Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60(Incoming)_NUCLEUS BT CTA-35 Date: 20-04-2025
Time: 02:00PM to 05:00PM JEE-ADV_(2021-P2) Max. Marks: 180

KEY SHEET
PHYSICS
1 ABC 2 ABCD 3 ABC 4 BD 5 ABC
6 ACD 7 0.1 8 1 9 200 10 200
11 200 12 32 13 D 14 A 15 A
16 C 17 8 18 8 19 4

CHEMISTRY
20 BC 21 AD 22 ABC 23 ABCD 24 ABC
25 AB 26 1 27 6 28 28 29 4
30 64 31 248 32 C 33 C 34 B
35 A 36 32 37 6 38 72

MATHEMATICS
39 ABD 40 B 41 AC 42 BD 43 BC
44 BCD 45 24 46 4 47 2 48 10
49 2 50 25 51 C 52 A 53 A
54 D 55 8 56 16 57 50
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s

SOLUTIONS
PHYSICS
Br 2
1. Due to rotation, emf 
2
Due to translation indeed emf = Bvr
Where r is the separation.
2. Use concept of motional emf.
3. E  NAB cos  , where  is the angle between plane of coil and magnetic field.
Substituting values, options (1),(2) and (3) are correct.
4. Let CAE  constant
FIG
At time t, DE=VT
AD  DE cot 
And DC  DE tan 
AC  DE   tan   cot  
= vt  tan   cot    1 (say)
Induced emf e=Bvl
e  Bv 2t  tan   cot  
e  v 2 and e  t
1 1
5. f res    500Hz
2 LC 1 1
2  10 6

 
At resonance, Z=R,
V V
So current I  
Z R
When L and C are in series, voltage across capacitor and inductor is 1800 out of phase.
6. VR2  VL2  1002 , VC  VL   120
FIG
1302  VR2  VR  50v
VL  1002  502  50 3V
Vc  120  50 3V
V 50 5
cos   R  
V 130 13
Since Vc  VL , so circuit is capacitive.

7,8 Eav 
 B
 B
A
 B
  r 2

t t t
1   0.10 
2

=  0.1V
0.314
Since the flux through the loop is decreasing, the induced current must produce a field
that goes into the page. Therefore, the current flows in clockwise direction.
av 0.1
I av    10 A
R 0.01
Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 2
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
9,10. The equivalent inductance L= 500 Mh. Just before opening the switch, current through
200
the inductors is I M   2A
100
Potential drop across the resistor is 2  100  2V
Hence, across capacitor potential difference is zero.
So energy stored
1 1
L  2    500 101  22  1 J
2
U
2 2
1 2 1
LI M  CVmax 2
 1J
2 2
L 500 10 3
Vmax  I M  2  200V
C 50  106
1 1
   200rad s 1
3 6
LC 500  10  50 10
V 60 1
11,12 At resonance as X  0,1    A
R 120 2
V
As VL  IX L  1 L, L  L
1
40
SO, L   0.2mH
 
1  4 105
2
1 1
 C 
LC L 2
1 1
i.e., C   F
0.2 10 3   4 105 
2
32

Now in case of series LCR circuit

X L  XC
tan  
R
So current will lag the applied voltage by 450 if,
1
L 
tan 45 
0 C
R
1
1 120    2  104 
 1 32  106
 2  6  105   16 1010  0
6 105   6  105   64  1010
2

i.e.,  
2
6 10  10 105
5
i.e.,    8  105 rad s 1 .
2
t

Equation of line AB is given by y  10   

10
13.
T 
T
1 T 1 T  10  1 5t 2
yav 
T 0
ydt 
T 
0  10  t dt  10 
 T  T T
 15
0

14. Mean square value

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 3

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
T T 2
1  10 
  y 2 dt   10  t  dt
T 0 0
T 
T
1  100 2 200 
 
T 0
100  2 t 
T
t
T 
T
1 100t 3 100t 2 700
 100t   
T 3T 2 T 0
3
Rms value  10 7 3 .
dl
15,16 When current is maximum 0
dt
 e.m.f across L=0, so potential difference across the capacitor will be same
FIG
From the law of conservation of charge on plates 2 and 3,
3CV  CV  6V0  CV0
5V
V  0
4
Loss in energy of capacitor = energy stored in inductor
1 2 1 1 1
cv0  3C  2V0    4CV 2  Lt 2 v
2

2 2 2 2
3 3C
 I  V0
2 L
17. After long time, from conservation of momentum.
v0
mv0  2mv; v   8 m s 1 .
2
dl
18. VA  IR  E  L  VB
dt
 VA  5  1  8  5  103  103   VB
 VB  BA  8V
19. VC  VL  120
VR2  VC  VL   EV2
2

VR2  120    200 

2 2
 VR  160
VR 160
I   4A
R 40

CHEMISTRY
20. A) NH NO  N 2O  2 H 2O
4 3

below300o c

B)  NH  Cr O 
4 2

 N 2  Cr2O3  4 H 2O
2 7

C) Ba  N   
 Ba  3 N 2
3 2

D) Mg N 
3 2

 3Mg  N 2
700 1500O C

21. A) 2 NO  2 NaOH  NaNO2  NaNO3  H 2O

2

B) 4 NaNO3  2 Na2O  2 N 2  5O2

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 4
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
2 Pb  NO3  2  2 PbO  4 NO2  O2

C) 2NH 3  NaOCl  N 2 H 4  NaCl  H 2O

D) NH 4Cl  NaOH  NaCl  H 2O  NH 3

22: A) P4 ( white)  3NaOH  3H 2O  3NaH 2 PO2  PH 3

B) 2H 3 PO2 

 H 3 PO4  PH 3

C) 4 H 3 PO3 

 3H 3 PO4  PH 3

D) 2 H 3 PO4 

 2 HPO3  2 H 2O

23. A) H 2 S2O8  H 2O  H 2 SO4  H 2 SO5

B) 3KClO3  3H 2 SO4  3KHSO4  HClO4  2ClO2  H 2O

C) 2 Na2 S 2O3  I 2  Na2 S 4O6  2 NaI

D) SO2  2 H 2O  I 2  H 2 SO4  2 HI

24. A) Na2 SO3  S 

boiling
 Na2 S 2O3

B) 2 Na2 S5  3O2  2 Na2 S2O3  6S

C) 6 NaOH  4S  Na2 S 2O3  2 Na2 S  3H 2O

D) Na2CO3  H 2 SO4  Na2 SO4  H 2O  CO2 .

25. A) ZnO  2 NaOH  Na2 ZnO2  H 2

B) NH 4 NO3  N 2O  2 H 2O

C) 2 Na2O2  2 H 2O  4 NaOH  O2

D) 2 KClO3  2 KCl  3O2

26,27
250o c
H 3 PO4 H 4 P2O7
600o c
600o c strong
HPO3 P4O10
heating

28,29

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 5

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
The solid A giving colourless gas is ammonium dichromate and the gas is N 2 . The
reactions are :

 NH4 2 Cr2O7 

Heat
 N 2g  +4H2O  l + Cr2 O3g 
 B
 A

3Ca+N 2 
Heat
 Ca 3 N 2
 C

Ca 3 N 2 +6H 2O  NH3 g  + Ca  OH 2
C  D

Cu 2+ aq  +4NH3 aq   Cu  NH 3 4 

2+

 aq 

Blue  D Deep blue  E 

 A  :  NH 4 2 Cr2 O7 ;  B  :N 2
 C  :Ca 3 N 2  D  :NH3  E  : Cu  NH3 4 
2+
; ;
 aq 

30,31

S + 6HNO3 6 NO2  H 2 SO4  2H 2O

(Yellow solid) (B)
(A) (Brown gas)

Na2 SO3
Na2 S2O3  2 HCl  SO2  S  2 NaCl  H 2O
(C) (D) (E)
(clear soln) (colourless
gas

excess AgNO3
Ag2 S2O3  H 2O  Ag2 S  H 2 SO4
(F) (G)

MATHEMATICS
  
39. Let n  cos  i  sin  j
 
PQ  v   at22  at12  i  2a  t2  t2  j
v .nˆ  a  t22  t12  cos   2a sin   t2  t1   c
Let t2  t1  2h and t1t2  k
Midpoint :
x  a  2h 2  k 
y  2ah
y x
Substituting h  and k  2h 2 
2a a
Simplifying the projection equation by using t2  t1  4h2  4k

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 6

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s

The projection becomes : 2a h 2  k 2  h cos   sin    c

Squaring and by replacing h and k
We get
y 2
 4ax   y cos   2a sin    a 2c 2  0
2

40.

Let Ak   2t , t 2 
t 2 1  
 slope of FAK   tan    k 
2t  0 2 
2t
 tan  k   tan  2   say 
1 t2
 k
  k  where tan   t
2 4n
 k 
t  1   2t   t 2  1  1  tan 2   sec 2 
2 2
Also FAk  2

 4n 
t
   k  x  4   x
t
1 n 1 n 4
 lim  FAK  lim  sec 2       sec 2  dx   tan  
x  n
k 1 x  n k 1  4  n  0  4   4 0 
41.

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 7

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s

P1 ;  y  2   4  x  1
2

P2 ;  x  2   4  y  1
2

Subtracting them we get  x  y  x  y   0  line QR is y  x

Hence x1 & x2 are roots of the equation

4  2 2  x1
 x  2  4  x  1  x 2  8 x  8  0
2
(given x2 > x1 )
4  2 2  x2

RS 2 2  2 2 1
So    3 2 2
QS 2 2  2 2 1

42.

1
Slope of Tgt =
t2

Slope of Normal = t 2

The general point on xy =16 is  4t , 

4
 t

4
Equation of normal is : t 2 x  y  t 2  4t   , it is passes through p  h, k 
t

4t 4  t 3 h  0.t 2  tk  4  0 . It is a bi- quadratic equation whose roots are t1 , t2

h K
S1  : S2  0 : S3  : S 4  1
4 4

1 1 1 1
Given condition t12  t22  t32  t42  4     
t t t t  1 2 3 4 

  t2t3t4 
S12  2 S 2  4  
 t1t2t3t4 

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 8

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
  K  
h2  4  
  0  4  
16  1 
 

h2
  K  h 2  16 K
16

 The locus of p  h, k  is h 2  16 y

x y
Equation of AB is  2
x1 y1

lx  my  n  0 
tgt
 x 2  4ay is al 2  mn

x y
  2  0 
Tgt
 x 2  16 y
x1 y1

2
1 2
  .4   x12  2 y1  0
x
 1 y1

The locus of M  x1. y1  is x 2  2 y  0

x2 y2
43. Consider central cone =   1
a2 b2

The fixed point on y-axis is p  o, c 

Tangent equation at point  h.k 

xh yk
 1
a 2 b2

Passing through p(o,c)

b2
k
c

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 9

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
2 2
h k
 2
 2 1
a b

h2 k
  1
a2 c

 h2 
k  c 1  2 
 a 

 x2 
y  c 1  2 
 a 

Locus of P is parabola ( C1 can be ellipse or Hyperbola, C2 will always be parabola)

44.

h  c  k 2   c cos   a  ……..(1)
2 2

Sub  h  c   k   c cos   a  …….(2)

2 2 2

_________________________

4ch=4ca cos   h  a cos  ……..(3)

Add 2 (c 2  h 2  k 2 )  2  c 2 cos 2   a 2  ……(4)

h
Put cos  = in equation (4)
a

h2
We get c 2  h 2  k 2  c 2 . 2
 a2
a

c 2 a 2  h2 a 2  k 2 a 2  c 2 h2  a 4
Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 10
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s

a 2
 c  h  k a  a  a2  c2 
2 2 2 2 2

h2 k2
 1
a2 a2  c2

x2 y 2
 1
a 2 b2

45&46

P(4,3) 4 x  3 y  7

x  4 y 3 5 5 
    Q  ,1
3 4 2 2 

x4 y 3
  5  R 1, 1
3 4

x2 y2
Let S :  1
a 2 b2

x2 y2
&S2 : 
A2 B 2  1

5 y
for S1 : 2
 2 1
2a b

5 4 1
 2
 . 2 1
2a 7 b

x2 y2 73 23
S1 :   1  e12 :  1  e12 
35 8 7 3 35 8 15

x2 y2 7 7
S2 : 2
 2  1  A2  .B 2 
A B 4 3

x2 y2 74 1 1
  1  e22   e22   e2 
74 73 73 4 2

4 8 
S1 & S 2      2  y  R
 7 35 

 4 common tangents.

47& 48

Let line x+2y+a =0 and 12x-6y-41=0 intersect at P then

PA.PB = PT 2 and PC.PD = PT 2

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 11
 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
Where T and T’ are the points on the respective circles.

Now , if A.B,C and D are concylic,

Then PA.PB = PC.PD  PT 2 = PT '2

Hence point P will be lie on the radical axis of both the circle.

Now equation of radical axis is 4x+2y-5=0.

Since radical axis, line x+2y+a =0 and 12x -6y – 41 = 0 are concurrent at P

4 2 5
 1 2 a 0 a 2
12 6 41

Equation of circle passing through point of intersection of circle x 2  y 2  4  0 and

x  2 y  2  0 is given by x 2  y 2  4    x  2 y  2   0 ...... 1

Again common chord of circle represented by equation (1) and circle

x2  y 2  4 x  2 y  1  0

   4  x  2    1 y  2  5  0 .....  2 

Since equation (2) and 12 x  6 y  41  0 represent the same line

  4 2    1 2  5 8
   
12 6 41 5

Hence equation of required circle is 5 x 2  5 y 2  8 x  16 y  36  0

49&50

x2 y 2
x2  y 2  r 2 ,  1
16 9

r2  y2 y2 144  9r 2
Solving the given curves  1 y 
2
(eliminating x 2 )
16 9 7

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 12

 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
Solving the given curves (eliminating y 2 ) we have

16r 2  144
x2 
7

If ABCD is square then x 2  y 2

12
r 2
5

Tangent of slope m to circle and ellipse is

y  mx  r 2 x 2  r 2 y  mx  16m 2  9

For common tangents r 2 m 2  r 2  16m 2  9


r2 1 m
2

  16m 2
9

Also A, B, C1 , D1 is a square then m  1

r 2  r 2  25

2r 2  25

5
r
2

51&52
x2 y 2
Given ellipse is  1
9 4
Hence AB is the chord of contact. So
xx1 yy1
 1
9 4
3x 4 y
  1
9 4
x
  y 1
3
Solving equation (i) and (ii), we get
 9 8
A    ,  , B   3, 0 
 5 5
The equation of the altitude through A is
8
y
5
1
and the slope of AB is 
3
The equation of the altitude through P is y  4  3  x  3
Solving equation (i) and (ii), we get

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
11 8
x ,y
5 5
Hence, the orthocenter is  ,  .
11 8
 5 5
Let the point be M  x, y 
It is given the PM = Length of perpendicular from Q to
x
 y 1
3
 x  3   y  4 
2 2
 
2
1
  1
3
 10  x  3    y  4    x  3 y  3
2 2 2

 10  x 2  y 2  6 x  8 y  25   x 2  9 y 2  9  6 xy  6 x  18 y
 9 x 2  y 2  6 xy  54 x  62 y  241  0

53& 54

Let two hinges be fixed at points A(0,0), B(0,0)

When rotating in opposite direction

k)
(h,

A  2
(0,0) B(0,0)

k
tan   ……..(1)
h

k
 tan 2  …….(2)
ha

From (1) &(2)

tan   h    tan  2  .  h  a 

a tan 2
h
tan 2  tan 

2a
h ……..(3)
3  tan 2 

2a
k .tan 
3  tan 2 

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
From (3) &(4)

k 2  3h2  2ah

Replace (h,k) by (x,y)

y 2  3 x 2  2ax

x  a3
2

y2
 1
a2 a2
g 3

Hyperbola

If rotation in some direction locus will be circle.

55.

C1 : x 2   y  2   4
2

Centre  0, 2 

Radius = 2

C2 : x 2  y 2  r 2

 r 4 r 2 
Point of intersection are :   r 2  , 
 16 4 


Equations of line PQ & PR:

The leftmost point P of C2 :  r ,0 

The lines PQ and PR pass through line PQ

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
r / 4
2
Slope 
r4
r2  r
16

Approximating for small ‘r’ the slope simples and the y intercept Q is found to be

4 1  1  r 2 / 16 
For line PR

r 2 / 4
Slope 
r4
r  r2 
16

 r2 
By approximating for small ‘r’ the y-intercept R is found to be 4 1  1  
 16 


Distance RQ:

r2
y R  yQ   8 1 
16

lim RQ  lim  yR  yQ   8
r 0 r 0

56.

Method – I
a  R2  R3

b  R1  R3

c  R1  R2

a  b  c  2( R1  R2  R3 )

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 Sri Chaitanya IIT Academy 20-04-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-35_Key & Sol’s
abc
R1  R2  R3   5 (Heron’s formula)
2
  s  s  a  s  b  s  c 
2
1 1 1 
  R2  4    R3  4    R1  4  
2 2 2 
= R1  R2  R3  R1 R2 R3 
4  R1  R2  R3   R1  R2  R3  R1 R2 R3 
2

R1R2 R3 16

R1  R2  R3 1
METHOD – II
tan  2  R2 4
tan  2  R1 4
8 R
tan  3
2 4
 tan A   tan A { A  B  C  180O }
  5
{   180}
2 2 2
 
5   5
tan  tan = tan  tan  tan
 tan
2 2 2 2 2 2
R1 R2 R3 R1 R2 R3
  
 4

4 4 4
R1R2 R3 16

R1  R2  R3 1
57 S1 : x 2  y 2  4 x  22 y  c  0
S2 : x 2  y 2  2 x  8 y  d  0
c  d  50

S1  S2  0

6 x  14 y  c  d  0

But equation S1  S2  0 passing through centre (1,-4)

6  14  4   c  d  0 , c  d  50

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