Sec: JR.

IIT_*CO SC(MODEL-A) CAT-12 Date: 10-08-25

Time: 3HRS 2020_PII Max. Marks: 198
KEY SHEET

MATHEMATICS
1 8 2 6 3 2 4 4 5 1
6 0 7 ABD 8 AC 9 ABCD 10 BC
11 B 12 AC 13 3 14 25 15 16
16 21 17 6 18 17

PHYSICS
19 1 20 1 21 2 22 2 23 3

24 6 25 BC 26 ABCD 27 AD 28 B

29 A 30 AC 31 13 32 0.64 33 0.41

34 1 35 0 36 3

CHEMISTRY
37 4 38 6 39 2 40 5 41 4

42 5 43 BCD 44 ACD 45 ABC 46 ACD

47 A 48 ACD 49 180 50 11 51 1

52 325 53 68 54 3600
Narayana IIT Academy 10-08-25_JR.IIT_*COSC(MODEL-A)_CAT-12_Key&Sol’s
SOLUTIONS
MATHEMATICS

1. log1/2 sin x  2  log1/2 cos x

 log1/2 sin x cos x  2
1 1
 sin x cos x   sin 2 x  
4 2

Hence, total number of solutions = 8.

3
2. cos3 3  cos3 5   cos3  cos5 
 3cos3 .cos5  cos3  cos5   0
 cos  0  or  cos3  0  or  cos 4  0  or  cos5  0
5 5 7
 3  or 4  ,
2 2 2
5 5 7 7 9 11
 3  or 4  , or 5  , ,
2 2 2 2 2 2
5 5 7 7 9 11
  or   , or   , ,
6 8 8 10 10 10
Sum of values of  equals to 906    906
a b   a b   d b 
3. Let B    , B  adj ( B )   c d    c a   b  c  0 and a  d
c d     
a 0
B     aI & Tr ( B)  2a … (1)
 0 a 
AB  BP  2 I ,  aA  aP  2 I  aA  aP  2 I ( from (1))
 
Let P   where Tr ( P)  4      4; det( P)  3      3
  
 a  2 a 
 aA   , taking det on both sides
 a a  2 
 a 2 | A | a 2 ( a   )  2a(   )  4
 a 2 | A | 3a 2  8a  4
| A | 15 Tr ( B )  0  a  0
12a 2  8a  4  0

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1
a   , 1  a  1 ( a  0)
3
2
Tr ( B)  2a    3 Tr ( B)  2
3
4.  2
 2  2  5  x 2  x  2 2   2    2   2  3   0 x  R
 2  2 2  5  0 and 2 2   2  0 and  2   2  3
  2  1&  2  2   ,    1,  2  
3
5. x16(log5 x ) 68log 5 x  516
Take log to the base 5 on both sides
16  log 5 x 3  68  log 5 x    log 5 x   16
 
put log 5 x  t  16t 4  68t 2  16  0
 where t1 , t2 , t3 , t4 are the roots of 4t 4  17t 2  4  0
t2  t 2  t3  t4  0
 log 5 x1  log 5 x2  log 5 x3  log 5 x4  0
 x1 x2 x3 x4  1
6.  x  1 P( x)  1  0 has roots 0,1,2,3,4,....,11 .
  x  1 P ( x)  1  A  x  0  x  1 x  2  ..... x  10  x  11
1
Put x  1, we get 1  A( 1)( 2)(3).....(12)  A 
12
1
x ( x  1)( x  2)....( x  11)  1
12 1  1
 P( x)   P(12)  0
x 1 13
 1 0 0  1 2 3  1 0 0 
   
7. A) PEP   0 0 1  2 3 4  0 0 1 
 0 1 0  8 13 18  0 1 0 
   
 1 2 3  1 0 0   1 3 2 
=  8 13 18   
 0 0 1    8 18 13 

 2 3 4  0 1 0   2 4 3 
    
 PEP  F and P2  I
B) EQ  PFQ 1 | EQ |  | PFQ 1 |
| E | 0 and | F | 0 and | Q | 0
| P || F |
RHS | EQ |  | PFQ 1 || E || Q |  0
| A|

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LHS = EQ  P( PEP)Q  EQ  IEPQ  EQ  EPQ  E I  P Q  0
C) | ( EF )3 || EF |2
Here 0  0 (false)
D) LHS = Tr ( P 1 EP)  Tr ( F )  Tr ( EPP 1 )  Tr ( F )  Tr ( E )  Tr ( F )
RHS = Tr ( E )  Tr ( P 1FP)  Tr ( E )  Tr ( FPP 1 )  Tr ( E )  Tr ( F )
8. For non trivial solution
1 c b
 c 1 a  0  1  2abc  a 2  b 2  c 2  0
b a 1
 a2  b2c2  2abc  1  b2  c 2  b2c 2
 ( a  bc) 2  (1  b 2 )(1  c 2 )
Similarly; (b  ac) 2  (1  a 2 )(1  b 2 )
(c  ab) 2  (1  a 2 )(1  b2 )
So 1  a 2 , 1  b 2 , 1  c 2 are of same sign and atleast one in proper fraction, so all are
positive.
 1  a 2  0, 1  b 2  0; 1  c 2  0  a 2  b 2  c 2  3
and 1  2abc  3  abc  1
1 1 
log0.25   2 .... 
  3 3 
 2 6 10 
9.    1   2  3  ... 
  3
3  3 
 S 
2 6 10
S 1    ....
3 32 33
S 1 2 6
  2  3  ....
3 3 3 3
2S 1 4 4
 1   2  3  ...
3 3 3 3
2S 4 4 4
    ....
3 3 32 33
 1 
 
 4  log 0.25  3   1
1
 1  log  1    1
3   4 2 
S   3   3 ,   (3)  3
3  
 3  3  2  3
2
2 1 1 
 3
10.

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Equation of A ' A '' is 2 x  y  8

 4 16 
B   3, 2  C   , 
3 3 
11.
B (1,-3)

A
C

D (0,4)

ABD is equilateral
Slope of BD= -7
Let slope of AB = m
m7
tan 600  .....1
1  7m
AB = BD
2 2 2
 x  1   y  3  x 2   y  4 
2 x  14 y  6  0
x  7 y  3  0..... 2 

y3
Slope of AB=m  .... 3 
x 1
1 7 3 1 3 
Solving (1), (2) & (3), we get A  , 
 2 2 
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a  3 b 1 
12. Let C  a, b   E   ,  ( E is midpoint of AC)
 2 2 
C lies on x  4 y  10  0  a  4b  10  0
E lies on 6 x  10 y  59  0  3a  5b  55  0
Solving, we get C  a, b   10,5 
The reflection of A  3, 1 in line CF  x  4 y  10  0  is 1, 7 
1,7  lies on line BC (CF is angular bisector)
 Equation of side BC is 2 x  9 y  65
(line joining 1,7  and C 10,5  )
Solving eqs. of line BE  6 x  10 y  59   0
7
and line BC  2 x  9 y  65  , we get B   ,8 
 2 
2
Slope of BC  ; Eq. of AB is 18x  13 y  41
9
13. tan    60      3
 tan   tan  60     3  3 tan  tan  60   
 tan   tan  60     3 tan  tan  60     3
Adding 3.tan 2  on both sides
 tan   3 tan 2  tan  60    1  3 tan     3 sec2 


 1  3 tan    tan   tan  60      3 sec 2 


1  3 tan    tan   tan  60    
 3
1  tan  
2

Now, put   10 and   20

1   
3 tan10 1  3 tan 20  tan100  tan 590  tan 20  tan 540 
 3. 3  3
1  tan 1 1  tan 2 
2 0 2 0

14.  sin x  cos x   tan 2 x  1   

3 tan x  3  3  3 sin x  cos x
Case I: sin x  cos x  0
3   7
 s  c   t 2  1  
3 t 3 0   t  1,1, 3  x  , , ,
4 4 3 4
Case II: sin x  cos x  0

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 s  c   t 2  1  
3 t 6 3 0 
 t  1
 No solution in this case
37
 Sum of solutions is  p  q  25
12
3 3
3n 2  1 1   n  1   n  1  1  1 1 
15. 3
      
  n  13 . n  13  2   n  13  n  13 
  
n 2
 1 2   
1 1

1 
S   3
 3 

n  2 2  n  1  n  1 
 
1  1 1   1 1  
S   3  3    3  4   .....
2  1 3   2 4  
1  1 9
S  1   
2  8  16
16. b  ar , c  ar 2
abc  66  a 3r 3  66  ar  36
 b  a   a  r  1 is a perfect cube
a  r  1   3 (  is a positive integer)
 1 3 3 1 36
36  1      1   r  an integer
 r 36 r 36   3
By verification
36 36 36
If   1, r  ,   2, r  ,   3, r   4 Z
35 28 9
Now ar  36  a  9
numbers are 9, 36, 144

17. p 2
 q 2  x 2  2q  p  r  x  q 2  r 2  0  1
q r
From (1), x  ,
p q
x2  2 x  8  0   2 
 x  4,2
q r
Put x  4 , x    4
p q
 q  4 p, r  4q
r  16 p

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2 2 2 2
q  r 16 p  256 p
   272
p2 p2

18. PQ  k 3 | P | 2 k  0 … (1)
P  12  20 … (2)
From (1) & (2) k  6  10 … (3)
(adj P) (adj P)
PQ  kI 3  Q  kp 1  k 
|P| 2
 k   3  4 
now q23    12  16  k ….. (4)
8 2
Solving (3) & (4)   1, k  4   2  k 2  17
PHYSICS

 
19. FNet  0. Hence torque is independent of choice of orgin.
20. Just after Nth collision, (N+1) blocks more together Let  0 be their speed. These
F
blocks more with an acceleration of for a displacement of ‘d’
 N  1 m
v 2  v02  2ad
v  v02  2 ad
th
Apply Conservation of linear momentum during  N  1 collision.
 N  1 mv   N  2  mv0
2 F  2
Squaring,  N  1 V02  2 d    N  2  V02
  N  1 m 
Fd
For N  1,V0 
m
F
21. aCM  . W.r.t CM,
2m
2T cos  F
F
T
2cos

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The particles move along a St. Line towards CM.

Work done by pseudo forces = Zero (  len to displacement)
= Fx displacement of midpoint
 Fx = loss in KE due to collision
22. Reflected rays rotate at double angular speed
w  2 x 2n  2 rad / s
v  Rw  2 m / s

23. xCM 
 xdm   xdA  3 a
 dm  dA 4
2 2ka 3
dA  2 ydx  2kx dx  A   dA 
3
4
2ka
 xdA 
4
24. T  f  mg sin   1
Rotational equilibrium:
T  f   2
mg sin 
f    mg cos
2
tan  1 1
  
2 2 3 12

T 
a A11  
m
25.  a A11  aB11
mg cos  T 
aB11 
m 
From string constraint
VA11  VB11
T T sin 
aAx  , aBx   a Ax
m m
A has more horizontal acceleration then B
 A moves faster horizontally.

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26. r1  1 sin 1
Vertical equilibrium
T1 cos 1  m1 g  1

Horizontally
T1 sin 1  m1w2 r1
 m1w2 r1 sin 1   2 
g
From (1) &(2) w1  .
 1 cos1
g
Similarly for m2 , w1 
 2 cos 2
Cos1  2 11
Given w1  w2   1 cos1   2 cos 2 or  
Cos 2  1 7
If the hanging rod is vertical  T1Sin1  T2 Sin 2
m1 1 sin 1  m2  2 sin  2
sin 1 m2  2 28  11 11
  
sin  2 m1 1 56  7 4
tan 1 sin 1 cos 2 11 7 1
    
tan 2 sin  2 cos1 14 11 2
g  1w 2
Cos1  or sec 1  and tan 1  sec 2 1  1
 1w 2
g
2
  1 w2 
   1
 g 

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2
  w2 
Similarly, tan  2   2   1
 g 
We know that tan  2  2 tan 1
 22 w4   21 w4 
Squaring on both sides  1  4  2 4
g2  g 
w4
2 
3 4  21   22   w  10 2rad / s
g
1 2 1  mM  2  mM 
27. W f   rel
2
 
2 mM 
 
 2 2 gh  
mM 
 gh
WAction  WRe action  independent of frame of reference
Using conservation of linear momentum
m 2 gh   m  M  v
 m 
v  2 gh
mM 
28. Centre of mass is at rest.
 
m1r1  m2 r2
29. The beam must have unequal length.
When the mass is kept in right pair.
W1 A  W  B  1
When the mass is kept in left pair,
W2  B  W  A   2 
1   2   W 2  WW
1 2 W  WW
1 2
30.

J1  10 1  1
J 0  cos 60  J1  5v1   2 
1
10 
1   2  J 0 cos 60  15v1  v1  2  1m / s
15 3
1
Value of 5kg block = V12  V22  3
9

31. Let  0 be the natural length

At equilibrium, L1  25   8  2   15m

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k   1   0   mg  1
When head touches the surfaces of water,
Loss in gravitational P.E = increase in strain energy
1 2
mgh  k  h   0  2    2 
2
1 2
From 1 &  2  k   1   0  h  k  h   0  2 
2
1 2
15   0  25   23   0 
2
 0  13m
32. Range  OA  AC  OA  AO  OC  20 A  OC
Horizontal velocity = Vx  constant (magnitude)
OA Range
tOA  ,T  20 A  OC
Vx Vx
Let OA  x  OC  3x
x
t0 A 
Vx
5x
T  5tOA
Vx
2
T 5 1 5 
Time of ascent =  tOA ; H  g  tOA 
2 2 2 2 
2
1 3 
h  g  tOA 
2 2 
h 52  32
  0.64
H 52
33.

N1   N 2  mg  1
 N1  N 2   2 
mgR
   N1   N 2  R   3
2
N1   2 N1  mg

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mg  mg
N1  2
, N2 
1  1 2
mgR  1  
  2 
mgR  1   2  2  2  2
2 1  
 2  2  1  0 , = 0.41

34. MS1  M * S rel

R
Srel  os  2
2
M
MS1   2  S1  1
2


35. J  18iˆ  6 ˆj

 J
V   9iˆ  3 ˆj
m
 
Vi  5 , V f  5
  
V f  Vi  V

 5iˆ  9iˆ  3 ˆj


V f  4iˆ  3 ˆj
KE  0  W
36. CM  R sin 
MP  R 1  sin  
Mg sin  R  T   MP 
Mg sin  R  mgr 1  sin  
M sin 
m  3kg
t  sin 

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CHEMISTRY

37. rn  n 2
But rn  1  rn  rn  1
2 2
 n  1  n2   n  1
n4

38. E  H  T  q  Pext  S surr  0

S sys  Stotal  ve
Gsys  ve

1.28
39.  H 2 SO3 O   0.02M
64
H 2 SO3  H   HSO3
xM
 0.02  x M xM

x.x 2
Now, K a  10 
 0.02  x 
 x  0.01M  pH   log x  2

40. CO2 , CH 3CN , NO2 , N 2O & C3O2

41. Let the mixture contains a moles Cx H8 and b moles C x H10 .

Now, a  12 x  8   6  12 x  10   28.4 (1)
PV 2.46  5
ab   0.5 (2)
RT 0.082  300
84.5
and 28.4   a  12 x  b  12 x (3)
100

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On solving, x  4

42.

Ag aq   Fe2aq   Fe3aq   Ag s 

Initial 500  0.9 500  1.0 0 0
moles 1000 1000
Equilibrium 0.45  x 0.50  x x x
moles

Now, neq Fe 2  neq MnO4

Or,
 0.50  x   30  1  25  0.06  5
1000 1000
 x  0.25
x
 K eq   5M 1
 0.45  x  0.5  x 
43. Al2Cl6 has three centre four electron bond.
P  F axial bond length  159.6 pm
P  Cl equatorial bond length  200.5 pm
Bond angle NH 3  107
Bond angle NF3  102

KW 1014
44. For NaA, K h   8  106
K a 10
KW 1014
For NaB, K h   6  108
K a 10
KW 1014 106
For NaC , K h   
K a 2  108 2
KW 1014
For NaD, K h   10  104
K a 10
KW 1014
For NaE , K h   7  107
K a 10
Since, K h of NaD is the highest, therefore, NaD is most extensively hydrolysed.
1
For NaB , pH   pKW  pK a  log C 
2
1 1 1 1
or pH  14  6  log    20  1   19
2 10  2 2
or pH  9.5
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For isohydric solution, K a1 C1  K a2 C2
 10 7  0.1  10 6  0.01  10 8
Hence, 0.1 M  HE isohydric to 0.1 M  HB solution.

45. Conceptual

46. Conceptual

150 0 150
47.  A V   37.5
V 4
K.E of photo electron  37.5 eV
13.6
Energy required to remove electron 
1
 54.4eV
Total energy of photon  91.9 eV
2
Now, 10.2 Z  91.9
Z 3

48. (A) K a .K b  KW
 K a  K b  107

(B)  H   K a .C  108  104 M
pH  4
(C) A  H 2O  HA  OH 
OH    K b .C  108  10 4 M
pOH  4  pH  10.0
  
(D)  H    H    H 
net HA HCl

  H   0.01M
HCl
pH  2.0

49. Graphite  Diamond; G    3.0  0  kJ / mol;

P1  1 bare
G  0 P2  P
Now,   G   V .P
Or,  G  G    VDia  VGra   P2  P1 
 12 12  6 

Or, 0  3.0  103    5
  10   P2  10 
 3.6 2.4  
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9 4
 P2  1.8  10 Pa  1.8  10 bar

50. Na2CO3  HCl  NaHCO3  NaCl

20 10
10 - 10
pH  pK  11

51. Conceptual

52.
2S 2O32 
3
AgBr s   Ag  S 2O3 2  Br 
0.1 aM 0 0
Eqn/fnal 0 a-0.2 0.1 0.1
0.1  0.1
K eq  4  10 13  1.6  1012  2
 a  0.325
 a  0.2 

53. neqOH   neq Metal hydroxide (or)

8.50
0.1  1   E  68
E  17

urms , CH 4 3R  R 64 4
54.   
urms , SO2 16 3R  300 1
 T  1200 K

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