Revision Date : 10/06/2011

Revision Number : 3

MATERIAL SAFETY DATA SHEET

MFIL-200(G)(RG Type)
According to Regulation (EU) No.453/2010
According to Regulation (EU) No.1907/2006)

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/ UNDERTAKING

1.1 Product Identifier :

• Product Name: Precipitated Silica
• Grade: MFIL-200(G)(RG Type)
• Chemical Name : Silicon Dioxide
• CAS No. 112926-00-8
• EC No. : 231-545-4
1.2 Relevant Identified Uses of the Substance: Polymers Industry: plastics, rubber, silicones
1.3 Details of the supplier of the Safety Data Sheet :
Manufacturer: Madhu Silica Pvt. Ltd.
53,55,56-B, GIDC, Chitra, Bhavnagar – 364 004.
Tel No : 0091-278-3209029 / 3209154 / 2939550 / 2939560
E-Mail:[email protected]
Website : www.madhusilica.com
OR in EU : Indus Chemie Ltd.,
18, Dove Park Uxbridge Road
Hatch End Pinner HA54EB, UK
Tel No. : 0044 208-259-2017
Email : [email protected]

1.4 Emergency Telephone No. 0091-278 – 3209029

(Mobile number of Sr. Product Development Manager should be asked beyond GMT time frame of 08.30 - 17.30 pm)
SECTION 2: HAZARDS IDENTIFICATION

Synthetic Amorphous Silica is not considered to be hazardous in accordance with Directive 67/548/EEC.
2.1 Classification of the substance : No classification according to Directive 67/548/EEC criteria
2.2 Label Elements : - no single word label
2.3 Other Hazards : - Prolonged exposure with skin, eyes and respiratory tract may cause irritation resulting in mind
restlessness, eyes closing and skin dryness.

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

3.1 Substance:

Ingredients EC No. CAS No. Content Classification

No classification
112926-00-8
Silicon dioxide 231-545-4 >98.5% according to Directive
(7631-86-9 old)
67/548/EEC criteria

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 SECTION 4: FIRST AID MEASURES :
No special first aid measures required
4.1 Description of first aid measures :
Inhalation
Remove to fresh air. Possible effects are cough & sneering.
Skin Contact
Rinse with water.
Eye Contact
Possible discomfort is due to foreign substance (Particles effect). Rinse the eyes with plenty of water.
Ingestion
Clean mouth with water and drink plenty of water.
4.2 Most Important symptoms and effects, both acute and delayed : as described in section 4.1 above
4.3 Indication of any Medical Attention and Special Treatment needed :
No immediate medical attention required
Movement of exposed individual from area to fresh air is recommended
There is no requirement for removal and special handling of clothing and shoes from the exposed individual
No personal protective equipment are recommended for the first aid responder
The material is not combustible. No special protection required beyond normal standard safety and good industrial
hygienic practice.

SECTION 5: FIRE FIGHTING MEASURES

5.1 Extinguishing media:

Not combustible. Stable, amorphous silica can be used as a fire extinguishing agent . Dry chemical powder,
appropriate foam, water spray or Carbon dioxide can also be used as extinguishing media.
Unsuitable extinguishing media
High pressure water jet
5.2 Special hazards arising from the substance :
Product is considered not to be flammable. Danger of dust explosion. Sufficient measures must be taken to retain fire-
control water and should not be allowed to enter drains or watercourses. Dispose of contaminated water and soil
according to local regulations.
5.3 Advice for Fire Fighters :
A self-contained breathing apparatus and suitable protective clothing should be worn by fire fighters.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, Protective Equipment and Emergency Procedures

For non- emergency personnel: If dust occurs, it is recommended to use mark with P2 filter and safety glasses with
side shield. Take precautionary measures against electrostatic discharge. Ventilate the area.
For emergency personnel : Suitable Personal Protective Clothes in full sleeves recommended in regular cotton/
nylon fabric and a dust mask along with safety glasses with side shield and a helmet in the manufacturing premises.
6.2 Environmental precautions :
Prevent any spillage from entering drains or water courses.
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6.3 Methods and Material for Containment and clean up :
Mechanically take up or sweep up the spillage. Avoid raising dust.
Transfer to a suitable container for waste disposal. Ventilate area.
No other special information needed
6.4 Reference to other sections : Section 8 & Section 13

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe Handling:

To avoid dust generation, this substance should only be handled by trained personnel wearing suitable protective
equipment (see section 8-personal protection).
Avoid inhalation, skin, and eye contact.
Avoid prolonged or repeated exposure to product.
Avoid creating dust by proper enclosures.
Do not handle near open flame, sources of heat, static charge or ignition. Take precautionary measures against static
discharge. All metal parts of the mixing and processing equipment must be earthed. Ensure all equipment is
electrically earthed before beginning transfer operations.
Good general ventilation is required.
When using, do not eat, drink or smoke at the workplace.
Wash hands with soap and water after handling.
7.2 Conditions for Safe Storage, including any incompatibilities :
Store in closed bags or containers tightly closed and properly labeled.
Store at ambient temperature and well-ventilated area.
Do not store together with volatile chemicals as they may be adsorbed onto the product.
The material will be highly susceptible to odour, moisture and microbial infestation ( for food grade applications ) if
stored in damp atmosphere , opened or exposed bags.
Take precautions against static charge by ensuring good earthing of equipment, particularly in flammable environment.
7.3 Specific end Uses :
The material will be used for specialty applications as referred in subsection 1.2.
As per Chemical Safety Report the use is identified in Polymers Industry: plastics, rubber, silicones
corroborating with SU11, SU12, PC0 and PC32 & PROC 2, 3, 5.
Storage conditions as per subsection 7.2 would be applicable.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control Parameters :

Exposure limit values
Type of limit: TWA 10mg/m3, the value is for total dust containing no asbestos & <1% crystalline silica.
Air sampling can be recommended to monitor silica dust particles.
8.2 Exposure Controls :
Appropriate Engineering Controls :
Use process enclosure, local exhaust ventilation or other controls to minimize airborne levels of the product.

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Individual Protection Measures, such as Personal Protective Equipment :
Wear recommended personal protective equipment as appropriate and detailed below :

Eye/ Face protection

Wear safety glasses.
Eye wash facilities and a safety shower should be easily accessible.
Respiratory protection
Seek professional advice prior to respirator selection. Atmospheric level should be maintained below the exposure
limit. If airborne concentration is high use mask or respirator.
Hand protection
Wear chemical protective gloves.
Before breaks and at the end of work thoroughly wash hands with soap and water and then apply protection cream.
Skin protection
Wear full sleeve clothes protective clothing.
Wash contaminated clothing before reuse.
Clean footwear before reuse.
Environmental exposure controls
All necessary precautions must be taken to avoid release of dust particles into the environment.
Refer to Local, State or National Legislation for Environmental and Pollution control.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on Basic Physical and Chemical Properties :

Form & Colour : White Granules amorphous
Odour : Odourless
Substance type : Inorganic
pH : 6.0 – 7.0
Boiling point/boiling range : > 1700°C
Flash point : conclusive, but not sufficient for classification
Flammability (solid, gas) : conclusive, but not sufficient for classification
Explosive properties : conclusive, but not sufficient for classification
Oxidizing properties : conclusive, but not sufficient for classification
Vapour pressure : No Vapour pressure at ambient Temperature
Specific Gravity : 2 ± 0.1
Solubility – water : Not Soluble
Solubility – other : soluble in 10% NaOH
Partition coefficient : Not applicable
Vapour density : Not applicable
Evaporation rate : Not applicable

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9.2 Other information :
Melting point/melting range : Approx. 1710°C
BET Surface area : 180 - 200 m2/gm
Conductivity : less than 1000 µS/cm

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity : This is an inert material
10.2 Chemical Stability: Stable under ordinary conditions of use and storage.
10.3 Possibilities of Hazardous Reaction : Nil
10.4 Conditions to avoid
Keep away from direct sunlight, heat and sources of ignition or moisture.
Take precautionary measures against static charge.
10.5 Incompatible materials: Avoid contact with strong oxidizers.
10.6 Hazardous decomposition products
No hazardous decomposition products under normal conditions of storage.
Stable and inert product.
May include oxides of carbon on burning.
Hazardous polymerization products not reported.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects :
As per EU Directive 67/548/EEC this substance is described as non-hazardous. It is an inert material hence not toxic.
Inhalation : No clinical symptoms, except restlessness & eye closing. Non-toxic.
Ingestion : No demonstratable health risk due to SAS exposure.
Skin contact : May be irritating to skin due to desiccative and defatting property resulting in skin dryness. Non-toxic.
Eye contact : Data not available; may be irritating to eyes.
Relevant Hazard Classes :
Acute toxicity : conclusive, but not sufficient for classification
Skin Corrosivity/irritation : conclusive, but not sufficient for classification
Respiratory Sensitization : conclusive, but not sufficient for classification
Repeated-dose toxicity : conclusive, but not sufficient for classification
Germ Cell Mutagenicity : conclusive, but not sufficient for classification
Carcinogenicity : conclusive, but not sufficient for classification
Reproductive toxicity : conclusive, but not sufficient for classification
Others : not applicable
SECTION 12: ECOLOGICAL INFORMATION
12.1 Toxicity : conclusive, but not sufficient for classification
12.2 Persistence and Degradability : conclusive, but not sufficient for classification
12.3 Bioaccumulative potential : conclusive, but not sufficient for classification
12.4 Mobility in soil : conclusive, but not sufficient for classification
12.5 Results of PBT and vPvB assessment : not assessed to be PBT or vPvB
12.6 Other adverse effects : conclusive, but not sufficient for classification

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 SECTION 13: DISPOSAL CONSIDERATIONS
Product & Contaminated Packaging: In accordance with local, Federal and state environmental regulations.

13.1 Waste Treatment Methods :

Land filling
Substance is inert hence there are no special physical / chemical properties that may affect treatment
Sewage disposal is discouraged
There are no special precautions on above recommended waste treatment except local, federal, state environmental
regulations

SECTION 14: TRANSPORT INFORMATION

Not classified as dangerous in the meaning of transport regulations.
This product is not classified as dangerous for transport in accordance with CDG, IMDG, ADR, RID, ICAO/IATA.
Unused SAS is not classified as a dangerous good or hazardous waste hence no UN number is applicable.
14.1 UN number : Not applicable
14.2 UN Proper Shipping Name : Not applicable
14.3 Transport Hazard Class(es) : Not applicable
14.4 Packing Group: Not applicable
14.5 Environmental Hazard : Not applicable
14.6 Special Precautions for use : Not applicable
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code : Not applicable

SECTION 15: REGULATORY INFORMATION

This product is not classified as dangerous for supply in accordance with Directive 67/548/EEC.
15.1 Safety, Health and Environmental Regulations / Legislation specific for the substance : Nil
15.2 Chemical Safety Assessment : Not required, since classified as non-hazardous for all end-points.

SECTION 16: OTHER INFORMATION

This information is furnished without warranty expressed or implied, except that it is accurate to the best of knowledge
with M/s. Madhu Silica Pvt. Ltd. The data on this sheet is related only to the specific material designated therein.
Madhu Silica assumes no legal responsibility for use or reliance upon these data.
Workers may be trained for proper PPE usage for protection of personal health.
Appropriate training in bag handling, transferring substance in relevant mixtures be given to avoid dust explosion in the
work environment.
Classification and Labeling Danger Symbol – No single word Label or classification
Risk Phrases – N.A.

Details of Revision:

Revised MSDS according to Regulation (EU) No.453/2010 & (EU) No.1907/2006

Issue No: 03 Issue Date: 10th June 2011

Replaces Issue No.: 02 Dated: 20th July 2009

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