//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [50]
1. The derivatives that are not found in nature are .........
(A) Alkanes (B) Carbohydrates (C) Haloalkanes (D) Fats
2. Which of the following is present in a hormone thyroxine ?
(A) Fluorine (B) Iodine (C) Bromine (D) Chlorine
3. Which of the following drug is used in treatment of typhoid fever ?
(A) Bromopheneramine (B) Chloramphenicol (C) Chloroquine (D) Iodoform
4. Deficiency of Thyroxine causes ..........
(A) Beri-Beri (B) Goiter (C) Urticaria (D) Cancer
5. Which of the following is an aryl halide ?
(A) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene (B) 1-Bromo-2-(1-methylpropyl) benzene
(C) 1-Bromo-3,3-dimethyl-1-phenylbutane (D) 3-Bromo-3-methyl-1-phenylbutane
6. Which of the following is the correct order of dipole moment ?
(A) CH2Cl2 > CHCl3 > CCl4 (B) CHCl3 > CH2Cl2 > CCl4
(C) CCl4 > CH2Cl2 > CCl4 (D) CHCl3 > CH2Cl2 > CCl4
7. The correct structure of o-dihalobenzene is .......
X
X X X
(A) (B) (C) (D)
X X
X X
8. The isomerism not shown by alkyl halides is....
(A) Chain isomerism (B) Functional isomersim (C) Position isomerism (D) Optical isomerism
9. In which of the following compounds the halogen is not bonded to sp3 carbon ?
(A) Ethylidene dichloride (B) Chloroethyl benzene
(C) 3-chlorocyclohex-1-ene (D) 1-chlorocyclohex-1-ene
10. Which of the following carbocation is maximum stable ?
CH3
| CH 2
Å Å
(A) CH 3 – C (B) (C) (D) H 2C = CH – CH 2
|
CH 3
11. Which substances are used in aerosol mixtures of insecticide substance ?
(A) Freon-22 (B) CClF3 (C) CCl2F2 (D) All of these
12. Which of the following alkylhalides show optical isomerism ?
(A) 2-Bromobutane (B) Isobutylbromide (C) Neopentylbromide (D) 1,4-dichlorobutane
13. Sym-Tribromobenzene is ..........
Br Br Br
Br
Br
Br Br
(A) (B) (C) (D)
Br Br Br
Br Br
14. To prepare alkyl iodides from alcohols, which of following reagent is used ?
(A) I2 + HIO3 (B) KI + H3PO4 (C) NaI + Acetone (D) KI + H2SO4
15. In the following reaction :
HCl
R – OH ¾¾¾
® R – Cl + H2O
the, ZnCl2 is not required if R is ..........
CH3
|
CH – C – CH – CH –
HCl
R – OH ¾¾¾
® R – Cl + H2O
the, ZnCl2 is not required if R is ..........
CH3
|
(A) CH3 – (B) CH 3 – C – (C) CH 3 – CH – (D) CH3 – CH2 –
| |
CH 3 C 2 H5
16. Which of the following reagent is not used to prepare alkyl halides from alcohols ?
(A) Br 2 / CCl4 (B) Red P + Br2 (C) NaBr / H2SO4 (D) KI + H3PO4
17. Which of the following have the maximum boiling point ?
CH3
CH 2 – Cl |
(A) (B) CH3 – CH2CH2CH2Cl (C) CH 3 – CH CH 2Cl (D) CH 3 – C – Cl
| |
CH 3 CH 3
18. The major product in the reaction is ........
H3C CH3
C=C + Br2
H H
CH3 CH3
H Br H Br
(A) H (B) Br + Enantiomer
Br H
CH3 CH3
Br – CH 2 CH 2 – Br Br – CH2 H
(C) (D) C C
C C
H H H CH 2 – Br
19. C2H5Br can be obtained in a laboratory by the action of ethyl alcohol with.....
(A) KBr (B) KBr + conc. (C) NH4Br (D) Br2
+ – F
NH2 N2 Cl
20. The reaction : NaNO 2 HBF4 is known as.....
0-5ºC D
(A) Sandmeyer’s reaction (B) Balz-schiemann reaction
(C) Birnbaum-Simonini reaction (D) Gatterman reaction
I
21. In the reaction : [X] The [X] is .........
+ I2
(A) FeI3 (B) HNO3 (C) HI (D) H3PO4
NBS
22. In the reaction : (P) The (P) is ..........
light
Br
Br Br
(A) (B) (C) (D)
Br Br
Br Br
23. Which of the following has highest bond enthalpy ?
(A) CH3 – F (B) CH3–Cl (C) CH3–Br (D) CH3 – I
24. Which of the following is 3o-Benzylic halide ?
CH 3 CH3 Cl
CH3
| | | CH2 – Cl
(A) C – Cl (B) CH 2 – C – Cl (C) CH2 CH2 – C – Cl (D)
| | |
CH3 CH3 CH3
25. The IUPAC name of CH2 - CH2 is .........
| |
Br Br
(A) Ethane-1,2-dibromide (B) 1,2,-dibromo ethane
(C) Ethylidene bromide (D) Ethylene dibromide
2 2
| |
Br Br
(A) Ethane-1,2-dibromide (B) 1,2,-dibromo ethane
(C) Ethylidene bromide (D) Ethylene dibromide
26. The general molecular formula of monohydric alcohols and ......... is same.
(A) Aldehyde (B) Ketones (C) Ethers (D) Ester
27. Which of the following isomerism is not shown by alcohols ?
(A) Chain (B) Position (C) Functional (D) Metamerism
28. Ordinary spirit is .........
(A) Methanol (B) Ethanol (C) Phenol (D) Butan-1-ol
29. Wood spirit is__________
(A) Methanol (B) Isopropyl alcohol (C) Butan-1-ol (D) Phenol
30. The IUPAC name of (CH3)3C – CH2OH is .........
(A) 2,2-Dimethylpropan-1-ol (B) Tertiary butyl carbinol
(C) Neopentyl alcohol (D) 1,1-Dimethylethylcarbinol
(i) LiAlH 4
31. Identify the product of the reaction : C6H5 – COOH ¾¾¾¾¾ ® X
(ii) H 2O
(A) Phenyl methanol (B) Ethyl benzene (C) 1-Phenyl ethanol (D) Ethyl benzoate
32. Alcohols are ........
(A) Bronsted Base (B) Lewis Base (C) Bronsted acid (D) All of these
33. The phenol with a high purity is obtained from ....
(A) Cumene (B) Benzene sulphonic acid
(C) Chlorobenzene (D) Diazonium salt
34. The enzyme that carries out the conversion of sucrose to glucose and fructose is ........
(A) Zymase (B) Transferase (C) Invertase (D) Zymase
35. The correct order of acidic strength of following compounds is ..........
(A) III > II > I > IV
OH OH OH OH
(B) II > I > IV > III
(C) III > II > IV > I Br Cl F I
(D) IV > I > II > III (I) (II) (III) (IV)
36. The major product in the following reaction is ..........
OH AgNO3(aq)
Br
O
OH O
OH N+
(A) (B) (C) –O (D)
37. Phenetole is ..........
(A) Diphenyl ether (B) Ethoxy benzene (C) Methoxy benzene (D) Diethyl ether
38. Which of the following is the strongest acid ?
(A) Cyclohexan-1-ol (B) Phenol (C) p-nitrophenol (D) p-methyl phenol
39. Identify the (X) in the following reaction :
X H C = C – CHO
H2C = C – CH2OH ¾® 2
CH3 CH3
(A) CrO3/H2SO4 (B) PCC/CH2Cl2 (C) Na2Cr2O7/H2SO4 (D) KMnO4/H2SO4
40. Which of the following alcohols give ketone on oxidation ?
(A) Propan-2-ol (B) Propan-1-ol (C) 2-Methyl propan-1-ol (D) Butan-1-ol
41. Which product obtained when diethyl ether is heated with Conc. HI ?
(A) Ethanol (B) Methyl iodide (C) Iodine (D) Ethyl iodide
42.
CH 3COCl
The following reaction is known as – C6H5OH ® C H OCOCH ?
Pyridine 6 5 3
(A) Remer-Tiemann reaction (B) Kolbe-Schmitt reaction
(C) Acetylation (D) Benzoylation
43. Glycerol is...
(A) Primary alcohol (B) Secondary alcohol (C) Monohydric acid (D) Trihydric alcohol
44. Picric acid is...
(A) Trinitro toluene (B) Trinitro aniline (C) Trinitro phenol (D) None of these
45. Lucas reagent is a...
(A) Concentrated HCl + Anhydrous ZnCl2 (B) Concentrated HNO3 + Anhydrous ZnCl2
(C) Concentrated HCl + Hydrated ZnCl2 (D) Concentrated HNO3 + Hydrated ZnCl2
46. Phenol is....
(A) strong base than ammonia (B) weak acid than carbonic acid
(C) strong acid than carbonic acid (D) neutral compound
47. Phenol on reduction with H2 in presence of Ni catalyst will give....
(A) benzene (B) toluene (C) cyclohexanol (D) cyclohaxane
48. What is C in the following reaction ?
NaOH Na CH3I
C2H5Br ®A ®B ®C
(A) Ethyl iodide (B) Ethane
(C) Propane (D) Methyl ethyl ether
49. Diethyl ether will not reacts with which of the following one ?
(A) H2SO4 (B) HCl (C) HI (D) CH3COOH
50. Which of the following is a 3o
alcohol ?
HNO 3 Br2 alcoholic
C8 H10 ¾¾¾¾ ® A ¾¾¾ ® B ¾¾¾¾¾® C
H 2SO 4 D KOH
(A) CH3CH2OH (B) (C) (D)
//X Section B
• Write the answer of the following questions. [Each carries 2 Marks]
(Any eight)
[16]
1. Give conversion : Benzene to 4-Bromonitro Benzene.
2. Write down chemical equations to prepare following substance from 1-Chloropropane.
(i) Propene (ii) Propan-1-ol
3. Give conversion: Ethene into butane.
4. Give conversion : Benzene into diphenyl.
5. Explain : Lucas test.
6. Write following conversion in two steps : Phenol to salicylic acid.
7. What are haloalkanes and haloarenes ?
8. Explain classification of haloalkanes and haloarenes on the basis of number of halogen atoms.
9. Give classification of ethers.
+
10. 1) Write the products of the following reaction : CH3 – CH = CH2 ¾¾¾¾¾
H O/H
2 ®
11. 1) Give following reaction of aryl halide : Halogenation
12. 4) Give following reaction of aryl halide : Friedel-crafts reaction
//X Section C
• Write the answer of the following questions. [Each carries 3 Marks] (Any six) [18]
13. Write the equations for the preparation of 1-iodobutane from
(i) 1-butanol
(ii) 1-chlorobutane
(iii) but-1-ene.
Write the equations for the preparation of 1-iodobutane from
(i) 1-butanol
(ii) 1-chlorobutane
(iii) but-1-ene.
14. Write a note on SN2 mechanism.
15. Write three chemical reactions for preparation of alkyl halides from alcohols. (Indicate byproducts if
any).
16. Give one example of each for Swarts reaction, Wurtz reaction and Finkelstein reaction of alkyl halide.
17. Write the structures of the products of the following reactions.
(i) CH3 – CH = CH2 H2O/H+
O
CH3 – C – OCH3 NaBH4
(ii)
O
(iii) CH3 – CH2 – CH – CHO NaBH4
CH3
18. Explain different Friedel-Crafts reactions of anisole.
19. What is meant by hydroboration-oxidation reaction ? Illustrate it with an example.
20. Write three chemical reactions for preparation of alkyl halides from alcohols. (Indicate byproducts
if any).
21. Write a note on DDT.
//X Section D
• Write the answer of the following questions. [Each carries 4 Marks] (Any four ) [16]
22. Write Kolbe and Reimer Tiemann reaction of phenol.
23. Write the reactions to prepared phenol from Aniline and Cumene.
24. Give chemical reaction for following conversion :(a) Butan-2-ol from acetaldehyde(b) Phenol from
aniline
25. Give only chemical formula to form following substances from phenol.
(a) Phenyl acetate (b) Benzene(c) p-bromophenol (d) 1,4-benzoquenone
26. Write chemical reaction to form Salicylic acid from phenol. Discuss uses of methyl salicylate by writing
structural formula.
27. Explain industrial method to form phenol by less expensive and having high quality. Also explain
bromination of phenol.
Section [ A ] : 1 Mark MCQ
No Ans Chap Sec Que Universal_QueId
1. C Chap 6 [Part... S5 1 QP24P11B1212_P2C6S5Q1
2. B Chap 6 [Part... S5 3 QP24P11B1212_P2C6S5Q3
3. B Chap 6 [Part... S5 4 QP24P11B1212_P2C6S5Q4
4. B Chap 6 [Part... S5 5 QP24P11B1212_P2C6S5Q5
5. B Chap 6 [Part... S5 13 QP24P11B1212_P2C6S5Q13
6. A Chap 6 [Part... S5 14 QP24P11B1212_P2C6S5Q14
7. B Chap 6 [Part... S5 16 QP24P11B1212_P2C6S5Q16
8. B Chap 6 [Part... S5 17 QP24P11B1212_P2C6S5Q17
9. D Chap 6 [Part... S5 18 QP24P11B1212_P2C6S5Q18
10. B Chap 6 [Part... S5 23 QP24P11B1212_P2C6S5Q23
11. D Chap 6 [Part... S5 24 QP24P11B1212_P2C6S5Q24
12. A Chap 6 [Part... S5 26 QP24P11B1212_P2C6S5Q26
13. B Chap 6 [Part... S5 29 QP24P11B1212_P2C6S5Q29
14. B Chap 6 [Part... S5 30 QP24P11B1212_P2C6S5Q30
15. B Chap 6 [Part... S5 31 QP24P11B1212_P2C6S5Q31
16. A Chap 6 [Part... S5 38 QP24P11B1212_P2C6S5Q38
17. A Chap 6 [Part... S5 39 QP24P11B1212_P2C6S5Q39
18. B Chap 6 [Part... S5 40 QP24P11B1212_P2C6S5Q40
19. B Chap 6 [Part... S5 48 QP24P11B1212_P2C6S5Q48
20. B Chap 6 [Part... S5 47 QP24P11B1212_P2C6S5Q47
21. B Chap 6 [Part... S5 53 QP24P11B1212_P2C6S5Q53
22. C Chap 6 [Part... S5 52 QP24P11B1212_P2C6S5Q52
23. A Chap 6 [Part... S5 21 QP24P11B1212_P2C6S5Q21
24. A Chap 6 [Part... S5 20 QP24P11B1212_P2C6S5Q20
25. B Chap 6 [Part... S5 19 QP24P11B1212_P2C6S5Q19
26. C Chap 7 [Part... S5 1 QP24P11B1212_P2C7S5Q1
27. D Chap 7 [Part... S5 2 QP24P11B1212_P2C7S5Q2
28. B Chap 7 [Part... S5 3 QP24P11B1212_P2C7S5Q3
29. A Chap 7 [Part... S5 4 QP24P11B1212_P2C7S5Q4
30. A Chap 7 [Part... S5 5 QP24P11B1212_P2C7S5Q5
31. A Chap 7 [Part... S5 15 QP24P11B1212_P2C7S5Q15
32. D Chap 7 [Part... S5 20 QP24P11B1212_P2C7S5Q20
33. A Chap 7 [Part... S5 21 QP24P11B1212_P2C7S5Q21
34. C Chap 7 [Part... S5 22 QP24P11B1212_P2C7S5Q22
35. B Chap 7 [Part... S5 34 QP24P11B1212_P2C7S5Q34
36. D Chap 7 [Part... S5 39 QP24P11B1212_P2C7S5Q39
37. B Chap 7 [Part... S5 48 QP24P11B1212_P2C7S5Q48
38. C Chap 7 [Part... S5 47 QP24P11B1212_P2C7S5Q47
39. B Chap 7 [Part... S5 49 QP24P11B1212_P2C7S5Q49
40. A Chap 7 [Part... S5 57 QP24P11B1212_P2C7S5Q57
41. D Chap 7 [Part... S6 1 QP24P11B1212_P2C7S6Q1
42. C Chap 7 [Part... S6 2 QP24P11B1212_P2C7S6Q2
43. D Chap 7 [Part... S6 3 QP24P11B1212_P2C7S6Q3
44. C Chap 7 [Part... S6 4 QP24P11B1212_P2C7S6Q4
45. A Chap 7 [Part... S6 5 QP24P11B1212_P2C7S6Q5
46. B Chap 7 [Part... S6 8 QP24P11B1212_P2C7S6Q8
47. C Chap 7 [Part... S6 9 QP24P11B1212_P2C7S6Q9
48. D Chap 7 [Part... S6 15 QP24P11B1212_P2C7S6Q15
49. D Chap 7 [Part... S6 18 QP24P11B1212_P2C7S6Q18
50. B Chap 7 [Part... S6 20 QP24P11B1212_P2C7S6Q20
Section [ B ] : 2 Marks Questions
No Ans Chap Sec Que Universal_QueId
1. - Chap 6 [Part... S8 5 QP24P11B1212_P2C6S8Q5
2. - Chap 6 [Part... S8 4 QP24P11B1212_P2C6S8Q4
3. - Chap 6 [Part... S1 42 QP24P11B1212_P2C6S1Q42
4. - Chap 6 [Part... S1 40 QP24P11B1212_P2C6S1Q40
5. - Chap 7 [Part... S8 2 QP24P11B1212_P2C7S8Q2
6. - Chap 7 [Part... S8 1 QP24P11B1212_P2C7S8Q1
7. - Chap 6 [Part... S1 1 QP24P11B1212_P2C6S1Q1
8. - Chap 6 [Part... S1 3 QP24P11B1212_P2C6S1Q3
9. - Chap 7 [Part... S1 4 QP24P11B1212_P2C7S1Q4
10. - Chap 7 [Part... S1 50.1 QP24P11B1212_P2C7S1Q50.1
11. - Chap 6 [Part... S1 34.1 QP24P11B1212_P2C6S1Q34.1
12. - Chap 6 [Part... S1 34.4 QP24P11B1212_P2C6S1Q34.4
Section [ C ] : 3 Marks Questions
No Ans Chap Sec Que Universal_QueId
13. - Chap 6 [Part... S3 7 QP24P11B1212_P2C6S3Q7
14. - Chap 6 [Part... S1 18 QP24P11B1212_P2C6S1Q18
15. - Chap 6 [Part... S8 10 QP24P11B1212_P2C6S8Q10
16. - Chap 6 [Part... S8 7 QP24P11B1212_P2C6S8Q7
17. - Chap 7 [Part... S2 5 QP24P11B1212_P2C7S2Q5
18. - Chap 7 [Part... S1 49 QP24P11B1212_P2C7S1Q49
19. - Chap 7 [Part... S3 6 QP24P11B1212_P2C7S3Q6
20. - Chap 6 [Part... S1 9R QP24P11B1212_P2C6S1Q9R
21. - Chap 6 [Part... S1 38 QP24P11B1212_P2C6S1Q38
Section [ D ] : 4 Marks Questions
No Ans Chap Sec Que Universal_QueId
22. - Chap 7 [Part... S8 19 QP24P11B1212_P2C7S8Q19
23. - Chap 7 [Part... S8 18 QP24P11B1212_P2C7S8Q18
24. - Chap 7 [Part... S8 17 QP24P11B1212_P2C7S8Q17
25. - Chap 7 [Part... S8 16 QP24P11B1212_P2C7S8Q16
26. - Chap 7 [Part... S8 15 QP24P11B1212_P2C7S8Q15
27. - Chap 7 [Part... S8 14 QP24P11B1212_P2C7S8Q14
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [50]
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[24]
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[27]
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