L-3 T-1, Che, 2022-2023
L-3 T-1, Che, 2022-2023
lICHE
BANGLADESH UNIVERSITY OF ENGINEERING AND TECHNOLOGY, DHAKA
Date: ~~~;?'21t
L-3rr -1 B. Sc. Engineering Examinations 2022-2023
SECTION-A
There are FOUR questions in this section. Answer Q. NO.1 and any TWO from the rest.
1. (COMPULSORY)
(a) Diameter of distillation column is very important in controlling costs and has to be
estimated even for preliminary designs. Explain clearly three fundamental steps to
estimate the column diameter. (7)
(b) Flow pattern on the trays is also an important design parameter for distillation
columns. With an appropriate diagram, demonstrate the selection guide of flow pattern
for sieve trays. (7)
(c) Rationalize how the single assumption that "solutes are independent of each other" can
specify more than one degree of freedom for muitisolute absorption and stripping process. (7)
(d) When Eo > R1 the difference point is on the left-side of the right triangular
equilibrium diagram; and when Rj > Eo the difference point is on the right of the
diagram. What happens when Rl = Eo? Answer this question using a logical argument. (7)
(e) Justify with proper reasoning the use of "effective equilibrium constant" in the
analysis ofleaching process. (7)
.3. (a) Selection of a proper solvent is very important for the development of an economical
extraction system. State solvent-selection criteria for an extraction system. (7)
(b) We have a mixture of linoleic and oleic acids dissolved in methylcellosolve and 10%
water. Feed is 0.003 wt frac linoleic acid and 0.0025 wt frac oleic acid. Feed flow rate is
1500 kg/h. A simple countercurrent extractor will be used with 750 kg/h of pure heptane
as solvent. We desire a 99% recovery of the oleic acid in the extract products. The
equilibrium distribution constant, Kt for the given condition are 2.17 and 4.14 for linoleic
and oleic acids, respectively. Find the required number of stages, N and the recovery of
linoleic acid in the extract product. (20)
Contd P12
=2=
CHE 303
Contd ... O. NO.3
(c) Consider that the specifications of feeds and fresh solvent are fully known. Show the
solution procedure using difference-point on a right triangular diagram for a two-feed
extractor. (8)
4. (a) Would you expect stage efficiencies to be higher or lower in leaching than in liquid-
liquid extraction? Explain. (10)
(b) A washing operation is processing 10,000 kg/h of wet solids. The liquid is essentially
3
. water with a density of 1000 kglm3, the dry solids have a density of 1500 kglm , and the
porosity is measured as E = 0.40. What is the flow rate of the underflow liquid in kg/h?
Also state all the crucial assumptions which are required for the stage-to-stage calculation
of washing process. (10+6)
(c) Reason why the notched weirs have better turndown characteristics than straight weirs
in distillation columns. (9)
SECTION-B
There are FOUR questions in this section. Answer any THREE.
Assume reasonably if any additional data/information are required.
Notations indicates their usual meaning.
5. (a) Sketch the T-x.y diagram for Ethanol-Water system using Enthalpy-Composition
Diagram attached in the question. Use at least 5 points for both T-x and T-y graph on ihe
same graph paper. It is also required to write down the steps these you have followed to
draw the graph. (15)
(b) Two flash distillation chambers are hooked together as shown below. Both are at
I atm pressure. The feed to the first drum is a binary mixture of methanol and water that
is 55 mol% methanol. The feed flow rate is 10,000 kmol/h. The second flash drum
operates with \'IfF)2 = 0.7 and the liquid product composition is 25 mol% methanol.
. Equilibrium data are given in Table Q. 5(b). (20)
(i) What is the fraction vaporized in the first flash drum?
(ii) What are yJ, Y2, x" T" and T2?
-------~----------------
p' 101m
10.000 l!!p!
z ;, O.lSlS 2
" • .1'
Contd P/3
=3=
CHE303
6. (a) A distillation column separating ethanol from water is shown as below. Pressure is
2
1 kg/cm . Instead of having a condenser, a stream of pure liquid ethanol is added directly
to the column to serve as the reflux. This stream is a saturated liquid. The feed is 40 wt%
ethanol and is at -20°C. Feed flow rate is 2000 kglb. We desire a distillate concentration
of 80 wt% ethanol and a bottom composition of 5 wt% ethanol. A total reboiler is used,
and the boilup is a saturated vapor. The cooling stream is input at C = 1000 kglb. Find the
Note: Set up the equations, solve in equation form for V for all required terms, read off
all required enthalpies from the enthalpy composition diagram in Figure Q. 6(a), and then
calculate a numerical answer.
[
I
i
QCOI=O
F. z
(b) Explain the concepts of total reflux and minimum reflux and how they relate to
purU~ (1~
Contd P/4
,
=4=
CHE303
8. (a) Discuss the benefits and drawbacks of using batch distillation In contrast to
distillate. Pressure is 1 atm. Equilibrium data are given in Table 8(c). (23)
-------- -"- ._--,-,""
--
ltl
l.I'l
c:J
----.,---- r
,I
'\ ,
.;',J
/
I
Tablt' (J 5(hJ and Qtl('slion '8fC) J j'por./iquid I!quilihrium tlattl.HJr ntl!lhll1lOl IrtUlO"" 'P ':: I arm) (ntOn;,;
o o 100
2.d 13.4 96.4
4.0 23.0 93.5
6.0 30.4 91.2
Ito 36.5 89.3
10.0 41.8 87.7
15.0 51.7 84.4
20.0" 57.9 81.7
30.0 66.5 7lW
40.6 72.9 75.3
50.0 ,
77.9 73.1
60.0 82.5 71.2
70.0, 87.0 69.3
80.0 915 67.6
90.0 95.8 66.0
'I
95.0 97.9 65.0
100.0 100.0 64.5
s..""n:.c: Pcn)'ct aL (19I\..\).r. 1)-~.
!
,I
\3\D~\7021
L-3/T-lICHE Date: J/iIl14,g024
BANGLADESH UNIVERSITY OF ENGINEERING AND TECHNOLOGY, DHAKA
L-3/T-I B. Sc. Engineering Examinations 2022-2023
SECTION-A
There are FOUR questions in this section. Answer Question No. I is Compulsory and carries 45
marks. Answer any TWO questionsrrom the rest of the 3 questions.
I. Answer the questions below. Clarify your answers with adequate reasoning. Answering
without any reasoning will bear zero marks.
(i) Explain what will happen if there is no stability to a vapor-liquid system in equilibrium.
You can use the stability criterion applicable to this scenario to clarify your answer. (7)
(ii) "After adsorption of molecules on a solid surface, the equilibrium is maintained between
the adsorbed molecules and vapor phase" - Is it true or, false? Give reasons to your answer. (7)
(iii) Liquefaction converts only a small fraction of a gas to liquid through Linde process.
Why is it still relevant to use this method in commercial scale? How can you overcome the
limitation? Provide reason(s) to your answer. (7)
(iv) Derive the simplified equation for solid-vapor equilibrium applicable under high
pressure scenario. Give an example of an application where this equation could be used. (8)
(v) Illustrate the basic mechanism (with reactions) for an alkaline fuel cell. How can
thermodynamic equilibrium provide effective estimation of fuel cell efficiency? Explain. (10)
(vi) "Despite the dependence on temperature, K is called the equilibrium constant for a
reaction" - using the expression for its temperature dependence (see formula sheet), asses
this statement.
2. (a) Describe the general method of liquefaction. Provide a schematic to differentiate between
Linde and Claude Process. (5+10=15)
(b) Describe the vapor-liquid compression cycle with a schematic of the process. Explain
different steps of the process using T-S and lnP-H diagrams. (8+7=15)
3. (a) The equilibrium composition at 1000 K and I bar of a gas-phase system containing the
species C, CO and C02 are to be detem1ined. In the initial unreacted state, there are I mol C
and I mol C02 present. (Reaction: C+C02 = 2CO).
Values of !leJ at 1000 K are:
Based on this data, estimate the equilibrium concentration of the components and Ak values. (20)
[Hint: see formula sheet]
Contd P/2
. ,
i
,
=2=
CHE 313
Contd ... Q.No.3
(b) Natural gas, assuming pure methane, is liquified in a simple Linde process. Compression is
to 60 bar and precooling is to 300 K. The separator is maintained at a pressure of I bar, and un-
liquefied gas at this pressure leaves the cooler at 295 K. What fraction of the gas is liquefied in
the process and what is the enthalpy of the high-pressure gas entering the throttle valve?
At 300 K and 60 bar, Enthalpy of superheated methane = 1140 kJlkg
At 295 K and 1 bar, Enthalpy of superheated methane = 1188.9 kJ/kg
At I bar pressure, under saturated condition of methane, T"t = 111.45 K, saturated liquid
enthalpy = 285.4 kJ/kg, and saturated vapor enthalpy = 796.9 kJ/kg
pO
4. (a) K = x,ydl I
(Yz q;; P) (x, y,f,)
This is an expression for a multiphase reaction equilibrium constant. Assuming the expression,
answer the following questions: (5+ 10=15)
(i) Identify the phase of the component I, 2 and 3 from the equation. Give reasons to your
identification.
I
(ii) Make possible assumptions that could be applied to simplify and solve the equation for
K. Clearly mention the circumstances when these assumptions will be applicable.
(b) 1 mol CO and 2 moll-bO are being reacted to produce C02 and H2 in presence of 2 mol N2
in the system. The reaction is taking place at 1100 K and 2 ba. Under ideal condition (12+3=15)
(i) Calculate the extent of reaction if the value of K is 1.1 under this condition.
(ii) Predict the outcome if the pressure is doubled for this system.
SECTION -B
There are FOUR questions in this section. Answer any FOUR questions.
Symbols have their usual meanings.
5. (a) Explain the term "retrograde condensation". Discuss its applicability in the operation of
deep natural gas wells. (10)
(b) A binary system of species I and 2 consists of vapor and liquid phases in equilibrium at
temperature T. , The overall mole fraction of species I in the system is ZI = 0.65. (25)
At temperature T ,
(ii) For a liquid mole fraction XI = 0.75, what is the pressure P and what molar fraction v
of the system is vapor?
(iii) Show whether or not the system exhibits an azeotrope.
Contd P/3
=3=
CHE 313
6. (a) Define partial molar properties and show that for constant P and T. (15)
LXidMi =0
(b) "For a pure species coexisting liquid and vapor phases are in equilibrium when they have
same temperature and fugacity" TruelFalse - Explain your answer. (5)
B sat +v'(p psat)
(c) Show that for pure liquid F. = psatexp uP; i - i
(15)
JI l RT
7. (a) VLE data for methyl tert-butyle ether( 1) dichloromethane (2) at 308.15 k are as follows:
P/kPa XI VI PlkPa XI VI (35)
85.2 0.00 0.00 53.6 0.674 0.588
82.2 0.058 0.025 50.4 0.847 0.824
76.7 0.166 0.08 49.7 0.953 0.950
68 0.332 0.197 49.62 1.00 1.00
59.6 0.504 0.368
eE
R = (A21Xl + A12X2 - CX1X2)X1X2
T
(b) Prepare a plot of Irryl, Irryz and eE/X1X2RT VS Xl showing both the experimental and
calculated values
(c) Prepare a P-x-y diagram.
8. (a) Th excess enthalpy for a liquid mixture of species I and 2 at fixed T and P is represented
by the equation HE = X1X2(40Xl + 20X2) (15)
where HE is in llmol. Detemline expressions for Hf and Hfas function of XI.
(b) If the molar density of a binary mixture is given by the empirical (10)
p = ao + alxl + a2xf
Find the Vi and V2
(c) Show that for pure liquid Lt 0 ~ = lnyf (10)
, Xl ... ~ Xlx2RT
r
List of Formulas
ChE-313.
Solution Thennodynamics
I. d(nG) = (nV)dP-(nS)dT
7. Gibbs-Duhem equation:
GE
20 . -RT = "',".x.ln 1
y I.
E
nG ) nVE nHE
21. d FiT ( = FiTdP + RT2 dT + Li In Yi dni
22. Gamma phi formulation, yi 0r P = XiYJ/
23 • J1'.1= (2l~atp.sat exp ~I(p
I
psa,)
- 1
ill l RT
r
I( psa')
24 cp.
• I
= 0ra'
::Iv
_"'_I
exp
[_ VI p-
RT
1 ] .- •.• :. -0,- • :."'. '.. ~,.
alnjl alnJi
29. Xl __ , + Xz ---1. = 0 (at constant T and P)
a". a".
30.RedlichlKister Expansion:
,
Y = Ao + L~=l Anzn
CE G a(GE/RT) E
31. -'
RT
=: -RT + Xz -'----<.
a".
Cf I GE a(GE/RT)
32. liT i -RT - Xl --'-a-,,"-.--'-
33. Margules equation:
lnYl = xHA12 + 2(Azl - A12)xd
inyz ,
= xf[AZl + 2(A12 - AZ1)xz]
At infinite dilution, in yf' = A1Z and in Yi - A
2l
34. Van Laar Equation:
,
xlxz .
GE/RT = A' + B'(x1 - xz) = A' + B'(2xl - 1)
GE A;2A;1
-
X1X2RT A;2X1 +A;IX2
I
In;l = A;2
I
(1 + 21X2
X
AA,;2 1)-2 and InY2 = 'A;] (1 +AA~1:2)-2
12 I
35. Wilson Equation:
, AI2
lnY1 = -In(xI + X2A12) + X2( A
'i XI + X2 12
, A12 A
InY2 = -In(X2 + x1A21) - x1( A - 21 A )
i Xl + X2 12 X2 + Xl 21
At infinite dilution,
In Yr' = -In A'2 + 1- A21 and In yi = -lnA21 + 1 - A
'2
36. NRTL Equation:
39.Flash Calculation
ZtKt
Yi = l+V(Kt-l)
X i-- ZI
l+1I(Kt-l)
F = L' ZI(Kt-l)
11+II(Kt-l)
I
,
I
40. VLE from Cubic Equation of State
,
~ ~l
YI0i = Xi0i
4l.Mixture ofVLE
,
Zv - 1 + pv vpv zV_pv
I- - q (Zv+'PV)(zv+uPV)
rnl
J,no dni = fJl f,'0 dE
I
I n. nl +19.,
Yi ' !
-!
n
= 0
no+19,
I (for single reaction)
n n'o+L'19'j"
y.I; = --!.
n
=' nO+Lj19jEj
I', I (for multi-reaction)
-{jGO
=-
RT
K -.: KoK1K2
!
For gas phase reaction
fit(Yi01
I ~)l91
I
= (P)-l9pO K
44. Pha~e
i
rule for reactive system, F=2-1t+N-r
45 E -we1eel
. '2F
I
df I dl'
-d I
x,'
> 0 and -..!
dx,
>0 (constant T and P)
dy,
dXl >0 I
when pressure effect is negligible
I
I
r
I
2. !!!...
P ,dx,
=: (y,-x,)
y,x,
dy,
dx,
when pressure effect is considered
-
dP
=:
O' In azeotrope
dx,
,
,
ya xp
In-' =: In-'
yf xf
47. Criteria of Stability and Equilibrium for SVE
r
48. Adsorption
I
49. R~frigeration:
I
Network
, in Camot Refrigeration Cycle, W= -(Qc+QH)
Coefficient ofPerfonnance, w =: Qc =: Tc-Th
i W ~
SECTION-A
There are FOUR questions in this section. Answer any THREE.
1. (a) Discuss in detail the role of various factors in the spoilage offoods. (10)
(b) How do native enzymes cause spoilage of food? How can the spoilage be prevented
or minimized? (15)
(c) Classify the various foods with appropriate examples on the basis of their ease of
spoilage. (10)
4. (a) Briefly explains the factors of relevance in the control offood drying. (10)
(b) Write a short note on the different kinds of drying equipment used in food industry. (13)
(c)Briefly explain refrigeration principle and requirements of freezing foods. (12)
SECTION-B
There are FOUR questions in this section. Answer any THREE questions.
5. (a) Food diseases can be deficiency type or diseases of affluence. Describe and contrast
one example of each. (10)
(b) Discuss the concept of water activIty In context of food spoilage and food
preservation. What are the zones of reaction in a moisture content-water activity
relationship, and how can you use this information for food preservation? (18)
(c)Briefly describe how you would test water content in food samples? (7)
6. (a) What is the A, H-B system and how is it related to a nutritional quality in sugars?
How are fructose and sucrose similar and how are they different from each other? (10)
(b) Illustrate the schematic structure of any polysachharide, using a diagram. Comment
on the stability of the molecule based on your structure.
Contd P/2
=2=
CHE 431
(c) Discuss any 2 non-starch polysachharides, and how they are used for food related
applications. (10)
(d) Below are linear and cyclic representations of two pentoses, discuss the differences
between them and pick the most probable cyclic structure that would be formed by
Linear Structure A. (5)
- ~./I---- •.. ~.~~.------~--------------,- ----
CHO CH,OH
I I
E.C.OH c=o
E.C.OI1
I
H.C.OH
I I
H.C- Oll !l.C'.01l
I
CH.,OH Cll,OE
QI:'OH
1
O
H/T-
I H
" H
'\..1
C C
b~?H ~/bH
C_C
1 1
OH OH H OH OH OH
Cyclic Structure A Cvclic Structure B Cvclie Structure C
7. (a) "Change of taste and texture in proteins is due to chemical reactions to modify them
or their constituent peptides or amino acids." Justify this statement with 4 suitable
examples. (12)
(b) State the type of secondary structure in the following proteins and elucidate the role
of these structures for the flavor or function of the food associated with them. Be sure
to include the name of a specific food item for each. (8)
(i) Collagen
(ii) Gluten
(c) What is rigor mortis? Discuss its significance for preservation, storage and cooking
of meat. (10+5)
Is there an equivalent phenomenon in the processing of fish? What, if any?
8. (a) What are the names and functions of some useful microorganisms to human?
(Name and describe 2) (13)
(b) How do the following enzymes contribute towards food processing? (12)
(i) Lipoxynase
(ii) Peroxidase
(iii) Amylase
(iv) Phenolase
(c) What are some food borne illnesses and what are the microorganisms associated
with the diseases? Name at least five. (10)
-.
SECTION-A
There are FOUR questions in this section. Answer any THREE.
them geometrically, and point out which is the principal root. (12)
(c) Find four roots of the equation z. +4=0 and use them factorize z' +4 into
2. (a) Define: analytic function and harmonic function. Show that the function j(z) = Izl2.
3. (a) Evaluate fzdz from z = 0 to z = 4 + 2i along the curve C given by (i) z = /2 + it;
c
integral f:
+ 1 dz, where C the circle 1z 1=3 described in the positive sense.
c z -2z
(17)
4. (a) Expanct j(z)= (I ) in a Laurent series valid for (i) 1<lzl<2,(ii) Izl>2. (18)
z z-2
3 .
2
(b) Using residue theorem find the value of the integral f( 3Z +2 )dz, taken
c z-l Xz +9
counterclockwise around the circle C with equation 1z 1=4 described in the positive
sense. (17)
Contd P/2
=2=
MATH 327/CHE
SECTION-B
There are FOUR questions in this section. Answer any THREE questions.
(a) B dB
f05 -sin4cosB
2 n 2
(15)
~ I
(b)
f-
-0>
dx
x' +1
(20)
6. (a) Let Xn,p be a data matrix containing n observations and p features. Derive the
formulas of mean vector, covariance matrix, correlation matrix for the data matrix
Xn,p' What is the relationship between covariance and correlation? (8)
(b) Calculate mean vector, covariance matrix, correlation matrix for the data matrix
x, x,
3 5
4 5.5
2 4
6 7
8 10
2 5
5 7.5
(c) What is the multivariate distribution, and how does it differ from the univariate
normal distribution? (7)
7.. (a) Derive the probability density function for the bivariate normal distribution. (10)
(b) Describe the method of least squares and how it is utilized to estimate parameter,
Contd P/3
=3=
MATH 327/CHE
8. (a) Compare the assumptions of ANOVA and MANOV A. How are they similar, and
how do they differ? (7)
(b) What is principal component analysis (PCA), and what is its primary purpose in