IIT CO SUPER CHAINA STAR-II(NEW) Date: 05.07.

2025
Time: 3 Hrs JEE-MAIN MODEL-WTM-05 Max. Marks: 300
PHYSICS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
01. A rod of length L has charge distrubuted on it such that linear charge density   kx, k is a constant
and x is the distance of a point from the end of the rod where no charge exists. The rod has a mass m
and the mass distribution is uniform. The rod is now rotated about an axis passing through the end of
the rod where no charge exists and this axis is perpendicular to the length of the rod with an angular
velocity  . The equivalent current, I , is….
kL2 kL2
A) I  B) I   kL C) I  D) I  Zero
 4
02. In a meter bridge, the gaps are closed by two reistances P and Q and the balance point is obtained at 40
cm. When Q is shunted by a resistance of 10  , the balance point shifts to 50 cm. The values of P
and Q are

10 15
A) ,5 B) 20,30 C) 10,15 D) 5, 
3 2
03. In the network shown, the potential difference between A and B for the values
R  r1  r2  r3  1, E1  3V , E2  2V , E3  1V is

A) 1 V B) 2 V C) 3 V D) 4 V
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
04. A 100 W bulb B1 and two 60 W bulbs B2 and B3 are connected to a 250 V source as shown in figure.
Now W1 ,W2 and W3 are the output powers of the bulbs B1 , B2 and B3 respectively. Then

A) W1  W2  W3 B) W1  W2  W3 C) W1  W2  W3 D) W1  W2  W3
05. Two bars of radii r and 2r are kept in contact as shown. An electric current I is passed through the
bars. Which one of the following is correct?

[ The materials of two bars are same]

A) Heat produced in bar BC is 4 times the heat produced in bar AB
B) Electric field in both halves is equal
C) Current density across AB is double that of across BC
D) Potential difference across AB is 4 times that of across BC
06. The charge flowing through a resistor R varies as Q   t   t 2 where  ,  are constants. The total
heat produced in R is [ only positive current is allowed in resistor]
 3R  3R  3R  3R
A) B) C) D)
 2 3 6
07. The total amount of charge at the junction of the two materials in figure is, [Assume I is the current
flowing through the junction, and  1 and  2 are the conductivities for the two materials.]

2 2 1 1    2 
A) zero B) I 0    C) I 0    D) I 0  1 
 2  1   2  1   2 1 2 
08. Two coils connected in series have resistance of 600 and 300 and temperature co-efficient of
1 1
0.001  0 C  and 0.004  0 C  respectively at 20 0 C. What is the effective temperature co-efficient of
resistance of combination (in 0 C 1 )
A) 0.002 B)0 .001 C) 0.004 D) 0.003

Page 2
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
09. The effective resistance of the circuit between the points A and B of figure is ….

 42   73   39   87 
A)    B)    C)    D)   
 7   3  5   9 
10. A rod of length L and cross-section area A lies along the x-axis between x  0 and x  L . The
material obeys Ohm’s Law and its resistivity varies along the rod according to,   x   0 e x / L
Then end of the rod at x  0 is at a potential V0 and it is zero at x  L .
The electric potential V  x  in the rod as a function of x is
 e  x / L  e 1  1  e  1  e x / L   e x / L  e 
A) V0   B) V0  C) V 0   D) V 0  
1  e 
1
 1 e   1 e   1 e 
11. A battery is made by joining m rows of identical cells in parallel each row consists n cells joined in
series. This battery sends a maximum current I in a given external circuit. Now the cells are so
arranged that instead of m rows, n rows are joined in parallel and each row consists of m cells joined
in series. The current through the same external circuit is now given by
 mn   2mn  3  mn 
A)  2 2 
I B)  2 2 
I C) I D)  2 I
m n  m n  2  m  n 2 
12. The potential difference between points a and b in following circuit is..

A) 4.5 V B) 5.4 V C) 8.2 V D) 1.4 V

13. A bulb is marked 220V, 100W. What will be the current in the filament when connected to 200V?
40 11 50 91
A) A B) A C) A D) A
101 121 121 121
14. A galvanometer has coil resistance 30 and full deflection current of 2mA. What resistance is needed
to convert it into a voltmeter of 0.2V range.
A) 40 B) 70 C) 50 D) 60
15. A battery has an open circuit potential of 6V between its terminals. When a load resistance of 60 is
connected across the battery, the total power dissipated by the battery is 0.4W. What should be the
load resistance R, so that maximum power will be dissipated in R. Calculate this pier. What is the total
power supplied by the battery when such a load is connected?
A) 0.6W B) 6W C) 60W D) 0.4 W

Page 3
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
16. A cell having a steady emf of 2 V is connected across the potentiometer wire of length 10m. The
potentiometer wire is of manganin and having resistance of 11.5 m 1 . An another cell gives a null
point at 6.9 m. If a resistor of resistance 5 is put in series with the potentiometer wire, find the new
position of the null point is..
A) 6.9 m B) 7.2 m C) 7.5 m D) 7.6 m
17. In a potentiometer experiment it is found that no current passes through the galvanometer when the
terminals of the cell are connected across 0.52 m of the potentiometer wire. If the cell is shunted by a
resistance of 5 a balance is obtained when the cell is connected across 0.4 m of the wire. The
internal resistance of the cell is
A) 0.5 B) 0.8 C) 1.5 D) 1.8
18. A battery of emf 4 V is connected across a 10 m long potentiometer wire having a resistance per unit
length 1.6 m1 . A cell of emf 2.4 V is connected so that its negative terminal is connected to the low
potential end of the potentiometer wire and the other end is connected though a galvanometer to a
sliding contact along the wire. It is found that the no-deflection point occurs against the balancing
length of 8m. The internal resistance of the 4 V battery is

8 4 16 10
A)  B)  C)  D) 
3 3 3 3
19. In the given circuit, a meter bridge is shown in a balanced state. The bridge wire has a resistance of
1 cm 1 . The current drawn from the battery of negligible internal resistance is

A) 0.66 A B) 0.11 A C) 0.22A D)0.44A

20. In a house having 220 V line, the following appliances are operating in parallel i) a 60 W bulb,
ii) a1000 W heater , and iii) a 40 W radio. The current passing through the fuse in the main line is..

50 3 2
A) A B) A C) A D)5A
11 11 11

Page 4
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the
decimal, Marks nearest Integer only. Have to Answer all questions.
Marking scheme : +4 for correct answer, 0 if not attempted and -1 if not correct.

21. At a certain instant of time, the potential difference between the plates of a capacitor of capacitance
2  F is charging at a rate of 2 106 Vs 1 . The current at that instant is ___A.
22. In the circuit shown in figure, R1  1, R2  2, C1  1 F , C2  2  F and E = 6V. The sum of
magnitude of charges on the two capacitors in steady state is 2K  F . Find ‘K’

23. In the circuit shown in figure the equivalent time constant of the circuit in mRC. What is value of n?

24. Figure shows a part of completer circuit. The current in various branches in steady state are shown in
figure. The energy stored in capacitor is ______  J

25. In the circuit shown in fig. find the current through battery.

Page 5
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
CHEMISTRY Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. What could be the product for the following reaction?
NaNO HCl
Ph  N  CH 3 2 
2,
 Product  Major 
CH3
N2 N(CH3)2 N
Cl NO
CH3
A) B) C) ON D)

H3C CH3
N

O
Cl H3O NaNO2/HCl
NH C A B C NH Cl/HCl D
AlCl3 0-5oC 4
27.
The product (D) is:

H3C
N N NH2

A) H3C

H3C CH3
N N N

B) H3C CH3

CH3
N N N

C) CH3

D)

Page 6
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
CH3
NaNH2/NH3(l)
Product
28. Br ; the product is:
CH3
CH3
CH3 CH2=NH2

A) NH2 B) NH2 C) H2N D)

29. Consider the following ions

H3C
N N2
NO2 N2
(i) H3C (ii)

CH3O N2 N2
(iii) (iv)
The reactivities of these ions in azo-coupling reactions (under similar conditions) will be such that
A) i < iv < ii < iii B) i < iii < iv < ii C) iii < i < ii < iv D) iii < i < iv < ii
30. What could be the product for the following reaction?
Cl
NO2
(i) NH3, Heat
(ii) OH-/H2O Product

NO2
NH2
NO2
OCH3

A) NO2 B) O2N NO2

NH2
Cl

C) O2N NO2 D) O2N NO2

Page 7
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
31. Predict the product in the following reaction:
O
*
C NH2
Br2
Product
KOD/D2O

*
NH2 ND2 ND2 NH Br

A) B) C) D)

32. Which of the following can undergo carbylamines reaction easily?

NH2 NH2 NH2

NH2

A) B) OCH3 C) NO2 D) CH3

OH

pH 910
33.  Ph  N2   X  major product  ; X will be:

NH2
OH OH OH O N2Ph
N=N Ph

N=N Ph

A) NH2 B) NH2 C) HN N=N Ph D) NH2

34. In the reaction sequence, the product (B) is:

CHO
CH2 OH

CH2 OH 1) NH2-NH2
CH3
Dry HCl
A B
2) KOH/C2H5OH
3) H3O
O

Page 8
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025

O CH3

A) CH3 B) CH3
CH3

CHO

C) CH3 D) CH3

KMnO4 P2O5
A B
35.
H /
The correct option is:
A) Product A is Phthalic acid B) Product B is Phthalic acid
C) Product A is Phthalic anhydride D) Product B is acetic anhydride

KCN H3 O heating
36. Cl A B C
IUPAC name of the product (C) is:
A) 2-Butene B) 1-Butene C) Butane D) Cyclobutane
Ca  OH 3 Distillation
37.  A 
Adipic acid  B
The product (B) is:
A) Cyclohexanone B) Cyclopentanone C) Cyclic anhydride D) Pentanone
NO2

Sn + HCl
Product
38.
The product is:
NH2 NO
N=N-Ph

A) B) C) D)
39. What is the final product of this sequence of reactions?
O
CH2 C H
LiAlH4 K2Cr2O7
O A B C
H
CH2 C H
O CHO
O
O
A) B) C) D) CH=CH2

Page 9
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025

OH
1) I2 + NaOH SOCl2 CH3MgBr OD / D2O
CHI3 + (A) (B) (C) excess (D)
2) H2O/ H 1 Mole
40.
Identify D in the above reaction sequence:
O O O O
|| || || ||
A) C6 H 5  C  CH 3 B) C6 H 5  C  CD3 C) C6 H 5  C  Cl D) Ph  CH 2  C  Cl
O
||
H 2 SO4
41.  X   Y   Ph  NH 2  CH 3  C  OH
Hydrolysis

Identify the configuration of [X] compound:

Ph Ph OH Ph Ph OH
C N C N C N C N

A) H3C OH B) H3C C) H3C CH2 OH D) H3C CH2

O
|| 
NaN3 D3O
42. R  C  Cl 
H
 R  N  C  O   X ; X is
Isocyanate

O O
|| ||
A) R-NH2 B) R-ND2 C) R  C  NH 2 D) R  NH  C  H
43. Statement-I: Glucose gives a reddish-brown precipitate with Fehling’s solution.
Statement-II: Reaction of glucose with Fehling’s solution gives CuO and gluconic acid.
A) Both statements are true and Statement-II is the correct explanation of Statement-I
B) Both statements are true and Statement-II is not the correct explanation of Statement-I
C) Statement-I is true, Statement-II is false
D) Statement-I is false, Statement-II is true
44. Which of the following pairs give positive Tollen’s test?
A) Glucose, acetophenone B) Fructose, acetophenone
C) Glucose, fructose D) benzaldehyde, acetone
45. Glucose when reduced with HI and red phosphorous gives

A) n-Hexane B) n-heptane C) n-pentane D) n-octane

SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the
decimal, Marks nearest Integer only. Have to Answer all questions.
Marking scheme : +4 for correct answer, 0 if not attempted and -1 if not correct.

Page 10
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
46. For the following compound, nitrogen at which position is most apt to be protonated?
4
1 N
N

N N3
2
H
47. How many of the following can give decarboxylation upon heating?
O COOH
COOH COOH COOH COOH

COOH
i) ii) iii) iv)

COOH

COOH
COOH
COOH

v) vi) O vii)

COOH
COOH
H2C
viii) HOOC ix) COOH x) HCOOH

O O
COOH HOOC COOH
COOH
xi) xii)
48. How many of the following can liberate CO2 gas from NaHCO3 ?
SH OH
NO2
SH OH

a) b) NO2 c) d) NO2

HO O

e) H2CO3 f) HCOOH g) Ph-COOH h) HO O

i) Picric acid j) TsOH k) Melonic acid l) HF

Page 11
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
o
49. How many of the following compounds can produce 1 amine when react with KOH + Br2?
O O O
|| || ||
i) R  C  NH 2 ii) R  C  NH  Br iii) R  C  NH  CH 3
OH OH OH
| | |
iv) R  C  NH v) Ph  C  NH vi) CH 3  C  NH
O O
C NH Br O
C NH2 ||
vii) viii) ix) Ph  C  NH  Ph
50. How many of the following are more basic than pyridine?
CH3
|
i) CH3 – NH2 ii) CH3 – NH – CH3 iii) CH 3  N  CH 3
NH2
N

N
O O
|| ||
iv) R  C  NH 2 v) Ph  C  NH 2 vi) vii) H
NH2

viii) CH3 ix) H

MATHEMATICS Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
n
r 1  r loge 10 
51. The value of   1 n cr r

r 0 1  loge 10n 
A) 1 B) -1 C) 0 D) n
n n
1  1  3 x  1   1  3 x  1  
52. p  x  
   
th
  is a 5 degree polynomial then value of n=___
3 x  1  5   5  

A) 10 B) 11 C) 12 D) 15
10
 x 1 x  1 
53. The term independent of x in the expansion of  1
 12
is equal to
 23 x  x 
 x  x3 1 
A) 210 B) 120 C) 102 D) 0

Page 12
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
11 11
 1 9 9  1  2
54. The coefficient of x in   x 3   and coefficient of x in   x  3  are equal than  
 x  x 
A) 100 B) 25 C) 16 D) 1
10
1  7
55. The middle term of   x sin x  is equal to 7 then value of x are
x  8
  n  n 
A) 2n  B) n  C) n   1 D) n   1
2 4 6 3
8
56. The numerically greatest term in expansion of 1  2 x  when x = 2 is
A) 8c6 46 B) 8c4 44 C) 217 D) 8c7 47
100
57. The number of irrational terms in  8
56 2  is
A) 50 B) 51 C) 79 D) 97
12
58. The value of  24
r 1
cr is equal to

1 1
A) 2 23 
2

24c12  1  B) 2 24  24c12  1 C) 2 23 
2
24c12  1  D) 2 23  1

20 40
89. If 1  x  x 2    ar x r then a1  3a3  5a5      39a39 
r 0

A) 40 B) -40 C) 80 D) -80
2
 x 2 x 4 x 6 x8 
60. The coefficient of x8 in expansion of 1      
 2 4 6 8
1 2 1 1
A) B) C) D)
315 315 105 210
2 2 2 2
61. 1 .c1  2 .c2  3 .c3  .....  n .cn 
A) n.2n1 B) n  n  1 2 n C) n  n  1 2 n 2 D) n  n  1 2n 1
n n
1 r t
62. If sn   and tn   then n 
r  0 ncr r  0 ncr sn
n 2n  1 1
A) B) C) n-1 D) n 1
2 2 2
200
63. Let p, q  R; and 1  3i    2199  p  iq  ; i  1 then p  q  q 2 and p  q  q 2 are roots of

eq n A) x 2  4 x  1  0 B) x 2  4 x  1  0 C) x 2  4 x  1  0 D) x 2  4 x  1  0

64.  
Let s  z  C : z  3  1 and z  4  3i   z  4  3i   24 if   i in the point in ‘s’ which is closet to

4i then 25    
A) 50 B) 70 C) 20 D) 80
65. If z1; z2 are roots of equation z 2  az  b  0 and z1; z2 origin be the vertices of an equilateral triangle
then a 2  3b 
A) 1 B) -1 C) 0 D) 2
Page 13
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
3 2
66. If  ,  ,  are roots of equation x  3x  3x  7  0 ,  is a cube roots of unity then
 1  1  1
  
  1  1   1
3
A) B)  2 C) 2 2 D) 3 2
2
67. If z1; z 2 ; z3 are vertices of an equilateral triangle which is inscribed in a circle z  2 and if

z1  1  i 3 then z2 z3 

A) 2  2i 3 B) 1  i 3 C) 1  i 3 D) 1 i
68. The locus of centre of circle which touch the circles z  z1  a ; z  z1  b externally will be
A) an ellipse B) a hyperbola C) a circle D) a parabola
2 2 1 1 1
69. If   cos  i sin then the value of  2
 ...  
n n 2  2  2   n 1
n.2n1 n.2 n1
A) B) 1 C) 0 D) 1
2n 2n  1
3
 2 2 
 1  sin 9  i cos 9 
70. The value of   =
2 2
 1  sin  i cos 
 9 9 
1 1 1 1
A) 
2

1 i 3  B)
2
1 i 3  C) 
2
 3 i  D)
2
 3 i 
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the
decimal, Marks nearest Integer only. Have to Answer all questions.
Marking scheme : +4 for correct answer, 0 if not attempted and -1 if not correct.

n 2  n 
71. If n in a positive integer then 1  i   1  i  
n n
 p cos 
 q 
 then p  q  __

a b c
72. If a  cis  ; b  cis  ; c  cis  and    1 then cos      cos       cos       ____
b c a
2 2 2 2 60!
73. If  30 
C1 
 2 30C2  
 3 30C3  
 ....  30 30C30    2
then   ____
 30!
sin  2 A B  C 
74. If  cos A  0, & sin A  0 then value of x . x sin 2 BC  A . x sin 2C  A B   ___
75. If z1; z2 be root of equation z 2  pz  q  0 with coefficients p, q are complex numbers. Let A, B
represents z1 & z2 in complex plane and AOB    0 and OA = OB with O is origin then

p 2  kq cos 2  k  ____
2

Page 14
Narayana IIT Academy SR. IIT STAR-II(New) WTM-05-Q.P_05-07-2025
****

Page 15