Problems Related To 1D Box
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Nissam ElliasProblems Related To 1D Box
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Nissam ElliasCalculate the average value of position of particle in one dimensional box if the
normalized wave function is sin x
<x>=∫ 𝛹 𝑥𝛹
ො dτ
<x>=
2
𝑎 2 𝑛𝜋𝑥 𝑛𝜋𝑥 1 2𝑛𝜋
<x>= Sin ( ) 𝑥𝑑𝑥 Sin2 = (1-cos( )𝑥)
𝑎 0 𝑎 𝑎 2 𝑎
𝒂𝟐 𝟐𝒏𝝅𝒙
<x>=𝒂𝟐 𝟏{ 𝟎− 𝒄𝒐𝒔( 𝒂
) 𝒙𝒅𝒙
1 𝑎 𝑎 2𝑛𝜋𝑥
(𝑥𝑑𝑥 − 0 cos 𝑥𝑑𝑥)
𝑎 0 𝑎
= ( -0)=
Calculate the average value of Energy of particle in one
dimensional box if the normalized wave function is 𝜳 =
sin x
ℏ2 𝑑 2
dτ
<E>=∫ 𝛹 𝐻𝛹 =-
H 2m 𝑑𝑥 2
<E>=
𝟐 ℏ𝟐
𝒂 𝒏𝝅𝒙 𝒅𝟐 𝒏𝝅𝒙
<E>= 𝒂
. − 𝟐𝐦 𝟎sin 𝒂 𝒅𝒙𝟐 sin 𝒂
dx
𝟐 ℏ 𝟐 𝒏𝟐 𝝅 𝟐 𝒂 𝒏𝝅𝒙 𝒏𝝅𝒙
<E>= . . 𝟎sin 𝒂 sin 𝒂 dx
𝒂 𝟐𝐦 𝒂𝟐
2 ℏ𝟐 𝑛2 𝜋2 𝑎 𝟐 𝒏𝝅𝒙
<E>= . . 𝒔𝒊𝒏 𝒅𝒙
𝑎 𝟐𝐦 𝑎2 0 𝒂
Calculate the average value of momentum in one dimensional box if
𝟐 𝒏𝝅
the normalized wave function is 𝜳 = sin x
𝒂 𝒂
<Px>=∫ 𝛹 𝑥𝛹 dτ
𝑃
<Px>=
𝟐 𝑎 𝑛𝜋𝑥 𝒅 𝑛𝜋𝑥
<Px>= . −iℏ sin( ) 𝒅𝒙 sin( 𝑎 ) 𝑑𝑥
𝒂 0 𝑎
𝟐 𝑛𝜋 𝑎 𝑛𝜋𝑥 𝑛𝜋𝑥
<Px>=
𝒂
. −iℏ . sin( 𝑎 ) cos( 𝑎 )
𝑎 0
𝑑𝑥
𝟐 𝑛𝜋
<Px>=𝒂 . −iℏ . 𝑎
𝑋0 = 0
sin x and sin x are two wave
functions of particle in one dimensional box, then prove that
they are orthogonal
න ᴪ1ᴪ 2 dτ = 0
𝟐 𝑎 𝜋𝑥 2𝜋𝑥 1
න sin( ) sin( ) 𝑑𝑥 Sin Asin B=2{Cos (A-B)-Cos( A+B)}
𝒂 0 𝑎 𝑎
𝟐 𝑎 𝜋𝑥 3𝜋𝑥
න [Cos ( ) − Cos( ) 𝑑𝑥]
𝟐𝒂 0 𝑎 𝑎
𝟏 𝑎 𝜋𝑥 𝑎 3𝜋𝑥
{
𝒂 0
[Cos ( 𝑎
)𝑑𝑥 − 0
[Cos ( 𝑎
) 𝑑𝑥]}
𝟏 𝑎 𝜋𝑥 𝑎 𝑎 3𝜋𝑥 𝑎
𝒂
{ 𝜋 [𝑠𝑖𝑛 ]
𝑎 0
− 3𝜋 [𝑠𝑖𝑛 ]
𝑎 0
}
𝟏 𝑎 𝑎
𝒂
{ 𝜋 𝑠𝑖𝑛𝜋 − sin(𝑜 − 3𝜋 (𝑠𝑖𝑛3𝜋 − sin 0 }=0
