SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 1.
1 (15/09/2017) - Page 1/7
BIO-EX SAS
ECOPOL 3 PREMIUM
SAFETY DATA SHEET
(REACH regulation (EC) n° 1907/2006 - n° 2015/830)
SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name : ECOPOL 3 PREMIUM
1.2. Relevant identified uses of the substance or mixture and uses advised against
Fire fighting foam concentrate
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
1.3. Details of the supplier of the safety data sheet
Registered company name : BIO-EX SAS.
Address : Z.I. La petite Olivière.69770.Montrottier.FRANCE.
Telephone : +33(0)474702381. Fax : +33(0)474702394.
[email protected]
1.4. Emergency telephone number : +33(0)145425959.
Association/Organisation : INRS / ORFILA http://www.centres-antipoison.net.
SECTION 2 : HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
In compliance with EC regulation No. 1272/2008 and its amendments.
Eye irritation, Category 2 (Eye Irrit. 2, H319).
May produce an allergic reaction (EUH208).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the
site.
This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard
conditions of use.
2.2. Label elements
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms :
GHS07
Signal Word :
WARNING
Additional labeling :
EUH208 Contains PRESERVATIVE. May produce an allergic reaction.
Hazard statements :
H319 Causes serious eye irritation.
Precautionary statements - Prevention :
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - Response :
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
Other information :
SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 1.1 (15/09/2017) - Page 2/7
BIO-EX SAS
ECOPOL 3 PREMIUM
2.3. Other hazards
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the
European CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table
The mixture satisfies neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH
regulations EC 1907/2006.
SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
Composition :
Identification (EC) 1272/2008 Note %
INDEX: 603-096-00-8 GHS07 [1] 10 <= x % < 25
EC: 203-961-6 Wng
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
Eye Irrit. 2, H319
2-(2-BUTOXYETHOXY)ETHANOL
INDEX: 603-027-00-1 GHS07 [1] 2.5 <= x % < 10
EC: 203-473-3 Wng
Acute Tox. 4, H302
ETHYLENE GLYCOL
SULFATE DE SODIUM ET D'OCTYLE GHS05 0 <= x % < 2.5
Dgr
Skin Irrit. 2, H315
Eye Dam. 1, H318
PRESERVATIVE GHS06, GHS05, GHS09 x % < 0.0015
Dgr
Acute Tox. 3, H301
Acute Tox. 3, H311
Skin Corr. 1B, H314
Skin Sens. 1, H317
Acute Tox. 3, H331
Aquatic Acute 1, H400
M Acute = 10
Aquatic Chronic 1, H410
M Chronic = 10
Information on ingredients :
[1] Substance for which maximum workplace exposure limits are available.
SECTION 4 : FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of exposure by inhalation :
In the event of an allergic reaction, seek medical attention.
In the event of splashes or contact with eyes :
Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment, consult an ophthalmologist.
In the event of splashes or contact with skin :
In the event of an allergic reaction, seek medical attention.
In the event of swallowing :
Seek medical attention, showing the label.
4.2. Most important symptoms and effects, both acute and delayed
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.
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BIO-EX SAS
ECOPOL 3 PREMIUM
SECTION 5 : FIREFIGHTING MEASURES
Non-flammable.
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
Aqueous solution ; does not present a specific risk in case of fire
5.3. Advice for firefighters
No data available.
SECTION 6 : ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
Consult the safety measures listed under headings 7 and 8.
6.2. Environmental precautions
Absorb onto sand or other absorbent material and shovel into container for disposal
6.3. Methods and material for containment and cleaning up
Collecting : Pump into clearly identified unbreakable containers
Wash thoroughly with water
6.4. Reference to other sections
No data available.
SECTION 7 : HANDLING AND STORAGE
Requirements relating to storage premises apply to all facilities where the mixture is handled.
7.1. Precautions for safe handling
Always wash hands after handling.
Remove and wash contaminated clothing before re-using.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations.
Avoid eye contact with this mixture.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
No data available.
Storage
Storage area should contain accidental spill
Packaging
Always keep in packaging made of an identical material to the original.
Recommended types of packaging :
Product in bulk : stainless steel, polyester or mild steel protected with epoxy or polyurethane coating. Tanks in PE, PP
Unsuitable packaging materials :
Mild steel
7.3. Specific end use(s)
No data available.
SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Occupational exposure limits :
- European Union (2009/161/EU, 2006/15/EC, 2000/39/EC, 98/24/EC)
CAS VME-mg/m3 : VME-ppm : VLE-mg/m3 : VLE-ppm : Notes :
112-34-5 67.5 10 101.2 15 -
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BIO-EX SAS
ECOPOL 3 PREMIUM
107-21-1 52 20 104 40 Peau
- ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 - - 100 - -
- Germany - AGW (BAuA - TRGS 900, 21/06/2010) :
CAS VME : VME : Excess Notes
112-34-5 10 ppm 1,5 (I)
67 mg/m3
107-21-1 10 ppm 2( )
26 mg/m3
- France (INRS - ED984 :2012) :
CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :
112-34-5 10 67.5 15 101.2 - -
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
107-21-1 20 52 40 104 * 84 -
- UK / WEL (Workplace exposure limits, EH40/2005, 2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 20 ppm 40 ppm Sk
52 mg/m3 104 mg/m3
8.2. Exposure controls
Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :
Use personal protective equipment that is clean and has been properly maintained.
- Eye / face protection
Avoid contact with eyes.
Before handling, wear safety goggles with protective sides accordance with standard EN166.
- Hand protection
Wear suitable protective gloves in the event of prolonged or repeated skin contact.
Type of gloves recommended :
- PVC (polyvinyl chloride)
Recommended properties :
- Impervious gloves in accordance with standard EN374
- Body protection
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed.
SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
General information :
Physical state : Fluid liquid.
Important health, safety and environmental information
pH : 7.00 +/-1.
Neutral.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Not relevant.
Density : 1.04 +/-0.02
Water solubility : Soluble.
Melting point/melting range : Not specified.
Self-ignition temperature : Not specified.
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BIO-EX SAS
ECOPOL 3 PREMIUM
Decomposition point/decomposition range : Not specified.
9.2. Other information
No data available.
SECTION 10 : STABILITY AND REACTIVITY
10.1. Reactivity
No data available.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
No data available.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
10.4. Conditions to avoid
No data available.
10.5. Incompatible materials
No data available.
10.6. Hazardous decomposition products
No data available.
SECTION 11 : TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days.
11.1.1. Substances
No toxicological data available for the substances.
11.1.2. Mixture
Respiratory or skin sensitisation :
Contains at least one sensitising substance. May cause an allergic reaction.
SECTION 12 : ECOLOGICAL INFORMATION
12.1. Toxicity
12.1.1. Substances
PRESERVATIVE
Fish toxicity : LC50 = 0.19 mg/l
Species : Oncorhynchus mykiss
Duration of exposure : 96 h
Crustacean toxicity : EC50 = 0.16 mg/l
Species : Daphnia magna
Duration of exposure : 48 h
Algae toxicity : ECr50 = 0.027 mg/l
Species : Scenedesmus capricornutum
Duration of exposure : 72 h
12.1.2. Mixtures
No aquatic toxicity data available for the mixture.
12.2. Persistence and degradability
12.2.1. Substances
SULFATE DE SODIUM ET D'OCTYLE
Biodegradability : Rapidly degradable.
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12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
No data available.
SECTION 13 : DISPOSAL CONSIDERATIONS
Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
13.1. Waste treatment methods
Do not discharge in the environment
Small amounts of product do not interfere with water treatment facilities. If released in sewage system, it is recommended to
control the flow rate in order to avoid any foaming excess
Do not pour into waterways
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular
without risk to water, air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Soiled packaging :
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
SECTION 14 : TRANSPORT INFORMATION
Exempt from transport classification and labelling.
14.1. UN number
-
14.2. UN proper shipping name
-
14.3. Transport hazard class(es)
-
14.4. Packing group
-
14.5. Environmental hazards
-
14.6. Special precautions for user
-
SECTION 15 : REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Classification and labelling information included in section 2:
The following regulations have been used:
- EU Regulation No. 1272/2008 amended by EU Regulation No. 2016/1179. (ATP 9)
- Container information:
No data available.
- Particular provisions :
No data available.
15.2. Chemical safety assessment
No data available.
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BIO-EX SAS
ECOPOL 3 PREMIUM
SECTION 16 : OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our
current level of knowledge and on national and community regulations.
The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling
instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local
regulations.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture
and not as a guarantee of the properties thereof.
Wording of the phrases mentioned in section 3 :
H301 Toxic if swallowed.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Abbreviations :
ADR : European agreement concerning the international carriage of dangerous goods by Road.
IMDG : International Maritime Dangerous Goods.
IATA : International Air Transport Association.
ICAO : International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail.
WGK : Wassergefahrdungsklasse (Water Hazard Class).
GHS07 : Exclamation mark
PBT: Persistent, bioaccumulable and toxic.
vPvB : Very persistent, very bioaccumulable.
SVHC : Substances of very high concern.
