Handbook of Laser Technology and Applications Volume 1 2nd Edition Chunlei Guo Editor Subhash Chandra Singh Editor Download
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Edited by
Chunlei Guo
Subhash Chandra Singh
Second edition published 2021
by CRC Press
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Contents
Preface ............................................................................................................................................................................................ ix
Editors ............................................................................................................................................................................................ xi
Contributors ..................................................................................................................................................................................xiii
v
vi Contents
Index............................................................................................................................................................................................ 537
Preface
This updated Handbook comes at the time when the world just As the laser shines in modern applications, we added a large
celebrated the 60th anniversary of the laser. Compared to most number of new chapters refecting the most recent advance-
felds in science and technology, the laser is still a relatively ments in laser technologies. Throughout the Handbook,
young one, but its developments have been astonishing. Today, entirely new sections were added, including sections on mate-
hardly any area of modern life is left untouched by lasers, so rials processing, laser spectroscopy and lasers in imaging and
it is almost impossible to provide a complete account of this communications. Nearly all chapters in these sections are
subject. either entirely new or substantially revised. On the other hand,
As challenging as it is, this updated Handbook attempts to some of the topics previously included have seen dwindling
provide a comprehensive coverage on modern laser technology relevance today. We had to make the hard decision to let go of
and applications, including recent advancements and state-of- some of these outdated chapters from the frst edition. Despite
the-art research and developments. The main goal of develop- these deletions, this new Handbook still grows signifcantly
ing this Handbook is to provide both an overview and details from the original three volumes to the current four volumes.
of ever-expanding technologies and applications in lasers. Bringing this large project to its conclusion is the collec-
We want this Handbook to be useful for both newcomers tive efforts of many individuals. It began with the encourage-
and experts in lasers. To meet these goals, the chapters in this ment and guidance of Lu Han, the then managing editor of
Handbook are typically developed in a style that does not this Handbook. I know how much Lu cared about this proj-
require advanced mathematical tools. On the other hand, they ect. I still remember an initial phone call with Lu, we fnished
are written by the experts in each area so that the most impor- it at a late afternoon past 5 p.m. Over the phone, I was told
tant concepts and developments are covered. that I would receive the frst edition of this Handbook. To my
The frst edition of the Handbook was released in 2003. It surprise, I had the handbooks in my hand the next morning.
has been hugely popular and ranked as one of the top ten most At CRC press, this project was later passed onto Carolina
referenced materials by the publisher. Eighteen years later, Antunes and fnally to Lara Spieker, who has been essential in
although a relatively short period for many more established bringing this project to its conclusion.
scientifc felds, the Handbook has become outdated, and an Many people have provided me with indispensable help.
update is overdue. The rapid changes in lasers are certainly My co-editor, Subhash Chandra Singh, at the University of
reinforced by my own experience of teaching and researching Rochester, helped chart the layout of this new edition and
the subject in the Institute of Optics at University of Rochester. worked along with me throughout this project. Ying Zhang,
Flipping through my old lecture notes on lasers, I am often who was a senior editor at Changchun Institute of Optics, Fine
amazed at how much progress we have witnessed in this feld Mechanics, and Physics (CIOMP) in China, spent a half year
over the years. with us in Rochester, where his years of professional edito-
I am indebted to the editors of the frst edition, Colin Webb rial experience helped move this project forward signifcantly.
and Julian Jones, who brought this original Handbook into Lastly, my thanks go to Pavel Redkin of CIOMP, who made
existence. When I was asked to take over this second edi- signifcant contributions in communicating with the chapter
tion, it laid before me a daunting task of how to rejuvenate the authors and guiding them throughout the project. Additionally,
Handbook while keeping its original favour. Since many of my appreciation goes to Kai Davies, Sandeep K. Maurya, Xin
the fundamental principles of the laser are well established, Wei, and Wenting Sun for their help in this Handbook project.
we tried to honour the original authors by keeping the chap-
ters on fundamental concepts where possible. If a revision is Chunlei Guo
needed, we usually started by asking the original authors for Editor-in-Chief
the revision but if impossible, we brought in new authors to University of Rochester
revise these chapters.
ix
Editors
xi
Contributors
xiii
xiv Contributors
Richard Shoemaker
Since the operation of the frst laser in 1960, literally hundreds propagation through gain and non-linear media including the
of different laser varieties have been developed and the light use of Beer’s law, rate equations, the Franz–Nodvik solution,
that they produce is being used in thousands of applications refractive index effects and the inclusion of spontaneous emis-
ranging from precision measurement to materials process- sion. The last section of the article discusses the selection and
ing to medicine. Underlying all these varieties, however, is a validation of laser-modelling software packages. Excluded
small set of basic physical principles upon which laser opera- from the discussion of numerical modelling in Chapter 4 is
tion, laser beam propagation and the interaction of laser beams a treatment of numerical modelling for semiconductor lasers.
with matter depend. The explanation of these principles is the Although obviously important, these lasers are by far the most
subject of this section. Chapter 2 begins by explaining the diffcult laser systems to model, and the development of soft-
basic physics that allows one to construct optical amplifers, ware that can do such modelling is currently an active research
including discussions of energy levels and level populations, topic at a number of universities and companies. The essen-
stimulated and spontaneous emission, optical lineshapes and tial physics needed to model these lasers properly includes the
gain saturation. It then discusses the principles that allow an complex non-linear interactions between the multi-component
optical amplifer to be turned into a laser (i.e. an optical oscil- electron-hole plasma that produces the laser radiation, the
lator) by the addition of feedback in the form of an optical intense laser radiation within the waveguide resonator, and the
resonator. The article closes with a discussion of the physics several layers of semiconductor materials that form the laser.
that determines the linewidth, coherence properties and power As a consequence, the gain and refractive index cannot be rep-
of the laser output. The frequency and spatial distribution of a resented in a parametric form using the laser rate equations
beam produced by a laser are largely determined by the laser discussed in Chapter 4. The gain peak and the gain lineshape
resonator, and as a result, an understanding of optical resona- both change on the fy with changes in internal carrier density
tors and their modes is key to understanding the properties of and temperature, and electrical and heat transport from the
laser beams. external contacts into the active region of the p-i-n structure
Many applications of lasers rely upon the fact that the light also critically infuence the optical properties by modifying
produced by most lasers is coherent and thus can exhibit strong the optical gain and refractive index.
interference effects. Usually, the light is also highly polarized, Chapter 5 presents the principles of Gaussian beams, stable
and this polarization can be utilized to good effect in many resonators, stable resonator axial and transverse modes, beam
other applications. Chapter 3 covers the basic principles of quality, mode matching, plane parallel resonators, unstable
coherent wave interference, Mach–Zehnder interferometers, resonators and frequency selection. Chapter 6 supplements
Michelson interferometers, Fabry–Pérot interferometers and this material by discussing the principles governing hollow
partial coherence. The discussion then moves to polarization waveguide optical resonators, widely used for carbon dioxide
concepts including the polarization ellipse, crystal optics, lasers. The purpose for which most lasers are purchased or
retarding wave-plates, polarizing prisms, circular birefrin- built is to make use of the laser beam that it produces. In many
gence, polarization analysis, and applications of polarization applications, making effective use of this beam requires that
optics, including electro-optic and magneto-optic effects. it be properly controlled in time (e.g. pulsed lasers), space (e.g.
Chapter 4 discusses the numerical modelling of laser beam focusing), frequency or amplitude.
beam propagation within and outside the laser resonator. Chapter 7 forms the theoretical basis for the non-linear opti-
These models are important tools used by optical engineers cal phenomena.
in designing laser systems and laser applications. The article Chapter 8 covers the principles used in laser beam con-
begins by discussing the representation of optical beams for trol, including beam focusing with lenses, beam transmission
numerical work, followed by descriptions of specifc meth- through apertures, the M value, transverse and axial mode con-
ods for handling beam propagation: the split step method, trol, frequency stabilization, frequency selection, astigmatic
fnite difference propagation and angular spectrum propaga- beam shaping, Q-switching, mode locking, cavity dumping
tion. Numerical calculations of propagation in homogeneous and spatial fltering. One of the key features that make lasers
media including issues of sampling and propagation control so useful is their ability to produce optical felds having very
are then presented, followed by an elementary discussion of high intensity. When these felds interact with matter, a great
1
2 Handbook of Laser Technology and Applications
variety of non-linear optical effects can occur. Some of these, fbres, beginning with basic fbre propagation theory and then
such as optical frequency doubling, can be very useful, while turning to a variety of important propagation effects including
others, such as optical damage, cause problems that need to be attenuation, dispersion, birefringence and polarization, non-
controlled. Some of the most economically important appli- linear effects and mode coupling. Many applications of lasers
cations of lasers rely upon our ability to confne laser beams would be severely limited or impossible if we were unable to
within optical waveguides where they can be modulated, accurately and sensitively detect the energy or intensity of the
amplifed, split, switched and recombined in ways similar to beam with some type of optical detector.
those used to manipulate currents in electronic circuits. These Chapter 9 presents basic descriptions and operating prin-
capabilities together with the ability to transmit the light over ciples of photomultipliers, p-n photodiodes, Schottky and ava-
long distances through optical fbres with very low loss make lanche diode detectors, photoconductive detectors and thermal
optical communication systems possible. Chapter 7 covers detectors, including bolometers and pyroelectric detectors.
the theory of optical waveguides and fbres. The chapter frst The fnal sections of the article discuss noise in photodetec-
introduces the primary types of waveguides and their fabri- tion, including detector fgures of merit, noise sources, and
cation, and then presents the basic theory of planar and 2D methods of minimizing detector noise.
waveguides. The second part of the article turns to optical Chapter 10 describes the principles of laser.
2
Basic Laser Principles1
Christopher C. Davis
CONTENTS
2.1 Introduction............................................................................................................................................................................4
2.2 The Amplifer–Oscillator Connection ...................................................................................................................................4
2.3 The Energy Levels of Atoms, Molecules and Condensed Matter .........................................................................................5
2.4 Spontaneous and Stimulated Transitions...............................................................................................................................6
2.4.1 Spontaneous Emission...............................................................................................................................................6
2.4.2 The Lineshape Function ............................................................................................................................................7
2.4.3 Stimulated Emission..................................................................................................................................................8
2.4.4 The Relation between Energy Density and Intensity ................................................................................................8
2.4.5 Stimulated Absorption.............................................................................................................................................10
2.5 Transitions between Energy Levels for a Collection of Particles in Thermal Equilibrium ................................................ 11
2.6 The Relationship between the Einstein A and B Coeffcients.............................................................................................. 11
2.6.1 The Effect of Level Degeneracy..............................................................................................................................12
2.6.2 Ratio of Spontaneous and Stimulated Transitions ..................................................................................................13
2.7 Optical Frequency Amplifers and Line Broadening........................................................................................................... 14
2.7.1 Homogeneous Line Broadening .............................................................................................................................. 14
2.7.2 Natural Broadening ................................................................................................................................................. 14
2.7.3 Other Homogeneous Broadening Mechanisms.......................................................................................................15
2.8 Inhomogeneous Broadening ................................................................................................................................................ 16
2.8.1 Doppler Broadening ................................................................................................................................................ 16
2.8.2 Energy Bands in Condensed Matter........................................................................................................................ 18
2.9 Optical Frequency Amplifcation with a Homogeneously Broadened Transition............................................................... 18
2.9.1 The Stimulated Emission Rate in a Homogeneously Broadened System ............................................................... 21
2.9.2 Optical Frequency Amplifcation with Inhomogeneous Broadening Included ...................................................... 21
2.10 Optical Frequency Oscillation—Saturation ........................................................................................................................22
2.10.1 Homogeneous Systems............................................................................................................................................22
2.10.2 Inhomogeneous Systems .........................................................................................................................................24
2.11 Power Output from a Laser Amplifer .................................................................................................................................28
2.12 The Electron Oscillator Model of a Radiative Transition....................................................................................................28
2.12.1 The Connection between the Complex Susceptibility, Gain and Absorption.........................................................30
2.12.2 The Classical Oscillator Explanation for Stimulated Emission .............................................................................. 31
2.13 From Amplifer to Oscillator—the Feedback Structure......................................................................................................33
2.14 Optical Resonators Containing an Amplifying Media........................................................................................................34
2.15 The Oscillation Frequency...................................................................................................................................................37
2.15.1 Multi-mode Laser Oscillation .................................................................................................................................37
2.15.2 Mode Beating ..........................................................................................................................................................42
2.16 The Characteristics of Laser Radiation ...............................................................................................................................43
2.16.1 Laser Modes ............................................................................................................................................................44
2.16.2 Beam Divergence.....................................................................................................................................................46
2.16.3 Linewidth of Laser Radiation..................................................................................................................................46
2.17 Coherence Properties ...........................................................................................................................................................47
2.17.1 Temporal Coherence................................................................................................................................................47
1 This chapter is based on a longer and more detailed exposition of these principles in Ref. [1].
3
4 Handbook of Laser Technology and Applications
FIGURE 2.2 Schematic diagram of a basic laser structure with an amplifying medium in a resonant cavity formed by two feedback mirrors, M.
molecule thus has electronic, vibrational and rotational com- reserve further discussion of the energy bands in condensed
ponents. A molecule in a particular combination of electronic matter until a little later and, for the moment, will consider the
and vibrational states is described as being in a vibronic state. energy levels of particles as relatively sharp and not strongly
A state with a specifc combination of vibrational and rota- infuenced by inter-particle interactions.
tional energies would be described as being in a vibrot state.
As a rough rule of thumb, transitions between different
vibronic states where the electronic state changes lie in the vis-
ible spectrum with energy spacings3 ~20 000 cm−1 and corre-
2.4 Spontaneous and Stimulated Transitions
spond to an energy spacing of 3 × 1010 h/λ J. Transitions between To build an amplifer that operates at optical frequencies,
vibrot states where the electronic energy does not change but we use the energy delivered as the particles that constitute
the vibrational state does are typically ~1000 cm−1. Transitions the amplifying medium make jumps between their different
between different rotational states where the electronic and energy levels. The medium may be gaseous, liquid, a crystal-
vibrational states do not change are typically ~100 cm−1. In line or glassy solid, an insulating material or a semi-conductor.
practical terms, vibrational transitions are typically in the The particles of the amplifying medium, whether these are
3–20 μm range and rotational transitions are typically in the atoms, molecules or ions, can occupy only certain discrete
50–1000 μm range. energy levels. Consider such a system of energy levels, shown
In the gas phase, the energy levels of atoms or molecules are schematically in Figure 2.3, particles can make jumps between
quite sharp and distinct, as shown schematically in Figure 2.3, these levels in three ways. In the case of an atomic amplifer,
although we shall see later that even these precise energies are these energy jumps involve electrons moving from one energy
‘broadened’. This broadening occurs for several reasons but level to another.
perhaps most importantly because of the interactions between
neighbouring particles. In condensed matter, whether this be
in the solid or liquid state, there are so many particles close to
2.4.1 Spontaneous Emission
any individual particle of interest, and the inter-particle inter- When a particle spontaneously falls from a higher energy level
actions are strong. Consequently, the allowed energies of parti- to a lower one, as shown in Figure 2.4, the emitted photon has
cles in the medium occupy broad, continuous ranges of energy frequency
called energy ‘bands’. The lowest-lying energy band, which is
analogous to the ground state of an isolated particle, is called Ei − E j
˜ ij = . (2.6)
the valence band. The next highest band of allowed energies h
is called the conduction band. An energy band can be thought This photon is emitted in a random direction with arbitrary
of as the result of very many sharp isolated energy states hav- polarization (except in the presence of magnetic felds but this
ing their energies ‘smeared’ out so that they overlap. We will need not concern us here). The photon carries away momentum
h/λ = hν/c, and the emitting particle (atom, molecule or ion)
3 The cm−1 unit is often used to describe energy spacings. A transition at recoils in the opposite direction. The probability of a sponta-
wavelength λ (cm) between two levels has an energy spacing character- neous jump within a small time interval is given quantitatively
ized by 1/λ cm−1. by the Einstein A coeffcient defned by AijΔt = ‘probability’ of
Basic Laser Principles 7
FIGURE 2.4 Representation of the spontaneous emission process for two levels of energy Ei and Ej.
a spontaneous jump from level i to level j during a short time to be absolutely forbidden, some jumps are so unlikely that
interval ˜t ° Aij has units of s−1. To preserve the concept of AijΔt levels whose electrons can only fall to lower levels by such
as a true measure of the probability of a spontaneous emission, jumps are very long lived. Levels with lifetimes in excess of
the time interval must be chosen so that Aij Δt ≪ 1. 1 h have been observed under laboratory conditions. Levels
For example, if there are Ni particles per unit volume in level which can only decay slowly, and usually only by forbidden
i, then Ni Aij Δt make jumps to level j in a short time interval. transitions, are said to be metastable.
The total rate at which jumps are made between the two levels is
The summation runs over all levels j lower in energy than level ˜ −˝
g(v0 , v) d v = 1. (2.11)
i. The total rate at which the population of level i changes by g(v0, v) dv represents the probability that a photon will be emit-
spontaneous emission is ted spontaneously in the frequency range v + dv. The lineshape
function g(v0, v) is a true probability function for the spectrum
dN i
= − N i Ai (2.9) of emitted radiation and is usually sharply peaked near the fre-
dt
quency ν 0, as shown in Figure 2.5. Since negative frequencies
which has the solution do not exist in reality, the question might properly be asked:
‘Why does the integral have a lower limit of minus infnity?’
N i = N i0 e − Ait (2.10) This is done because g(v0, v) can be viewed as the Fourier
transform of a real function of time, so negative frequencies
where N i0 is the population density of level i at time t = 0. have to be permitted mathematically. In practice, g(v0, v0) is
The population of level i falls exponentially with time as only of signifcant value around a large value of v0 so
particles leave that level by spontaneous emission. The time
˛
˜
in which the population falls to 1/e of its initial value is called
g(° 0 ,° ) d° 1. (2.12)
the natural lifetime of level i, τi, where τi = 1/Ai. The magni- 0
tude of this lifetime is determined by the actual probabilities
The amount of radiation emitted spontaneously by a collection
of jumps from level i by spontaneous emission. Jumps which
of particles can be described quantitatively by their spectral
are likely to occur are called allowed transitions, those which
radiant intensity Ie(v). The units of spectral radiant intensity
are unlikely are said to be forbidden. Allowed transitions in
are watts per hertz per steradian.4 The total power (watts) emit-
the visible region typically have Aij coeffcients in the range
ted in a given frequency interval dv is
106 –108 s−1. Forbidden transitions in this region have Aij coef-
fcients below 104 s−1. These probabilities decrease as the wave-
length of the transition increases. Consequently, levels that
can decay by allowed transitions in the visible have lifetimes
W (° ) =
˜ I (° ) d° d˝,
s
e (2.13)
generally shorter than 1 μs; similar forbidden transitions have 4 The steradian is the unit of solid angle, Ω. The surface of a sphere
lifetimes in excess of 10–100 μs. Although no jump turns out encompasses a solid angle of 4π steradians.
8 Handbook of Laser Technology and Applications
area in the direction of travel of the wave. The spectral distri- (2.20)
ˇ
bution of intensity, I (v), is related to the total intensity, I0, by = − N 2 B21
˜
−ˇ
g( v) ˛ ( v) d° .
FIGURE 2.7 A volume of space swept through per second by part of a plane wave.
I(° )
˜ (° ) = . (2.21)
c FIGURE 2.9 A monochromatic energy density spectrum.
and
= −N 2 B21
˜
−
g ( v0 , v )˛ 21˝ ( v − v21 ) d° (2.26)
we can assume that the energy density ρ(v) is constant over the dt
= −N1 B12
˜−ˆ
g(° 0 ,° ) ˛ (° ) d° . (2.28)
narrow range of frequencies where g(v0 , v) is signifcant. In
this case, equation (2.20) gives Once again B12 is a constant specifc to the transition between
dN 2 levels 1 and 2 and is called the Einstein coeffcient for stim-
= −N 2 B21 ˜ (v) (2.27) ulated absorption. Here, again, ρ(v) is the energy density of
dt
the stimulating feld. There is no analogue in the absorption
where ρ(v) ≃ ρ(v0) is the energy density in the frequency range process to spontaneous emission. A particle cannot spontane-
where transitions take place. ously gain energy without an external energy supply. Thus, it
is unnecessary for us to continue to describe the absorption
2.4.5 Stimulated Absorption process as stimulated absorption.
It is interesting to view both stimulated emission and
As well as making stimulated transitions in a downward direction,
absorption as photon–particle collision processes. In stimu-
particles may make transitions in an upward direction between
lated emission, the incident photon produces an identical
their energy levels by absorbing energy from an electromagnetic
photon by ‘colliding’ with the particle in an excited level, as
feld, as shown in Figure 2.10. The rate of such absorptions and
shown in Figure 2.11a. After the stimulated emission process,
the rate at which particles leave the lower level are N1ρ(v)B12g(v0,
both photons are travelling in the same direction and with the
v) s−1 Hz−1 m−3, which yields a result similar to equation (2.20)
same polarization as the incident photon originally had. When
light is described in particle terms, the polarization state
describes the angular motion or spin of individual photons.
Left- and right-hand circularly polarized light corresponds in
this particle picture to beams of photons that spin clockwise
and counterclockwise, respectively, about their direction of
propagation. Linearly polarized light corresponds to a beam
of photons that has no net angular momentum about an axis
parallel to their direction of propagation. In stimulated emis-
sion, the stimulated photon has exactly the same frequency
as the stimulating photon. In absorption, the incident photon
disappears, as shown in Figure 2.11b. In both stimulated emis-
FIGURE 2.10 Representation of the stimulated absorption process for sion and absorption, the particle recoils to conserve linear
two levels of energy E1 and E2 . momentum.
FIGURE 2.11 Photon–particle ‘collision’ pictures of the stimulated emission and absorption processes: (a) stimulated emission and (b) absorption.
Basic Laser Principles 11
8˝h° 3 ˆ 1
˜ (° ) = ˘ (2.32)
c3 ˇ e h° kT − 1
since in thermal equilibrium, the radiation in the cavity will be
black-body radiation. Although real particles in such a cavity
possess many energy levels, we can restrict ourselves to con-
sidering the dynamic equilibrium between any two of them, as
shown in Figure 2.13. The transitions that occur between two
such levels as a result of interaction with radiation essentially
FIGURE 2.12 Spectral distribution of black-body radiation at different occur independently of the energy levels of the system, which
temperatures. are not themselves involved in the transition.
S62
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63
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