CHEM 107: L-lIT-lIMME Date: 04/07/2011
CHEM 107: L-lIT-lIMME Date: 04/07/2011
SECTION -A
There are FOUR questions in this Section. Answer any THREE.
1. (a) Explain the process of emission of light by an atom. Calculate the largest wavelength
found in the Balmer series of hydrogen. (R = 1.097 x 1Q7/m). (15)
(b) What are the limitations of Bohr atom model? (8)
2
(c) Derive the Schrodinger wave equation. Mention the significance of\!f and \!f • (12)
2. (a) What are transition elements? Write down the atomic numbers of 151 transition series.
Discuss the important properties of the transition elements. (15) /
(b) Write short notes on: (10x2=20)
(i) Diamond and graphite.
(ii) The noble gas elements.
3. (a) Describe the condition favourable for the formation of ionic bond. (8)
(b) What hybrid orbitals would be expected for the central atom of the following? (10)
(i) XeF2 (ii) H20
Explain their structures also.
,
(c) Discuss the formation of 02 molecule according to valence bond theory and molecular
orbital theory. Which one is better to explain the properties of O2 molecule? (10)
(d) What are the conditions for the formation of a hydrogen bond? Discuss the properties
of H20 with reference to hydrogen bonding. (7)
4. (a) Define reversible and irreversible cells. Discuss various type of reversible electrodes. (16)
(b) What is standard electrode potential? Is it safe to stirr 1 M AgN03 solution with a
copper spoon? Explain your answer. (9)
(c) Write the cell reactions of (10)
(i) SHE coupled with Ag/ AgCI electrode
(ii) Zn/Zn2+ electrode coupled with calomel electrode
(iii) Leclanche dry cell
(iv) Lead storage battery.
Contd P/2
""J."
=2=
CHEM 107
SECTION-~
There are FOUR questions in this Section. Answer anyTHREE.
5. (a) Explain the effect of pressure on the solubility of gases in liquids. Why solubility of a
gas in a given liquid decreases with rise in temperature? (8+3=11)
(b) State Raoutt's laws of b.p. elevation and derive the equation ~Tb = Kb.m, where
~Tb = elevation of boiling point, kb = molal ebullioscopic constant and m = molality. (12)
(c) 0.562 g of naphthalene was dissolved in 30 g of canbon tetrachloride. If the normal
boiling point of carbon tetrachloride is taken as 76.91 °c, at what temperature the solution
6. (a) Define the terms phase, component and degrees of freedom. (6)
(b) Water and sulphur are one component system, but water has only one triple point
whereas sulphur has three triple points. Explain it with the help of phase diagram. (14)
(c) Determine the number of phases, components and no. of degrees of freedom for the
following system: (6)
(i) NH4CI (s) ~ NH3 (g) + HCI (g)
(ii) N204 (g) ~ 2 N02
(d) Draw the phase diagram of a two component system where two components are
completely miscible with each other in the liquid state and there is no chemical
interaction between them: Explain the eutectic point present in the system. Why eutectic
mixture is not a compound? (9)
7. (a) Discuss the preparation, properties and uses of PVC. What is the importance of
plasticizer in polymer processing? (6+3=9)
(b) Write a short note on - (i) Chromophore (ii) Auxochrome (8)
(c) What is equilibrium constant? Derive the equation ~Go = - RT InK (8+4=12)
(d) A buffer solution contains 0.2 g. mole of acetic acid and 0.25 g, mole of potassium
acetate per dm3. Calculate the change in pH of the solution if 0.5 mL of IN HCI is added
to it. [ Ka = 1.8 X 10-5 ] (6)
8. (a) How do you differentiate the order and molecularity of a reaction? (8)
(b) Derive an expression for the rate constant of a second order reaction. Explain two
methods for the determination of reaction order. (10+8=18)
(c) How activation energy (Ea) can be calculated using Arrhenius equation? The rate
constant of a reaction at 25°C is doubled on raising the temperature through ten degree.
SECTION -A
There are FOUR questions in this Section. Answer any THREE.
1. (a) Discuss the important conditions for the interference of light. Distinguish between
constructive and destructive interference of light. (10)
(b) Describe with necessary theory of the Newton's rings method of measuring
wavelength of light. (15)
(c) In a Newton's rings experiment the diameter of the 15th ring was found to be 0.590 cm
and that of the 5th ring was 0.336 cm. If the radius of the plano-convex lens is 100 cm,
calculate the wavelength of light used. (10)
2. (a) What is diffraction of light? Derive an expression for the intensity distribution due to
Fraunhofer diffraction at a single slit and hence find the conditions for maxima and
mInIma. (20)
(b) A parallel of light is incident normally on a narrow slit of width 0.2 mm. The
Fraunhofer diffraction pattern is observed on a screen, placed at the focal plane of a
convex lens of focal length 20 cm. Calculate the distance between the first two minima.
(Assume A = 5 x 10-5 cm and that the lens is placed very close the slit). (7)
(c) What is a grating? Define the resolving power of a grating. (8)
3. (a) State the Brewster's law. Show that at the polarizing angle of incidence, the reflected
and refracted rays are mutually perpendicular to each other. (12)
(b) Explain the Malus' law. How will you orient the polarizer and the analyzer so that a
beam of natural light is reduced to (i) 0.25 and (ii) 0.5 of its original intensity? (13)
(c) Write short notes on (10)
(i) Specific rotation and
(ii) Quarter and half wave plates.
4. (a) What are Lissajous figures? Derive a general expression for the resultant vibration of
a particle simultaneously acted upon by two initially perpendicular simple harmonic
vibrations, having the same frequency but different amplitudes and phase angles. Hence
discuss the cases if phase difference are (i) n/2 and (ii) n14. (15)
(b) Show that for a body executing simple harmonic motion, both the average potential
energy and average kinetic energy are half of the total energy of the harmonic oscillator. (12)
Contd P/3
Ii
=3=
PHY l03(MME)
Contd ... Q. No.4
(c) The displacement of an oscillating particle having mass 4 kg at an instant t is given by
y = 2 sin 0.5 t, where y is in meters and t is in seconds. If its angular frequency become
double, then calculate the average kinetic energy of that particle. (8)
SECTION -B
There are FOUR questions in this Section. Answer any THREE.
6. (a) What are the requirements of a good auditorium? Derive expressions for the growth
and decay of sound intensity inside an auditorium and hence obtain an expression for the
reverberation time. (25)
(b) A room is 32 feet wide by 65 feet long by 10 feet high. The ceiling is acoustic, the
walls are plaster, the floor is concrete and there are 40 people in the room. Calculate
(i) the number of reflections (n) per second and (ii) reverberation time. Assume that the
sound absorption coefficients are: ceiling = 0.60, plaster = 0.03, concrete = 0.2 and
absorbing power per person to be 0.5. (10)
7. (a) Explain the terms cardinal points and power of a lens. (9)
(b) Define equivalent lens and equivalent focal length. Derive an expression for the focal
length of a system of two coaxial thin lenses placed in air and separated by a distance. (20)
(c) Two similar thin convex lenses of focal lengths 10 ern each are coaxial and 5 ern
apart. Find the equivalent focal length and the position of principal points. Also find the
position of the object for which the image is formed at infinity. (6)
8. (a) What are the methods to minimize spherical aberration? How is spherical aberration
minimized when two thin lenses are placed at a distance form each other? (10)
(b) Explain what is meant by chromatic aberration in lens. Derive and discuss the
condition of achromatism for two thin lenses separated by a distance. (20)
(c) Two thin lenses of focal length f1 and f2 separated by a distance, d have an equivalent
focal length 50 ern. The combination satisfies the conditions for minimum spherical
aberration and is also achromatic. Find the values of fj, f2 and d. Assume that both lenses
are of same material. (5)
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L-l/T-l/MME Date: 01108/2011
BANGLADESH UNIVERSITY OF ENGINEERING AND TECHNOLOGY, DHAKA
L-l/T..:I B. Sc. Engineering Examinations 2010-2011
SECTION-A
There are FOUR questions in this section. Answer any THREE.
1
~x+!4 '
--sxsO
4
3
-x -1 x> 1
2
(b) If F (i - i, i -l, i-i) = 0 and v = f(x, y, z), then find the value of
18v 18v 18v.
--+--+-- mtermsofv. (13)
xOx yOy z8z
u ~ tau -1 fx + Jy .
x+ y
Verify Euler's theorem for tauu and find the value of x au + y au .
Ox Oy
(10)
3. (a) A farmer can afford for buying 8800 ft of wire fencing. He wishes to enclose a
rectangular field of largest area. What should be the dimension of the field? (10)
(b) Find the area of the triangle formed by the coordinate axes and the tangent at e = 1[/4
3
to the curve x = 27 cos e, y = 27 sin3e. (12)
(c) Find the angle of intersection of two curves x
2
-l = a2
and i + l = a2.J2 . (13)
Contd P12
=2=
MATH 171
(a) J dx (12)
(2x + 3)~x2 + 5x + 4
SECTION - B ....
There are FOUR questions in this section. Answer any THREE.
1t
(b) J x
a2 cos2 x + b2 sin2 x
dx (12)
o
~
(c) J In (1 + cosx)dx (13)
o
(b) Find the volume of the solid generated by the. revolution of the loop of the curve
l (a - x) = i (a + x) about x-axis. (18)
SECTION -A
There are FOUR questions in this section. Answer any THREE.
1. (a) Find the equivalent resistance Req in the network shown in fig I(a) (15)
.. I
240 i
a , I
I
48 240
Req
.80
r b
, 80
.300
f
I
(b) Using nodal analysis find the node voltages of the circuit in fig I(b) (20)
. L 1A
200 100
2A
so
Contd P/2
=2=
EEE 155 (MME)
2. (a) Using superposition theorem find i for the circuit in fig 2(a) (20)
15mA
15V
2kO 30mA
12k 6kO'
. i
I
r'~
,
;
"~__ ~"""""_. __
"""':" " __ "~.. ~.".'__
-'~:-- --~,-." ~.
-, , .. ,.~--
""_.,,,--- .~.~'."',
y:v:
",""-"_"_" ._. _" ._..•......_~_
,. ".-."_._,' ,- . J
I
(b) Find 10 in the circuit in fig 2(b) (15)
- --.- -1-kO~
~-------~"'--"
2.5 kO
.~'~
I~
j. '
5kO 5kO 20V I
I
4kO
I
5kO I
!
I
3. (a) Find the equivalent resistance Req for the network left to a-b shown in fig 3(a) (15)
40
a I '
5A
120
i
, ..n- 6 ..n- , -0- b I
_._-------~---------~----,---_.~
j1'~ ~ ~. 2(~
Contd P/3
f ..
~'
=3=
(b) Find the power dissipitated in 2 n resistor for the circuit shown in fig 3(b) (20)
--~~--2A--~- -
...L..' --------.-.~--,-.~-l
,', ''':
. >.. :< 'J\'
,(::,'
, ',!"
10 20 I
ix
+
1V 30
'.".:' \.
4. (a) Find the voltage V x for the circuit shown in fig 4(a) using supermesh analysis. (20)
8V
2i. 20
(b) Find the thevenin equivalent circuit for the network left to a-b in fig 4(b). (15)
_.-,------------------~
60' 2 Vab
a
+
i
6V Vab
40 j
i
bl
Contd P/4
. .
=4=
SECTION -B
There are FOUR questions in this section. Answer any THREE.
5. ' (a) Determine the value of current I required to establish a magnetic flux of <I> = 0.016 Wb
in the magnetic circuit shown in Fig. for 5(a). Cast steel core is used in the circuit. Cross-
sectional area = 16 sq in. throughout. The B-H characteristics chart is attached with the
28 in
• ~l '~
r-----~------I---~----.------ I
I
8 in : " 8 in
I
I
L I
~ ~ _
N=200 turns
Fig. for Q 5(a)
(b) One motor takes 250 amperes at 0.8 power factor'lag while another motor takes
"
50 KW at 0.5 leading power factor from a line of 220 volts. What is the resultant line
current for these two motors? What is the power factor of the combined loads? Is it
6. (a) A voltage v = 200 cos (157t + 30°) Volts is applied to a particular circuit element and
it is found that i = 5 sin (157t - 150°) Amperes. Sketch the v and i waves. Find the nature
(b) Find the expression of instantaneous power delivered to RL branch where the phase
shift between vet) and i(t) is e. Prove that the volt-amperes of the circuit is Vmlm, where
2
V m and 1m are the maximum value of the sinusoidal variation of voltage and current
respectively. (18)
Contd PIS
to
=5=
7. (a) Draw the phasor diagram for the circuit shown in Fig. for Q 7(a) displaying the
quantities vs, VR, Ve, i, i] and i2. Choose arbitrary magnitudes for all the quantities. (15)
.
--+
1
V(J C,
R2
(b) If the current shown in Fig. for Q 7(b) flows through a 5-ohm resistance, how much
heat energy is produced each cycle? (15)
Sinusoidal
/!f\
.. ~~. __ ._wt_(_ra~~)
o rr/2 1t 5rr/2 3n
8. (a) The voltage applied to two parallel branches is 40L80° volts. The current through
branch 1 is 5L30° amperes, and the current through branch 2 is (-6 + j8) amperes. Find
the real power and the reactive volt-amperes supplied to the parallel combination by the
method of conjugates. (14)
(b) When C is varied to produce series resonance why does the maximum drop across the
capacitor occur before resonance? (7)
(c) As L is varied to produce resonance in a series circuit containing R = 100 ohms,
C = 13.26 J.lFand f = 60 Hz, find the voltage drop across L at resonance and also when
the drop across L is a maximum if 1000 volts are impressed. (14)
I.B : I
I
i
1.6
1.4
1.2
! t
B(1) 1.0'
I
j I Ca t iron
.-::'~ I 0.8
I'
I 0.6
0.4
0.2
__I _
-"-<---"--r-"'-'-
o , lOOO 2000 . 3000 4000 5000 6000 7000' 8000' 9000 10,0{)0
"'-'" H (AIm) ~
. '"r," •..; !.. . '\ .' ~• .~'; I . ..
~
.... ..
, .
B-H cur've for ~ 5(a)
L-l/T-l/MME Date: 19/07/2011
BANGLADESH UNIVERSITY OF ENGINEERING AND TECHNOLOGY, DHAKA
L-l/T-I B. Sc. Engineering Examinations 2010-2011
SECTION-A
There are FOUR questions in this Section. Answer any THREE.
The questions are of equal value.
2. (a) Define hardness. Discuss the Brinell hardness test and describe the precautions
which must be taken in its operation.
(b) Draw a neat phase diagram for two metals (A, B) which are mutually soluble in both
solid and liquid states.
For an alloy containing 30 pet B find:
(i) the temperature of initial solidification
(ii) the temperature of final solidification.
3. (a) What is a unit cell? Differentiate between a unit cell and a primitive cell. Give
examples, if necessary.
(b) Determine the atomic packing factor (Packing Density) for a face centred cubic cell.
4. (a) Differentiate between different types of materials on the basic of bonds that exists
between them.
(b) Explain the nature of semi-conductors. Differentiate between different types of
semiconductors.
Contd P 12
"
=2=
MME 131
SECTION -B
There are FOUR questions in this Section. Answer any THREE.
The figures in the margin indicate full marks.
5. (a) Differentiate between hot working and cold working. Mention advantages and
6. (a) Distinguish between 'drying and firing' during processing of ceramics. (8)
(b) What are the general characteristics of polymer? Discuss the divisions of polymers
7. (a) Explain how metal degrades by galvanic corrosion. How can galvanic corrosion be
prevented? (15)
(b) For intergranular corrosion, describe why, where and the conditions under which the
8. (a) Differentiate between ores and minerals. What are the sources of scrap metals? (10)
(b) Write the steps involved in hydrometallurgical processing. (5)
(c) Define electrowinning and electrorefining. With suitable diagrams, describe the