Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60(Incoming)_STERLING WTA-29 Date: 20-04-2025
Time: 09:00AM to 12:00PM JEE-ADV-2022_P1 Max: Marks: 180

KEY SHEET
MATHEMATICS
1 3 2 3 3 6.5 4 5 5 4 6 9

7 288 8 6561 9 BCD 10 BC 11 AC 12 ABC

13 BC 14 AD 15 A 16 A 17 A 18 D

PHYSICS

19 4 20 8 21 81 22 54 23 18 24 11

25 20 26 20 27 ABCD 28 ABC 29 ABCD 30 AD

31 ABD 32 AC 33 B 34 A 35 B 36 C

CHEMISTRY
37 1000 38 84 39 12-12.5 40 390-391 41 56 42 1

43 5790 44 760 45 ABC 46 ACD 47 BC 48 AC

49 A 50 D 51 A 52 A 53 C 54 A
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s

SOLUTIONS
MATHEMATICS
1
1 2
x2  1 x dx
1.  dx  
x4 x3
1
put1  2  t 2
x
   t 2 dt
t3
 c
3
1
1 1 2
  1  2   c
3 x 

x3  x x3 x
2. 
x 9
4
dx   x 9
4
dx   4
x 9
dx

1 1 2x
 log x 4  9   dx
x 2   3  
2
4 2 2

1 1 1

log x 4  9   2 2 dt
4 2 t 3
1 1 1 t 3
 log x 4  9   log C
4 2 2(3) t 3
1 1 x2  3
 log x 4  9  log 2 C
4 12 x 3
1 22
A/ B   3
4 1


 
cosx 1  4 1  2sin 2 x  dx

sinx 1  4cos 2 x 


cosx 5  8sin 2 x  dx
sinx  5  4sin x  2

put sin x  t  cos x dx  dt

3.
5  8t 2
 dt

t 5  4t 2 
1 4t 
   2 
dt
 t 5  4t 
1
 log t  log 5  4t 2  c 
2

Sec: Sr.Super60(Incoming)_STERLING Page 2

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
1
I  log sinx  log 5  4sin 2
2
1
 log sinx  log 1  4cos 2 x
2
1
 log sinx  log sin 2 x  5cos 2 x  c
2
1
 P  1, Q  , R  5
2
1
P  Q  R  1   5  6.5
2

4. We have,

5  x10
I  dx
16
x
5  x10 1
 I   dx
10
x x11
1 5 50
 I  1  dx
50 x10 x11
1 5  5 
 I   1 d 1  
50 10 10
x  x 
3/2 3/2
1 2 5  1 5 
 I    1    C   1   C
50 3  x10  75  x10 
1
 a
75

dx
5. 

cos x 1  cosec2 x
2

sec 2 x
 dx
2  cot 2  x

Sec: Sr.Super60(Incoming)_STERLING Page 3

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
put tanx  t
 set 2 xdx  dt
1
dt 
1
2 2
t
v
t
 2 dt
2t  1
1 2t 2  t  1 1 1 
  dt   t   2 dt 
2 2t  1
2
2 2t  1 
1 1 
 t   dt 
2 1  ( 2t ) 2

1
 t  tan 1 2t  c
2
  
tan 1
1
 tan 2 
2
 2

2tan  C  

3x 2  1
6. f  x   dx
x 
3
2
1



 x2 1  dx   4 x2
dx
   
3 3
x2 1 x2 1
 
1 4x
   x  dx

 x2 1
   
2 3

 x2 1 
 
dx  4x 4 xdx
  x   ( x) 
'
dx  dx
  
 
  
2 3 3
x 1
2
x 1
2
 x 1
2

 
1 
 x C

 x2 1 2 
  
x
 C
 
2
x2 1
f 0  0  C  0
x
 f  x  
x 
2
2
1
2
Now, f  2   
9

Sec: Sr.Super60(Incoming)_STERLING Page 4

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
7.
  
1/3
Let I   x9  x 6  x 3 2 x 6  3x3  6 dx

  x  x  x  1 2 x  3x  6 
1/3
3 6 3 6 3
dx

  x  x  x  1 2 x  3x  6 x 
1/3
2 6 3 9 6 3
dx
Put 2 x  3x  6 x  t
9 6 3


18 x8  x 5  x 2 dx  dt 
dt

x 2 x6  x3  1 dx 
18
1 1/3 1 t 4/3
I  t dt   c
18 18 4 / 3

1
 
4/3
I  2 x9  3x6  6 x3 c
24
 a  24
Then, 12a  12  24  288

8.  a 5  b 4  25  4 4  32  256  288
 cos8 x  cos7 x 
Let I     dx
 1  2cos5 x 

  dx
2
x
4e  6e x 4 ex  6
9.  dx  
9e x  4e  x 9ex   4
2

Sec: Sr.Super60(Incoming)_STERLING Page 5

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
4e 2 x 6
  2x dx
9e  4 9e  4
2x

4 18e 2 x 6/9
  2x dx   dx
18 9e  4 4
e  
2x

9
2 2 1
 log 9e 2 x  4   x
dx
9 3 2
 
2
e  
x

3
35 3
  log 9e 2 x  4  x  C
36 2

 A  3Ze x dx  dt

35
A
36

3 35 19
A  
2 36 36
10.
1 sin  b  a 
  dx
sin  b  a  sin  x  a  sin  x  b 
1  cos  x  b  cos  x  a  
    dx
sin  xa   sin  x  b  sin  x  a  
1
 log sin  x  b   log  x  a    c
sin  b  a   

1 sin  x  b 
 log  c
sin  b  a  sin  x  a 
ex  1  2
11.  dx
e4  1
2
 x x dx
e 1

put e x  1  t
 e x dx  dt
2 dt
 x
t t 1
 x  2log 1  e x  2loge x  c
 2log 1  e x  x  c
1 1 
 x  2   dt
 t t 1 
t
 x  2log c
t 1

Sec: Sr.Super60(Incoming)_STERLING Page 6

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s

12.


1

 x       x d
    x      x 

1  x   x 
     dx
    x x   

put x   cos 2   sin 2  dx       sin2

 x        sin 2
  x       cos 2
x 
and   sin 1
 

1
  
 tan 2 dx  cot 2 dx 
  2sin 2 d  2cos 2 d
  2d
 2  c
x 
 2sin 1 C
 

secx  2  secx  f  x
13. If  dx  C
(1  2secx) 2
2  g  x
2cosx  1
I dx
(cosx  2) 2
2cosx  cos 2 x  sin 2 x
 dx
(cosx  2) 2
cosx  2  cosx  sin 2 x
 dx   dx
(cosx  2) 2 (cosx  2) 2
cosx sin 2 x
 dx   dx
2  cosx (cosx  2) 2
sinx sin 2 x sin 2 x
  dx   dx
2  cosx (cosx  2)2  
2
cos 2 x  2
sinx
 C
2  cosx

14. Let cosx  t so, cos2 x  2t 2  1 and dt  sinxdx . Thus,

Sec: Sr.Super60(Incoming)_STERLING Page 7

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
t2  2
I  dt
2t 2  1
1 2t 2  4
  2 dt
2 2t  1
1 3 dt
  dt   2
2 2 2t  1
1 3 1 2t  1
 t  log C
2 2 2 2 2t  1
1 3 2
 cosx  log C
2 4 2 2cosx  1
3 2cosx  1
So, P  1/ 2, Q   , f  x 
4 2 2cosx  1
3 2cosx  1
or P  1/ 2, Q  , f  x 
4 2 2cosx  1

dx dx
15.  

x x 1
n
  1 
x n 1  1  n 
 x 
1
Put 1  t
xn

n
 dx  dt
x n 1
dx 1 dt 1
Then,      ln t
x x 1
n
 n t n

1 1
  ln 1  n  c  S
n x


1
n

ln 1  x n  nln x  c 
1
 ln x  ln 1  x n  c  Q 
n
dx dx
(B)  
x 2  x n  1
 n 1 / n  n 1 / n
 1 
x 2  x n 1  1  n 
 x 
dx
  n 1 / n
 1 
x n 1 1  n 
 x 
1
Put 1  n  t
x

n
 dx  dt
x n 1

Sec: Sr.Super60(Incoming)_STERLING Page 8

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
dx 1 dt
Then,      n 1 / n
 
 n 1 / n n t
x2 x n  1

1
   t  n 1 / n dt
n

  n 1
1
1 t n
  c
n   n  1
1
n
1/ n
 1 
  1  n  c
 x 
 
1/ n
  1  xn  c( T
dx dx
(C)  
 
n 1/ n 1/ n
xn 1  x  1 
x n 1  n  1
 x 
1
Put 1  t
xn

n
 dx  dt
x n 1
dx 1 dt
Then,     1/ n
 
1/ n
x 1 x
n n n t

1
   t 1/ n dt
n
1
 1
1 t n
  c
n  1 
   1
 n 
1 11/ n
 t c
1  n 
1
 
11/ n
 x n  1  c P
1  n 
   
11/ n
1  1 x
n

 c
 
1  n  x n 1

 
1 n
x
 
11/ n
 1  x  c R 
1  n 

Sec: Sr.Super60(Incoming)_STERLING Page 9

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
16.
dx e 2 x 1
I   
e 1 1 e
2x 2 x
dx   ln 1  e2 x  c  R 
2
 
1  1  e2 x 
  ln  2 x   c
2  e 

1
2
  
ln 1  e 2 x  2 x  c 
1

 x  ln 1  e 2 x  c
2

e x dx
(B) I 
e 2x
1 
Put e x  t

 e x dx  dt
Then, I  
t
dt
2
1 

 ln t  t 2  1  c 


 ln e x  (e2 x  1}  c  P 


 ln e x (1  1  e }  c
2 x


 x  ln 1  1  e    c  T 
2 x

dx e x dx
(C) I   
e   
2 2
2x
1 e x e2 x  1

Put e x  tan

 e x dx  sec 2 d
sec 2 d d
Then, I   
tan  sec 4
tan  sec 2


cos3 d


1  sin 2 cos d 
sin sin
Put sin  t

 cosd  dt

Then, I  
1  t 2  dt
t

Sec: Sr.Super60(Incoming)_STERLING Page 10

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
t2
 lnt  c
2
sin 2
 lnsin  c
2
 ex  1 e2 x
 ln     2x c
 e 1  2 e 1
2x
 
1 1 1 
 
 x  ln 1  e 2 x   2 x
2 2  e 1 
  c Q 
1
17. A) put x   t
x
B) put atanx  b  t
 asec 2 xdx  dt
C) put xesinx  t
D) put x  cos (or) sin
18. a  p, q, r; b  p, q, r; c  p, q, r , s; d  p, q, r, s .
x2  x  1 A B C 
a.  dx      2
dx
x  4x  4x
3 2
 x x  2 ( x  2) 
x2 1 A B C D 
b.  dx       3
dx
x( x  2) 3
 x x  2 ( x  2) ( x  2) 
2

x3  1  x 3  1  
c.  dx      1   1 dx
x( x  2)2  x( x  2)
2
 

 x3  1  x ( x  2) 2  
     1 dx
 x( x  2) 2  
 A B C  
     2 
 1 dx
 x x  2 ( x  2)  
x5  1  g  x 
d.  dx    x  k  3
dx ,
x( x  2) 3
 x ( x  2) 
where k is constant  0 and g  x  is a polynomial of degree less than 4

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s

PHYSICS
19. KEY: 4
SOL:
 A
In the figure, c  0
3d

C2  0 A
2d

And C3  0 A
d

Now, C2 is short circuited so that C1 and C3 are in series

20. key : 8
Sol:
Q 1 1 1  1 Q 1 Q 1 Q Q
VA      , Vc    
4 0  b a (a  b)  4 0 b 4 0 2b 4 0 b 8 0b
Q 8 0ab(a  b)
C AC  
V (a 2  2b 2  ab)
21. key: 81
Sol:

Ceq  0 ( K1 A1  K 2 A2 ),Vol  250  20, hliq  20
d
22. key: 54
Sol:

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
1 1 2 1
  
Ceq 6C 27C 9C
1 946

Ceq 54C
54C
Ceq 
19

23. KEY: 18
SOL:
When the switch S is closed, potential difference across both of them is 30 V .
Charges on each of them is

The heat developed in the circuit

24. KEY: 11
SOL:
Apply K V L before and after closing the switch, before q1  c1E , after closing switch
charges Redistribute till potential become same
25. KEY: 20
SOL:

Various charges flow after closing the switch are given as:
q1  60  40  20 C
q2  20  0  20 C
q3  20  0  20 C
26. key: 20
Sol: As charge redistribution doesnot occur charge and potential of each remains same.

27. key: A, B, C, D
Q  ( 3Q)
SOL: The charges on surface (ii), q2  = 2Q
2

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s

(iii) IF the plates are connected, 2Q and 2Q will be neutralized, so 2Q charge will flow
from the left to the right plate.
(2Q)2
(iv) Energy lost = initial energy stored in capacitor
2C
28. KEY: A, B, C
SOL:
Across points 1 and 2 equivalent capacitance can be calculated as
15C
C12  C | P | (C / 2 | S | 4C / 3) 
11
Where |P| and |S| stands for parallel and series combination respectively. Across
point 3 and 6 equivalent capacitance can be calculated as
5C
C36  C / 3 | P | C / 3 | P | C 
3
Across points 1 and 3 equivalent capacitance can be calculated as
4C
C12  C / 2 | P | (C | S | 4C / 3) 
15
29. KEY: A, B, C, D
SOL:
Apply kirchoffs voltage law
30. KEY: A, D
SOL:
When the battery is disconnected Q remains constant
31. KEY: A, B, D
SOL:
Q  nq, R  n1 3r
32. KEY: A, C
SOL:
A A 0
C  0 , C1  , Q  C1V  4  103 C
d ( d 2)
Extension of each spring is d
4
d  Q2
K  F   K  8000 N m
4 2 A 0
33. KEY: B
Q Q2 1 A
SOL: When battery is disconnected q is same, V  ,U  ,u   0E 2,C  0
C 2C 2 d

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
34. KEY: A
SOL:
KQ Q
Vins  ,C 
rad V
KQ
Vout 
dist
35. KEY: B
SOL: C1 and C2 are in series, C3 and C4 are in parallel
Q Q2 1 A
V  ,U  ,u   0E 2,C  0
C 2C 2 d
36. KEY: C
SOL: standard Symmetric circuits

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s

CHEMISTRY
37. Molarity  0.01M ; Resistance  40ohm ;
l
Cell constant  0.4 cm1 .
A
cell constant 0.4
Specific conductivity (  )    0.01ohm 1 cm 1
resistance 40
1000 1000  0.01
Molar conductance  Λ m     103 ohm 1 cm 2 mol1
Molarity 0.01
56
38. Fe2  2e  Fe; EFe   28
2
1 Faraday liberates  28 g of Fe
3 Faraday liberates  3  28  84g
39.
K
 m  1000 
M
2  105
 1000   20 Scm2mol 1
0.001
 20  2 
  m   

 m 190  19 
Ha H   A
0.0011  0.001 0.001
2
 2
  
2 0.001   
K a  0.001   19   12.3  106
1   2
  1  
 19 
   
AcOH   HCl   AcONa   NaCl
40.
  426.2  91.0  126.5  390.7
41. Equivalent volume of gas of O2 = 5.6 lit
I  t  Ve
Vgas   56ml
96500

42. 1 equivalent of any substance is deposited by 1 F of charge.

20 g calcium contains,
Atomic mass 40
Equivalent mass of Ca    20
Valency 2
Given mass 20
Number of equivalents   1
Equivalent mass 20
So, 1 Faraday of charge is required to deposit 1 equivalent of Ca

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
43.
C6 H5 NO 2  6H   6e   C6H5 NH 2  2H 2O
123
EC6 H5 NO 2  eq.wt    20.5
6
w  96500
Number of coulombs required 
Eq  wt
12.3  96500
  57900C
20.5

44.
1  1  
 l / A     1.14  Scm
1

R   1500  
 1.14 
1000    
1500 
 Λm   1000   Scm 2 mol1
C 0.001
 760Scm 2 mol1
45. Theory Based
46. Theory Based
47. Fe 2 SO 4 3 and Fe  NO3 3 have same equivalent mass.
48. NO3 ,SO 42 are not electrolysed.
49. Strong acid and strong base conduct metric titration
50. Explanation: During the working of the lead storage battery, PbSO 4 is formed at both
the electrodes and sulphuric acid is used up. At the anode, Pb is oxidised to form PbSO 4
and at the cathode, PbO2 is reduced to form PbSO 4
51.

52.

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_STERLING& BT_Jee-Adv(2022-P1)_WTA-29_Key & Sol’s
53. (P) KCl  AgNO3  AgCl   KNO3
Cl  ions is replaced by NO3 ions
Conductance will first decrease and then after equivalence point, it will increase
P   3
(Q) AgNO3  KCl  AgCl  KNO3
Ag  ions is replaced by K  ions
Conductance will first increase slightly and then will increase further
(R) NaOH  HCl  NaCl  H 2O
OH  Ions is replaced by Cl ions
(S) NaOH  CH 3COOH  CH 3COONa  H 2O, OH  ions is
Replaced by CH 3COO  , Ions conductance will first decrease and them become almost
constant due to buffer formation.

54. (a)
 P   C2 H 5 3 N  CH 3COOH 
X Y
 C2 H 5 3 NH CH 3COO
Initially conductivity increase because on neutralisation ions are created. After that it
becomes practically constant because X alone cannot form ions.
(Q) KI  0.1M   AgNO3  0.01M   Agl  KNO3
Number of ions in the solution remains constant as only AgNO3 precipitated as Agl.
Thereafter, conductance increases due to increase in number of ions
(R) Initially conductance decreases due to the decrease in the number of OH ions as
OH  is getting replaced by CH 3COO  which has poorer conductivity. Thereafter, it
slowly increases due to the increase in number of H  ions
(S) Initially it decrease due to decrease in H  ions and then increase due to the increase
in OH  ions

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