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Chem 1

The history of the periodic table showcases the evolution of element classification, beginning with early methods like Dobereiner's Triads and Newlands' Law of Octaves. Dmitri Mendeleev created the first useful periodic table in 1869, organizing elements by atomic mass and predicting undiscovered elements, while Henry Moseley later refined it in 1913 by arranging elements based on atomic number, resolving inconsistencies. This progression established a scientifically grounded periodic law and laid the foundation for the modern periodic table.

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0% found this document useful (0 votes)
10 views2 pages

Chem 1

The history of the periodic table showcases the evolution of element classification, beginning with early methods like Dobereiner's Triads and Newlands' Law of Octaves. Dmitri Mendeleev created the first useful periodic table in 1869, organizing elements by atomic mass and predicting undiscovered elements, while Henry Moseley later refined it in 1913 by arranging elements based on atomic number, resolving inconsistencies. This progression established a scientifically grounded periodic law and laid the foundation for the modern periodic table.

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The history of the periodic table is a fascinating journey of scientific discovery and refinement.

It began with early attempts to classify elements and reached a major turning point through the
work of Dmitri Mendeleev and later Henry Moseley.

🧪 1. Early Attempts at Classification


Before Mendeleev, scientists noticed patterns among elements:

a. Dobereiner’s Triads (1829)

 Grouped elements in threes (e.g., Li, Na, K).


 The atomic mass of the middle element was roughly the average of the other two.
 Limited success — only a few triads found.

b. Newlands’ Law of Octaves (1864)

 Arranged elements by increasing atomic mass.


 Noted that every eighth element had similar properties.
 Worked only for the first 20 elements.
 Criticized for being too musical and not scientific.

🧠 2. Mendeleev’s Periodic Table (1869)


 Dmitri Mendeleev, a Russian chemist, arranged 63 known elements by increasing
atomic mass.
 He placed elements with similar chemical properties in the same columns (groups).
 His genius:
o Left gaps for undiscovered elements like gallium (Ga), scandium (Sc), and
germanium (Ge).
o Predicted properties of these missing elements accurately.
 Problems:
o Some elements were out of order based on atomic mass (e.g., Te and I).
o Inconsistencies were known but unresolved.

⚛️3. Moseley’s Atomic Number Concept (1913)


 Henry Moseley, an English physicist, used X-ray spectroscopy to study atomic
structure.
 Discovered that each element has a unique atomic number (number of protons).
 Re-arranged the periodic table based on atomic number instead of atomic mass.
 Solved the inconsistencies in Mendeleev’s table (e.g., iodine comes after tellurium
because it has a higher atomic number, despite lower mass).
 Gave the periodic table a clear scientific basis rooted in atomic structure.

🧩 Impact of Moseley’s Work


 Periodic law was redefined:

"The properties of elements are a periodic function of their atomic


numbers."

 Led to the modern periodic table layout.


 Enabled the prediction and discovery of new elements more accurately.
 Confirmed the need for undiscovered elements to complete atomic number sequence.

📊 Timeline Summary
Year Scientist Contribution
1829 Dobereiner Triads (groups of 3 elements)
1864 Newlands Law of Octaves
1869 Mendeleev Periodic table by atomic mass; predicted elements
1913 Moseley Periodic table by atomic number

✅ Conclusion
 Mendeleev established the first scientifically useful periodic table using atomic mass and
predicted missing elements.
 Moseley corrected and modernized it by organizing elements by atomic number,
forming the basis of the modern periodic law.
 The table evolved from pattern recognition to a structure grounded in atomic theory.

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