Sri Chaitanya IIT Academy, India 09-08-25_Sr.

Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT JEE-MAIN Date: 09-08-2025
Time: 09:00AM to 12:00PM RPTM-01 Max. Marks: 300

KEY SHEET

MATHEMATICS

1) 3 2 4 3) 3 4) 4 5) 2
6) 4 7) 3 8) 1 9) 4 10) 2
11) 4 12) 4 13) 4 14) 3 15) 2
16) 1 17) 1 18) 3 19) 4 20) 2
21) 0 22) 1 23) 3 24) 5 25) 50

PHYSICS

26 4 27 2 28 3 29 1 30 2
31 3 32 2 33 4 34 4 35 2
36 2 37 4 38 3 39 1 40 1
41 1 42 3 43 4 44 1 45 4
46 5 47 270 48 1400 49 750 50 2

CHEMISTRY

51 4 52 2 53 2 54 1 55 4
56 1 57 4 58 3 59 3 60 4
61 3 62 2 63 2 64 4 65 1
66 2 67 2 68 1 69 1 70 3
71 9 72 5 73 16 74 2 75 4

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. If x  I then  x  x and  x  r  0 for any r  I . Thus f  x   x . If x  R  I then  x =
integral part of x and  x  r   x for any r  1, 2,....1000 . Thus f  x    x   x  x
2. But y  f  x    x  12
h  x   f 1  x 
 x  y  1 so f 1  x   x  1 . g  x   h  x  3  x  3  1
3. f  x   0 if x  I and for x  R  I
2  x   x   1  x   x  . Thus f  x   1/ 2
1
2
4. We have the  2 tan 1 1/ 5    5  2  25  5
1 5 24 12
1
25
So, that the given equation can be written is
1   5 /12 
17 x 2  17 x tan  / 4  2 tan 1 1 / 5    10  0  17 x 2  17 x  10  0
1   5 /12 
 17 x 2  7 x  10  0   x  117 x  10   0
 x  1 is a root of the given equation.
5. We have from the given equation
tan 1
a  b x    tan 1
c  d  x  tan 1
 a  b  x  cot 1  c  d  x  tan 1
x 2  cd
x 2  ab 2 x 2  cd x 2  ab x 2  cd c  d  x
  x 2  ab  x 2  cd    a  b  c  d  x 2  x 4  x 2  ab  abcd  0
6. Put x  cos y then cos 1 x  y
1  cos y
 2sin 1 y
2
1  cos y
2cos 1 y
2
2 3 42 3 3 1 2 3 3 1 
7. We have    sin 1  sin 1 
4 8 2 2 4 2 2 12
12 3 
Also cos 1  cos 1  And sec 1 2   / 4
4 2 6
   
So the given expression is equal to sin 1 cot      sin 1 cot    0
 12 6 4  2
8. The given equation can be written as
x 1  x  1 3x  x
tan 1  x  1  tan 1  x  1  tan 1 3x  tan 1 x  tan 1  tan 1
1   x  1 x  1 1  3x 2
2x 2x 1
   x  3 x 3  2 x  x 3  4 x 3  x  0  x  4 x 2  1  0  x  0, x  
2 x 2
1  3x 2
2
None of which satisfies 1  x  2
  x  5 for x  5
9. f  x  
  x  5  for x  5

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

 7  9   9 
fof    f  f  3,5    f  9   4 = fof    f  f     f 1  4
 2  2   2 
10. We have been given that
f  g  x  x  3  x  f  
x  1  x  3  x Put x 1  t
x  t  1  x   t  1  f  t    t  1  3   t  1 = f 1  3
2 2

 3 5 33  
11. sin  tan 1  tan 1  tan 1   sin  1
 4 12 56  2
f  x   n  1; f  x    n  1   n  1  0
2 2
12.
If n  1  x  n,  x   n  1 and
 n  1   x   n 2  1  0   x 2    x    n 2  1   n  1
2 2 2 2

0  f  x   2n  2
The set of values of f  x  is
0,1, 2,..........  2n  2 
   1      1     
13.  tan 1    tan      tan  
 1     1     1   
     0 

    
 tan 1   tan 1   tan 1   tan 1   tan 1   tan 1      
  
14. Replace x by  x  2 f  cos x   f sin  x      x  f  sin x   x    f  x   sin 1  x   
2 2 6  6
1  1  4 log 2y
15. log 2y  x  x  1 = x 2  x  log 2y  0  x 
2
 4x  3 

4 3 16 x  12  18 x  12 2 x
 4 x 3   6x  4 
16. g  x  f     x
 6x  4  6  4x  3   4 24 x  18  24 x  16 2
 
 6x  4 
17. sin 1   x    sin 1 x,cos 1   x     cos 1 x
tan 1   x    tan 1 x,cot 1   x     cot 1 x
18. Put x  3  f  3  3 f  8  12 …….(1)
Put x  8  f  8  3 f  3  32 …….(2)
1   2   f  3  f 8   11
1
x
19. f  x   2 x  1; g  x   2
x 1
x
fog  x   fg  x   2 g  x   1 
x 1
Here x  1 , Range  co-domain
So, fog  x  not onto function
1
f 1  g  x   0
 x  12
Which is decreasing function
So fog  x  is one-one but not onto.
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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

20.  fogoh  x   f  g  h  x   
3x 2  1
 
 f g  x 2   f  3 x 2  1 
6 x2  3
 
21. sin 1 2 x  2   sin 1 x     sin 1 x
2 
 
sin 1 2 x  3sin 1 x  2 x  sin 3sin 1 x  2 x  3 x  4 x 3  x  4 x 3  0
1 1
 
x 1  4x2  0 x  0, ,
2 2
816
22. Since sin 1 x   / 2  x  y  z  1 and 3000  x  y  z    9000  272  8728
x  y2  z2
2

e x  e x
23. Let y   e 2 x  1  2 ye x
2
Therefore, t 2  2 yt  1  0, t  e x
2 y  4 y2  4
t   y  y2 1
2
 
 x  log y  y 2  1 (since e x  0 )

 f  x   g  x   log x 
1
 x2  1 
 e1002  1   e1002  1 e1002  1 
g 501   log  501
 
 2e   2e 2e501 
 log e501  501 .
24.  K  2  x 2  8 x  k  4  12  4  4  12
 k  2  x 2  8 x  K  4  0x  R
 k  2  0 and   0
25. Put x  1, y  1  f 1  2
1
Put y  f  x   1  xn
x
f  2  5  n  2  f  x   1  x2

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

PHYSICS
R100  R0 100  0 7.74  6.74 100
26.        210 C
R  R0  0 6.53  6.74 
27. l1  l2  l
 2  eq

l 2l 3l

5
l1  l2  l   l T   2  2l  T   eq  3l  T =  eq    1.67
3
28. If mass of the bullet is m,g heat absorbed by it to raise its temperature from 27 0 C to
327 0 C = mcT  m  0.03   327  27   9m cal
And heat required by the bullet to melt mL= m  6
Total heat
Q1   9m  6m   15m cal  15m  4.2  J [as cal =4.2 J]
Now when bullet is stopped by the obstacle loss in its mechanical energy.
1
ME 
2
 m 103  v 2 J [as mg  m 102 kg ]
As 25% of this energy is absorbed by the obstacle, the energy absorbed by the bullet.
1 1
Q2   mv 2  103 Q2  Q1 v  410m / s
4 2
29. In cooling 200 g of water from 25 0 C to 10 0 C heat to be extracted from water.
Q1   mcT W  200 1  25  10   3000Cal
And heat absorbed by m g ice at  14 0 C to convert into water of 10 0 C ,
Q2   mcT ice  mL   mcT W
i.e., Q2  m  0.5 0   14     80  110  0  =97m cal
According to given problem, Q2  Q1 , i.e.,
97 m=3000, i.e.m=31g
30. As work done W   P dv= are under P-V curve, so

WABC  WAB  WBC

WABC  0  15  4  60 J
1
And WAC   5  15    6  2   40 J
2
So work done along AC is least.
As according to first law of thermodynamics,
dQ  dU  dW

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s
So for path AC
U C  U A   dQ  dW  200  40  160 J
So, U C  160  U A  160  10  170 J
31. W3  W2  W1 and U 2  0 so U1  U 2  U3
W W nR T nRT 2
32.    
Q W  U nRT  nC1T 5  7
nR T   R  T
2 

7
33. For adiabatic process PT  1 where  
5
34. According to principle of calorimetry
Qgiven  Qused  0.2  S  150  40   1501  40  27   25   40  27   0.2  S  110  150  13  25  13
13  25  7
Specific heat of aluminum S   434 J / kg .0 C
0.2 110
35. By ideal gas equation
PV  nRT
PV 105  2000  10 6
n   0.08
RT 8.314  300
So, nh  n0  0.08 ………….(i)
As m=0.76g  2nh  32n0  0.76  nh  16n0  0.38 …………..(ii)
Subtracting (i) from (ii), we get
15n0  0.30  n0  0.02
So, nh  0.08  n0  0.08  0.02  0.06
nh 0.06 3
There fore,  
n0 0.02 1
36. Average kinetic energy for diatomic gases
5  K av  H  27  273  1
K av  kT  
2  K av O  27  273
37. Given, n1  2, n2  4
Specific heat of mixture at constant volume
5 3
2  4 R
n CV  n CV 2 2  11R
 Cv mix  1 1 2 2 
n1  n2 24 6
11R
Total internal energy of mixture U  n  Cv  mix T=  T  11RT
6
38. In adiabatic process
m  m
PV   constant  p   constant V  
  

As mass is constant  P
If Pi and Pf be the initial and final pressure of the gas and 1 and  f be the initial and
final density of the gas. Then
Pf   nP
  f    32   i   25   27  n  27  128
7/5 7/5

Pi  i  Pi

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s
39. From the conservation of energy change in potential energy =Heat energy
gh 10  63
 mgh  mcT T    0.147 0 C
c 4200 J / KgC
V
40.  100  100T  300T
V
41. dU  0
dW  dQ
42. According to 1st law of thermodynamics
Q  U  W
If  Q  0,  U  0 and W  0 is also possible
Hence T  0 , so T decreases
Statement I is false.
W  0 ;  PdV  0
Therefore volume of system must increase during positive work done by the system.
Statement II is true.
43. The total translational kinetic energy of n moles of
3
Gas  nRT ( PV=nRT)=1.5PV
2
Yes, the molecules of a gas collide with each other and the velocities of the molecules
change due to collision.
44. A) Process A  B
This is an isobaric process, P=constant and volume (V) of the gas decreases. Therefore
work is done on the gas.
W  P  3V  V   2 PV
Also V decreases so temperature at B decreases o
 Internal energy U decreases.
From Q  U  W as U and W decreases so Q decreases that means heat is lost.
B) Process B  C
This is an isochoric process V=constant pressure decreases P T So temperature also
decreases W  0;  U  negative so  Q negative
Hence heat is lost
C) Process C  D
This isobaric, pressure P=constant V increases and V  T So T increases. Hence  W ,  U
and  Q +ve so heat gained by the gas.
D) Process D  A
Applying PV=nRT
9 PV
For D P  9V   1RTD : TD 
R
9 PV
For A 3P  3V   1RTA  TA 
R
i.e., the process is isothermal  U  0
Now  Q   U  W  Q  W
As volume decrease in this process so W negative ie., wom done on the gas and  Q
negative hence heat is lost. .
45. a  isobaric, b  isothermal, c  adiabatic, d  isochoric.

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s
Y
Elastic energy stored, =  strain  ×area×length  Elastic energy stored, per unit length
2
46.
2
Y Y  l 
  strain   area  T   A  strain 
2 2
  
2 2  l 
11 11
10 10
 10 5  10   10 2   10 4   10 2  5 J / m
2 2

2 2
47. Let C be the specific heat capacity of liquid and L be the latent heat of vapoursisation.
From principle of calorimetry.
Heat lost = heat gain
mC SC T  mCT  mL
mC SC 110  80   5C  80  30   5L ……..(1)
Where, mC =mass of calorimeter
SC  sp . Heat of calorimeter
Again, when 80gm liquid is poured and equilibrium temperature is 50 0 C
mC SC  80  50   80C  50  30  ………(ii)
From equ. (i) & (ii)
1600C=250C+5L
L 1350
   2700 C
C 5
48. Work done  P V  400  P V  400  nRT [ PV  nRT at constant pressure]
R  1.4
Now, Q  nC p T  n T  400   400   1400 J
 1  1 0.4
49. W  nR  T  150 J  PV  nRT 
f  f   8 
Q  U  W  nR T  nR T  Q    1 nRT    1150  750 J
2 2   22 
50. Initially, at temperature T bnoyant force
FB  mg or Ax l g  ALb g

At temperature T   T the volume of the cube increases but the density of liquid
decreases so depth upto which the cube is immersed in the liquid remains same.
 FB '  mg
Or, A ' x  ' g  AL  bg
Now, A '  A 1  2T 
 '    1  T 
 x   1  2T 1  T   L b
 x   1  2T 1     x  [from eq. (i)]  1  2  T    T  1    2 or  l  2 a

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s

CHEMISTRY
51. Double bond is given more preference over halogen atoms.
52. Classification of organic compounds.
53. Metameres are the isomers having same molecular formula and same functional group
but different alkyl (or) aryl groups on either side of functional group
54. IUPAC rules.
55. All alkenes do not show geometrical isomerism and rotation about C=C is restricted.
56. IUPAC rules
57. The given compound shows both geometrical and optical isomerism.
58. The carbon which is directly attached to benzene ring is alpha carbon.
59. Number stereo isomers is given by 2 n  23

60. Fully eclipsed conformer is least stable due to repulsions.

61. Classification based on functional groups.
62. In compound 3 due to plane of symmetry it is meso form.
63. In Anti conformer intramolecular hydrogen bonding is not possible.

*
64. Br

65. Chair form is free from angle strain and torsional strain. Therefore it is most stable.

Optically active Meso-compound

66. (Optically inactive)

67. Priority order according to IUPAC rules.

68. IUPAC rules
69. Other than alkanes other functional group compounds also shows chain isomerism.
70. Pent-1-ene and pentan-2-one are not isomers.

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 Sri Chaitanya IIT Academy, India 09-08-25_Sr.Super60_STERLING# BT_Jee-Main_RPTM-01_Key & Sol’s
71.

heptane 2-methyl hexane

3-methyl hexane

2,2 -Dimethyl pentane 2,3-Dimethyl pentane 2,4-Dimethyl hexane

3,3-Dimethyl pentane 3-Ethyl pentane 2,2-Trimethyl butane

72.

73. 2,6 Dimethyl -2,5-diether acid.

74. The given compounds differ in IUPAC names.
75. four structures are possible, one in CH 2 group 3 in benzene ring.

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