SAFETY DATA SHEET

Section 1. Identification
Product name : BPR 81156R NEUTRALIZER
Product code : BPR81156R

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Neutralizer.

Print date : 1/12/2024

Validation date : 1/12/2024
Version : 3.02

Supplier's details : Baker Petrolite LLC

12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400
www.bakerhughes.com

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)

number (with hours of Baker Petrolite: 800-231-3606 (North America 24 hour)
operation) Chemtrec International: 01-703-527-3887 (International 24 hour)
CHEMTREC Int'l 01-703-527-3887 (Latin America 24 hour)
CHEMTREC Argentina (Buenos Aires) 54-1159839431
Venezuela 58-212-277-2222 (Venezuela 24 hour)
Chile 56-225-814-934
Peru (Lima) +(51)-17071295
Colombia 01800-710-2151

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 4
substance or mixture ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 3
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Combustible liquid.
Harmful in contact with skin.
Causes severe skin burns and eye damage.
Toxic if inhaled.
May cause respiratory irritation.
Precautionary statements

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Section 2. Hazards identification

Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile or Neoprene gloves..
Wear protective clothing. Wear eye or face protection. Keep away from flames and hot
surfaces. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing
vapor. Wash thoroughly after handling.
Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor. IF SWALLOWED: Immediately call a
POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER or doctor. Wash contaminated clothing before
reuse. IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. Wash with
plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified
Hazard statements : H227, H312, H314, H331, H335
(Code)
Precautionary statements : P280, P210, P271, P261, P264, P304 + P340, P310, P301 + P310, P330, P331, P303 +
(Code) P361 + P353, P310, P363, P302 + P312, P352, P305 + P351 + P338, P310, P405,
P403 + P233, P403 + P235, P501

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Alkanolamine 70 - 80 108-01-0
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes
while holding the eyelid(s) open. Check for and remove any contact lenses. Chemical
burns must be treated promptly by a physician.
Inhalation : Call a poison center or physician. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under medical surveillance
for 48 hours.

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Section 4. First aid measures

Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected
area with soap and mild detergent for at least 20 - 60 minutes. Wash with plenty of
soap and water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Chemical burns must
be treated promptly by a physician. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Chemical
burns must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled. May cause respiratory irritation.
Skin contact : Causes severe burns. Harmful in contact with skin.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : respiratory tract irritation,coughing
Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Combustible liquid. Runoff to sewer may create fire or explosion hazard. In a fire or if
from the chemical heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.

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Section 5. Fire-fighting measures

Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Empty containers retain
product residue and can be hazardous. Do not reuse container.

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Section 7. Handling and storage

Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in a dry, cool and well-ventilated area, away from incompatible materials (see
incompatibilities Section 10). Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Argentina
Ingredient name Exposure limits

Colombia
Ingredient name Exposure limits

Mexico
Ingredient name Exposure limits

United States
Ingredient name Exposure limits
Alkanolamine None.

Venezuela
Ingredient name Exposure limits

Biological exposure indices

Argentina
No exposure indices known.
Colombia
No exposure indices known.
Mexico
No exposure indices known.

United States
No exposure indices known.
Venezuela
No exposure indices known.

Consult local authorities for acceptable exposure limits.

Only components of this product with established exposure limits appear in the box above.

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Section 8. Exposure controls/personal protection

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles. If inhalation hazards exist, a full-face respirator may be
required instead.
Hand protection : Chemical-resistant gloves: Nitrile or Neoprene gloves.
Skin protection : Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin
contact.
Respiratory protection : If a risk assessment indicates it is necessary, use a properly fitted, air purifying or
supplied air respirator complying with an approved standard. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.

Section 9. Physical and chemical properties and safety

characteristics
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid. [Clear.]
Color : Colorless.
Odor : Amine like. [Strong]
Odor threshold : Not available.
pH : 11
: Neat - without dilution.
Melting point/freezing point : Not available.
Initial Boiling Point : 100°C (212°F)
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: 61°C (141.8°F) [SFCC]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability : Flammable in the presence of the following materials or conditions: open flames, sparks
and static discharge and heat.
Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure : 0.11 kPa (0.8 mm Hg) @ 21.1°C (Calculated Value for all Components.)
Relative vapor density : >1 [Air = 1]
Relative density : 0.9577 (15.6°C)
Density : 7.98 (lbs/gal)

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Section 9. Physical and chemical properties and safety

characteristics
Solubility in water : Soluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic (4.4°C): 40 cP

VOC : Not available.

Pour Point : <-42.8°C (<-45°F)
Particle characteristics
Median particle size : Not applicable.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials and acids.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Alkanolamine LC50 Inhalation Vapor Rat 1641 ppm 4 hours
LD50 Dermal Rabbit 1.22 g/kg -
LD50 Oral Female rat 1210 mg/kg -
LD50 Oral Rat 2 g/kg -
Irritation/Corrosion
No available toxicity data.
Sensitization
No available toxicity data.
Mutagenicity
No available toxicity data.

Carcinogenicity
No available toxicity data.

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Section 11. Toxicological information

Reproductive toxicity
No available toxicity data.
Teratogenicity
No available toxicity data.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Alkanolamine Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Not applicable.
Aspiration hazard
Not available.

Information on the likely : Routes of entry anticipated: Dermal, Inhalation, Eyes.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled. May cause respiratory irritation.
Skin contact : Causes severe burns. Harmful in contact with skin.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : respiratory tract irritation,coughing
Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

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Section 11. Toxicological information

Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
BPR 81156R NEUTRALIZER 2840.9 1562.5 Not 4.3 Not
available. available.
Alkanolamine 2000 1100 Not 3 Not
available. available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
BPR 81156R NEUTRALIZER Acute EC50 19 mg/l Algae - Daphnia magna 48 hours
Acute EC50 47 mg/l Daphnia - Ceriodaphnia dubia 48 hours
Acute EC50 45 mg/l Daphnia - Daphnia pulex 48 hours
Acute EC50 41.7 mg/l Marine water Micro-organism - Vibrio fischeri 15 minutes
Acute LC50 132 mg/l Fish - Pimephales promelas 96 hours

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
2-dimethylaminoethanol -0.55 - Low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.

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Section 14. Transport information

IMDG IATA
UN number UN3267 UN3267

UN proper CORROSIVE LIQUID, CORROSIVE LIQUID,

shipping name BASIC, ORGANIC, N.O. BASIC, ORGANIC, N.O.
S. (Contains: S. (Contains:
Alkanolamine) Alkanolamine)
Transport 8 8
hazard class(es)

Packing group III III

Environmental No. No.
hazards
Additional information
UN Classification : Emergency schedules F-A S-B
IMDG : Emergency schedules F-A S-B

Marine pollutant Not available.

Section 15. Regulatory information

U.S. Federal regulations : TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are active or exempted.

Section 16. Other information

National Fire Protection Association (U.S.A.)

2 Flammability BPC
Health 3 0 Instability/Reactivity
Special

History
Date of printing : 1/12/2024
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations

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Section 16. Other information

Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

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