Sri Chaitanya IIT Academy., India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
Sec: Jr.Super60_NUCLEUS BT 2022_P2 Date: 10-08-2025
Time: 02.00Pm to 05.00Pm CTA-10 Max. Marks:180
MATHEMATICS : Functions
PHYSICS : Law of Conservation of Linear Momentum (Complete),
Collisions (Complete)
CHEMISTRY : Chemical Bonding, Gaseous State

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 10-08-2025_Jr.Super60_NUCLEUS BT_Jee-Adv(2022-P2)_CTA-10_Q. P
JEE-ADVANCE-2022-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice +4 -2 6 24
Sec – II(Q.N : 27 – 32)
with partial mark
Sec – III(Q.N : 33 – 36) Questions with Single Correct Choice +3 -1 4 12

Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 44) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice +4 -2 6 24
Sec – II(Q.N : 45 – 50)
with partial mark
Sec – III(Q.N : 51 – 54) Questions with Single Correct Choice +3 -1 4 12

Total 18 60

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MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
1. Let f be a real valued function defined on R (the set of all real numbers) such that
f 1  f  1  5 and whose graph of f is symmetrical with respect to the lines x  1 .
99 99 150
 r   r   r  150   r 
Given  f   10 and
 100 
 f   5 . If S   f 
 100 
  f   . Then
r  50 r  50 r  50  100  r  50  100 

S
the value of is
8
2. Given that f  x  is a function defined on R, satisfying f 1  1 and for any

x  R , f  x  5   f  x   5 and f  x  1  f  x   1 . If g  x   f  x   7  x , then

g  2023  is equal to__________

If the range of the function f  x   24 x  5  16 x , ( 

2
3. . denotes fractional part of x )
is  a , b  then the value of b 2  a is equal to______
4. f  x  be a real values function defined on the interval  2, 2  as follows
 1 if 2  x  1
 1
f  x    x  2 if 1  x  1 then number of solutions of the equation  f  x   is,
1  x if 2
 1 x  2
(where  f  x   denotes fractional part of f  x  )
5. The number of integer(s) in the domain of
1  1 1
1
2 2
   4x   x 2015  2015 x   is/are________, where .
sin  cos 2015 x    2015 x

and 
. represents Greatest integer function and fractional part function respectively

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6. If the minimum value of f  x   sin 2014   x   2cos ec 2014   x  is m, then  m 

is________, where   represents greatest integer function
7. If the periodic function f  x  satisfies the equation f  x  1  f  x  1  3 f  x  x  R
and the fundamental period of f  x  is 6 then  

3x 2  mx  n
8. Let f : R  R and f ( x)  . If the range of this function is [-4,3), then the
x2  1
m2  n2
value of is_________
8
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.

 x2  6x  8
9. A function f : R  R , is defined by: f  x   ,  R
  6 x  8x2
A) for    2,14  , f is onto B) for   3, f is not one one

C) for   3, f is one one D) f is onto for all   R

10. f : R  [1, ) and f  x   ln  sin 2 x  cos 2 x  (where . is the greatest integer

function). Then which of the following is/are correct?

A) f  x  has range Z


B) f  x  is periodic with fundamental period
4
 
C) f  x  is invertible in 0, 
 4
D) f  x  is into function

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 1
1  x5 , x  0   x  1 5, x0
11. Let f  x    and g  x    1
. Then which of the following
4
 x  1, x  0  x  1 4 , x  0

is/are correct?
A) gof  x   x for x  R
B) fog  x   x for x  R

 x,   x  1
 1

 
5 4
 2  x , 1  x  0
C) gof  x   
1
 4

 x 2 , 
5 0  x 1

 x, 1 x  
D) gof  x  is a bijective function from R to R
12. If the function f(x)=ax+b has its own inverse then the ordered pair (a,b) can be:
A) (1,0) B) (-1,0) C) (-1,1) D) (1,1)
13.  
If a function satisfies  x  y  f  x  y    x  y  f  x  y   2 x 2 y  y 3 , x, y  R and
f 1  2, then
A) f  2   6 B) f  x  must be polynomial function
C) f  0   2 D) f  3   12
2 4x  
14. f :[1, )  [a, ) defined by f  x   22 x ; g :  ,     c, d  defined by
2 
cos x  3
g  x  are two invertible functions which of the following is/are true
cos x  2
4  16  8log 2 x
A) f 1  x  
4
 1 
B) Range of function h  x   4ax 2  2cx  d , x  R is   ,  
 4 
1
C) Value of c is
3
1
D) value of a is
4
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SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
15. If the complete set of values of ' x ' satisfying the inequality
 1 1  1 
 log 2 x 2  5 log 2 x  6  2 5 is  ,    , c   b, a  (where a, b, c  N ), then value
a b c 
of a  b  c is
A) 0 B) 140 C) 136 D) 272
16. Let f  x   2 x  2  x  ,0  x  2 . If the number of roots and sum of all roots of equation

x

f f  f  x    2
are equal to ' a ' and ' b ' respectively, then  b  a  is equal to_______

A) 13 B) 14 C) 15 D) 16
17. For the real number x, let  x  denote the greatest integer less than or equal to x . Let

f : R  R be defined as f  x   2 x 
 x x2  1
 1
  
   x   sin x.cos x, then f is
 4 x4  x2  1 8 
  
A) one-one but not onto B) onto but not one-one
C) both one-one and onto D) neither one-one nor onto

18. f  x    x   x  1   x  2  .....   x  99 , then  f

  2   ____
 where [.] is G.I .F & . is F .P.F 
A) 5050 B) 4950 C) 41 D) 14

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PHYSICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
19. A boy of mass m is standing at one end of a long boat of length  and mass 4m which is
floating motionless on a calm lake. The boy walks to the other end of the boat and stops
with respect to boat. The boat moves for some more time and stops due to water
resistance. If the force due to water resistance is proportional to speed of the boat, the
magnitude of displacement of the boat from the beginning upto the time boat stops finally
n
is . Find the value of n
10
20. A ball of mass m moving with velocity u makes a head on elastic collision with another
identical ball initially at rest. The maximum energy of deformation of the striking ball
mu 2
during the collision is . Find the value of k .
k
21. A smooth inextensible string of length  is tied at supports A and B which are at the same

horizontal level and separated by a distance . A small bead is released from A to move
2
on the string. The speed of the bead immediately after the string becomes taut is
g Tan370
. Find the value of n .
n

22.
A block of mass m is placed on the rough surface of a plank of mass 7m . Both are
connected through a spring of force constant k and the surface below the plank is
smooth. When the spring is in relaxed state, the block is given velocity v towards right.
The block compresses the spring by x and stops on the plank completely without
24kx 2
reversing. If the maximum value of v is , determine the value of n .
nm

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23. Two small balls A and B of mass m and 2m respectively are connected by a string of
length  and kept on a smooth horizontal surface with a separation of  between them.
Ball A is given vertically upward velocity u so that ball B just loses contact with the
surface subsequently. If the value of u is kg  , what is the value of k ?
24. The two ends of a flexible rope of mass m and length  with uniform distribution are
attached to the ceiling close to each other. When one of the ends is released and falls
 7mg
through a distance , the force acting on the ceiling is . Find the value of n .
n 8
25. A small ball of mass m is kept inside a thin cubical box of side length  and mass m .
The inner surface of the box is smooth. The box is placed on horizontal surface having a
 
thin layer of oil with resistive force on the box F  kv where v is the velocity of the
box in m/s and F is in Newton. When the ball is near the left wall of the box, it is given a
velocity of 5 m/s towards right. If all the collisions are elastic, m  4 kg ,   3m and
k  2 kg / s , find the number of collisions between the ball and the box.

26. A smooth solid hemisphere of mass m and radius R is placed on a smooth horizontal
surface. A small block of same mass m is kept at the top and slightly disturbed. When
the block slides down by angle  from the vertical line passing through the centre of the
hemisphere, it loses contact with the hemisphere. If the final speed of the hemisphere v
gR cos x 
is given as , find the value of x  y
y


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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
27. A ball X of mass 2m and radius R moving with velocity u makes oblique collision with
another ball Y of mass m and radius R in free space. After elastic collision, ball X
deviates by maximum possible angle from the initial direction. Which of the following
are correct after the collision?
u
A) Speed of ball X is
3
2u
B) Speed of ball Y is
3
C) Angle of divergence between the paths of X and Y is 600
D) Angle of divergence between the paths of X and Y is 900
28. Consider a cart at rest on a frictionless surface that can hold a full tank of water. A fire-
hose sprays water with a constant ejection speed Vw (wrt cart) at a constant mass rate
dm
r and the hose pipe makes an angle  with the horizontal. If the total initial mass
dt
of cart with water is M and spraying starts at t=0,

Vw

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A) The acceleration at any time t of the cart while it is spraying water is given by
Vwr cos
M  rt
V rt cos
B) The speed of the cart as a function of time during spraying is w
M  rt
 M 
C) The speed of the cart as a function of time during spraying is Vw cos n  
 M  rt 
D) If the cart is kept stationary while spraying water the external horizontal force that
must be applied to the cart is rVw cos
29. Two particles of masses m1 and m2 moving with velocities 1 and 2 along the same
m1m2
direction collide head-on. If   , v1  v2 and e is the coefficient of restitution,
m1  m2
which of the following are correct?
1
 1  2  1  e 
2 2
A) The loss of kinetic energy of the system due to collision is
2

B) The loss of kinetic energy of the system due to collision is

1
2

 1  2  1  e2
2

C) The magnitude of change in momentum of each particle is  1  e 1   2 
D) The magnitude of change in momentum of each particle is  1  e 1   2 
30. Two masses A and B are connected by a spring. A has mass M , B a mass 2M , and the
spring has a negligible mass. The spring is compressed so that the potential energy stored
in it is V0 . The system is placed on a horizontal frictionless surface and is given a
velocity ukˆ in the z-direction as shown, and the spring is released.
M ˆ
A uk x

ukˆ iˆ

Initial
z
k̂
potential
B ukˆ
energy  V0
2M
Initial velocity

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A) In the subsequent motion the line from B to A always points along the iˆ unit vector.
B) At maximum elongation of the spring, the potential energy stored in it is V0
C) At some instant of time B is at point P and has a component of velocity in the x-
direction of  xiˆ . At that instant of time, in terms of the given quantities, the velocity
 
vector  A of A is  A  2 xiˆ  ukˆ
D) In subsequent motion A and B undergo circular motion about centre of mass.
31. A sphere of mass m makes a head-on elastic collision with a sphere of mass 2m initially
at rest. The velocity of the first sphere before and after collision is given to be u1 and 1 .
Then which of the following statements are correct?
A) The maximum deformation energy during the collision is 3mv12
8
B) The fractional loss in kinetic energy of the first sphere due to collision is
9
C) The kinetic energy of the second sphere keeps increasing during the collision.
D) The sum of kinetic energy of the spheres remains constant at every instant during the
collision
32. Two balls of same radius and masses M and 3M collide moving on a horizontal
frictionless surface  xy plane  as shown. Before the collision the mass M has a velocity
 5
1 in the y  direction. The mass 3M has a velocity  0 making an angle   370 to
 12 
the x  axis as shown. After the collision the mass 3M comes to rest and the mass M
moves along the x  axis with the velocity 1 ' .
y
5

3M 12 0

 3M M
x 1 '
Before After

1
M

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5M 0
A) The impulse on M is
4
B) The angle between x -axis and impulse on M is 37 0
M 02
C) The loss of kinetic energy of the system due to collision is
24
12
D) Coefficient of restitution e 
13
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
33. Three masses are connected with a spring of force constant K and a string as shown.
They are initially at rest, with spring at its natural length and string too at its original
length. Find the maximum extension in the spring after the forces start acting as shown:
F
F 3F
m m 2m

A B C
2F 5F F 4F
A) B) C) D)
K 2K 2K K
34. A ball of mass m is suspended from a light string of length L attached to a cart of
mass 3m which can move freely on frictionless horizontal rails. If the ball is
 
given an initial horizontal velocity  0  gL ,while the cart is at rest, the
maximum vertical distance H through which the ball will rise from initial level is

0

02 02 02 302

A) B) C) D)
2g g 4g 8g

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35. From what minimum height h must the system be released when spring is unstretched so
that after perfectly inelastic collision  e  0  with ground, B loses contact with the
ground? Spring constant is k and no collision takes place between A and B.
m A

2m B

mg 4mg mg 3mg
A) B) C) D)
4k k 2k k
36. A ball of mass m collides horizontally with a stationary wedge on a rough horizontal
surface, in the two orientations as shown. Neglect friction between ball and wedge. Two
students comment on the momentum of the system of ball and wedge just before and just
after the collision.
y
m m
m m
x
Rough Rough
(I) (II)

Saurav : Momentum of system in x  direction will change by significant amount due to

collision in both cases.
Rahul : There are no impulsive external forces in y  direction in both cases hence the
total momentum of system in y  direction will not change due to collision
A) Saurav is wrong and Rahul is correct
B) Saurav is correct and Rahul is wrong
C) Both are correct
D) Both are wrong
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CHEMISTRY Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
37. Consider the following orders:
1) H 2 SO4  H 2 SO3 : Boiling point 2) H 2O  HF : Extent of H-bond
3) H 2O  H 2O2 : Strength of H-bond 4) HF  HCl  HBr : Melting point
5) CH 3 F  CH 3Cl  dipole moment 
Then calculate value of x (where ' x ' is total number of correct orders.)
38. Among the following the number of compounds/ions having a linear structure is
C3O2 , N 3 , XeF2 , I3 , IF2 , CO2 , O3 , N 2O, NH 2
39. Consider the following compounds:

1) H 3CF 2) H 2CF2 3) CH 4 4) CH 3
5) C2 H 4
And calculate value of Y  X , (where X is the total number of compounds which have

H  C  H bond angles equal to 1090 28' and Y is the total number of compounds
which have H  C  H bond angles greater than 1090 28' and less than are equal to1200 ).
40. Consider two covalent compounds ALn1 and BLn2 , if central atom (A) of first

compounds has total six electron pairs and central atom (B) of second compound contains
total five electron pairs in its valence shell and both compounds are planar and non-polar

then calculate value of expression  n1  n2  . [where n1 and n2 are number of

2

monovalent surrounding atom (L)]

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41. One litre of N 2 and 2 litre of O2 under identical conditions of T and P are mixed. Find
the volume (in L) of mixture if the pressure of the mixture is reduced to half of initial
value.

42. The gas ‘A’ decomposes as A 

 B  5C

A partially decomposed gaseous mixture is allowed to effuse through a pin hole and the
gas coming out initially was analysed. The mole fraction of C in effused gas was found to
be 0.6. Determine:
a) ratio of rate of effusion of ' C ' and ' B ' ,
b) the percentage of dissociation of ‘A’. (Give answer excluding the decimal places)
[Given : molecular mass of A = 360,
Molecular mass of B = 160,
Molecular mass of C = 40]

Hence, fill OMR with answer of (a) and (b) with the value of
b .
a
43. 4 mole of A are mixed with 4 mole of B when 2 mole of C are formed at equilibrium,
 C  D . Then what will be the equilibrium constant.
according to the reaction, A  B 
44. At constant temperature equal volumes of HCl and NH 3 are present at 2 atm pressure
each. If both the vessels are connected, then total pressure of the mixture is.
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
45. Which of the following statements are correct-
A) Bond angle in ClO2 is greater than Cl2O
B) Bond order in NO3 is approximately equal to 1.33
C) HCl  H 2 S  order of dipole moment 
D) H 2 is lesser stable than H 2
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46. N 2O has a linear, unsymmetrical structure that may be thought of as a hybrid of two
resonance forms. If a resonance form must have a satisfactory Lewis structure, which two
of the structures shown below are the two resonance forms of N 2O ?
N  N O N  N O N  N O N  N O
A) B) C) D)
47. Which of the following statements is/are true?
A) Covalent bonds are directional
B) Ionic bonds are non-directional
C) A polar covalent bond can be formed between two atoms of same electro negativity
value
D) The presence of polar bonds in a polyatomic molecules do not suggests that it should
have zero dipole moment
48. In which of the following case(s) pressure of gas is less or equal to atmospheric pressure?

A) B)

C) D)
49. At the same temperature and pressure, which of the following will have same kinetic
energy per mole as N 2O ?
A) He B) H 2 S C) CO2 D) NO2
50. Select the correct options(s).
Container-I Container-II
Valve

300 K 400 K
2 mol H 2 1 mol H 2
16.42 lit. 8.21 lit.

A) Pressure in container – I is 3 atm before opening the valve.

B) Pressure after opening the valve is 3.57 atm
C) Moles in each compartment are same after opening the valve
D) Pressure in each compartment are same after opening the valve
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SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
51. In the figure shown the pressure of the confined gas will be:

A) 30 cm of Hg B) 40 cm of Hg C) 36 cm of Hg D) 46 cm of Hg
52.

Total pressure at point (X) is:

A) 0.5 atm B) 1 atm C) 1.8 atm D) 1.5 atm
53. In which of the following cases, the strength of back bonding is the maximum?
A) PF3 B) BF3 C)  H 3 Si 3 N D)  SiH 3 2 O
54. Correct order of C  O bond order:
A) CO   C2O42   CO2 B) CO   CO2  C2O42 
C) CO2  CO   C2O42  D) C2O42   CO2  CO 

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