Subject: Chemistry Topic: States of matter Date: 12th Dec 2024
DPP - 43
1. At 25°C and 730 mm pressure, 380 mL of dry oxygen was collected. If the temperature is constant, what
volume will the oxygen occupy at 760 mm pressure?
(a) 569 mL (b) 365 mL (c) 265 mL (d) 621 mL
2. Pressure remaining the same, the volume of a given mass of an ideal gas increases for every degree
centrigrade rise in temperature by definite fraction of its volume at
(a) 0°C (b) its critical temperature (c) absolute zero (d) its Boyle temperature.
3. A mixture of N₂ and Ar gases in a cylinder contains 7 g of N₂ and 8 g of Ar. If the total pressure of the
mixture of the gases in the cylinder is 27 bar, the partial pressure of N₂ is
[Use atomic masses (in g mol−1 ): N = 14, Ar = 40]
(a) 9 bar (b) 12 bar (c) 15 bar (d) 18 bar
4. The volume occupied by 1.8 g of water vapour at 374°C and 1 bar pressure will be [Use R = 0.083 bar
L K −1 mol−1 ]
(a) 96.66 L (b) 55.87 L (c) 3.10 L (d) 5.37 L
5. What is the density of N₂ gas at 227°C and 5.00 atm pressure? (R = 0.082 L atm K −1 mol−1)
(a) 1.40 g/mL (b) 2.81 g/mL (c) 3.41 g/mL (d) 0.29 g/mL
6. A gaseous mixture was prepared by taking equal moles of CO and N₂. If the total pressure of the mixture was
found 1 atmosphere, the partial pressure of the nitrogen (N₂) in the mixture is
(a) 0.5 atm (b) 0.8 atm (c) 0.9 atm (d) 1 atm
7. The pressure exerted by 6.0 g of methane gas in a 0.03 m³ vessel at 129°C is (Atomic masses: C = 12.01,
H = 1.01 and R = 8.314 J K −1 mol−1 )
(a) 215216 Pa (b) 13409 Pa (c) 41648 Pa (d) 31684 Pa
8. Which of the following mixtures of gases does not obey Dalton's law of partial pressure?
(a) Cl₂ and SO₂ (b) CO₂ and He (c) O₂ and CO₂ (d) N₂ and O₂
9. Under what conditions will a pure sample of an ideal gas not only exhibit a pressure of 1 atm but also a
concentration of 1 mole litre−1 ? (R = 0.082 litre atm mol−1 deg −1 )
(a) At STP (b) When V = 22.4 litres (c) When T = 12 K (d) Impossible under any conditions
10. The correct value of the gas constant 'R' is close to
(a) 0.082 litre-atmosphere K (b) 0.082 litre-atmosphere K −1 mol−1
(c) 0.082 litre-atmosphere K mol
−1 −1
(d) 0.082 litre−1 atmosphere−1 K mol−1 .
11. Select one correct statement. In the gas equation, PV = 𝑛𝑛RT
(a) 𝑛𝑛 is the number of molecules of a gas (b) 𝑉𝑉 denotes volume of one mole of the gas
(c) 𝑛𝑛 moles of the gas have a volume 𝑉𝑉 (d) 𝑃𝑃 is the pressure of the gas when only one mole of gas is present.
12. At constant temperature, in a given mass of an ideal gas
(a) the ratio of pressure and volume always remains constant
(b) volume always remains constant
(c) pressure always remains constant
(d) the product of pressure and volume always remains constant.
13. If P, V, M, Tand R are pressure, volume, molar mass, temperature and gas constant respectively, then for an
ideal gas, the density is given by
𝑅𝑅𝑅𝑅 𝑃𝑃 𝑀𝑀 𝑃𝑃𝑃𝑃
(a) 𝑃𝑃𝑃𝑃 (b) 𝑅𝑅𝑅𝑅 (c) 𝑉𝑉 (d) 𝑅𝑅𝑅𝑅
14. Correct gas equation is
𝑉𝑉 𝑇𝑇 𝑉𝑉 𝑇𝑇 𝑃𝑃 𝑉𝑉 𝑇𝑇 𝑃𝑃1 𝑇𝑇1 𝑃𝑃2 𝑉𝑉2 𝑉𝑉 𝑉𝑉
(a) 𝑃𝑃1 2 = 𝑃𝑃2 1 (b) 𝑃𝑃1𝑉𝑉1 = 𝑇𝑇1 (c) = (d) 𝑇𝑇1 𝑇𝑇2 = 𝑃𝑃1 𝑃𝑃2
1 2 2 2 2 𝑉𝑉1 𝑇𝑇2 1 2
15. By what factor does the average velocity of a gaseous molecule increase when the temperature is doubled?
(in Kelvin)
(a) 2.0 (b) 2.8 (c) 4.0 (d) 1.4
16. The temperature of a gas is raised from 27°C to 927°C. The root mean square speed of the gas
927
(a) remains same (b) gets � 27 times (c) gets halved (d) gets doubled
17. The ratio among most probable velocity, mean velocity and root mean square velocity is given by
(a) 1:2:3 (b) 1: √2: √3 (c) √2: √3: �8/𝜋𝜋 (d) √2: �8/𝜋𝜋: √3
18. The root mean square velocity at STP for the gases H2 , N2 , O2 and HBr are in the order
(a) H2 < N2 < O2 < HBr (b) HBr < O2 < N2 <H2 (c) H2 < N2 = O2 < HBr (d) HBr < O2 < H2 < N2
19. Root mean square velocity of a gas molecule is proportional to
(a) 𝑚𝑚1/2 (b) 𝑚𝑚0 (c) 𝑚𝑚−1/2 (d) m
20. 1. Which one of the following gas is not correct for ideal gas?
(a) (b) (c) (d)
21. A mixture of one mole each of H2 , He and O2 each are enclosed in a cylinder of volume V at temperature T.
If the partial pressure of H2 is 2 atm, the total pressure of the gases in the cylinder is
(a) 6 atm (b) 38 atm (c) 14 atm (d) 22 atm.
22. The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than that of
gas B at same temperature. The pressures of the gases for equal number of moles are
(a) 2P𝐴𝐴 = 3P𝐵𝐵 (b) 3P𝐴𝐴 = 2P𝐵𝐵 (c) P𝐴𝐴 = 2P𝐵𝐵 (d) P𝐴𝐴 = 3P𝐵𝐵
23. Assuming ideal gas behaviour, the ratio of density of ammonia to that of hydrogen chloride at same
temperature and pressure is (Atomic wt. of Cl = 35.5 u)
(a) 0.64 (b) 1.64 (c) 1.46 (d) 0.46
24. At 300 K, the density of a certain gaseous molecule at 2 bar is double to that of dinitrogen (N₂) at 4 bar.
The molar mass of gaseous molecule is
(a) 56 g mol−1 (b) 112 g mol−1 (c) 224 g mol−1 (d) 28 g mol−1
25. Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure p, and temperature T₁ are
connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of
the bulbs is then raised to T2 . The final pressure 𝑝𝑝𝑓𝑓 is
𝑇𝑇 𝑇𝑇 𝑇𝑇 𝑇𝑇 𝑇𝑇 𝑇𝑇
(a) 𝑝𝑝𝑖𝑖 �𝑇𝑇 1+ 2𝑇𝑇 � (b) 2𝑝𝑝𝑖𝑖 �𝑇𝑇 +1𝑇𝑇 � (c) 2𝑝𝑝𝑖𝑖 �𝑇𝑇 +2𝑇𝑇 � (d) 2𝑝𝑝𝑖𝑖 �𝑇𝑇 1+ 2𝑇𝑇 �
1 2 1 2 1 2 1 2
26. Initially, the root mean square (𝑟𝑟𝑟𝑟𝑟𝑟) velocity of N₂ molecules at certain temperature is 𝑢𝑢. If this
temperature is doubled and all the nitrogen molecules dissociate into nitrogen atoms, then the new 𝑟𝑟𝑟𝑟𝑟𝑟 velocity
will be
(a) 2𝑢𝑢 (b) 14𝑢𝑢 (c) 4𝑢𝑢 (d) 𝑢𝑢/2
27. For gaseous state, if most probable speed is denoted by C*, average speed by C� and mean square speed by
C, then for a large number of molecules the ratios of these speed are
(a) C ∗ : C� : C = 1: 1.225: 1.128 (b) C ∗ : C� : C = 1.225: 1.128: 1
(c) C ∗ : C� : C = 1.128: 1: 1.225 (d) C ∗ : C� : C = 1: 1.128: 1.225
28. If 10−4 dm³ of water is introduced into a 1.0 dm³ flask at 300 K, how many moles of water are in the
vapour phase when equilibrium is established?
(Given: Vapour pressure of H₂O at 300 K is 3170 Pa; R = 8.314 J K −1 mol−1 )
(a) 1.27 × 10−3 mol (b) 5.56 × 10−3 mol (c) 1.53 × 10−2 mol (d) 4.46 × 10−2 mol
29. A spherical balloon of radius 3 cm containing helium 103 bar. At the same gas has a pressure of 48 × 10−3
temperature, the pressure, of a spherical balloon of radius 12 cm containing the same amount of gas will be____
× 10−6 bar.
Answer Key
1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
(b) (a) (c) (d) (c) (a) (c) (a) (c) (b)
11. 12. 13. 14. 15. 16. 17. 18. 19. 20.
(c) (d) (d) (b) (d) (d) (d) (b) (c) (b)
21. 22. 23 24. 25. 26. 27. 28. 29.
(a) (a) (d) (b) (c) (a) (d) (a) 750
