SEC: JR_*CO-SC(MODEL-A) Date: 10-08-25

Time: 3 Hrs Max. Marks: 198

10-08-25_JR.IIT_STAR CO-SC(MODEL-A)_JEE ADV_2020(P-II)_CAT-12_SYLLABUS

MATHEMATCS: (100% CUMULATIVE) SYLLABUS COVERED FROM
07-04-25 TO 09-08-25

PHYSICS: (100% CUMULATIVE) SYLLABUS COVERED FROM

07-04-25 TO 09-08-25

CHEMISTRY: (100% CUMULATIVE) SYLLABUS COVERED FROM

07-04-25 TO 09-08-25
Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single digit Integer (0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 –
(e.g. 6.25, 7.00, 0.33, .30, 30.27, +4 0 6 24
18)
127.30)
Total 18 66

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 –
Questions with Single digit Integer (0-9) +3 -1 6 18
24)
Sec – II (Q.N : 25 – One of More Correct Options Type
+4 -1 6 24
30) (partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 –
(e.g. 6.25, 7.00, 0.33, .30, 30.27, +4 0 6 24
36)
127.30)
Total 18 66

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 –
Questions with Single digit Integer (0-9) +3 -1 6 18
42)
Sec – II (Q.N : 43 – One of More Correct Options Type
+4 -1 6 24
48) (partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 –
(e.g. 6.25, 7.00, 0.33, .30, 30.27, +4 0 6 24
54)
127.30)
Total 18 66

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P

MATHS Max Marks: 66

SECTION 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks : 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks : -1 In all other cases.

1. The number of distinct solutions of the equation, log1/2 sin x  2  log1/2 cos x in the
interval  0,2  , is___________.
2. The sum of all possible 
values of
(in degrees) such that
cos3 3  cos3 5  8cos3 4 cos3  where 
is measured in degrees and
  100 ,200  , is  , then the unit place digit of  is
0 0 0

3. Let A, B and P be three non-singular matrices of order 2 satisfying AB  BP  2 I and

det( P )  3, Tr ( P )  4 and B  adj ( B), If det( A)  15 and Tr ( B)  0, then the value of
3 | Tr ( B ) | is equal to ________
(where I is identity matrix, det( P) represents determinant value of matrix P and
Tr ( P)  Trace of matrix P, | x | absolute value of x ).
2
4. If the quadratic equation  2  x  1   2  2 x 2  x  1  5 x 2  3  0 is satisfied for all
x  R, then number of ordered pair  ,   which is possible is/are
5. The product of all positive real values of x satisfying the equation
3
x(16(log5 x ) 68log5 x )  516 is _______.
1
6. Let P ( x ) be a polynomial of degree 11 such that P( x)  , for x  0,1,2,3,4,....11.
x 1
Then P(12) is equal to:

SECTION 2 (Maximum Marks: 24)

 This section contains SIX (06) questions.
 Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is/are
correct option(s).
 For each question, choose the correct option(s) to answer the question.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks: -2 In all other cases.

7. For any 3  3 matrix M, let | M | denote the determinant of M . Let

1 2 3  1 0 0 1 3 2 
E  2 3 4  , P  0 0 1  and F   8 18 13
     
8 13 18  0 1 0   2 4 3 
If Q is a nonsingular matrix of order 3  3 , then which of the following statements is
(are) TRUE?
1 0 0
A) F  PEP and P 2  0 1 0
 
0 0 1 
B) EQ  PFQ 1  EQ  PFQ 1
2
C) ( EF )3  EF
D) Sum of the diagonal entries of P 1 EP  F is equal to the sum of diagonal entries of
E  P 1 FP
8. If the system of equations x  cy  bz  0, cx  y  ax  0 and bx  ay  z  0 has a non-
zero solution and atleast one of a, b, c is a proper fraction, then
A) a 2  b 2  c 2  3 B) abc  1 C) abc  1 D) a 2  b 2  c 2  3
1 1 1 
log ( 0.25 )   2  3 .....upto  
 2 6 10  3 3 3 
9. If the value of  1   2  3  ....upto   is  , then  2 is coprime
 3 3 3 
with
2 2
   3 
A)  1  tan  B)  tan  1
 8  8 
2
C)  tan150  2   1 D) 8sin100 sin 500 sin 700
10. For a ABC , vertex A   4,4  , vertex B lies on L1 : y  2  0 and vertex C lies on
L2 : x  y  4  0 if perimeter of ABC is minimum then which of following options
is/are correct.
A) B   4,2 and C   0,4
 4 16 
B) B   3,2  and C   , 
3 3 
10
C) Area of ABC is equal to square units
3
D) Minimum Perimeter of ABC is 6  2 5
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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
11. Let B 1, 3 and D  0, 4  represent vertices of rhombus ABCD in  x, y  plane, then

coordinates of vertex A if BAD  600 can be equal to

1 7 3 1 3  1 7 3 1 3 
A)  ,  B)  , 
 2 2   2 2 

 1  14 3 1  2 3   1  14 3 1  2 3 
C)  ,  D)  , 
 2 2   2 2 

12. The vertex A of a triangle ABC is (3, 1) . The equations of median BE and angular
bisector CF are 6 x  10 y  59  0 and x  4 y  10  0 respectively. Then
2
A) Slope of the side BC must be 
9
1
B) Slope of the side BC must be
7
C) The equation of AB must be 18 x  13 y  41
D) The equation of AB must be 23 x  y  70

SECTION 3 (Maximum Marks: 24)

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual.numeric keypad in the place designated to enter answer. If the numerical value has more than
two decimal places truncate/round- off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct numerical value is entered as answer.
 Zero Marks: 0 In all other cases.

13. The value of

1   
3 tan10 1  3 tan 20  tan10  tan 590  tan 20  tan 580 
is
1  tan 1 1  tan 2 
2 0 2 0

14. If sum of the values of x satisfying the equation

 
 4
   
2 sin  x   sec2 x  1  3 tan x  2  3  9  18sin x cos x

 p
in  0,2  is    , where p and q are co-prime natural numbers, then p  q is equal
q
to

3n2  1 9
15. If S   3
then is equal to
 2
n 2 n  1  S

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
16. If a, b, c are positive integers forming an increasing G.P. and (b  a ) is a perfect cube

of an integer and log 6 a  log 6 b  log 6 c  6, then the value of is

a  b  c
9
17. If for some p, q, r  R , not all have same sign, one of the roots of the equation
p 2
 q 2  x 2  2q  p  r  x  q 2  r 2  0 is also a root of the equation x 2  2 x  8  0 then
1  q2  r 2 
the digit in the unit place of   is
17  p 2 
 3 1 2
18. Let P   2 0   , where   R, suppose Q  qij  matrix such that PQ  kI3
33
 3 5 0 
k k2
for some non-zero k  R . If q23  and Q  then  2  k 2 is equal to:
8 2
( I3 is Identity matrix of order 3  3 )

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
PHYSICS Max Marks: 66
SECTION 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks : 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks : -1 In all other cases.

19. Three forces are applied to a square plate as shown in Fig. Let  A and  D be the
magnitudes of net torque on the plate with respect to A and D respectively. Then find
A
the ratio
D

20. A large number of small identical blocks, each of mass m , are placed on a smooth
horizontal surface with distance between two successive blocks being d . A constant
force F is applied on the first block as shown in the figure.

Assume the collisions to be perfectly inelastic. After a sufficiently large number of

collisions, speed of the blocks immediately after nth collision will be equal to that
kFd
immediately after (n+1)th collision – this speed is called terminal speed(vt). If vt2 
m
find the value of k.

21. Two small balls, each of mass m are placed on a smooth table (XY- Plane), connected
with a light string of length 2l , as shown in the figure. The midpoint of the string is
pulled along Y direction by applying a constant force F . If the two masses collide and
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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
 Fl
stick to each other, and the loss in kinetic energy is , find the value of  .
2

22. A flat mirror revolves at a constant angular velocity, making n  0.5 revolution per
second. The mirror is placed at the center of curvature of a spherical screen of radius
1m. Velocity of the light spot on the screen is kπ m/s. Find the value of k.
23. A thin sheet of metal of uniform thickness is cut into the shape bounded by the line x =
a and y = ± kx2 , as shown. If a = 4, the coordinates of the centre of mass is:

24. A thin hoop of weight 500 N and radius 1 m rests on a rough inclined plane as shown
1
in the figure. The minimum coefficient of friction needed for this configuration is
2k
, then find the value of k.

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
SECTION 2 (Maximum Marks: 24)
 This section contains SIX (06) questions.
 Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is/are
correct option(s).
 For each question, choose the correct option(s) to answer the question.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks: -2 In all other cases.

25. Two small identical blocks are connected by a weightless inextensible thread of length
2 through a small weightless pulley as shown. The left block A, rests on a table at a

distance  from its edge, while the right block B is kept at the same level so that the
thread is unstretched and does not sag. Now, the system is released from rest.

A) At any instant during the subsequent motion, both the blocks will have same
components of acceleration along the string
B) At any instant during the subsequent motion, both the blocks will have same
components of velocity along the string
C) A reaches the edge of the table first
D) B reaches the edge of the table first
26. Two balls of mass m1  56 g and m2  28 g are suspended on two threads of length
1  7 cm and  2  11 cm at the end of a freely hanging rod. The hanging rod is rotated

at a constant angular velocity  about the vertical axle so that it remains in the vertical
position while both the particles move with the same angular velocity. Let θ1 and θ2 be

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
the angles made by the threads with the vertical respectively.

A) cosθ1: cos 2 = 11:7 B) tan θ1: tan 2 = 1:2

C) sinθ1: sin 2 = 11:14 D)  = 10 2 rad/s
27. A small disc of mass m slides down a smooth hill of height h without initial velocity
and gets onto a plank of mass M lying on the horizontal plane at the base of the hill as
shown. Due to friction between the disc and the plank the disc slows down and, after
some time, moves together with the plank.

A) The total work performed by the friction forces in this process with respect to
mM
ground I  gh .
mM
B) The total work performed by the friction forces in this process with respect to plank
mM
is gh .
mM
M
C) The common velocity of plank + disc system is 2 gh
mM
m
D) The common velocity of plank + disc system is 2 gh
mM
28. Two interacting particles form a closed system whose centre of mass is at rest. Fig.
illustrates the positions of both particles at a centre moment and the trajectory of the

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
particles of mass m1. Select the trajectory of the particle of mass m2 if m2 = m1.

A) B) C) D)
29. The beam and pans of a balance have negligible mass. An object weighs W1 when
placed in one pan and W2 when placed in the other pan. The weight W of the object is:

A) W1W2 B)  W1  W2  C) W12  W22 D) (W11  W21 ) / 2

30. Two point masses connected by a light inextensible string are lying on a frictionless
horizontal surface as shown in figure. A horizontal impulse of magnitude 10 kg-m/s is
given to 5 kg block.

1
A) Velocity of 10 kg block immediately after impulse is given by m/s
3
B) Velocity of 10 kg block immediately after impulse is given 2 m / s

28
C) Speed of 5 kg block immediately after impulse is given m/s
9

28
D) Speed of 5 kg block immediately after impulse is given m/s
9

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P

SECTION 3 (Maximum Marks: 24)

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual.numeric keypad in the place designated to enter answer. If the numerical value has more than
two decimal places truncate/round- off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct numerical value is entered as answer.
 Zero Marks: 0 In all other cases.

31. A man of height h0  2 m is bungee jumping from a platform situated a height h  25 m

above a lake. One end of an elastic rope is attached to his foot and the other end is
fixed to the platform. He starts falling from rest in a vertical position. Assume that
centre of mass of the man lies at the mid-point of the man.

The length and elastic properties of the rope are chosen so that his speed will have been
reduced to zero at the instant when his head reaches the surface of the water.
Ultimately the jumper is hanging from the rope, with his head 8 m above the water.
Find the unstretched length of the rope in SI units.
32. A ball is projected from point O on the ground. It hits a smooth vertical wall AB at a
height h and rebounds elastically. The ball finally lands at a point C on the ground.
During the course of motion, the maximum height attained by the ball is H . Find the
h OA 1
ratio if 
H OC 3

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P

33. A plate, bent at right angles along its centre line, is placed onto a horizontal fixed
cylinder of radius R as shown in the figure. Find minimum value of coefficient of
static friction between the cylinder and the plate if the plate is not to slip off the
cylinder?

34. A disc of mass M and radius R = 2 2 m lies on a smooth horizontal table. Two men,
M
each of mass , are standing on the edges of two perpendicular radii at A and B .
2

Find the displacement of the centre of the disc (SI units) if the two men walk radially
relative to the disc so as to meet at the centre C .
35. A block of mass 2.0 kg is sliding on a frictionless horizontal floor with a velocity of
5.0 m / s due east. It is subjected to a variable net force for 10 seconds resulting in an
impulse of 6.0 N  s in the north and 18.0 N  s in the west. What is the total work done
by this force?
36. A cylinder of mass M  2.0 kg is placed on two parallel rails inclined at an angle   37 
to the horizontal (side view shown in the figure). A load of unknown mass is suspended
from a light inextensible cord wound on the cylinder. If the cylinder remains at rest,
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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
what should the mass of the load be (SI units)?

CHEMISTRY Max Marks: 66

SECTION 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks : 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks : -1 In all other cases.

th th
37. Difference between nth and  n  1 Bohr’s radius of H -atom is equal to its  n  1
Bohr’s radius. The value of n is
38. For isothermal expansion of an ideal gas into vacuum, among the following, how many
are zero?
E, H , T , q, Pext , Ssys , Ssurr , Stotal , Gsys

39. The average concentration of SO2 in the atmosphere over a city on a certain day is 10
ppm, when the average temperature is 298 K. Given that the solubility of SO2 in water

at 298 K is 1.28 gm litre -1 and the pK a of H 2 SO3 is 2.0, estimate the pH of rain on that
day. (Assume rain water is saturated with SO2 )
40. Total number of species among the following in which at least one atom has same
hybridization as the N -atom in azide  N 3  ion.

I 3 , CO2 , XeF2 , CH3CN , NO2 , N 2O, SO2 , C3O2

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
41. A 5.0 L box contains 28.4 g of mixture of gases C x H 8 and C x H 10 . The pressure of the
gas mixture at 300K is 2.46 atm . The analysis of the gas mixture shows that carbon is
84.5% by mass. The value of x is
42. To 500 ml of 0.9M  AgNO3 solution was added 500 ml of 1.0M  Fe 2 solution and
the reaction is allowed to achieve equilibrium at 25C .
Ag aq   Fe2aq   Fe3aq   Ag  s  for 30 ml of the solution, 25 ml of 0.06M  KMnO4

was required for oxidation of Fe2 present. The equilibrium constant  in M 1  for the
reaction at 25C is
SECTION 2 (Maximum Marks: 24)
 This section contains SIX (06) questions.
 Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is/are
correct option(s).
 For each question, choose the correct option(s) to answer the question.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks: -2 In all other cases.

43. The incorrect statement(s) among the following statements is (are)

A) In trisilylamine molecule the nitrogen atom is sp 2 hybridized.
B) Al2Cl6 has three-centre two electron bonds.
C) IN PF2Cl3 molecule the P  F axial bond length is greater than P  Cl equatorial
bond length
D) Bong angle in NF3 is greater than the bond angle in NH 3

44. In the given question K a values of five weak acids are given. K a for HA  108 ,

HB  106 , HC  2 108 , HD  1010 , HE  107 .

Select the correct statement(s) as per the information. Given: log 2  0.3 .
A) Among NaA, NaB, NaC , NaD and NaE , the NaD is most extensively hydrolysed.
B) Among NaA, NaB, NaC , NaD and NaE , the NaB is most extensively hydrolysed.

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
C) pH of 0.1 M  aqueous solution of NaB is approximately 9.5

D) 0.1 M  solution of HE and 0.01 M  solution of HB are isohydric to each other

approximately.

45. Which of the following molecular orbital representation along with probability density
function is/are correct for H 2 ?

A) B)

C) D)

46.  G 
0
f Cr2O3 s 
 527 kJ mol 1

 G 
0
f Al2O3 s 
 827 kJ mol 1

 f H0
Cr2O3 s 
 1100 kJ

 f H0
Al2O3 s 
 1600 kJ

Which is/are correct?

A) Cr2O3 s  is reduced by Al s  in given standard condition

B) Al2O3 s  is reduced by Cr s  in given standard condition

C)  r H  for reduction of Cr2O3 by Al is 500 kJ

D) Al is strong reducing agent than Cr

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
47. A H -like species emitted a photon corresponding to the first line of Lyman series. The
photon liberated a photoelectron from He  in ground state. The de-Broglie
0
wavelength of the photoelectron is 2A . Then, the atomic number of H - like species
is
Given: Energy of electron in ground state of H -atom = 13.6 eV /atom

h  6.626  1034 J  sec , mass electron  9.1 1031 kg

A) 3 B) 2 C) 4 D) 6
48. At 25C , the dissociation constant  Ka  of weak mono basic acid  HA is numerically

equal to the dissociation constant  Kb  of its conjugate base  A  . Then, identify the

CORRECT option(s)
A) K a  HA   10 7
B) pH of 0.1M HA aqueous solution .  3.0 .

C) pH of 0.1M aqueous solution of A  10.0

D) pH of aqueous solution containing 0.1 M HA and 0.01 M HCl  2.0

SECTION 3 (Maximum Marks: 24)

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual.numeric keypad in the place designated to enter answer. If the numerical value has more than
two decimal places truncate/round- off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct numerical value is entered as answer.
 Zero Marks: 0 In all other cases.

49. The diamonds are formed from graphite under very high pressure. Given that the
densities of graphite and diamond are, respectively, 2.4 and 3.6 g / cm3 and are

independent of pressure.  f G values for graphite and diamond are zero and

3.0 kJ / mol , respectively. If the equilibrium pressure at which graphite is converted

into diamond at 25C is P bar, then the value of 0.01P is

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Narayana IIT Academy 10-08-2025_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-12_Q’P
50. 100ml 0.1 M HCl is added to 200 ml 0.1 M Na2CO3 solution. What would be the
pH of the final solution.

[For H 2CO3 , K a1  107 , K a2  1011 ]

51. Ag   A2g H  1100 KJ / mol

A g   A2g H  1200KJ / mol

Electron gain enthalpy of ‘A’ is P 10 2 KJ / mol . What is the value of P ?

52. Unexposed silver halides are removed from photographic film when they react with
3
sodium thiosulphate to form the complex ion Ag  S 2O3 2 . If the moles of Na2 S 2O3

needed to prepare 1L of a solution that dissolves 0.1 moles of AgBr by the formation
3
of Ag  S 2O3 2 is ‘ p ’, then what is 1000 p . ( K sp of AgBr  4.0  1013 and K f of
3
Ag  S 2O3 2  1.6  1012. )

53. An amount of 0.1 moles of OH  ions is obtained from 8.50 g of hydroxide of a metal.
What is the equivalent weight of the metal?
54. The ratio of the RMS speeds of CH 4 at T and SO2 at 300K is 4 :1 . The average
kinetic energy per mole of CH 4 in cal.

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