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No. of MCQs = 50
MDCAT-2024 Unit # 06 (Chemical Equilibrium) Total Marks = 50
Duration = 45 min
NOTE: Do not write or mark answers on the question paper. Carefully fill in the circle for answer of each question on the OMR answer sheet.
CHEMISTRY A) K sP C) K sP
1. The units of Kc is same as that of molar concentration for 3
which of the following reaction 4
A) N 2  O2  2 NO C) B) K sP D) 2 K
sP

B) D) 4
2. The value of Kc for any reversible reaction depends upon 13. 0.001 M NaOH solution has pH
A) Concentration of reactants C) Pressure and volume A) 3 C) 11
B) Concentration of products D) Temperature B) 4 D) 10
3. For which one of the following reaction K p> Kc? 14. 

A) 2SO2+O2 2SO3 C) N2O4 2NO2 0.1 M H2S get 50 % ionized to form H ion and S-2 ion.
B) N2+3H2 2NH3 D) H2+ 2 2HI What is the pH of this solution?
A) 1 C) 3
4. The solubility of which salt decreases by increase of
B) 2 D) 4
temperature?
15. Which one of the followings is strongest acid?
A) NaCl C) LiCl
A) 0.1 M CH3COOH C) 0.01 CH3COOH
B) KCl D) Glucose
B) 1 M CH3COOH D) 0.05 M CH3COOH
5. The value of Kc for the following reaction at 500 oC and
16. Which one of the following pair behave as a buffer solution?
1atm pressure is 6.5 × 10-2. what would be the value of Kp
A) PhOH, PhONa C) Na2CO3, NaCl
for this reaction at same conditions of temperature at and
B) CH3COOH, CH3COONa D) All of these
pressure:
17. Benzoic acid and sodium benzoate are equimolar and are
N 2  O2 2 NO mixed to form buffer. If pKa = 5.3. What will be the pH?
g g g
A) 6.3 C) 2.85
-3
A) 1.3×10 C) 6.5×10-2 B) 5.3 D) 2.5
-2
B) 1.3×10 D) 6.5×10-3 18. The idea of pH and pOH was put forward by:
-4
6. Benzoic acid (Ka = 10 ) when get ionized its conjugate base A) Gibb’s C) Sorenson

benzoate C 6 H 5CO2
1
 will be form. What is possible value B) Brown
19. If Ka< 103. It means that
D) Faraday

of Kb for benzoate ion? A) Base is very strong C) Acid is very strong

A) 10-6 C) 10-7 B) Base is very weak D) Very weak acid
-10
B) 10 D) 10-3 20. Which of the following is a buffer solution?
7. NH3 behave as Lewis base as well as bronstead –Base. Its Pkb A) Brine C) CuSO4 solution
value is 3.5. After acceptance of proton from aqueous media B) Glue D) Blood
its conjugate acid  NH  
4 will be formed. What is its 21. For a reaction A + B C + D when we start with
ka 2 moles of each A and B, Kc = 25. What will be the value of
possible value of its P ?
Kc? If we start with 1 mole of each A and B.
A) 2.5 C) 10.5
A) 25 C) 12.5
B) 3.5 D) 6.5
B) 5 D) 50
8. If we have a mixture of two acids A1 and A2 having Pka
22. The solubility of Ca(OH)2 is exothermic its solubility will
values 2.5 and 4.5 respectively then it means that
increase
A) A1 is ten times stronger than C) A2 is 100 times stronger
A) At high temperature C) Temperature independent
A2 than A2
B) At low temperature D) No relation
B) A1 is 100 times stronger D) A2 is 10 times stronger than
23. The PH of a solution is 5. To this solution, sufficient acid
than A2 A1
was added and its pH decreased to 2. The increase in
9. 0.1 M CH3COOH and 0.01 M CH3COONa mixed to form a
hydrogen ion concentration is
buffer solution if Pka = 4.74 then what would be the P H of A) 100 times C) 10 times
this buffer solution. B) 1000 times D) 2.5 times
A) 4.74 C) 3.74
24. For which system does the equilibrium constant Kc has units of
B) 5.74 D) 2.72
(concentration)1?
10. Which one of the following combination is used as group
A) N2 + 3H2 2NH3 C) 2NO2 N2O4
reagent for identification of basic radicals of group III.
A) HCl+H2S C) NH4OH+NH4Cl B) H2 + I2 2HI D) 2HF H2 + F2
B) H2S+H2O D) NH4Cl+NH4Cl+H2S 25. The concept of solubility product is used for
11. If the value of KSP of an ionic compound is equal to 108 S5 A) Insoluble salts C) Sparingly soluble salts
then what is possible formula of this compound? B) Soluble salts D) Miscible salts
A) MX C) M2X3 26. With the increasing temperature, the ionic product of water
B) MX3 D) MX2 increases and pH value
12. If the KSP of an ionic salt is equal to 4S3 then its solubility A) Increases C) Remains same
can be found by the formula. B) Decreases D) May increase or decrease

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27. What will be the pH of 1 M NH4OH solution if it is only 1% 42. The equilibrium constant for the reaction,
ionized? ( ) ( ) ( )
A) 7 C) 8 at 2000 K. In presence of a catalyst, equilibrium is
B) 9 D) 12 attained ten times faster. Therefore, the equilibrium
28. The conjugate base of H2CO3 constant, in presence of the catalyst, at 2000 K is
A) HCO 31 C) CO2 A) 40 x 10-4 C) 4 x 10-3
-4
B) CO 32 D) HCO 2 B) 4 x 10 D) Difficult to compute
without more data.
29. If ‘s’ moles of Al(OH)3 is soluble in one litre, what will be 43. At the given temperature, the equilibrium constant for the
the value of Ksp? reaction ( ) ( ) ( ) is 2.0x10-3. At the
A) 8 s2 C) 4 s3 same temperature, the equilibrium constant for the
B) 18 s3 D) 27 s4 reaction, ( ) ( ) ( ) will be
30. The value of Ksp for PbSO4 at 250C is A) -2.0 x 10 -3
C) 5.0 x 10-3
A) 1.6 x 10-4 C) 1.6 x 10-8 B) 2.0 x 10 3
D) 5.0 x 102
-6 -10
B) 1.6 x 10 D) 1.6 x 10 44. The solubility of PbCl2 is
31. Units of Kw are A) K C) (K )1/3
A) mol dm3 C) mole2 dm6 sp sp

B) mole2 dm3 D) mole2 dm3 B) (K / 4)1/3

sp
D) (8K )1/2
sp
32. Buffer action can be explained by 45. The equilibrium constant for equilibria
A) Common ion effect C) Le-Chatlier’s principle
( ) ( ) ( ) and
B) Law of mass action D) All above
( ) ( ) ( ) are K1 and K2, respectively.
33. The precipitation occurs if the ionic concentration is
Then
A) Less than Ksp C) Equal to Ksp
A) K2 = K1 C) 1
B) More than Ksp D) Is present at any moment K2 =
34. If Kc is very small than the product is in K 1
A) Small amount C) Normal amount B) K2 = K 12 D) 1
B) Large amount D) Unpredictable K2 = 2
K1
35. The reaction A + 2B  C + D is at equilibrium,
concentration of reactants and products are [A] = 0.2 [B] = 46. A higher value of equilibrium constant K shows that
0.1 [C] = 0.3 [D] = 0.5 what is K c? A) The reaction has not yet C) The reaction has gone to
A) 75 C) 7.5 started. near completion towards
B) 1.50 D) 4 left
36. Which one of the following is strongest base? B) The reaction has gone to D) None of these.
A) NH4OH C) C6H5NH2 near completion towards
B) CH3NH2 D) Ca(OH)2 right.
37. Which one has the highest pH value? 47. The equilibrium constant for the reactions are
A) Gastric Juice C) Vinegar
B) Milk D) Grape fruit
38. What would be the solubility product of AB 2 when solubility
of A is 2? The equilibrium constant for is
A) 8 C) 32 A) K1/K2. K3 C) K1 + K2 + K3
B) 16 D) 64 B) K2/K1. K3 D) K1 x K2 x K3
39. Which one of the following parameter does not disturb the 48. In a reaction A + B C + D when one mole of each of the
position of equilibrium? two reactants are mixed. 0.6 mole of each product is formed.
A) Temperature C) Concentration The equilibrium constant calculated is
B) Pressure D) Catalyst A) 1 C) 0.36
40. Which strategy will shift the equilibrium position towards B) 2.25 D) 0.5
right in the following reaction 49. Which of the following reaction is not affected by change of
PCl5 PCl3 + Cl2,  H = +ve pressure?
A) increase of pressure C) By removing PCl5 A) N2 + O2  2NO C) PCl3 + Cl  PCl5
B) increases of temperature D) By adding suitable catalyst B) 2SO 2 + O 2  2SO 3 D) N2 + 3H2  2NH3
41. 50. When pressure is applied to equilibrium system Ice 
For the reaction, the ratio is equal to Water which of the following will happen?
A) RT C) (RT)2 A) More ice is formed C) Water will evaporate
B) 1 D) 1 B) More water will be formed D) Equilibrium will not
RT (RT) 2
attained

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