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Registration No :

Total Number of Pages : 02 B.Tech

15BS1103
109 109 1st Semester
109 109 Back Examination
109 2019-20
109 109 109
CHEMISTRY
BRANCH : AEIE, AERO, AUTO, BIOMED, BIOTECH, CHEM, CIVIL, CSE, ECE, EEE, EIE,
ELECTRICAL, ENV, ETC, FASHION, FAT, IEE, IT, ITE, MANUFAC, MANUTECH, MARINE,
MECH, METTA, METTAMIN, MINERAL, MINING, MME, PE, PLASTIC, TEXTILE
Max Marks : 100
Time : 3 Hours
Q.CODE : HB773
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Answer Question No.1 (Part-1) which is compulsory, any EIGHT from Part-II and any TWO
from Part-III.
The figures in the right hand margin indicate marks.

Part-I
Q1 Only Short Answer Type Questions (Answer All-10) (2 x 10)
a) Calculate the kinetic energy of a moving electron which has a wavelength of 4.8pm.
2
b) .
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c) Why H2 ion is more stable than H2 ion, though both of them have the same bond
order?
d) What is the significance of the negative slope of fusion curve of ice in water system?
e) What is triple point of water?
f) What do you mean by the packing efficiency of a crystal?
g) If the rate of the reaction is equal to the rate constant, find the order of the reaction.
h) The Standard EMF of the Daniel cell involving the cell reaction Zn+ Cu2+ (aq.) Cu+
Zn+2(aq.) is 1.10V. Calculate the equilibrium constant
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i) What is the difference between Pearlite and Ledburite?
j) What is the significance of Gibb’s free energy.

Part-II
Q2 Only Focused-Short Answer Type Questions- (Answer Any Eight out of Twelve) (6 x 8)
a) State and explain Heisenberg’s uncertainty principle.
b) Compare the relative stability of O2- and N2+ and predict their magnetic behavior.
c) Discuss about Frenkel and Schotty defects.
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d) Define the term phase, component and degrees of freedom with suitable examples.
e) Discuss the phase diagram of Bi-Cd system.
f) What do you mean by order of a reaction? Derive the expression for the rate constant
of a first order reaction.
g) 5 moles of an ideal gas expanded reversibly at a temperature of 50oC and pressure of
760 mm of Hg to 25oC and 380 mm of Hg. Calculate the change in entropy. Given Cv =
R.
h) If enthalpies of formation of CO2, H2O are -393.5 kJ mole-1& -285.8 kJ mole-1
109 109 respectively109 109of combustion 109
and the enthalpy 109
of propane is 2220.2 kJmole-1, calculate
109 109
the enthalpy of formation of propane
i)
CP CV ൌ V ]
j) Calculate the maximum work that can be accomplished by the operation of the
following cell at 25 o C. Ni(s) / Ni2+ (0.01M) // Cu2+ (o.1M)/Cu(s).
Given that E Ni /Ni=-0.25V and E0Cu/Cu2+= 0.34V.
0 2+

109 k)
109 What is quinhydrone
109 electrode?
109 How can the109pH of an unknown 109 solution be found
109 out 109
by using this electrode.
l) Write the construction, cell reaction and applications of Leclanche cell.
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Part-III
Only Long Answer Type Questions (Answer Any Two out of Four)
Q3 a) What do you mean by bonding and antibonding molecular orbital? Discuss the M.O (8)
diagram of CO molecule. Calculate its bond order & explain its magnetic character.
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b) Write down the Schrodinger wave equation for the wave mechanical model of an atom. (8)
Name three quantum numbers of an electron which are yielded by this equation. What
is Eigen values and Eigen functions?

Q4 a) State and explain Hess`s law. The molar heat of combustion of C2H2(g), C (graphite) (8)
and H2(g) are 310.62, 94.05 and 68.32 Kcal respectively, Calculate the heat of
formation of C2H2(g).
b) What do you mean by pH of a solution? Describe the method of determination of pH of (8)
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a solution by109
glass electrode.109 109
What are the disadvantages 109
of this method? 109 109

Q5 a) Derive the expression for the rate constant of a second order reaction when (i) both the (8)
reactants are same and (ii) both the reactants are different.
b) Draw and explain the phase diagram of Sulphur system. Why all four phases of (8)
Sulphur system do not co-exist at equilibrium

Q6 a) Discuss the method of determination of Lattice energy of Calcium Chloride by Born- (8)
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b) Derive Gibbs-Helmholtz equation. (8)

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