NEET ANSWER KEY & SOLUTIONS
SUBJECT :- CHEMISTRY
CLASS :- 12th PAPER CODE :- CWT-1
CHAPTER :- SOLUTION
ANSWER KEY
1. (A) 2. (C) 3. (A) 4. (C) 5. (D) 6. (B) 7. (C)
8. (B) 9. (B) 10. (C) 11. (D) 12. (B) 13. (C) 14. (C)
15. (C) 16. (B) 17. (D) 18. (B) 19. (D) 20. (B) 21. (B)
22. (D) 23. (D) 24. (D) 25. (D) 26. (B) 27. (A) 28. (A)
29. (C) 30. (A) 31. (A) 32. (A) 33. (C) 34. (A) 35. (C)
36. (D) 37. (C) 38. (A) 39. (B) 40. (C) 41. (C) 42. (D)
43. (B) 44. (D) 45. (C) 46. (B) 47. (D) 48. (D) 49. (D)
50. (B)
SOLUTIONS
7. (C)
SECTION-A
Sol. V.P. depends on temperature.
1. (A)
Sol. Due to H-bonding 8. (B)
Sol. Non volatile substance has no V.P.
2. (C)
8 9. (B)
40 = 0.2 M Sol. Vapour pr. depends on temperature not
Sol.
1 volume.
3. (A) 10. (C)
Sol. Total mass of solution = (15 + 35) gram = Sol. Colligative properties of the solution
50 gram depend upon concentration of solute
mass percentage of methyl alcohol particles.
Mass of methyl alcohol
= × 100 11. (D)
Mass of solution
15 12. (B)
= × 100 = 30%
50 Sol. For dissociation (i > 1)
4. (C) 13. (C)
w C
C (1 )
Sol.
0.25
= 46 Sol. i= n i = 1 –
1 w 100 w C n
46 18
w 14. (C)
0.25 46
=
1 w 100 w 15. (C)
46 18 P n w mA
Sol. = XB B B
w = 46 P0 nA mB w A
w% = 46%
w B mA w mA
= B
5. (D) mB w A glucos e mB w A urea
xB 1000 w B 18 1 18
Sol. We know, m = =
1– xB mA 180 100 60 50
wB= 6g
Given m = 5.2 and mA = 18
x 1000
5.2 = B 16. (B)
1– xB 18 in
Sol. RLVP =
xB = 0.086 in N
2n
so 0.167 =
6. (B) 180
2n
Sol. V.P. does not depends on surface area of 18
liquid. (it depends on temperature). so n=1
1
17. (D) 26. (B)
Sol. On addition of water, mole fraction of Sol. x3y2 3x2+ + 2y3– for complete
solvent will increase hence vapour ionization.
pressure of solution will also increase 1– n m
p = p0xA i = 1 + (m + n – 1)
18. (B) i = 1 + (2 + 3 – 1) × 0.25 = 1 + 1 = 2
268 167 Tb = i × kb × m = 2 × 0.52 × 1 = 1.04
Sol. = x/1 So x = 0.605 B.P. of solution (Tb) = Tb + Tbº = 1.04 +
167
373 = 374.04 K Ans.
19. (D) 27. (A)
Pº P 2.08
Sol. = 0.05 = XB Sol. Tb = ikb m so i= =4
Pº 0.52 1
Where XB = mole fraction of solute. so the compex is K3 [Fe(CN6)]
1000 XB K3 [Fe(CN)6]
+
3 K + [Fe(CN)6]
3–
Molality = = 1000 × 0.05 / 0.95
(XA MA )
× 18 28. (A)
Sol. Higher freezing point lesser Tf
20. (B) lesser molality
lesser number of particles
21. (B)
wB 29. (C)
Sol. V = RT w B 1000
mB Sol. T = Kf ×
mB w A
4
6 × 10–4 × 1 = ×0.082 × 300 50 1000
mB 9.3 = 1.86×
62 w A
mB = 1.6 × 105
wA = 161.29 gm (water)
Amount of ice = 200 – 161.29 = 38.71 g
22. (D)
Sol. All solution have same No. of particle and
also have same value of . n1 = n2; 1 = 2 30. (A)
(Isotonic).
31. (A)
Sol. A : Benzene B : Toluene
23. (D)
P = P A + PB
Sol. For isotonic solution 1 = 2 ; C1 = C2 ; n1 =
P = PA0 X A PB0 XB
n2
W1 W 10.5 30
= 2 = = 75 × +22× = 37.5 + 11= 48.5
M1 M2 M 180 2 2
Mole fraction of benzene in vapour , YA =
10.5 180
M= = 63 Ans. PA 37.5
30 = = 0.78
P 48
24. (D) Similarly, mole fraction of toluene in
3+ 3– vapour , YB = 0.22
Sol. AIPO4 Al + PO4
The vapour will contain higher
i=1+x=2
percentage of benzene
Tb = molality Kbi
Tb
= 0.02. 32. (A)
Kb
Sol. CHCl6 + CHCOCH3
25. (D) 33. (C)
Sol. Highest boiling point will be of that
solutions for which Tb is high. 34. (A)
Here in this case Tb i (van’t hoff factor) Sol. An azeotropic mixture boil at perticular
i = 4 for Al(NO3)3 temperture without changing its
3+ –
Al (NO3)3 Al + 3 NO3 composition.
2
35. (C) 42. (D)
Sol. Some solids dissolves exothermically as Sol. Semipermeable membrane allows the
LiCl (H = –ve) and other dissolved solvent particles only to pass through it.
endothermically as KCl (H = +ve).
43. (B)
solvent-solvent interaction and solute-
Sol. No. of particle/ion.
solute interaction are endothermic while BaCl2 = 3, NaCl = 2 glucose = 1
solvent-solute interaction is exothermic. So. order of = BaCl2 > NaCl > glucose.
The sum of the three interaction
determines whether Hsol is endothermic 44. (D)
or exothermic. Sol. for a ideal solution Smix 0
45. (C)
SECTION-B
Sol. Isotonic solution has same conc.
36. (D)
W1 W2
1 = 2 C1 = C2 n1 = n2
M1 M2
37. (C)
Sol. Solubility increases with decrease in x 4
So, = x = 12 g Ans.
temperature. But solubility increases with 18 60
increase in pressure according to Henry’s
Law. 46. (B)
Sol. K f = –186° cm – 1
T f = i × K f . m
38. (A)
5 1000
Sol. Henry’s law is m = K · P ; where m = mass 3.82 = i × 1.86 ×
142 45
of gas absorbed by given volume of the
i = 2.63
solvent.
P = pressure of gas ;
47. (D)
log m = log K + log P Sol. P = PAXA + PBXB
= PAXA + PB (1 – XA)
39. (B) PAXA + PB – PBXA
Sol. Solubility pressure PB + XA (PA – PB)
S2 P
= 2 48. (D)
S1 P1
Sol. When solute undergoes dissociation than
P2 vant Hoff factor i > 1
S2 = 5.3 × 10–4 × = 6.8 × 10–4 M
P1 Tb = i Kb m
49. (D)
40. (C) Sol. Kf depends only nature of solvent, it
Sol. B.P. of water is elevated. doesnot depend on the concentration of
solution.
41. (C)
50. (B)
Sol. P = XAPA0 + XBPB0 = (PA0 – PB0)XA + PB0
Sol. The maximum boiling azeotrope is shows
So PB0 = 254
by negative deviation solution so it is H2O
PA0 – PB0 = –119
and HNO3 mixture
PA0 = 135
