SRI CHAITANYA IIT ACADEMY, INDIA 04-08-25_ Sr.

Super60_NUCLEUS-BT _Jee-Main_CTM-01_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS-BT JEE-MAIN Date: 04-08-2025
Time: 09.00Am to 12.00Pm ^* CTM-01 Max. Marks: 300
KEY SHEET
MATHEMATICS
1 2 2 4 3 3 4 2 5 1
6 4 7 3 8 2 9 1 10 3
11 4 12 2 13 1 14 1 15 3
16 2 17 3 18 2 19 3 20 1
21 1 22 2 23 70 24 5 25 9

PHYSICS
26 1 27 4 28 3 29 3 30 4
31 1 32 3 33 4 34 3 35 2
36 3 37 1 38 2 39 1 40 3
41 2 42 2 43 2 44 3 45 1
46 4 47 5 48 0 49 6 50 35

CHEMISTRY
51 4 52 1 53 2 54 2 55 3
56 3 57 1 58 3 59 3 60 3
61 2 62 3 63 1 64 1 65 1
66 1 67 4 68 4 69 1 70 4
71 2 72 4 73 17 74 3 75 3

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SOLUTION
MATHEMATICS
1. p  x   x2  4 x  5 lim f  x   e3/10
x 1

1 x1/ x
2. f  x  x 1/ x
ln f  x   ln x f '  x   2 1  ln x 
x x
Hence statement 2 is correct.
F(2) > f (7) so 21/2 is greatest.
Hence statement 1 is false.
e x  f  x   e x x   0,1 e x  f  x   e x x  1,  
4 2 2 4
3.
x3
sin 2 x  cos 3x  ke 2 x 
4. lim 3 k  1, L  4
x 0 xn
e x  x  1  2
5. f  x 
x2
6. Equation of tangent is y  4ex  2e
f ' x  e  x  1 x  2 
x x 1
7.
8. f '  x   0 at x  1,3
9. Using condition of continuity at x=3 we get 9a  3b  5  9b  6a  3a  6b  5  0 .
Using condition of differentiability at x=3 we get 4a  5b
10. f  x   2 x3  2 x2  x  2
11. f 2  x  f 2  y  3 f  x  3 f  y  x  y .
1
Differentiating wrt ‘x’ we get 2 f  x  f '  x   3 f '  x  
2 x
  2 f  x   3 f '  x  
1
2 x
 f  x 
1
23  4 x 1 
1 d  4 
 g '  3   12     3
f ' 4 dx  g  x  
x 3

   m2  m  1  m2  m  1
2m  1 
12. tan  4 1
  tan   =
 m  m2  2   1  m  m  1
4 2 

tan1 m2  m  1  tan1 m2  m  1

   
 tan tan1 n2  n  1      .
n
 2m
Lt 1
  Lt
n
m1
 m  m  2  n 
4 2
4  4
cot 1  3   cot 1  7   cot 1 13  cot 1  21  ........
13. Given series =
1 1 1 1   1  
 tan 1    tan 1    tan 1    tan 1    ..........   tan 1  
 3 7  13   21  n 1  1  n  n  1  4

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 
    
14.  cos 1 cos  2  2
2   cot cot 1  2  2   
2  x 5 x 3 9 x  2
   

 0   2 
 2 2  2
2 2   2   x  4 x  3  0 x  1, 3  x  1, 3
2 x 5 x 3 9 x 2
15.

16. f  x   e x  e1 x  2
17. f '( x )  x 2  2(a  3) x  1
Both roots<0 a>4 a=5,6,7,...........50
Sum of values of ‘a’=1265
Take P  ct 3 , 4  . Slope of tangent at P=  7
c 4
18.
 t  3t
19. (a) f is odd function
 2 tan 1 x, 1  x  1
1  2 x  
(b) sin  2 
    2 tan x,
1
x 1
 1 x  
   2 tan x,
1
x  1
n
(c) f is not differentiable at x  ,n I
2
(d) f is not differentiable at x  2
x x
20) f ( x)      
5 2
7x
 10 0 x2

7x 1 2 x4
 10
7x
 2 4 x5
 10 .
 7 x
f ( x)   3 5 x6
 10
7x
 10 4 6 x8

7x 5 8  x  10
 10

7x  7 10  x  12
 10
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Checking LHL and RHL at x=2,4,5,6,8,10 we can see that f(x) is discontinuous at these
points
f ( x ) is periodic with period = 10
Now in [0,10] f ( x ) is discontinuous at x=2,4,5,6,8,10 i.e. six points
Hence in [0,100], 60 points of discontinuity are there
2024 1 2024
21. 
r 1 0
f  r  1  x  dx   f  x  dx  30
0

cos 1 cos 5  2  5  1.28

22. f '( x )  2  3x 2  0  f ( x ) is decreasing function

 f ( x)   x  ( x  3)( x 2  3 x  10)  0  x  3

Hence x=1 and x=2

23. f '( x )  ax 2  bx  5  0  b 2  20a  0

For a=1, b=1,2,3,4 i.e. 4 pairs are possible

a=2, b=1,2,3,4,5,6 i.e. 6 pairs are possible
a=3, b=1,2,3,4,5,6,7 i.e. 7 pairs are possible
a=4, b=1,2,3,4,5,6,7,8 i.e. 8 pairs are possible
a=5,6,7,8,9 b=1,2,3,4,5,6,7,8,9 i.e. 45 pairs are possible
Total 70 pairs of (a,b) are possible
24. f  x   2 x 3  3 x 2  36 x  120

f '  x   6 x 2  6 x  36

 6  x 2  x  6   6  x  3 x  2 

Sign of f '(x) -2 3

So a = –2, b = 3
5
25. k  9, a  
2

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PHYSICS
26.
y

3mm
P x
x=0 Q x=π

Wave is heading towards positive x-direction

Equation of y
𝑦 = 𝐴sin 𝜔𝑡 +
Wave equation 𝑦 = (2 × 10 )sin 10𝑡 − 2𝑥 +
Given:
Relative velocity of P & Q = 2𝜔𝐴 = 4 cm/s
⇒ 2𝜔(2 × 10 ) = 4 × 10
⇒ 𝜔 = 10 rad/s
From snapshot: 𝜆 = 𝜋 m ⇒ 𝑘 = = 2 m
Final Wave Equation: 𝑦 = (2 × 10 )sin 10𝑡 − 2𝑥 +
27. 7 harmonic of closed pipe = 5 harmonic of open pipe =

= = = ×
= ∴𝐿 =
28. By the definition of thermo dynamic process
4 A 2v0
29. average speed in one complete oscillation = 
T 

30. =𝛾
adiabatic isothermal
For same value of Δ𝑉,
(Δ𝑃)adiabatic = 𝛾(Δ𝑃)isothermal
T2
T1
T3 C
R θ
2 a

31. a b

𝑃 = 𝜎(4𝜋𝑅 )𝑇
𝑃 =𝑃 +𝑃
= {𝜎(4𝜋𝑅 )𝑇 } + (1 − cos𝜃)
{𝜎(4𝜋𝑅 )𝑇 } = + {𝜎(4𝜋𝑅 )𝑇 }
∴ =
32. According to 1st law of thermodynamics Q = U + W
W > 0; PdV > 0
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33. The change in entropy is given by
Δ𝑠 = = 𝑚𝑐
So, the change in entropy depends on mass of the substance, specific heat, and change in
temperature of the substance.
34. Conceptual
35. let L be the side of the cube and d be depth up to which it is submerged. If M is the mass
of cube and p is the density of liquid, then
Mg=pL2dg ...(1)
When the temperature is raised by T,
Mg=p(1-lT)[L(1+sT)2 ...(2)
From (1) and (2)
p L2 dg (1-lT)((1+sT)2 = pL2dg
(1-lT)((1+2sT) = 1
36.
37. 10 × 3 × 60 = 𝑚 × 80 + 𝑚 × 2 × 1
1 × 10 × 60 = 𝑚 × 5 × 1
𝑚 = 100 gm
1800 − 240 = 𝑚 × 80
𝑚 = 19.5 gm
38. The equation <K.E. of translation>=(3/2)RT, <Rotational energy>=RT is taught. The fact
that the distribution of the two is independent of each other is not emphasized. They are
independently mazwellian.
39. Conceptually, it is not often clear to the students that elastic collisions with a moving
object leads to change in its energy.
 3
40. l1  , l2  and l1 : l2  1: 3
2 2
41.
42. The process equation for the thermodynamic process is given as:
𝑇 = 𝑇 + 𝛼𝑉
From the ideal gas law, we have:
𝑃= = (𝑇 + 𝛼𝑉)
The heat capacity of a gas in a thermodynamic process is given as
𝐶=𝐶 +
Differentiating equation (3.88), we get:
𝑃𝑑𝑉 + 𝑉𝑑𝑃 = 𝛼𝑅𝑑𝑉
Now from equations (3.88), (3.89), and (3.90), we have:
( )
𝐶=𝐶 +
𝐶=𝐶 + (𝑇 + 𝛼𝑉)
43. 𝑈 = 𝑎 + 𝑏𝑃𝑉 = 𝑎 + 𝑛𝑏𝑅𝑇 ⇒ = 𝑛𝑏𝑅

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But = ⇒𝛾=
44.

P0 V0 P0 V0 PV1 PV2
T0 T0 T1 T2

2⋅ = + , 𝑉 + 𝑉 = 2𝑉
𝑉 = 𝑥 𝐴, 𝑉 = 𝑥 𝐴 ⇒ 𝑥 = 44 𝑐𝑚, 𝑥 = 40 𝑐𝑚
45.
46. Change in tension = ΔT ∴ 2Δ𝑇sin37∘ = Δ𝑚𝑔 ⇒ Δ𝑇 = ∘
; Δ𝑙 =
But Δ𝑙 = 𝐿𝛼Δ𝜃 ∴ ∘
⋅ = 𝐿𝛼Δ𝜃 ⇒ Δ𝑚 = 𝛼Δ𝜃 × 𝐴 × 𝑌 × 2sin37∘ /𝑔
× × × × × × ×
= = 12
×
47. Process is polytropic 𝐶 = 𝐶 = = 𝑅⇒ ⇒𝑚=2
𝑃𝑉 = 𝐶
40 × 𝑉 = 𝑃(2𝑉 ) ⇒ 𝑃 = 10 kPa
×
= ⇒ = ⇒ 𝑇 = 100 K
48. Given that
𝑥 = 40cos(50𝜋𝑡 − 0.02𝜋𝑦) ∴ particle velocity
𝑣 = = (40 × 50){−sin(50𝜋𝑡 − 0.02𝜋𝑦)}
Putting 𝑥 = 25 and 𝑡 = 𝑠,
𝑣 = −(2000𝜋 cm/s)sin 50𝜋 − 0.02𝜋(25) = 10𝜋√2 m/s

49. 𝐸 = 𝑚𝜔 𝐴 ⇒ 𝐸 = 𝑚(2𝜋𝑓) 𝐴 ⇒ 𝐴 =
×( . . )
Putting 𝐸 = 𝐾 + 𝑈, we obtain: 𝐴 = ⇒ 𝐴 = 0.06 m
( / ) .
50. Let 𝐴 be the area of cross-section of wire and 𝑇 be the tension applied.

The lowest frequency of transverse vibration is given by: 𝑛=

Where 𝜇 = mass per unit length of wire = Volume of unit length × density

= 𝐴 × 1 × 𝜌 or 𝑛 =
We know that Young’s modulus
Stress /
𝑌= = or 𝑇 = 𝑌𝐴
Strain /

from equation-(6.183) and (6.184) 𝑛= =

( × )×( . × )
Substitute the given values: 𝑛= )
= 35 Hz
× ×( ×

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CHEMISTRY
51.
CH3 CH3 CH3
Br Br

HBr HBr

Br
NO2 NO2 NO2

52. Stability order : Neutral > Charged

NH

53. C Me Aromatic ion D 2° allylic ion

B 2° A Anti aromatic.
54. In case of Cl(III) more no. of resonating structures can form. Of resultant intermediate.
55. (II) symmetrical.
56. SN2 : Involved waldon inversion.
57. Br is electron withdrawing group
58. Middle carbon is SP hybridized
59. Strength of acid order
60. Conjugated alkene more stable.
61. Both carbon get hydrozen in two different structures respectively.
62. 2*2*2 = 8
63. CH3 is electron donating group
64. BP directly proportional to molor mass
Θ 
65. CH 3 NH H is unstable structure.
66. (a) has got one chiral centre
67. Rate of SN2 decreases with -crowding.
68. Step I: Attack of bromine atom as electrophile and formation of cyclic bromonium ion.
Step II: Attack of lone pair on electron-deficient carbon.
Step III: Removal of hydrogen as H+.

69. SN1 process

70.

(i) - Electrophilic aromatic substitution

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CH
3
(ii) | - Electrophilic addition
CH  C  CH  HBr  CH  C  CH
3 | 2 3 | 3
CH Br
3

(iii) -Nucleophilic substitution(SN1)

(iv) Nucleophilic aromatic substitution

alc.KOH CH CH  CHCH
CH3CH2CHCH3  3 3
(v) Br - Saytzeff elimination

71. x=iii,iv,v , y=i,ii,vi, vii,viii

72. 4n+2 rule
73.
Cl
H
Cl
&
H

74. Compound A : Compound B : CH 3 – CH– CH – CH 3

|
Br

CH

(A)
75.

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