Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS-BT JEE-MAIN Date: 02-08-2025
Time: 09.00Am to 12.00Pm RPTM-04 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any
electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
 SRI CHAITANYA IIT ACADEMY, INDIA 02-08-25_ Sr.Super60_ NUCLEUS-BT _Jee-Main_RPTM-04_Q.P
02-08-2025_Sr.Super60_NUCLEUS-BT_Jee-Main_RPTM-04_Test Syllabus
MATHEMATICS : Total Differential Calculus
PHYSICS : Waves & Sound: Wave motion (plane waves only), longitudinal and
transverse waves, superposition of waves; Progressive and stationary
waves; Vibration of strings and air columns; Resonance; Beats; Speed of
sound in gases; Doppler effect (in sound) (Deleted for MAINS);
Measurement of speed of sound using resonance column.

CHEMISTRY : Benzene, Alkyl Halides & Aryl Halides:

Benzene :Reactions of benzene, Structure and aromaticity ; Electrophilic
Substitution Reactions; halogenation, nitration, sulphonation, friedel-
crafts alkylation and acylation; Effect of directing groups (mono
substituted benzenes) in these reactions. Alkyl halides & aryl halides:
rearrangement reactions of alkyl carbocation, Grignard reactions,
nucleophilic substitution reactions; Haloarenes :Fittig, Wurtz-Fittig,
nucleophilic aromatic substitution in haloarenes and substituted
haloarenes (excluding Benzyne mechanism and Cine substitution).

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MATHEMATICS Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
sin x
1. Let f  x   ,x  0
x2
Let x1  x 2  x 3  ...  x n  ... be all the points of local maximum of f and
y1  y 2  y3  ...  y n  ... be all the points of local minimum of f. Then which of the
following options is NOT correct?
1) x n  yn  1for every n 2) x1  y1
1
3) x n   2n, 2n   for every n 4) x n 1  x n  2 for every n
 2
3
1
2. If f  x  be an identity function in R and g  x    f  x    2016  k  , then which of the
k 1

following is correct?
1) g  x  is strictly increasing in  2018, 2019
2) lim g  x   1
x 

3) g  x  has no real roots

49
4) Slope of tangent to the curve g  x  at x  f  2016  is 
36
3. Let f  x  be a twice differentiable function in  a, b  , given that f  x  and f   x  are either
both positive or both negative (i.e both are of same sign and never equal to zero) in  a, b

Statement-I: f   x   0 has atleast one real root in  a, b .

Statement-II: A Strictly decreasing function or a strictly increasing function can intersect
the X-axis atmost once.
1) Statement-I is true, Statement-II is also true.
2) Statement-I is true, Statement-II is false.
3) Statement-I is false, Statement-II is also false.
4) Statement-I is false, Statement-II is true.

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Lim n 2  n 1   n 2  n 1  
n     
4. e ,  n  I  , where . denotes the greatest integer function is:
1) 1 2) e 3) 3 e 4) 4 e
n
npnq
5. Lim   , p, q  0 equals:
n   2
 
pq
1) 1 2) pq 3) pq 4)
2
1  1 
 2  x    2 
6. f x  , 1  x  2 . denote greatest integer function 
x
1
1) is continuous at x  0 2) is continuous x 
2
3
3) is continuous at x  1 4) is continuous x 
2
g  x  , x  0
7. Let g  x  be a polynomial of degree one and f  x  be defined by f  x    sin x
. If
 x ,x0
f  x  is continuous satisfying f  1  f  1 , then g  x  is
1) 1  sin1 x  1 2) 1  sin1 x 1 3) 1  sin1 x 1 4) 1  sin1 x 1
1  sin x dy 
8. If y  tan 1 , then the value of at x  is
1  sin x dx 6
1 1
1)  2) 3) 1 4) does not exist
2 2
2 2
9. Let F  x    f  x     f '  x   , F  0   6 where f  x  is a thrice differentiable function such
that f  x   1, x   1, 2  , then choose the correct statement(s)
1) There must be a point of local maximum for F  x  in  1,1
2) f   x   2 x   1,1
3) F  x   5 x   1,1
4) F  x  has no point of extremum in  1,1
10. The displacement of the particle moving in a straight line from a fixed point on the line is
's ' . Where s 2  at 2  2bt  c , then acceleration is proportional to
1) s 2 2) s 3 3) s1/2 4) s 4
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2 2 4
11. At any point of the curve 2x y  x  4 , lying in the first quadrant, such that x>2, the
mean proportional (i.e, the geometric mean of the two numbers) between the abscissa and
the positive difference between the abscissa and the subnormal drawn to the curve at the
same point is equal to
1) ordinate 2) radius vector
3) x-intercept of tangent 4) subtangent

12. If f   x   0, x  R, f   3   0 and g  x   f  tan 2 x  2 tan x  4  , 0  x  , then g  x  is increasing
2
in
     
1)  0,  2)  ,  3)  0,  4)  , 
 4  6 3
    3  4 2 
1/2 1/3 1/4 1/5 1/6 1/8
13. The greatest of the numbers 1,2 ,3 ,4 ,5 ,6 and 8 is
1) 21/2 2) 31/3 3) 71/7 4) All but 1 are equal
14. Let f  x   ex cos x  sgn  sin x  cos x  and slope of curve y  f  x  is maximum at x  a ,
where a  Domain of sin1 x then sin 1 a  _____(where sgn() denotes signum fuction)
 3 
1) 0 2) 3) 4)
2 2 4
15. The largest area of a trapezium inscribed in a semi-circle of radius, 2R with its lower base
along the diameter is
3 2 3 3 2
1) 3 3R 2 2) R 3) R 4) R 2
2 8
16. The least length of the normal chord intercepted by the parabola y 2  8x is
1) 6 3 2) 12 3 3) 18 3 4) 8 3
17. Set of values of b for which local extrema of the function f  x  are positive where
2 2 3 5a 2 1
f x  a x  x  3x  b and maximum occurs at x  is contains
3 2 3
3
1)  5 2) 3) 10 4) -2
8
n 
18. The function f  x    4sin 2 x  1  x 2  x  1 , n  N has a local minimum at x  . Then n can
6
be
1) 2 2) 3 3) 5 4) 7
3 2 2
19. If f  x   2x  9ax  12a x  1 has a local maximum at x  x1 and a local minimum at x  x 2
such that x 2  x12 , ( x1  x 2 ) then the value of a2  2 is
1) 1 2) 2 3) 4 4) 2
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20. Match the following
List-I List-II
2
e 1/x , x  0
(p) f x   (1) f(x) is continuous in R
0, x0

(q) f  x  x x (2) f(x) is differentiable in R

(r) f  x   sin 1 sin x (3) First derivative is continuous in R

 2 1
 x sin , x0
(s) f x   x (4) lim f  x  exists
x 0
0, x 0

Codes:
1) p  4,q 1, r 1,s  2 2) p 1,q  2,r  3,s  4
3) p  2,q 1,r  3,s  4 4) p  3,q  4,r  2,s 1
SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

21. If   lim
3 1/3

ex  1  x3   1  x 2 
1/2

 1 sin x
, then the value of
6
is
2
x 0 x sin x 5
22. Let f  x    x   1  x ,  1  x  3 , (here . denotes greatest integer function). The
number of points, where f  x  is non-differentiable is
 max  x , x 2  x 2
23. Let f  x    . Let S be the set of points in the interval  4, 4 at
8  2 x 2 x 4
which f is not differentiable. Then n  S  =
24. The tangent to the curve y  x 2  5x  5 , parallel to the line y  2x  3 , also passes through
1
the point  , k  where k 
8 
25. If the acute angles between the curves y  x 2  1 and y  x 2  3 at their points of
m
intersection be  such that tan   , then number of positive integral factors of m 2 is
7
equal to
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PHYSICS Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. Find the equation of a wave travelling along the positive x-axis, whose snapshot at t = 0
as shown in figure

 
1) y  sin  kx  t   2) y  sin  kx  t  
 6  6
 
3) y  sin  t  kx   4) y  sin  t  kx  
 6  6
27. A wire of linear mass density 10 2 kgm 1 passes over a frictionless light pulley fixed on the
top of a frictionless fixed inclined plane which makes an angle of 30° with the horizontal.
Masses m and M are tied at two ends of wire such that m rests on the inclined plane and
M hangs freely vertically downwards as shown in the figure. The entire system is in
equilibrium and a transverse wave propagates along the wire with a velocity

 
of 100ms 1. g  10 m / sec 2 . Then choose the correct option

m 1 m
1) M  5kg 2)  3) m  20kg 4) 4
M 4 M

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28. y-x curve at an instant for a transverse wave travelling along x axis on a string is shown.
Angle made by tangent with horizontal at the point A on the curve is 60, as shown

A) Transverse velocity of the particle at a point A is parallel to positive y- direction if the

wave is travelling along positive x axis.
B) Transverse velocity of the particle at point A is parallel to positive y direction if the
wave is travelling along negative x axis
C) Magnitude of transverse velocity of the particle at point A is greater than wave speed
D) Magnitude of transverse velocity of the particle at point A is lesser than wave speed
1) Only A, C are correct 2) Only B, D are correct
3) Only A, D are correct 4) Only B, C are correct
29. The transverse displacement versus time graph for two waves A and B which travel along
two identical strings having same tension are as shown in the figure. Their average
intensity ratio I A / I B is

9 81 3
1) 2) 1 3) 4)
4 16 2
30. A Circular loop of a string of mass per unit length  and radius R is rotated about an axis
passing through its center and perpendicular to the plane with an angular velocity . A
small disturbance is created in the loop in the same sense of rotation. The linear speed of
the disturbance for a stationary observer is:
1)  R 2) 2R 3) 3 R 4) Zero
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31. Two identical pulses in a stretched string whose centres are initially 8 cm apart are
moving towards each other as shown in figure. The speed of each pulse is 2cm/s After 2s
the total energy of the pulses will be

1) zero 2) purely potential

3) purely kinetic 4) Partly kinetic and partly potential
32. The equation of a transverse wave travelling along a string is
y  x, t   4.0sin(40 103 x  600t)mm , where x is in the mm and t is in second. The

velocity of the wave is:

1) 15m / s 2) 15m / s 3) 30m / s 4) 30m / s
33. The transverse displacement y  x, t  of a wave on a string is given by

y  x, t   e

 ax2 bt 2  2 abxt . This represents a
a
1) Wave moving in +ve x direction with speed
b
b
2) Wave moving in –ve x direction with speed
a
3) Standing wave of frequency b
1
4) Standing wave of frequency
b
34. A wire of variable mass per unit length    0 y , is hanging from the ceiling as shown in
the figure. The length of the wire is L0. A small transverse disturbance is produced at its
lower end. The time after which the disturbance will reach the other end is

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2L0 8L0 L0 12L0

1) 2) 3) 2 4)
g g g g
35. A plane progressive transverse wave is passing through medium along the positive x-axis
at the given instant of time. The nature of the displacement-position (y vs x) graph of
particles of medium at that instant is as shown in figure. Which of the following
statement are correct. (Consider A,B,C are three particles of the vibrating string)

A) Elastic potential energy per unit length of the string at the point B is more than that at
points A and C
B) Elastic potential energy per unit length of the string at the point C is more than that at
points A and B
C) Velocity of the particle at A is along negative y-axis.
D) Velocity of the particle at C is along positive y-axis.
1) Only B,C,D are correct 2) Only A,C,D are correct
3) Only A,C are correct 4) Only A,D are correct
36. An open organ pipe is vibrating in its fifth overtone. The distance between two

consecutive points where pressure amplitude is 1 time pressure amplitude at pressure

2

antinodes, is 40 cm. Then the length of open organ pipe is (neglect end correction)
1) 3m 2) 3.6 m 3) 4.2 m 4) 4.8 m

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37. In the figure are shown, two strings. Linear mass density of string 2 is nine times that of
string 1. Tension in both the strings is same. A transverse wave in string 1 is incident at
the boundary. Part of waves is reflected in to medium 1 (i.e. string 1) and part is
transmitted in medium 2(i.e string 2). If A,v,I and P represent amplitude, speed of wave,
intensity and power, ,Match the Column I with Column II and mark the correct option (
A1 , V1 , I1 , P1 are the respective parameters for reflected wave and A2 , V2 , I 2 , P2 are the
respective parameters for the transmitted wave)

COLUMN-I COLUMN-II
I) | A1 / A2 | P) 9
II) V1 / V2 Q) 1
III) I1 / I 2 R) 3
IV) P2 / P1 S) Data insufficient
T) 1/3
1) I  Q, II  R, III  S , IV  R 2) I  S , II  T , III  P, IV  R
3) I  Q , II  R , III  S , IV  T 4) I  P, II  R , III  Q , IV  T
38. A string is clamped at both the ends and it is vibrating in its 4th harmonic. The equation of
the stationary wave is Y  0.3sin  0.314x  cos  200t  . The length of the string is (All
quantities are in SI units)
1) 20 m 2) 80 m 3) 40 m 4) 60 m
39. A sound source is situated in a medium of bulk modulus 1.6  105 N / m 2 . The equation for
the wave emitted from it is given by y  A0 sin  7.5 x  3000 t  ; (where x is in m and t is in
s). Then velocity of wave is v and the displacement amplitude of the waves received by
the observer standing at a distance 5 m from the source is A. The density of medium is  .
The maximum pressure amplitude as observed by the observers ear is 30 Pa. The
intensity of wave received by the observer is I. Then choose the incorrect option
4
8
1)   1kg / m 3 2) v  400m / s 3) A  10 m 4) I  W / m 2
4 9

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40. A closed organ and an open organ tube filled by two different gases having same bulk
modulus but different densities 1 and  2 respectively. The frequency of 9th harmonic of
closed tube is identical with 4th harmonic of open tube. If the length of the closed tube is
10 cm and the density ratio of the gases is 1 :  2  1:16, then the length of the open tube
is:
20 15 20 15
1) cm 2) cm 3) cm 4) cm
7 7 9 9
41. Given below are two statements: one is labelled as Assertion A and the other is labelled
as Reason R
Assertion A: A sound wave has higher speed in solids than gases
Reason R: Gases have higher value of Bulk Modulus than solids.
In the light of the above statements, choose the correct answer from the options given
below
1) Both A and R are true and R is the correct explanation of A
2) A is false but R is true
3) Both A and R are true but R is NOT the correct explanation of A
4) A is true but R is false.
42. Statement-1: If oil of density higher than of water is used in place of water in a resonance
tube experiment, the frequency of vibrating air Colum decreases.

Statement-2: The Frequency of vibrating air Colum in the resonance tube experiment is
independent of nature of the liquid taken in the tube.
1) Both Statement-1and statement-2 are true
2) Both Statement-1and statement-2 are false
3) Statement-1 is true and statement-2 is false
4) Statement-1 is false but statement-2 is true.
43. Assertion A: Sound waves cannot be polarised.
Reason R: Only transverse waves can be polarised.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true but R is NOT the correct explanation of A
3) A is false but R is true
4) A is true but R is false.

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44. Statement-1: The change in air pressure at constant temperature effects the speed of
sound.
Statement-2: The speed of sound in gases is proportional to the square root of absolute
temperature.
1) Statement-1and Statement-2 are TRUE and STATEMENT 2 is the correct explanation
of Statement-1
2) Statement-1and Statement-2 are TRUE and STATEMENT 2 is not the correct
explanation of Statement-1
3) Statement-1 is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE but STATEMENT-2 is TRUE.
45. The amplitude and phase of a wave that is formed by the superposition of two harmonic
2
travelling waves, y1  x, t   4 sin  kx   t  and y2  x, t   2sin  kx  t  
 , are :
 3 

(Take the angular frequency of initial waves same as )

2   
1)  6,  2)  6,  3)  3,  4)  2 3, 
 3   3  6  6
SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46. A sample of oxygen at NTP has volume V and a sample of hydrogen at NTP has the
volume 4V Both the gases are mixed and the mixture is maintained at NTP. If the speed
of sound in hydrogen at NTP is 1270 m/s, the speed of sound in the mixture is x m / sec
then x is___
47. In the resonance experiment, two air columns (closed at one end) of 100 cm and 120 cm
long, give 15 beats per second when each one is sounding in the respective fundamental
modes. The velocity of sound in the air column is x m / sec then x is___
48. Two harmonic waves moving in the same direction superimpose to form a wave x = a cos
(1.5t) cos (50.5t) where t is in seconds. The period with which they beat is
 x  sec then x is
3

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49. A thin string of density 0.1 kg/m is held at one end and the other end is oscillated
according to the equation y  l  0, t   20  cm sin  40t  where t is in seconds and l in cm is
the coordinate along the length of the string. The string is under a uniform tension of
40
10N. The string passes through a bath filled with kg of water. Due to wet friction,
21
heat is transferred through the bath and a snapshot at sometime is given in figure. After 

second the temperature of the bath rises by one kelvin. Then find the value of  [specific
heat capacity of water =4.2kJ/kg-K]

(where A is the amplitude of the wave on the string before entering the tub and A is the
2

amplitude of the wave on the string after coming from the tub)

50. Two sound waves of frequencies 100 Hz and 102 Hz and having same amplitude ‘A’ Are
interfering A detector which can detect waves of amplitude greater than or equal to A is
kept at rest. In a time interval of 12 seconds, find the total duration (in sec) in which
detector is active.

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CHEMISTRY Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. The set of meta directing functional groups from the following sets is
1) CN ,  NH 2 ,  NHR, OCH 3 , CH 3 2) CN , CHO,  NHCOCH 3 , COOR, CH 3
3)  NO2 ,  NH 2 , COOH , COOR, CH 3 4)  NO2 , CHO,  SO3 H , COR, COOH , COOR
52. Arrange the following in increasing order of reactivity towards nitration
A) p-xylene B) Bromobenzene C) mesitylene D) nitrobenzene E) benzene
F) Cyano Benzene
Choose the correct answer from the options given below:
1) F  C < D < E < A < B 2) D < F  B < E < A < C
3) F  D < C < E < A < B 4) C < D < E < B < A  F
53. Which of the following is incorrect?
1) dipole moment    : CH3 F  CH3Cl  CH3 Br  CH3 I
CH 3

Ph Cl Ph
Zn ,  Me
 
C C
Ph Cl
Me Ph (Major)
CH 3
2)
Ph

Ph Ph
H 3C Cl
NaI , acetone
  C C

Cl CH 3
H 3C CH 3
(major)
3) Ph

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CH 3

Ph H Ph CH 3
alc . KOH
  C C

Ph Br
H 3C Ph
(major)
CH 3
4)
54. Given below are two statements:
Statement I: Generally in S N 2 reaction inversion of configuration takes place.
Statement II: SN 1 reactions generally result in formation of intermediate as carbocation
In the light of the above statements, choose the correct answer from the options given
below.
1) Statement I is false but Statement II is true.
2) statement I is true but Statement II is false.
3) Both Statement I and Statement II are false.
4) Both Statement I and Statement II are true.
55. Given below are two statements: one is labelled as
Assertion (A)and the other is labelled as reason (R).
Assertion (A): Haloalkanes react with KCN to form alkyl cyanides as a main product
while with AgCN form isocyanide as the main product.
Reason (R):KCN and AgCN both are highly covalent compounds.
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both (A) and (R) are correct and (R) is the correct explanation of (A)
2) (A)is not correct but (R) is correct.
3)Both (A) and (R) are correct but (R) is not the correct explanation of (A)
4) (A) is correct but (R) is not correct
56. Assertion A: Hydrolysis of an alkyl chloride is slow reaction but in the presence of NaI,
the rate of the hydrolysis increases.
Reason R: leaving group ability order: F   Cl   Br 1  I  .
In the light of the above statements, choose the correct answer from the options given
below.
1) A is false but R is true
2) A is true but R is false
3) Both A and R are true but R is not the correct explanation of A
4) Both A and R are true and R is the correct explanation of A.
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57. Given below are two statements:
Statement –I: High concentration of strong nucleophilic reagent with secondary alkyl
halides which do not have bulky substituents will follow S N 2 mechanism.
Statement –II: A Tertiary alkyl halide when treated with a large excess of ethanol
follows SN 1 mechanism.
In the light of the above statements, choose the most appropriate from the options given
below.
1) Both Statement I and Statement II are false.
2) Both statement I and Statement II are true.
3) Statement I is false but Statement II is true.
4) Statement I is true but Statement II is false.
58. Match List I with List II.
List I (Reaction) List II (Name of the reaction)
A. Cl C2 H 5 I. Fittig reaction

Na
+C2H5Cl 

Dry Ether

B. Cl II. Wurtz-fittig reaction

Na

Dry Ether


C. N +2 Cl- Br III. Swart’s reaction

Cu Br
2 2
 + N2

D. CH 3  Br  AgF  CH 3 F  AgBr IV. Sandmeyer reaction

Choose the correct answer from the options given below:
1) A- III, B- II, C- IV, D- I 2) A- II, B- I, C- IV, D- III
3) A- IV, B- II, C- III, D- I 4) A- II, B- I, C- III, D- IV

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59. The correct decreasing order of densities of the following compounds is
F

(E)
1) D  E  C  B  A 2) D  C  E  B  A
3) E  D  C  B  A 4) D  C  B  E  A
60. The correct order of the following compounds showing increasing tendency towards
nucleophilic substitution reactions is

1)  v    iv  <  iii  <  ii  <  i  2)  iv  <  i  <  ii  <  iii    v 

3)  i  <  v  <  ii    iii  <  iv  4)  iv  <  i  <  iii  <  ii    v 

61.


H
HO   B:B is (major product)

1) 2) 3) 4)
62. In sulphonation, acylation, nitration and alkylation of benzene the group of effective
electrophiles would be:
 
1) SO3 , CH 3  C  O , NO2 , R  2) SO3 , CH 3 C O , NO2 , R 

3) SO3 , CH 3  COCl , NO2 , R  4) SO3 , CH 3CHO, NO2 , R 

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63. Arrange the following in decreasing order of reaction with Cl2 / AlCl3 :

1) Q  R  P 2) P  Q  R 3) R  Q  P 4) R  P  Q
64.
O

Ph-C-Cl/AlCl3
H2O
 Major product of the reaction is

Ph

O O Ph
1) 2)

O Ph

Ph

3) 4) O
65.
H
O
N

Cl2 +Fe Cl3

  Major product of the reaction is

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H
O H
O
N
N

1) Cl 2) Cl

H H
O O
N N

Cl

3) Cl 4)
66. The hydrolysis of
H3C H CH 3

H 3CO NO 2

H Br CH3

In aqueous acetone gives:

Where
H 3C H CH 3

K = CH3O NO 2 ;

H OH CH 3

Where
H3C H CH 3

L = H3CO NO 2 ;

OH H
CH 3

H 3C CH 3 CH
3

M = H 3CO NO 2

H CH 3 OH

1) K and L 2) Only K 3) L and M 4) Only M

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67. In nitration of benzene by mixed acid  conc.H2SO4 + conc.HNO3  the rate of reaction will
be:
1) C 6 H 6 = C 6 D 6 = C 6 T6 2) C 6 H 6  C 6 D 6  C 6 T6
3) C 6 H 6  C 6 D 6  C 6 T6 4) C 6 H 6  C 6 D 6  C 6 T6
68.
Br
Ph Ph
2 AgBF
4
  x  2BF4 ;compound  x  will be :
Ph Ph
Br
Ph Ph Ph Ph

2 2

Ph Ph
1) Ph 2) Ph

Ph Ph Ph
Ph
1 1

Ph Ph
3) Ph 4) Ph
69. Which of the following molecules is expected to have the greatest resonance
stabilization?

1) 2)

3) 4)
70.
O

AlCl3  
Zn Hg H 3PO4
O    A  
Conc.HCl
  B     C ;

O
 succinic anhydride

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Product (C) of the above reaction is:
O

1) 2)
OH
OH

3) 4)

SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. Each of the compounds shown below has two aromatic rings, labelled as A and B.
Identify number of compounds in which ring B is more active than ring A for
electrophilic aromatic substitution reaction

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72. Identify the number of Aromatic compounds or ions

73.
SH O SH HO

HO HO
Cl
1.'X' CH3MgBr
Cl 2.H3O+

HO
O
Find out the value of ‘X’
74. Identify number of reactions that can be give benzene as major product.

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75.
SO 3H

H  ,steam

A 

Cl2 / FeCl3
S
Excess

A
Cl2 / hv
J
Excess

The molecular weight difference between J and S is x. Then the value of x is?

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