 (1  ay ) where y is depth of liquid from the surface. If u is the speed of insect, its
apparent speed to the observer E is .

u u
1) u ln(1  aH ) 2) 3) 4) u
(1  aH ) 0 l n (1  aH )

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13. A fish rising vertically at the rate of 3 m/s, to the surface of water observed a bird
above the water, diving vertically towards at the rate of 9 m/s. The ref. index of water
is 4/3, calculate the actual velocity (velocity w.r.t ground) of bird
1) 1.5 m/s 2) 6 m/s 3) 12 m/s 4) 4.5 m/s
14. An equilateral glass prism has a refractive index 2 . A light ray is incident at 450 on

one face. Total deviation of ray is.

1) 300 2) 450 3) 600 4) 750
15. A light ray is normally incident on one face of equilateral glass prism and emerges
grazing the second surface . The refractive index of prism is
1) 3 / 2 2) 3 3) 2 / 3 4) 1 / 3
16. A ray of light is incident at an angle of 75o into a medium having refractive index  .
The reflected and the refracted rays are found to suffer equal deviations in opposite
direction . Then  equals to.
3 1 3 1 2 2 3 1
1) 2) 3) 4)
3 1 2 3 1 2

17. A tiny air bubble in a glass slab (   1.5) appears from one side to be 6 cm from the
glass surface and from other side, 4 cm. The thickness of the glass slab is .
1) 10 cm 2) 6.67 cm 3) 15 cm 4) 3cm
18. A ray of light is incident on one face of a transparent slab of thickness 15 cm. The
angle of incidence is 60 o . If the lateral displacement of the ray on emerging from the
parallel plane is 5 3cm, the refractive index of the material of the slab is .
1) 1.414 2) 1.532 3) 1.732 4) 2.236
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19. A spherical surface of radius of curvature R separates air from glass (refractive
index=1.5). The centre of curvature is in the glass. A point object P placed in air is
found to form a real image Q in the glass. The line PQ cuts the surface at a point O,
and PO=OQ. The distance PO is equal to
1) 5R 2) 3R 3) 2R 4) 1.5R
20. A point source of light at the surface of a sphere causes a very narrow parallel beam of
light to emerge from the opposite surface of the sphere. The refractive index of the
material of the sphere is
1) 1.5 2) 5/3 3) 2 4) 2.5
21. A swimmer S inside water is vertically above a fixed point P. A rectangular glass slab
B is placed between S and P. As seen by S, the position of P will appear to change, if
1) B is moved horizontally 2) B is moved vertically
3) S moves horizontally 4) S moves vertically
22. A ray of light travels from a medium of refractive index  to air. Its angle of incidence
in in the medium is  , measured from the normal to the boundary, and its angle of
deviation is  .  is plotted against  . Which of the following best represents the
resulting curve ?

1) 2)

3) 4)

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23. A ray of light travelling in a transparent medium falls on a surface separating the

medium from air, at an angle on incidence 450 .The ray undergoes total internal

reflection. If “n” is refractive index of the medium of the medium with respect to air,

select the possible value of n from the following :

1) 1.2 2) 1.3 3) 1.4 4) 1.6

24.

A ray of light ab passing through air enters a liquid of refractive index 1 at the

boundary XY. In the liquid, the ray is shown as bc. The angle between ab and bc

(angle of deviation) is  . The ray then passes through a rectangular slab ABCD of

refractive index 2 2  1  and emerges form the slab as the ray de. The angle between

XY and AB is  . The angular between ab and de is

   
1)  2)    3)   sin 1  1  4)     sin 1  1 
 2   2 

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25. In the experiment to find the minimum deviation for a glass prism, by ray tracing, the
deviation (  ) is measured for different values of the angle of incidence (i). Which of
the following plots of  against i is closest to the experimental result?

1) 2)

3) 4)
26. To measure the refracting angle (A) of a prism, the paths of rays reflected from the
prism surface are traced using vertical pins placed on a sheet of paper. If the angle of
minimum deviation for the prism is m then the angle between the rays reflected from
two surfaces of the prism will be
1) A  m 2) 2  A  m  3) 2A 4) A
27. Which of the following quantities can be measured using only a travelling microscope ?
1) Refractive index of a glass slab 2) Refractive index of a prism
3) Refracting angle of a prism 4) Refractive index a small drop of water
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28. A prism of glass (   1.5) is dipped in to water as shown in the figure. If the refractive
index of water is 4/3, then the incident ray will be totally reflected if.

8 8 9 8
1) sin   2) sin   3) sin   4) sin  
9 9 8 9
29. There is a water film formed on a glass block. A light ray is incident on water film
from air at an angle 60 o with the normal. The angle of refraction inside glass slab is
(  g  1.5, w  4 / 3)

3 3  1  4 3 9 3
1) Sin 1   2) Sin1   3) Sin 1   4) Sin 1  
 8   3  9   16 

30. A point source of light is placed at the bottom of a water lake. If the area of the
illuminated circle on the surface is equal to 3 times the square of the depth of the lake.
The refractive index of water is .
  
1)   1 2) 1 3) 1 4) 1
3 3 4

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MATHEMATICS
31 . The equation of the plane passing through the points (3,2, -1), (3,4,2) and (7,0,6) is
5x+3y-2z=  ,where  is
1) 23 2) 21 3) 19 4) 27

x2 y 3 z 5
32. The point on the line   at a distance of 6 from the point (2,-3, - 5) is
1 2 2
1) (3,-5,-3) 2) (4,-7, -9) 3) (0,2,-1) 4) (-3,5,3)
x  1 y 1 z  2 x  1 y z  1
33. The lines   ,   are
1 2 1 2 1 4
1) parallel lines 2) intersecting lines
3) perpendicular skew lines 4) none of the above
34. The lines makes angles  ,  ,  ,  with the four diagonals of a cube. Then
cos 2   cos 2   cos 2   cos 2  is

4 2
1) 2) 3) 3 4) none of these
3 3
35. The equation of the plane passing through the intersection of the planes 2x-5y+z=3 and
x+y+4z=5 and parallel to the plane x+3y+6z=1 is x+3y+6z=k, where k is
1) 5 2) 3 3) 7 4) 2
x 1 y 1
36. The coordinates of a point on the line   z at a distance 4 14 from the point
2 3
(1,-1,0) nearer the origin are
1) (9,-13,4) 2) (8 14,  12, 1) 3) (8 14,12,1) 4) ( 7,11, 4)

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x  2 y 1 z 1
37. The line   intersects the curve xy  c 2 , z  0 if c is equal to
3 2 1
1
1) 1 2)  3)  5 4) none of these
3
38. The distance of the point A(-2,3,1) from the line PQ through P(-3,5,2) which make
equal angles with the axes is
2 14 16 5
1) 2) 3) 4)
3 3 3 3

39. A plane meets the coordinate axes in A,B,C such that the centroid of the triangle ABC
is the point (a,a,a). Then the equation of the plane is x+y +z=p, where p is
1) a 2) 3/a 3) a / 3 4) 3a
x 1 y 1 z 1
40. The line   meets the plane x  2 y  3 z  14,in the po int
2 3 4
1) (3,-2,5) 2) (3,2,-5) 3) (2,0,4) 4) (1,2,3)
x  3 y  15 z  9 x 1 y 1 z  9
41. The shortest distance between the lines   and   is
2 7 5 2 1 3

1) 2 3 2) 4 3 3) 3 6 4) 5 6
  
42. The image of a point 2 i  2 j k in the line passing through the points
     
i  j  2 k and 3 i  j  2 k is
 
  
 i  11 j  7 k
1) 3 i  11 j  7 k 2)
3
   1
3) 2 i  2 j  k 4) (10i  2 j  5k )
3

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  
43. The equation of the plane containing the line r  a  kb and perpendicular to the plane

r.n  q are intersect at
        
1) ( r  b).( n  a)  0 2) ( r  a). n  (a  b)  0
        
3) ( r  a).( n  b)  0 4) (r  b).n  (a  b)  0
     
44. The line joining the points 6 a  4b  5c, 6a  4b  3c and the line joining the points
     
a  2b  3c, a  2b  5c are intersect at
  
1) 2c 2) 4c 3) 8c 4) none of these
   
45. A line L1 passes through the point 3 i and parallel to the vector  i  j  k and another
   
line L2 passes through the point i  j and parallel to the vector i  k , then point of
intersection of the lines is
        
1) 2 i  j  k 2) 2 i  2 j  k 3) i  2 j  k 4) none of these
46. If a flagstaff 6 metres high placed on the top of a tower throws a shadow of 2 3 metres
along the ground , then the angle (in degrees) that the sun makes with the ground is :
1) 30o 2) 60 o 3) 45o 4) none of these
47. At a point 15 metres away from the base of a 15 metres high house, the angle of
elevation of the top is :
1) 90o 2) 60 o 3) 30o 4) 45o
48. The angle of depression from the top of a tower to a point situated at a distance of 70
metres from the base of a tower is 45o . The height of the tower is :
70
1) 70 meters 2) 70 2 meters 3) meters 4) 35 meters
2

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49. If the elevation of the sun is 30 o , then the length of the shadow cast by a tower of 150
ft height, is :
1) 75 3 ft. 2) 200 3 ft. 3) 150 3 ft. 4) None of these
50. A chimney of 20 m high, standing vertically on the top of a building, subtends an angle
1
tan 1   at a distance of 70 meters from the foot of the building. The height of the
6

building is .
1) 25 meters 2) 90 meters 3) 50 meters 4) 30 meters
51. The angle of elevation of the top of a hill observed from the top and bottom of a
building of height ‘h’ are 1 and  2 respectively. The height of the hill is equal to :
h cot  2 h cot 1 h tan  2 h tan 1
1) 2) 3) 4)
cot 1  cot 2 cot  2  cot 1 tan 2  tan 1 tan 2  tan 1

52. The man from the top of a 100 meters high tower sees a car moving towards the tower
at an angle of depression of 30o . After some time, the angle of depression becomes
60 o . The distance (in meters) travelled by the car during this time, is

200 3 100 3
1) 100 3 2) 3) 4) 200 3
3 3
53. A person standing on the bank of a river observes that the angle of elevation of the top
of a tree on the opposite bank of the river is 60 o and when he retires 40 meters away
from the tree the angle of elevation becomes 30 o . The breadth of the river is
1) 20 meters 2) 30 meters 3) 40 meters 4) 60 meters

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54. The angle of elevation of the top of a TV tower from three points A,B,C in a straight
line, (in the horizontal plane ) through the foot of the tower are  , 2 ,3 respectively.
If AB = a, the height of the tower is
1) a tan  2) a sin  3) a sin 2 4) a sin 3
55. The angle of elevation of the top of a tower A from the top and bottome B and D at a
building of height a are 30 o and 45o respectively. If the tower and the building stand at
the same level, then the height of the tower.
a 3 a(3  3)
1) a 3 2) 3) 4) none of these
3 1 2
1 1 1 1 n
56. The value of    ......  is then the value of k is
1.3 3.5 5.7 (2n  1)(2n  1) kn  1

1) 2 2) 3 3) 4 4) 5
1 1 1 1 n
57. The value of    ......  is then the value of k is
3.7 7.11 11.15 (4n  1)(4n  3) k (4n  3)

1) 2 2) 3 3) 4 4) 5
58. 10 2 n1  1 is divisible by

1) 8 2) 9 3) 10 4) 11
59. 7 n  3n is divisible by .

1) 2 2) 3 3) 4 4) 5
60. (41) n  (14) n is a multiple of

1) 27 2) 28 3) 29 4) 15

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CHEMISTRY
61. CH 3CH 2  CH 2  C  CH  
alc . KOH

A CH 3CH 2  C  CCH 3 
NaNH 2
Paraffin
B

A & B are

1 ) Homomers 2) Chain Isomers

3) Position Isomers 4) Functional isomers

62 .

Br

R C Br

R C Br

Br

  X  
Pd/D2
Z
Zn
excess BaCO3
Controlled Reduction

  
Na/Liquid
ND3
Z*
Controlled Reduction

Z and Z* are

1) Homomers 2) Diastereomers 3) Enantiomers 4) Homologues

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63. Among the following compounds (I-III), the correct order in reaction with electrophile
is
OCH3 NO2

I II III

1) I>II>III 2) III<I<II 3) II>III>I 4) I=II>III

CH3CH2Cl NBS alc.

P Q S ; "S"
AlCl3 KOH
64. is

1) Phenol 2) Aniline 3) Styrene 4) Toluene

65. Which of these give three isomeric products when one more substituent is introduced
through an electrophilic substution
Br
Br Br
Br
Br
1) 2) 3) 4)
Br
Br
Br

66. dil H 2 SO4

P (C6 H10 ) 
HgSO
 Q (A ketone with Four 1o and one Neo carbon)
4

one mole of “P” can react with a maximum

1) 1 Mole of NaNH 2 2) 2 Moles of NaNH 2
3) Zero moles of NaNH 2 4) One mole of NaHCO3

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

67. In the given compound which ring is preferentially reduced by hydrogenation as

indicated

A) 1 2) 2 3) 3 4) 4

o
68. is Major product in
() 2
H3 O Hg / H 2 SO4
I. CH 2  C  CH 2   II. CH 3  C  CH 
Aq .Solution

BH 3 ,THF Baeyer ' s reagent
III. CH 3  C  CH 
H 2 O2 , H 
 IV. CH 3  CH  CH 2    
1) I & II 2) II & III 3) I & IV 4) II & IV

CH 3 CH 2 CH 2 Cl
69.  AlCl3
 Major product “X”


CH 3 CH 2 COCl N 2 H 4 / OH / 
  
AlCl
 A   Y
3

X is ‘n-propyl benzene’ II. X is Isopropyl benzene

III. Y is Isopropyl benzene IV. Y is n-propyl benzene
Correct Options for X and Y

1)I & II 2) II & IV 3) III & II 4) I & IV

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

70. Which of the following sets of reagents can be used to convert 1-pentene to 1-pentyne?

1) 1.Br2 in CCl4 , 2. NaNH 2 in THF 2) 1.HBr in CCl4 2.NaOH in ethanol

3) 1. Br2 in CCl4 , 2. H 2 SO 4 / Hg 2 4) 1. Br2 in CCl4 ,2.ethanol/heat

71. Identify the final product, R in the following reaction sequences ?

H 2. 
1.NaNH2
CH3CH2Br
P

3 
P Q
Na,NH liq.

QC
Br2

H2Cl2
R

Br
Q
Br Br
Q
1) 2) Br

Br Br
Q Q

Br NH2
3) 4)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

72.
OCH 3


Br2
Fe
 Major Product

O2 N

OCH 3
OCH 3
OCH 3 OCH 3

Br Br
1) 2) 3) 4)
O2 N
O2 N Br
Br O2 N O2 N

73. Ph  C  C  CH 3  H 2O 
HgSO4
H 2 SO4
 Major product

Ph OH Ph
O
Ph Ph
1) 2) O 3) 4) OH

HH
NO3

2SO4
AF
Br2
eBr3

B

74. The compound B is

NO2
NO2
NO2 NO2
Br

Br Br Br Br
1) 2) 3) 4)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

75. The major product obtained,on the monobromination (with Br2 / FeBr3 ) of the following
compound A is
OCH3

CH3
(A)

OCH3
OCH3 OCH 3
OCH3
Br
1) 2) 3) 4)
CH3 CH3
Br CH3 CH 2 Br
Br

O C CH3

Br2+FeBr3
X
76)
O C

OCH3 ”X” can be

O
O

O C CH3 O C CH3

1) 2)
O C Br O C

OCH3
OCH3 Br
O

Br
Br O C CH3

3) 4)
HO
O C

OCH3 Br

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

77. Major product formation takes place at which position in ArSE Reaction
2 3 4 5

1 O CH2 6

1) 3 2) 1 3) 6 4) 4

78. Find the major product in following reaction

1) 2)

3) 4)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

79. Ethene and ethyne can be distinguished by

1) Br2 water 2) KMnO4 solution
3) ammonical cuprouschloride solution
4) any of the above
C  CH

1. BH 3 ,THF

2. H O ,OH 
X
2 2
80.
CHO COOH O
CH 2 CHO CH 2  C  CH 3
1) 2) 3) 4)

Me
C  CH
2 HCl
81. 
ether
X X is

Me
CH 2 CHCl2 CCl2 .CH 3
1) 2)

CCl3 Me
CH 2  CH 3
3) 4)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

Br
C
1. NaNH 1hot . alk . KMnO
CH 2 2. H
 X 

2

2. H
4
 Y  CO2

82. Y is

1) Benzoic acid 2) Benzaldehyde 3) Ethyl benzene 4) Benzyl Alcohol

83. Which of the following boron derivatives is highly suitable for hydroboration of

terminal alkynes

1) B2 H 6 2) BH 3 3) Diisoamylborane 4) H 3 BO3

84)

A is

1) 2) 3) 4)

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

85) “ X “ is

1) SOBr2 2) NBS 3) Br2 / Fe 4) HBr

86. Arrange given a,b,c in decreasing order of reactivity towards Electrophilic aromatic

substitution Reaction

CH 3 CD3 CT3

(a ) (b) (c)

1) a>b>c 2) c>b>a 3) a>c>b 4) c>a>b

87. To get 3-hexanone by hydration best starting material

1) 2) CH 3  H 2C  C  C  CH 3

3) 4) CH 3  CH 2  C  C  CH 2  CH 3

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 Sri Chaitanya Narayana IIT Academy 01/02/14_Jr.COIPL_JEE-Main_WTM-35

Cu2 Cl2
88. H 2 C  CH  C  CH  HCl  NH 4Cl
 " X " “X “ is
(1mole )

Cl CH 2  CH  C  CH 2

1) CH 3  CH  C  CH 2) Cl

Cl

Cl
CH3 CH C CH2

CH2Cl CH C Cl  CH2
3) 4) Cl

89. To get Ethane, Ethene and Ethyne by Kolbe electrolysis Respective starting materials
can be
1) Sodium acetate, sodium Oxalate, Sodium Malliate
2) Potassium acetate, Potassium Succinate, Potassium maleate
3) Potassium acetate, Potassium Carbonate, Potassium Cyanide
4) All these can Not be Prepared by Electrolysis.
90.

O 1.Anhy.Alcl3
2. N2 H 4 / OH  / 
3. Pcl5
+ O X ; "X" is
4.Anhy.Alcl3
5. N2 H 4 / OH  / 
O 6. S  or  Se

1) Naphthalene 2) Phenanthrene 3) Anthracene 4) Pyrene

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