Safety data sheet
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
1. Identification
Product identifier
Basorol® 904
Chemical name: Ethylenediamine, ethoxylated and propoxylated
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Performance Chemicals for Oilfield Applications
Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Global Oilfield Chemicals
Telephone: +49 621 60-0
E-mail address:
[email protected] Emergency telephone number
International emergency number:
Telephone: +49 180 2273-112
2. Hazards Identification
Classification of the substance or mixture
According to UN GHS criteria
No need for classification according to GHS criteria for this product.
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Label elements
Globally Harmonized System (GHS)
The product does not require a hazard warning label in accordance with GHS criteria.
Other hazards
According to UN GHS criteria
No specific dangers known, if the regulations/notes for storage and handling are considered.
3. Composition/Information on Ingredients
Substances
Chemical nature
Ethylenediamine, ethoxylated and propoxylated
CAS Number: 26316-40-5
Hazardous ingredients (GHS)
According to UN GHS criteria
No particular hazards known.
Mixtures
Not applicable
4. First-Aid Measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Rinse mouth and then drink 200-300 ml of water.
Most important symptoms and effects, both acute and delayed
Symptoms: (Further) symptoms and / or effects are not known so far
Hazards: No data available.
Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam
Special hazards arising from the substance or mixture
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Information regarding personal protective measures, see section 8.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Dispose of absorbed material in accordance with regulations.
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
7. Handling and Storage
Precautions for safe handling
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place.
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
8. Exposure Controls/Personal Protection
Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with low
efficiency for solid particles (e.g. EN 143 or 149, Type P1or FFP1)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Form: solid
Colour: slightly milky, cloudy
Odour: mild, of polyol
Odour threshold:
not determined
pH value: 8 - 11
Freezing point: approx. 29 °C
(1.013 hPa)
Boiling point: > 149 °C
Flash point: > 262 °C (ASTM D92)
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.
Flammability: not flammable (derived from flash point)
Lower explosion limit:
For liquids not relevant for
classification and labelling.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature:
not determined
Vapour pressure: < 0,1 mmHg
(25 °C)
Density: 1,03 g/cm3
(60 °C)
Solubility in water: soluble
Partitioning coefficient n-octanol/water (log Kow):
not determined
Thermal decomposition: not determined
Viscosity, dynamic: 320 mPa.s
(60 °C)
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
Other information
Self heating ability: It is not a substance capable of
spontaneous heating.
Bulk density:
not determined
Hygroscopy: The product has not been tested.
Grain size distribution: No data available.
Molar mass: 6.700 g/mol
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
Corrosion to metals: No corrosive effect on metal.
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
caustics, halogens, Alkalines, acids, reactive chemicals
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information
Information on toxicological effects
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 5.000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)
Respiratory/Skin sensitization
Assessment of sensitization:
The chemical structure does not suggest a sensitizing effect.
Germ cell mutagenicity
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect.
Carcinogenicity
Assessment of carcinogenicity:
The chemical structure does not suggest a specific alert for such an effect.
Experimental/calculated data:
Not listed as a carcinogen by OSHA, IARC, & NTP.
Reproductive toxicity
Assessment of reproduction toxicity:
The chemical structure does not suggest a specific alert for such an effect.
Experimental/calculated data:
not applicable
Developmental toxicity
Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect.
Specific target organ toxicity (single exposure)
Remarks: No applicable information available.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
No data available.
Aspiration hazard
No aspiration hazard expected.
Other relevant toxicity information
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
12. Ecological Information
Toxicity
Toxicity to fish:
LC50 (96 h) > 500 mg/l, Leuciscus idus
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l
Aquatic plants:
EC50 (72 h), algae
not determined
Microorganisms/Effect on activated sludge:
EC50 > 1.000 mg/l
Chronic toxicity to fish:
No data available.
Chronic toxicity to aquatic invertebrates:
No data available.
Persistence and degradability
Assessment biodegradation and elimination (H2O):
Moderately/partially eliminated from water.
Elimination information:
60 - 70 % Bismuth-active substance (mod. OECD 303A)
30 % DOC reduction (OECD Guideline 302 B) Moderately/partially eliminated from water.
Bioaccumulative potential
Assessment bioaccumulation potential:
Accumulation in organisms is not to be expected.
Mobility in soil
Assessment transport between environmental compartments:
Volatility: The substance will not evaporate into the atmosphere from the water surface.
Adsorption in soil: Adsorption to solid soil phase is possible.
Results of PBT and vPvB assessment
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria. Self classification
Other adverse effects
The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Additional information
Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.
Add. remarks environm. fate & pathway:
Treatment in biological waste water treatment plants has to be performed according to local and
administrative regulations.
Other ecotoxicological advice:
Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations. Do not release untreated into natural waters.
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
13. Disposal Considerations
Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
14. Transport Information
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Page: 10/11
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Inland waterway transport
ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user:
Transport in inland waterway vessel
Not evaluated
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Page: 11/11
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 27.09.2019 Version: 2.1
Product: Basorol® 904
(ID no. 30430413/SDS_GEN_00/EN)
Date of print 10.01.2025
Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or
mixture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
16. Other Information
Information on intended use: This product is of industrial quality and unless otherwise specified or
agreed intended exclusively for industrial use. This includes the mentioned and recommended
usage. Any other intended applications should be discussed with the manufacturer. In particular this
concerns the application for products that are the object of special standards and regulations.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.