An Investigation On Laser - DP-MIG Hybrid Weldability of Aluminum To Al-Si Coated Boron Steel
An Investigation On Laser - DP-MIG Hybrid Weldability of Aluminum To Al-Si Coated Boron Steel
A R T I C L E I N F O A B S T R A C T
Keywords: Laser/double pulse-MIG (laser/DP-MIG) hybrid welding-brazing of 5052 aluminum alloy to Al-Si coated boron
Laser/DP-MIG hybrid welding steel was successfully conducted in a lap configuration with an Al-5Si filler. The heat input plays a significant role
Dissimilar metals joining in determining the welding performance. The satisfactory appearance and excellent brazed interface with a
Aluminum
maximum thickness of 4.1 μm was achieved at the optimum heat input of 161.8 J/mm, and the maximum joint
Al-Si coating
Boron steel
strength reached to 168.8 MPa in excess of 75% aluminum resistance. Three kinds of intermetallic compounds
Intermetallic compounds (IMC) phases were nicely identified: τ5-Fe2Al8Si, θ-Fe(Al,Si)3 and η-Fe2(Al,Si)5. Microstructure evolution of
brazed joint showed that microstructure of upper-critical HAZ (UCHAZ) consisted of martensite whereas that of
inter-critical HAZ (ICHAZ) consisted of ferrite and martensite. The two failure modes (interfacial failure (IF) and
HAZ failure (HF)) was associated with the interfacial characteristic and porosity percentage. IF mode was a
typical intergranular fracture, and its cracks initiated from notch of weld joint and then redirected toward the
region of pore concentration. HF mode was a mixture of major ductile fracture and minor cleavage fracture, and
its cracks might initiate from notch of weld joint and then propagated along the IMC throughout the whole
interface.
1. Introduction aluminum and liquid steel at high temperature, leading to a weaker joint
strength [9,10]. For these reasons above, more attractions were mainly
The aluminum/steel hybrid parts in automotive body have great focused on the welding-brazing processes, which involved solid/liquid
potential for making a compromise between decreasing cost and guar interface by only liquid aluminum with solid steel. For example, Pour
anteeing security performance by using the combination of advance anvari and Abbasi [11] concluded that there is a critical heat input to
high strength steel (AHSS) and aluminum [1–3]. The limited weldability obtain an excellent joint during the MIG welding-brazing of aluminum
between steel and aluminum has been reported in many studies. Li et al. to steel. Liu et al. [12] explored the laser welding-brazing of aluminum
[4] showed in their works that joining aluminum to steel remained a to galvanized steel using pure Al powder. Hence, the welding-brazing
difficult task due to the large differences of physical properties including process provides us a promising alternative to effectively suppress the
thermal conductivity and melting points as well as thermal expansion. formation and growth of IMC.
Another factor of low bonding strength of interface is the formation and The laser-MIG hybrid welding-brazing coupled arc and laser beam
growth of brittle intermetallic compounds (IMC) [5]. The formation of heat source in a single molten pool. The synergistic enhancement be
IMC had a negative impact on the joint strength when its thickness tween arc and laser integrated their respective advantages, making it
excessed 10 μm [6,7]. Such suppressing the formation and growth of strongly suitable for joining of dissimilar metals [13–15]. During the
IMC became an important issue via various joining techniques. The laser-MIG hybrid welding, the laser beam induces the formation of sta
solid-state friction stir welding (FSW) can reach a better dissimilar Al/ ble arc plasma [16]. The laser-MIG hybrid welding-brazing has unique
steel joint [8]. However, the engineering application of FSW was limited advantages of a higher welding stability, bridge ability and better
by the shape of joint. The conventional fusion welding easily induced the welding formation especially increasing the wettability of aluminum to
formation of large IMC due to the directed interaction of liquid steel [15,17,18]. It is known to all that a lower heat input can effectively
* Corresponding authors.
E-mail addresses: [email protected] (J. Duan), [email protected] (Z. Li).
https://doi.org/10.1016/j.optlastec.2022.107939
Received 25 September 2021; Received in revised form 8 December 2021; Accepted 27 January 2022
Available online 12 February 2022
0030-3992/© 2022 Elsevier Ltd. All rights reserved.
X. Cao et al. Optics and Laser Technology 150 (2022) 107939
Table 1
Chemical compositions of steel and 6061 aluminum alloy (w-%).
Materials C Si Mg Mn Zn B Fe Al
Fig. 1. The microstructure of (a) boron steel and (b) Al-Si coating.
limit the formation and growth of IMC. Such it is necessary to maintain a However, the comprehensive studies weren’t discussed during the laser/
lower heat input during laser-MIG hybrid welding-brazing. The double DP-MIG welding-brazing especially its application to join aluminum/
pulse MIG (DP-MIG) is a variation of gas metal arc welding (GMAW), steel joint.
which provides a modified pathway to reduce the arc heat input [19,20]. Most recently, aluminized steel replacing galvanized steel in dis
Wang et al. [21] demonstrated that the DP-MIG could significantly similar Al/steel joining become a popular alternative. The joining
refine microstructure of fusion zone due to the effect of period alter mechanisms of Al alloy/aluminized steel differed from that of Al alloy/
nation of thermal peak and base current. It is reasonable to assume that galvanized steel [23,24]. The Al-Si coating become a research focus for
the formation of IMC can be suppressed by the periodical vibration of the aim of limiting IMC thickness [24–27]. For example, Kang and Kim
molten pool. Therefore, a novel attempt was conducted to develop laser/ [24] observed a lower IMC layer thickness in the CMT of aluminum to
DP-MIG hybrid welding-brazing in order to give a suitable method of aluminized steel rather than galvanized steel. Ding et al. [25] revealed
dissimilar aluminum/steel welding. The possibility of the hybrid laser/ the role of Al-Si coating in refill friction stir spot welding of aluminum to
DP-MIG method was preliminarily investigated in our previous study Al-Si coated steel. Huang et al. [26] conducted the laser welding-brazing
[22]. The laser/DP-MIG welding-brazing could limit IMC and improve of aluminum to Al-Si coated press-hardened steel using Zn-Al15 filler.
wettability compared with conventional MIG welding-brazing. For these cases, the Al-Si coating plays a key role in the improvement of
Fig. 2. The laser/DP-MIG hybrid welding system: (a) and (b) the right view and frontal view of schematic diagram, (c) the current waveform of double pulse MIG, (d)
experimental setup.
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Table 2
The detailed welding parameters.
Specimens Laser power (W) Average current (A) Average voltage (V) Current frequency (Hz) Welding speed (mm/s) Line heat input (J/mm)
2.1. Materials
The Al-Si coated boron steel and 5052 aluminum having the same
thickness of 2 mm were selected as base metals. The Al-5Si wire
(ER4043) with a diameter of 1.2 mm was employed as the filler material.
Table 1 lists the chemical composition of filler material and base metals.
As shown in Fig. 1(a), the as-received boron steel is original state, which
is composed of ferrite and pearlite. The microstructure of boron steel
evolves from ferrite and pearlite to fully martensite during press-
hardened process [28]. Fig. 1(b) displays a 30 μm thick Al-Si coating
deposited on boron steel substrate, which is comprised of regions A and
B. According to EDS analysis and relevant literatures [25,29], it seems to
be identified as Al-Si eutectics and Fe2Al7Si, respectively.
Fig. 3. The preparative of tensile-shear and microstructural samples.
2.2. Welding configuration
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Fig. 5. The welding appearances and cross-sectional macrostructures in different heat input of (a) S1, (b) S2, (c) S3, and (d) S4.
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Fig. 6. The interface microstructure of head, central, foot regions with different heat inputs: (a-c) S1, (d-f) S2, (g-i) S3, (j-l) S4.
As for the cross-section of the joint S1 in Fig. 5(a-3), the narrow weld was detected. The hydrogen in aluminum oxides may play an important
width of 4 mm and the pore concentration near the HAZ of welded joint role to induce the formation of pores [31,32]. Another reason may be the
mismatch of heat input, leading to an instable pool. The latter is not
conducive to exhaust pores. These characteristics might suggest a bad
tensile-shear strength. With the increase of heat input, the sound and
stable ripples without obvious defects of spatters, burn and pits was
nicely fabricated in Fig. 5(b-1). Fig. 5(b-2) shows an acceptable weld
width of 5 mm and pore distribution except for some small pores. This is
because the appropriate match of heat input induces the strong peri
odical force to accelerative the escape of pores. However, when the heat
input increased from 161.8 J/mm to 236.1 J/mm, the ripples feature
became more and more inapparent (Fig. 5(c-1)) or even disappear (Fig. 5
(d-1)). The defects of spatters and pits could be observed in the surface of
weld seam. The HAZ of near Al-Si coating firstly occurred in Fig. 5(c-2)
and then extended to 3.8 mm in Fig. 5(c-3) due to the excessive heat
input. Although the wettability was gradually improved as the heat
input increases from 161.8 J/mm to 236.1 J/mm, the generation of
pores in weld seam, large brittle IMC and residual stress in brazed
interface was extraordinarily facilitated. Particularly, when laser power
increased to 900 W, a laser spot appeared in brazed interface in Fig. 5(d-
3), which was the directed evidence of strong intermetallic reaction
between aluminum and steel. The consecutive cracks spontaneously
propagated along the interface. This interesting fact also revealed that
Fig. 7. The effect of heat input on the thickness of IMC layer.
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Table 3 average thickness of IMC layer. The latter increased with the increase of
The atomic percentage of different zones marked in Fig. 6(d-f). the former due to the accelerated diffusion of Al and Fe atoms across at
Points Fe Al Si Possible phases the Al/steel interface. The detailed analysis will be carried out below.
Fig. 6(a-c) shows the interface microstructure of joint S1. The
1 16.51 77.45 6.04 τ5-Fe2Al8Si
2 24.96 68.72 6.32 θ-Fe(Al, Si)3 lamellar IMC was observed in head region and foot region while a
3 16.93 77.62 5.45 τ5-Fe2Al8Si mixture of acicular and lamellar IMC was observed in central region.
4 25.55 69.48 5.12 θ-Fe(Al, Si)3 During laser/DP-MIG welding-brazing, the highest temperature of
5 28.31 66.56 5.13 η-Fe2(Al, Si)5 hybrid heat source occurred near central region of interface where the
6 17.84 77.24 4.92 τ5-Fe2Al8Si
growth of the IMC layer was sharply driven. The IMC thickness of central
region has reached 4.1 μm. Similarly, it can be seen that the IMC shapes
there is a critical threshold for laser power in this study. of joint S2 (Fig. 6(d-f)) is similar to that of joint S1 (Fig. 6(a-c)), as the
For all the cases discussed above, the welding appearance is posi heat input increases from 135.5 J/mm to 161.8 J/mm. It can be found
tively correlated to cross-sectioned macrostructure. An excellent that the IMC thicknesses increased slightly, implying that the formation
appearance normally indicates a satisfactory cross section. On the other of IMC could be slowly controlled within the limit of 161.8 J/mm. The
hand, the inadequate heat input can lead to poor wettability and uneven different IMC layers were marked in white dot line in accordance with
appearance whereas excessive heat input will cause indistinct welding the diffracted color in back-scattered electron (BSE). The details of
ripples and defects of large residual stress and pores. These two cases phases identification will be discussed in following paragraph. Fig. 6(g-
aren’t an ideal one when adjusting heat input. Hence, it is supposed to i) show the interface microstructure of joint S3 when the heat input was
make a compromise in heat input so as to achieve an excellent 202.8 J/mm. The mixture of acicular and lamellar IMC with a thickness
appearance. of 4.1 μm begun to appear at the head region due to the increase of heat
input. The similar structure except for a thicker size of 6.5 μm was
observed in central region. To make matter worse, as the heat input
3.2. Interface microstructure
increased to 236.1 J/mm by increasing laser power, the formation of
IMC layers was quickly developed in excess of 10 μm in Fig. 6(j-l). The
In order to understand the bonding mechanism of interface, the
defects of chipped IMC and consecutive cracks were found, which
interface microstructure of head, central, and foot regions was given in
catastrophically deteriorated the tensile-shear strength. The excessive
Fig. 6. The noticeable IMC layer was observed at the brazed interface
heat input was not conducive to the improvement of welded quality.
due to the metallurgical reactions of aluminum and steel. The temper
The IMC phases marked in Fig. 6(d-f) was discussed to identify its
ature gradient differentia resulted in the various IMC thicknesses and
types. Table 3 lists the EDS results of different zones marked in Fig. 6(d-
structures from head region to foot region [33]. In vertical comparison
f). In heat region interface, the lamellar IMC can be divided into two
with different heat input, the variation of IMC thickness was summa
zones according to the different diffraction colors. The Si content of the
rized in Fig. 7. The heat input played a significant role in dominating the
Fig. 8. The microstructure evolution of the joint S2: (a) the welded interface, (b) the magnification of dotted region (b) marked in (a), (c) FZ, (d) the of brazed
interface, (e) UCHAZ (i.e., region (e)) marked in (d), (f) ICHAZ (i.e., region (f)) marked in (d).
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X. Cao et al. Optics and Laser Technology 150 (2022) 107939
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strength of 5052 base materials. Two failure modes (see Fig. 10(b)) are
observed among all the cases: interface failure (IF) and HAZ failure (HF).
The fracture surface of failure modes will be examination in below
section. When the heat input is less than 161.8 J/mm, the tensile-shear
strength increases with the increase of heat input. The failure mode is
predominated by IF mode. The appropriate increase of heat input is
beneficial to improve the weld width with a slight increasing of IMC
Fig. 11. The schematic diagram of stress analysis under the applied load. thickness, strengthening the strength of interface. The previous discus
sions in Sections 3.1 and 3.2 have been stated these facts. As the heat
Fig. 12. The fracture morphology of the HAZ failure (HF) mode: (a, b) different area of fracture surface, (c) a high magnification of dimples, (d) the EDS result of red
dotted square marked in (a).
Fig. 13. The fracture morphology of the interface failure (IF) mode: (a-c) different area of fracture surface, (d) the EDS result of red dotted square marked in (a).
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input exceeds 161.8 J/mm or higher, the tensile-shear strength gradu 4. Conclusions
ally decreases and the porosity percentage maintains in an extremely
high level over 6%. Despite the formation of spontaneous cracks (1) The heat input plays a significant role in determining the welding
inducing by the large brittle IMC and rather high residual stress weakens performance during the laser/DP-MIG hybrid welding-brazing of
the Al/steel interface strength, the joint fractures at the HAZ of welded aluminum to steel. The satisfactory appearance with stable rip
joint rather than Al/steel interface. This interesting phenomenon may be ples and the maximum joint strength of 168.8 MPa were obtained
explained by the reason that higher porosity percentage (beyond 6%) when the heat input with a well match between laser and arc
sharply depressed the strength near HAZ of welded joint. The pore parameters was 161.8 J/mm.
concentration near HAZ is considered as a preferential region to fracture (2) The IMC thickness increases with the increase of heat input, but
during tensile-shear tests. Hence, the joints basically fracture near HAZ the formation of IMC can be slowly controlled within a low heat
of welded joint. input. Three IMC phases were nicely confirmed in detail: τ5-
The failure mode dramatically transforms from IF to HF when the Fe2Al8Si, θ-Fe(Al,Si)3 and η-Fe2(Al,Si)5.
heat input increases. It can be found that the IF mode does not represent (3) Limiting peak temperature below steel melting point is necessary
a low tensile-shear strength compared with HF mode. To furtherly un for the formation of sound brazed interface. The microstructure
derstand the determined factors of the two failure modes, the stress of UCHAZ consists of martensite whereas that of ICHAZ consists
analysis should be carried out. Fig. 11 shows the schematic diagram of of ferrite and martensite due to different peak temperatures.
stress analysis under the loading state. The ultimate stress of interface (i. (4) There are two failure modes among all the cases: interfacial
e., F2) is mainly dependent on the adhesion weld width and IMC failure and HAZ failure. The brazed interface and pore concen
thickness. Another stress is the ultimate stress of welded joint near HAZ tration are the two weak regions to fracture preferentially ac
(i.e., FN), which is commonly slashed by the higher porosity percentage. cording to the stress analysis. The IF mode is a typical
This is because the present of pores directly decreases the stressed area intergranular fracture, and its cracks initiates from notch of weld
during the tensile-shear tests. Therefore, the failure modes are deter joint and then redirects toward the region of pore concentration.
mined by their competitive relationship. For example, the ultimate The HF mode is a mixture of major ductile fracture and minor
stress of interface in joint S1 is less than that of HAZ in joint S1 due to the cleavage fracture, and its cracks may initiate from notch of weld
relatively narrow weld width, resulting in the occurrence of IF mode. joint and then propagate along the IMC throughout the whole
interface.
3.6. Fracture analysis
Different failure modes presented different fracture positions and Declaration of Competing Interest
fracture surface. In the HAZ failure (HF) mode, the original cracks easily
initiated from notch of weld joint due to the concentration stress under The authors declare that they have no known competing financial
the applied load, and then redirected toward the region of pore con interests or personal relationships that could have appeared to influence
centration. This assumption was demonstrated by the fact that HF mode the work reported in this paper.
surface consisted of dimples and dense pores at the parameters of S3
sample in Fig. 12(a). As shown in Fig. 12(b), there is a small cleavage Acknowledgement
terrace around some pore characteristic. Fig. 12(c) displays a high
magnification of dimples feature. These dimples indicate different for This study was supported by the National Key Research and Devel
mation mechanism. The deep dimples with the rough and irregular opment Program of China (2017YFB1104801), the Fundamental
surface may belong to intergranular dimple while the shallow dimples Research Funds for the Central Universities of Central South University
with smooth surface may belong to transgranular dimple. The second- (2021zzts0130), Postgraduate Scientific Research Innovation Project of
phase particle in the bottom of dimple is the direct evidence of ductile Hunan Province (CX20210206).
fracture. Hence, the HF mode is a mixture of major ductile fracture and
minor cleavage fracture. Fig. 12(d) shows that the Si content of dimples References
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