2024 Theo Eng
2024 Theo Eng
0 Hours
Points: 30
EXAMINATION RULES
1. You are NOT allowed to bring any personal items into the examination room, except for personal
medicine or approved personal medical equipment.
2. You must sit at your designated desk.
3. Check the stationery items (pen and pencil, calculator) provided by the organizers.
4. Do NOT start answering the questions before the “START” signal.
5. You are NOT allowed to leave the examination room during the examination except in an emergency
in which case you will be accompanied by a supervisor/ volunteer/invigilator.
6. If you need to visit the bathroom, please raise your hand.
7. Do NOT disturb other competitors. If you need any assistance, raise your hand and wait for a
supervisor to come.
8. Do NOT discuss the examination questions. You must stay at your desk until the end of the
examination time, even if you have finished the exam.
9. At the end of the examination time you will hear the “STOP” signal. Do NOT write anything more on
the answer sheet after this stop signal. Arrange the exam, answer sheets, and the stationary items
(pen, calculator) neatly on your desk. Do NOT leave your seat before all the answer sheets have been
collected.
EXAM INSTRUCTIONS
1. After the “START” signal, you will have 3 hours to complete the exam.
2. ONLY use the pen and pencil provided by the organizers.
3. Check if your code and country name are filled in on your answer sheets. Raise your hand, if you do
not have the answer sheets.
4. You have 24 pages of answer sheets. Raise your hand, if you find any sheets missing.
5. Read the problems carefully and write the correct answers in the corresponding boxes of the answer
sheets.
6. Only the answer sheets will be evaluated.
7. The number of points that can be obtained is indicated for each question.
8. The total number of pages on the test paper is 25 including this front page. Check if you have a
complete set of the test questions sheets after the “START” signal is given. Raise your hand, if you
find any sheets missing.
9. Useful information for answering the questions (atomic masses, constants and formulas) is
provided.
10. Always show your calculations. If you do not show your calculations, no points are awarded for the
question.
11. You should write your final answers down in the appropriate number of digits.
General information
Notes
Formulas
Acidity exponent
pK a = − log K a
Q
n e− =
F
where n e
− is the number of electrons, Q is the electric charge, and F is the faraday constant.
Q = I ⋅ Δt
where Q is the electric charge, I is the current intensity, and Δt is the time interval.
0 0 0
E = E − E
cell cathode anode
where E 0
cell
is the electromotive force and E 0
cathode
and E 0
anode
are the standard reduction potential at the
cathode and anode, respectively.
Constants
0ºC 273.15 K
Faraday constant (F) 96485 C·mol-1
gas constant (R) 0.08206 L·atm·mol-1·K-1
Notations
g gram
L liter
atm atmosphere
ºC Celsius degree
M mol/L
A ampere
h hour
% (w/w) weight percent
Fundamental Constants
Speed of light in vacuum c = 2. 998 × 10
8
m s
−1
Part 1: Physics
Imagine that you are going on a hike, the purpose of which is, in addition to direct observation of the
environment, to carry out investigations of physical phenomena and quantities that can be influenced by
specific environmental conditions. The device used for the investigation is a smartphone (with mass
M = 0. 150 kg) which, by means of a software application and the accelerometer it is equipped with, can
record the accelerations to which it is subjected, corresponding to its three axes. The image below (with
the display towards you) illustrates how the smartphone's three axes are oriented.
When the phone lies flat on the table with the display up, the accelerometer readings are a x = 0 m/s
2
,
a = 0 m/s , a = 9. 80 m/s .
2 2
y z
The smartphone is held at rest and then released from a certain height relative to a horizontal surface.
Some of the acceleration versus time data for the three axes are shown in the table below. The value of
the gravitational acceleration is g = 9. 80 m/s . 2
t/s 1.789 1.868 1.880 1.894 1.966 1.979 1.994 2.086 2.101
ax/ m
s
2 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -1.20 -18.70
ay / m
s
2 9.80 0.00 0.00 0.00 0.00 0.00 0.00 2.00 40.80
az/ m
s
2 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.20 11.80
P_1a) [0.6 pt] Based on the numerical values in the table, specify the orientation of the smartphone
corresponding to the time moment 1.789 s by drawing an X in each of the appropriate free cells in the
answer sheet.
P_1b) [1.6 pt] Calculate the net force F acting on the phone at the moment 2.101 s, given that the phone
maintains its orientation throughout the experiment.
P_1c) [0.8 pt] Using the data in the table, determine the maximum and minimum possible values of the
height h through which the smartphone falls.
A parallel plate capacitor is a device that consists of two parallel, oppositely charged plates. The physical
quantity that provides information in this context is called the electric capacitance, C , and for the
capacitor described above it is determined by the relation C = , where: ε is the electric permittivity
ε0 A
d 0
of air, A is the surface area of a conductive plate, and the distance d between the two plate conductors
(see Fig. 2.1).
The accelerometer of a smartphone is a mechano-electric device which consists of three such capacitors,
one orientated along each of the x, y, and z axes. An acceleration along one of these axes will change the
distance d between the plates of the capacitor along that axis. Fig. 2.2 shows a simplified model of the
capacitor that measures acceleration in the x direction. One plate is fixed and the other (with the mass m)
is connected to a spring, with the spring constant k.
P_2a) [0.4 pt] Prove that the magnitude of the deformation Δx of the spring, with the elastic constant k, is
directly proportional to the magnitude of the acceleration a of the smartphone (which accelerates in the
x
positive direction of the horizontal x axis). Express the proportionality constant as a function of the
physical quantities given above. Neglect the electrostatic interaction between the plates.
P_2b) [1.2 pt] Prove that the variation ΔC of the capacity is directly proportional with the acceleration a x
of the smartphone for small deformations Δx of the spring, and express the proportionality constant as
a function of the given physical quantities. The smartphone accelerates in the positive direction of the
horizontal x axis.
b 2 +x
≃
b1
b2
−
b1
b
2
⋅ x , when x ≪ b . Here, b and b are constants, and x is variable.
2 1 2
2
To study some properties of sound waves in air, a student uses a tube, open at both ends, inserted
vertically into a container of water. At the upper end, they generate a sound with a constant frequency
f = 1. 20 kHz and constant sound intensity level (see the picture). They find that for a given air column
length in the tube, h, the sound intensity level is much higher than those obtained for other lengths,
smaller or higher than the above value. The speed of sound in air is v = 342 m/s.
4
. Here λ is the wavelength of the
sound wave.
P_3b) [2.0 pt] You want to investigate how the motion of a sound source with respect to a receptor
influences the recorded sound by the latter. In this context they generate a constant-frequency sound that
is recorded by a smartphone at rest, using a software application. The data obtained are shown in the
table below.
Associate the three different values of the frequency in the table with the following situations: the source
is at rest; the source is moving towards the receptor; the source is moving away from the receptor.
Obtain an expression for the speed v with which the sound source approached the smartphone and the
1
speed v with which the sound source moved away from the same smartphone, and calculate their
2
numerical values. The speed of sound has the same value as before.
P_3c) [1.4 pt] Considering that the process of sound propagation in air involves compressions and
expansions of the air, derive the dependence of the speed of sound on air pressure p and density ρ, using
dimensional analysis. Denote the proportionality constant with α (its numerical value is 1.18).
P_3d) [1.2 pt] Consider the air as an ideal gas. Express the density ρ of air as a function of its temperature
T . Using the result obtained at P_3c), derive the dependence of the speed of sound v on the temperature
T of the air. Calculate the air temperature if the molar mass of air is μ = 29. 0 g/ mol.
C_1) [2.00 pt] The Blue Lake from Maramures, the only one that changes its color depending on the light
intensity, was formed in 1920 by the collapse of an old mine gallery. The blue-green color of the lake is due
to the presence of melanterite in the surrounding soil, a mineral of hydrated iron sulfate, FeSO4·nH2O,
and also due to some Cu(II) salts.
A mixture of melanterite and CuSO4·5H2O, weighing 38.90 g, was dissolved in 61.10 g of distilled water. The
resulting solution contained 2.79% (w/w) Fe2+ ions and 6.36% (w/w) Cu2+ ions.
C_1.1) [0.65 pt] Calculate the molar ratio of the hydrated salts in the initial mixture.
The standard reduction potentials of some redox couples are listed below:
C_1.3) [0.25 pt] Calculate the standard electromotive force for the cell.
C_1.4) [0.25 pt] Write the ionic equation of the chemical reaction that generates electricity for the cell.
C_1.5) [0.15 pt] Choose the direction of the electrons flow in the external circuit in your answer sheet.
C_2) [2.00 pt] The chemical element (Z) discovered in Romania is situated in the periodic table in the 5th
period. It is usually found together with other chemical elements, in different minerals, such as sylvanite,
whose name comes from the region Transylvania, where it was first extracted.
Sylvanite is a mineral containing the chemical elements Z, gold and silver. The mineral, with the empirical
formula Au0.75Ag0.25Z2, contains 59.36% (w/w) Z.
C_2.1) [0.50 pt] Write the symbol for the chemical element Z and show your calculations. No points will be
awarded without calculations.
The chemical element Z is obtained from copper ores, by processing the mud resulting at the anode
during the electrolytic purification of copper. The mud also contains Cu2Z (where copper has the oxidation
number +1), which, in the reaction with Na2CO3 and air at 500 °C, forms Na2ZO3, the black solid oxide A,
and the gaseous oxide B, according to reaction 1:
The resulting Na2ZO3 is further treated with a H2SO4 solution generating the insoluble ZO2, which is
subsequently reduced to Z with SO2 in aqueous solution.
C_2.2) [0.40 pt] Write the chemical formulas of the oxides A and B.
C_2.3) [0.60 pt] Choose for each of the following species involved in reaction 1 if it is an oxidizing agent or
a reducing agent: Cu+, Z2-, O2.
C_3) [6.00 pt] Romania presents important halide mineral deposits in the Carpathian Mountains. Besides
the advantages for industry, this also means tourist attractions like salt mines, salty lakes and salt
mountains.
Let’s consider such a deposit of halite, which consists of NaCl, as well as gypsum (CaSO4·2H2O) and KCl
impurities.
The solubilities of the components of the rock at 20 ºC are 358 g NaCl / kg water, 342 g KCl / kg water and
3.60 g CaSO4·2H2O / kg water.
C_3.1) [0.60 pt] Associate the letter of each curve in the graph to the corresponding compound.
In order to determine the composition of the rock, a series of experiments were performed:
Experiment 1
A ground sample of halite weighing 150.00 g was transferred to a beaker containing 500.0 g of distilled
water at 20 ºC. After vigorous stirring, the mixture was filtered. The solid on the filter paper weighed 1.40 g
and the volume of the filtrate (solution F) was 550 mL.
C_3.2) [0.20 pt] Check the box in the answer sheet, corresponding to the compound collected over the
filter paper in experiment 1.
C_3.3) [0.30 pt] Calculate the mass of the compound from question C_3.2 that is dissolved in water at 20 °C,
if we assume that other two compounds do not affect its solubility.
Experiment 2
Solution B was prepared from 5.00 mL of solution F, transferred to a 1000 mL volumetric flask and
brought to the mark with distilled water. 5.00 mL of solution B were diluted with distilled water in a conical
flask and titrated with 11.30 mL of 0.0100 M silver nitrate solution. In these conditions, no silver sulfate is
precipitated.
C_3.4) [0.25 pt] Write the net ionic equation of the chemical reaction involved in experiment 2.
C_3.5) [2.00 pt] Calculate the mass percent of each compound in the rock.
C_3.6) [0.25 pt] Write the balanced equation of the electrolysis reaction of molten NaCl and write the
chemical formula of gas X.
C_3.7) [0.20 pt] Check the box in the answer sheet, corresponding to the electrode at which the gas was
formed.
C_3.8) [0.70 pt] Calculate the volume of gas X obtained at 25.0 ºC and 1.00 atm, if a current of 15.00 A
passed the electrochemical cell for 2.00 h.
C_3.9) [0.30 pt] If the electrolysis of NaCl is performed in aqueous solution, NaOH is formed, which can be
used to prepare buffer solutions. Choose from the following table (check the box/boxes in the answer
sheet) the acids that can form buffer solutions by partial neutralization with NaOH. (For every wrong
answer marked, 0.15 pt will be deducted; no negative overall scores will be given.)
HF 6.76·10-4 3.17
HCl 108 -8
HBr 109 -9
CH3COOH 1.74·10-5 4.76
HCOOH 1.78·10-4 3.75
One acid from the table, denoted HA, was titrated with a NaOH solution. The pH values of the titrated
solution, recorded with a pH-meter, corresponding to different titration volumes are given in the table
below. The data are plotted in the following figure.
C_3.10) [0.20 pt] Write the value of the titration volume at the equivalence point.
C_3.11) [0.30 pt] Check the box in the answer sheet, corresponding to the chemical formula of the acid HA,
knowing that, at a neutralization degree of 50%, the pH is equal to the pKa value of the acid.
C_3.12) [0.30 pt] Check the box in the answer sheet, corresponding to the species present in the highest
concentration in the titrated solution when the titration volume reaches 2 mL.
C_3.13) [0.20 pt] Write the value of the titration volume corresponding to the formation of a buffer
solution with maximum buffering capacity, characterized by the lowest variation of pH / the lowest value
of the slope in the titration curve.
C_3.14) [0.20 pt] Choose the true statements regarding the effect of the addition of a small amount of a
HCl solution to the buffer solution from question C_3.13. Check one box for each row in the answer sheet.
The waters of the Danube River flow into the Black Sea through three branches, forming the Danube
Delta between them. A portion of the river’s waters has been diverted to another discharge point,
the port of Constanța, through the construction of the Danube-Black Sea Canal. To observe the
anthropogenic influence on this port region, research was conducted on the population of seafloor
crustaceans in the coastal area, from the shore to a depth of 0.5 meters. The crustaceans were
collected using methods specific to each type of substrate present, during a summer month, from
four sites (I-IV) marked and described on the map.
Site I – slide gates for dam regulation on the Danube-Black Sea canal route, situated near Agigea town,
rocky substrate
Site II – the discharge point of the canal into the Black Sea, rocky and muddy substrate
Crustacean species present in the analyzed sites Site I Site II Site III Site IV TOTAL
Specimen number/m2
2 Idothea baltica – prefers relatively clean waters 600 3950 4200 15500 24250
4 Sphaeroma pulchellum – tolerates organic waste 3550 1425 1025 500 6500
pollution
6 Gammarus olivii - less tolerant to pollution and - 375 2800 7000 10175
oxygen deficiency
TOTAL 55825
For the analysis of the living organisms, the following parameters were used:
Frequency represents the proportion between the number of sites in which species X is found (pX) and
the total number of sites (P).
FX =( pX/P) x100
Constancy allows for grouping species into four categories based on frequency. The most used are the
following four categories: 100-76 (euconstant), 75-51 (constant), 50-26 (accessory), 25-0 (accidental).
Numerical relative abundance represents the percentage ratio between the number of individuals of
species X (nX) and the number of all individuals for all species collected in total (N).
AX=(nX/N) x 100
Analyze the characteristics of the sites and the data obtained to determine whether the statements
1 to 6 are TRUE or FALSE. On the answer sheet, mark an X in the corresponding box.
3. 0.4 In Site IV, the waters are less oxygenated than in Sites I and
II.
On a trip to the Danube Delta, a group of school children spotted many species of animals, noted in the
order in which they were encountered, with the letters A-M. They tried to categorize them into the
taxonomic groups to which they belonged, taking into account the morphological characters observed.
They first grouped the species according to their body-covering structures (Table 1), then identified other
common characteristics (Table 2) and characteristics particular to each (Table 3).
Tabel 1
Tabel 2
Tabel 3
Based on the characteristics in the three tables, identify which animal group each species belongs to by
marking an X in the appropriate box in the table below on the answer sheet.
Transmission of the nerve impulse through chemical synapses is achieved through neurotransmitters
released by the presynaptic neuron. These interact with protein receptors on the membrane of the
postsynaptic neuron, having either an excitatory or inhibitory effect.
The resting membrane is electrically polarized, with an excess of positive charges on the outside and an
excess of negative charges on the inside. Stimulating the postsynaptic neuron membrane implies
depolarization of the membrane (an excess of positive charge on the inside).
Synapse function can be influenced by a series of natural or artificial agents, acting through various
mechanisms. The effect of many psychotropic substances on the human body, such as alcohol, nicotine,
and medications, can be explained by their influence at the level of chemical synapses.
GABA is a neurotransmitter, a chemical messenger in the brain. It slows down the brain by blocking
specific signals in the central nervous system. It has an inhibitory effect mediated by receptors that allow
the influx of anions (Cl-) into the post-synaptic neuron. Substances that block the synthesis or release of
GABA cause convulsions. Alcohol enhances GABA’s inhibitory effect leading to anxiolytic effects, sedation,
anesthesia, and impaired motor activity. A type of GABA receptor sensitive to low alcohol levels has been
identified in the frontal and temporal cortices, and in the cerebellum. To observe which brain regions are
more affected by alcohol, a group of volunteers was injected with a safe dose of radioactive glucose (the
preferred energy source for neurons) and right after consumed a small amount of alcohol. Volunteers
then underwent a PET scan (Positron Emission Tomography is an imaging test that uses radioactive
material to diagnose, monitor and treat a variety of conditions and diseases). Regions that consumed
glucose appeared bright, while others appeared darker.
Analyze whether the following statements are TRUE or FALSE. On the answer sheet, mark an X in the
corresponding box:
Statements
B_III.1 Points TRUE FALSE
Glutamate is the most abundant neurotransmitters in the brain. It has a role in learning and memory. It
has an excitatory effect mediated by receptors that allow the influx of cations (Na+, Ca2+). It is produced in
the brain and spinal cord. Alcohol inhibits its receptors and reduces the release of glutamate, contributing
to sedative effects, a reduction in reflexes, and cognitive functions. As compensation for the reduced
response of glutamate receptors, in alcohol consumers, the neuronal membrane will form an additional
number of receptors, which remain active after the cessation of alcohol consumption
Analyze whether the following statements are TRUE or FALSE. On the answer sheet, mark an X in the
corresponding box.
ACh has a stimulating effect on neurons in the central nervous system and muscle fibers through
receptors called nicotine receptors. ACh binding to these receptors allows the influx of cations. Nicotine
binds to the same receptors, changing its conformation, and causes the synthesis and release of
dopamine.
Dopamine stimulates other neurons, generating a state of generalized excitation. Nicotine binding to the
receptor prevents its removal from the membrane. With prolonged exposure to nicotine, the receptors no
longer respond to it.
Analyze whether the following statements are TRUE or FALSE. On the answer sheet, mark an X in the
corresponding box.
Statements
B_III.3 Points TRUE FALSE
An agonist is a chemical substance that activates a receptor when it binds to it. An antagonist is a chemical
substance that, by binding to a receptor, blocks the action that would be triggered by an agonist. These
two possible relationships between a psychotropic substance and receptor activity in a synapse are
illustrated in the two graphs. Alcohol, caffeine, nicotine, marijuana, and certain pain medicines are
psychotropic substances. Such substances affect how the brain works and cause changes in mood,
awareness, thoughts, feelings, or behavior.
Mark an X only in the boxes indicating the correct relationship between psychotropic substances and
their effect on receptors and mark O where there is no relationship:
Zostera noltei (seagrass) is a plant that can be found in the coastal areas of the Black Sea, playing a
significant role by contributing to sediment stabilization and water filtration. The plant grows rapidly
through a meristem located at its base. However, in recent years, a slowdown in its growth rate and the
disappearance of large seagrass meadows have been observed.
In an experiment, the partial pressure of oxygen (PO2 ) was recorded along the diameter of a seagrass
stem at different temperatures and oxygen saturation levels of seawater. The atmospheric PO2 is usually
160 mmHg.
Analyze whether the following statements are TRUE or FALSE or cannot be determined from the
data. On the answer sheet, mark an X in the corresponding box.