Version: 1.

0
Revision Date: 02/24/2020

SAFETY DATA SHEET

1. Identification

Product identifier: NAPA Mac's 1397 Belt Dressing

Other means of identification

SDS number: RE1000036034

Recommended restrictions
Product use: Lubricant
Restrictions on use: Not known.

Manufacturer/Importer/Distributor Information

Manufacturer

Company Name: NAPA BALKAMP

Address: 1601 Whitaker Rd
INDIANAPOLIS,IN 46168
Telephone: 317-837-2800
Fax:

Emergency telephone number: 1-866-836-8855

2. Hazard(s) identification

Hazard Classification
Physical Hazards
Flammable aerosol Category 1

Health Hazards
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Skin sensitizer Category 1
Specific Target Organ Toxicity - Category 31.
Single Exposure
Aspiration Hazard Category 1

Target Organs
1. Narcotic effect.

Environmental Hazards
Acute hazards to the aquatic Category 2
environment
Chronic hazards to the aquatic Category 3
environment

Label Elements

Hazard Symbol:

Signal Word: Danger

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Hazard Statement: Extremely flammable aerosol.

Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.

Precautionary
Statements

Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Wash thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face
protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated
work clothing should not be allowed out of the workplace. Use only outdoors
or in a well-ventilated area. Avoid release to the environment.

Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/attention. IF ON SKIN: Wash with
plenty of water If skin irritation or rash occurs: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTER/doctor Do NOT
induce vomiting. Call a POISON CENTER/doctor if you feel unwell. Specific
treatment (see on this label). Wash contaminated clothing before reuse.

Storage: Protect from sunlight. Do not expose to temperatures exceeding

50°C/122°F. Store in a well-ventilated place. Keep container tightly closed.
Store locked up.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.

classified (HNOC):

3. Composition/information on ingredients

Mixtures
Chemical Identity CAS number Content in percent (%)*
2-Propanone 67-64-1 20 - <50%
Propane 74-98-6 10 - <20%
Butane 106-97-8 10 - <20%
Solvent naphtha (petroleum), light aliph. 64742-89-8 10 - <20%
Heptane 142-82-5 5 - <10%
Heptane, branched, cyclic and linear 426260-76-6 5 - <10%
Naphtha (petroleum), hydrotreated light 64742-49-0 5 - <10%
Naphtha (petroleum), heavy alkylate 64741-65-7 5 - <10%
Maleic Anhydride Modified Liquid Polyisoprene 841251-34-1 1 - <5%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Ingestion: Call a physician or poison control center immediately. Rinse mouth. Never
give liquid to an unconscious person. If vomiting occurs, keep head low so
that stomach content doesn't get into the lungs.

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Inhalation: Move to fresh air.

Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated shoes.
Immediately remove contaminated clothing and shoes and wash skin with
soap and plenty of water. If skin irritation or an allergic skin reaction
develops, get medical attention.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Most important symptoms/effects, acute and delayed

Symptoms: No data available.

Hazards: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: No data available.

5. Fire-fighting measures

General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from Vapors may travel considerable distance to a source of ignition and flash
the chemical: back.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.

procedures:

Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

6. Accidental release measures

Personal precautions, Ventilate closed spaces before entering them. ELIMINATE all ignition
protective equipment and sources (no smoking, flares, sparks or flames in immediate area). Keep
emergency procedures: upwind. See Section 8 of the SDS for Personal Protective Equipment. Do
not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Keep unauthorized personnel away.

Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste.
up:

Notification Procedures: Prevent entry into waterways, sewer, basements or confined areas. Stop
the flow of material, if this is without risk. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk.
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Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so. Avoid release to the environment.

7. Handling and storage

Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Avoid contact with skin. Avoid contact with
eyes, skin, and clothing.

Conditions for safe storage, Store locked up. Pressurized container: protect from sunlight and do not
including any expose to temperatures exceeding 50°C. Do not pierce or burn, even after
incompatibilities: use. Aerosol Level 3

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

2-Propanone STEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 250 ppm US. ACGIH Threshold Limit Values (03 2015)
TWA 750 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
STEL 500 ppm US. ACGIH Threshold Limit Values (03 2015)
REL 250 ppm 590 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Butane REL 800 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
STEL 1,000 ppm US. ACGIH Threshold Limit Values (03 2018)
TWA 800 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Solvent naphtha (petroleum), REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)
light aliph.
TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (03 2016)
Naphtha (petroleum), PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
hydrotreated light CFR 1910.1000) (03 2016)
REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)
TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Heptane TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 85 ppm 350 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
STEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
TWA 400 ppm US. ACGIH Threshold Limit Values (02 2012)
STEL 500 ppm US. ACGIH Threshold Limit Values (02 2012)
Ceil_Time 440 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Naphtha (petroleum), heavy PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
alkylate CFR 1910.1000) (02 2006)
TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)
Distillates (petroleum), TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
hydrotreated heavy
naphthenic
PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
Distillates (petroleum), REL 5 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
hydrotreated heavy
naphthenic - Mist.
STEL 10 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Distillates (petroleum), Ceil_Time 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)

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hydrotreated heavy
naphthenic
Distillates (petroleum), TWA 5 mg/m3 US. ACGIH Threshold Limit Values (03 2014)
hydrotreated heavy
naphthenic - Inhalable
fraction.
Distillates (petroleum), REL 350 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)
hydrotreated heavy
naphthenic
Benzene, methyl- STEL 150 ppm 560 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 100 ppm 375 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 100 ppm 375 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ceiling 300 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
MAX. 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
CONC
STEL 150 ppm 560 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Benzene REL 0.1 ppm US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 1 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ceiling 25 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
TWA 0.5 ppm US. ACGIH Threshold Limit Values (2008)
STEL 2.5 ppm US. ACGIH Threshold Limit Values (2008)
STEL 5 ppm US. OSHA Specifically Regulated Substances (29
CFR 1910.1001-1053) (02 2006)
OSHA_AC 0.5 ppm US. OSHA Specifically Regulated Substances (29
T CFR 1910.1001-1053) (02 2006)
TWA 10 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
MAX. 50 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
CONC
STEL 5 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
TWA 1 ppm US. OSHA Specifically Regulated Substances (29
CFR 1910.1001-1053) (02 2006)
STEL 1 ppm US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Benzene, (1-methylethyl)- REL 50 ppm 245 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 50 ppm US. ACGIH Threshold Limit Values (2008)
PEL 50 ppm 245 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 50 ppm 245 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
TWA 1 ppm US. ACGIH Notice of Intended Changes (NIC) to
Threshold Limit Values (03 2018)
Benzene, ethyl- STEL 125 ppm 545 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
REL 100 ppm 435 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
STEL 125 ppm 545 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
TWA 100 ppm 435 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
TWA 20 ppm US. ACGIH Threshold Limit Values (12 2010)
Hexane TWA 50 ppm 180 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 500 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
REL 50 ppm 180 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 50 ppm US. ACGIH Threshold Limit Values (2008)
Cyclohexane TWA 100 ppm US. ACGIH Threshold Limit Values (2008)
TWA 300 ppm 1,050 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 300 ppm 1,050 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 300 ppm 1,050 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)

Biological Limit Values

Chemical Identity Exposure Limit Values Source
2-Propanone (acetone: Sampling time: End of shift.) 25 mg/l (Urine) ACGIH BEL (03 2015)
Benzene, methyl- (toluene: Sampling time: End of shift.) 0.03 mg/l (Urine) ACGIH BEL (03 2013)
Benzene, methyl- (o-Cresol, with hydrolysis: Sampling 0.3 mg/g (Creatinine in urine) ACGIH BEL (03 2013)
time: End of shift.)
Benzene, methyl- (toluene: Sampling time: Prior to last 0.02 mg/l (Blood) ACGIH BEL (03 2013)
shift of work week.)
Benzene (S-Phenylmercapturic acid: Sampling time: 25 µg/g (Creatinine in urine) ACGIH BEL (03 2013)
End of shift.)
Benzene (t,t-Muconic acid: Sampling time: End of shift.) 500 µg/g (Creatinine in urine) ACGIH BEL (03 2013)
Benzene, ethyl- (Sum of mandelic acid and 0.15 g/g (Creatinine in urine) ACGIH BEL (02 2014)
phenylglyoxylic acid: Sampling time: End of shift.)
Hexane (2,5-Hexanedion, without hydrolysis: Sampling 0.5 mg/l (Urine) ACGIH BEL (03 2018)
time: End of shift.)

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Appropriate Engineering No data available.

Controls

Individual protection measures, such as personal protective equipment

General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level.

Eye/face protection: Wear safety glasses with side shields (or goggles).

Skin Protection
Hand Protection: No data available.

Other: Wear suitable protective clothing. Wear chemical-resistant gloves, footwear,

and protective clothing appropriate for the risk of exposure. Contact health
and safety professional or manufacturer for specific information.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.

Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. When
using do not smoke. Wash contaminated clothing before reuse. Avoid
contact with skin. Wash hands before breaks and immediately after
handling the product. Contaminated work clothing should not be allowed
out of the workplace.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: Spray Aerosol
Color: No data available.
Odor: No data available.
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: Estimated -104.44 °C
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): Estimated 9.5 %(V)
Flammability limit - lower (%): Estimated 1.9 %(V)
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: Estimated 2,068 - 3,447 hPa (20 °C)
Vapor density: No data available.
Density: No data available.
Relative density: No data available.
Solubility(ies)
Solubility in water: No data available.

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Solubility (other): No data available.

Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.

reactions:

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

Hazardous Decomposition No data available.

Products:

11. Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
2-Propanone LD 50 (Rat): 5,800 mg/kg

Solvent naphtha LD 50 (Rat): > 5,000 mg/kg

(petroleum), light aliph.

Heptane LD 50 (Rat): > 5,000 mg/kg

Heptane, branched, LD 50: > 2,000 mg/kg

cyclic and linear

Naphtha (petroleum), LD 50 (Rat): > 5,000 mg/kg

hydrotreated light

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Naphtha (petroleum), LD 50: > 2,000 mg/kg

heavy alkylate

Maleic Anhydride LD 50: > 2,000 mg/kg

Modified Liquid
Polyisoprene

Dermal
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
2-Propanone LD 50 (Rabbit): > 7,426 mg/kg

Solvent naphtha LD 50 (Rabbit): > 2,000 mg/kg

(petroleum), light aliph.

Heptane LD 50 (Rabbit): > 2,000 mg/kg

Heptane, branched, LD 50: > 2,000 mg/kg

cyclic and linear

Naphtha (petroleum), LD 50 (Rabbit): > 3,750 mg/kg

hydrotreated light

Naphtha (petroleum), LD 50: > 2,000 mg/kg

heavy alkylate

Maleic Anhydride LD 50: > 2,000 mg/kg

Modified Liquid
Polyisoprene

Inhalation
Product: ATEmix: 65.21 mg/l

Repeated dose toxicity

Product: No data available.

Specified substance(s):
2-Propanone NOAEL (Rat(Male), Oral, 13 Weeks): 10,000 ppm(m) Oral Experimental
result, Key study
Propane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
Butane LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
Solvent naphtha NOAEL (Mouse, Rat(Female, Male), Inhalation, 107 - 113 Weeks): 1,402
(petroleum), light aliph. mg/m3 Inhalation Experimental result, Key study
NOAEL (Rat(Female, Male), Dermal, 5 - 28 d): 3,750 mg/kg Dermal
Experimental result, Key study
NOAEL (Rat(Female, Male), Dermal, 28 d): > 375 mg/kg Dermal
Experimental result, Supporting study
Heptane NOAEL (Rat(Male), Inhalation): 12,470 mg/m3 Inhalation Experimental
result, Key study
Naphtha (petroleum), LOAEL (Rat(Female, Male), Oral, 13 Weeks): 1,250 mg/kg Oral Read-
hydrotreated light across based on grouping of substances (category approach), Key study
NOAEL (Rat(Female, Male), Dermal, 28 d): > 375 mg/kg Dermal
Experimental result, Supporting study
NOAEL (Rat(Female, Male), Inhalation): 10,000 mg/m3 Inhalation
Experimental result, Key study

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Skin Corrosion/Irritation
Product: No data available.

Specified substance(s):
2-Propanone in vivo (Rabbit): Not irritant Experimental result, Supporting study

Solvent naphtha Assessment Non-Irritating

(petroleum), light aliph. in vivo (Rabbit): Irritating Experimental result, Key study

Heptane in vivo (Rabbit): Irritating Read-across based on grouping of substances

(category approach), Key study

Serious Eye Damage/Eye Irritation

Product: No data available.
Specified substance(s):

2-Propanone Irritating.
Rabbit, 24 hrs: Minimum grade of severe eye irritant

Solvent naphtha Rabbit: Not irritating

(petroleum), light aliph.

Heptane Rabbit, 24 - 72 hrs: Not irritating

Naphtha (petroleum), Rabbit, 24 - 72 hrs: Not irritating

hydrotreated light

Respiratory or Skin Sensitization

Product: No data available.

Specified substance(s):
2-Propanone Skin sensitization:, in vivo (Guinea pig): Non sensitising
Solvent naphtha Skin sensitization:, in vivo (Guinea pig): Non sensitising
(petroleum), light aliph.
Heptane Skin sensitization:, in vivo (Guinea pig): Non sensitising
Naphtha (petroleum), Skin sensitization:, in vivo (Guinea pig): Non sensitising
hydrotreated light

Carcinogenicity
Product: No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

Specific Target Organ Toxicity - Single Exposure

Product: No data available.

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Specified substance(s):
2-Propanone Inhalation - vapor: Narcotic effect. - Category 3 with narcotic effects.
Heptane Narcotic effect. - Category 3 with narcotic effects.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.

Target Organs
Specific Target Organ Toxicity - Single Exposure: Narcotic effect.

Aspiration Hazard
Product: No data available.

Specified substance(s):
Solvent naphtha May be fatal if swallowed and enters airways.
(petroleum), light aliph.
Heptane May be fatal if swallowed and enters airways.
Heptane, branched, cyclic May be fatal if swallowed and enters airways.
and linear
Naphtha (petroleum), May be fatal if swallowed and enters airways.
hydrotreated light
Naphtha (petroleum), May be fatal if swallowed and enters airways.
heavy alkylate

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
2-Propanone LC 50 (Oncorhynchus mykiss, 96 h): 5,540 mg/l Experimental result, Key
study

Propane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study

Butane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study

Solvent naphtha LL 50 (Pimephales promelas, 96 h): 8.2 mg/l Experimental result, Key study
(petroleum), light aliph.

Heptane LC 50 (Mozambique tilapia (Tilapia mossambica), 96 h): 375 mg/l Mortality

Naphtha (petroleum), LC 50 (96 h): 8.41 mg/l Experimental result, Key study
hydrotreated light

Aquatic Invertebrates
Product: No data available.

Specified substance(s):
2-Propanone LC 50 (Daphnia pulex, 48 h): 8,800 mg/l Experimental result, Key study

Butane LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study

Solvent naphtha EC 50 (Daphnia magna, 48 h): 4.5 mg/l Experimental result, Key study
(petroleum), light aliph. NOAEL (Daphnia magna, 48 h): 0.5 mg/l Experimental result, Key study

Heptane EC 50 (Daphnia magna, 48 h): 1.5 mg/l Experimental result, Key study
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Naphtha (petroleum), EC 50 (Daphnia magna, 48 h): 4.5 mg/l Experimental result, Key study
hydrotreated light

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
Solvent naphtha NOAEL (Daphnia magna): 2.6 mg/l Other, Key study
(petroleum), light aliph.

Heptane NOAEL (Oncorhynchus mykiss): 1.284 mg/l QSAR QSAR, Key study

Naphtha (petroleum), EC 50 (Daphnia magna): 10 mg/l Other, Key study

hydrotreated light NOAEL (Daphnia magna): 2.6 mg/l Other, Key study

Aquatic Invertebrates
Product: No data available.

Specified substance(s):
2-Propanone LOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study
NOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study

Solvent naphtha EC 50 (Daphnia magna): > 40 mg/l Experimental result, Key study
(petroleum), light aliph.

Heptane NOAEL (Daphnia magna): 0.17 mg/l Read-across based on grouping of

substances (category approach), Key study
EC 50 (Daphnia magna): 0.23 mg/l Read-across based on grouping of
substances (category approach), Key study

Heptane, branched, NOEC : < 1 mg/l estimation

cyclic and linear

Naphtha (petroleum), EC 50 (Daphnia magna): 10 mg/l Experimental result, Key study

hydrotreated light NOAEL (Daphnia magna): 2.6 mg/l Experimental result, Key study

Toxicity to Aquatic Plants

Product: No data available.

Persistence and Degradability

Biodegradation
Product: No data available.

Specified substance(s):
2-Propanone 90.9 % (28 d) Detected in water. Experimental result, Key study

Propane 100 % (385.5 h) Detected in water. Experimental result, Key study

50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study

Butane 100 % (385.5 h) Detected in water. Experimental result, Key study

Solvent naphtha 90.35 % (28 d) Detected in water. Experimental result, Supporting study
(petroleum), light aliph. 77.05 % Detected in water. Experimental result, Supporting study

Heptane 70 % Detected in water. Experimental result, Key study

Naphtha (petroleum), 90.35 % (28 d) Detected in water. Experimental result, Supporting study
hydrotreated light

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BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.

Specified substance(s):
2-Propanone Haddock, adult, Bioconcentration Factor (BCF): 0.69 Aquatic sediment
Experimental result, Not specified

Solvent naphtha Bioconcentration Factor (BCF): 10 - 2,500 Aquatic sediment Estimated by

(petroleum), light aliph. calculation, Key study

Heptane Bioconcentration Factor (BCF): 552 Aquatic sediment Estimated by

calculation, Key study

Naphtha (petroleum), Bioconcentration Factor (BCF): 10 - 2,500 Aquatic sediment Estimated by

hydrotreated light calculation, Key study

Partition Coefficient n-octanol / water (log Kow)

Product: No data available.

Specified substance(s):
Naphtha (petroleum), Log Kow: > 2.4 - < 5.7 23 °C Yes Experimental result, Key study
hydrotreated light Log Kow: 2.2 - 5.2 23 °C Yes Experimental result, Key study
Log Kow: 2.2 - 6.1 23 °C Yes Experimental result, Key study

Mobility in soil: No data available.

Known or predicted distribution to environmental compartments

2-Propanone No data available.
Propane No data available.
Butane No data available.
Solvent naphtha (petroleum), light aliph. No data available.
Heptane No data available.
Heptane, branched, cyclic and linear No data available.
Naphtha (petroleum), hydrotreated light No data available.
Naphtha (petroleum), heavy alkylate No data available.
Maleic Anhydride Modified Liquid Polyisoprene No data available.

Other adverse effects: Toxic to aquatic organisms. Harmful to aquatic life with long lasting effects.

13. Disposal considerations

Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws.

Contaminated Packaging: No data available.

14. Transport information

DOT
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2.1
Label(s): –
Packing Group: II
Marine Pollutant: No

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

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IMDG
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2
Label(s): –
EmS No.:
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

IATA
UN Number: UN 1950
Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es):
Class: 2.1
Label(s): –
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

15. Regulatory information

US Federal Regulations

Restrictions on use: Not known.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Chemical Identity OSHA hazard(s)
Benzene Flammability
Cancer
Aspiration
Eye
Blood
Skin
respiratory tract irritation
Central nervous system

CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Identity Reportable quantity
2-Propanone lbs. 5000
Propane lbs. 100
Butane lbs. 100
Heptane lbs. 100
Benzene, methyl- lbs. 1000
Benzene lbs. 10
Benzene, (1-methylethyl)- lbs. 5000
Benzene, ethyl- lbs. 1000
Hexane lbs. 5000
Cyclohexane lbs. 1000

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Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Fire Hazard
Immediate (Acute) Health Hazards
Flammable aerosol
Skin Corrosion/Irritation
Serious Eye Damage/Eye Irritation
Skin sensitizer
Specific Target Organ Toxicity - Single Exposure
Aspiration Hazard

SARA 302 Extremely Hazardous Substance

Reportable
Chemical Identity quantity Threshold Planning Quantity
2-Propanone
Hexane

SARA 304 Emergency Release Notification

Chemical Identity Reportable quantity
2-Propanone lbs. 5000
Propane lbs. 100
Butane lbs. 100
Heptane lbs. 100
Benzene, methyl- lbs. 1000
Benzene lbs. 10
Benzene, (1-methylethyl)- lbs. 5000
Benzene, ethyl- lbs. 1000
Hexane lbs. 5000
Cyclohexane lbs. 1000

SARA 311/312 Hazardous Chemical

Chemical Identity Threshold Planning Quantity
2-Propanone 10000 lbs
Propane 10000 lbs
Butane 10000 lbs
Solvent naphtha (petroleum), light aliph. 10000 lbs
Heptane 10000 lbs
Heptane, branched, cyclic and linear 10000 lbs
Naphtha (petroleum), hydrotreated light 10000 lbs
Naphtha (petroleum), heavy alkylate 10000 lbs
Maleic Anhydride Modified Liquid Polyisoprene 10000 lbs
Distillates (petroleum), hydrotreated heavy naphthenic 10000 lbs
Benzene, methyl- 10000 lbs
Benzene 10000 lbs
Benzene, (1-methylethyl)- 10000 lbs
Benzene, ethyl- 10000 lbs
Hexane 10000 lbs
Cyclohexane 10000 lbs

SARA 313 (TRI Reporting)

None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations

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US. California Proposition 65

This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm.

Benzene, methyl- Developmental toxin. 03 2008

Benzene Developmental toxin. 03 2008
Benzene Carcinogenic. 05 2011
Benzene Male reproductive toxin. 03 2008
Benzene, (1-methylethyl)- Carcinogenic. 05 2011
Benzene, ethyl- Carcinogenic. 05 2011
Hexane Male reproductive toxin. 12 2017

US. New Jersey Worker and Community Right-to-Know Act

Chemical Identity
2-Propanone
Propane
Butane
Solvent naphtha (petroleum), light aliph.
Naphtha (petroleum), hydrotreated light
Heptane
Naphtha (petroleum), heavy alkylate
Distillates (petroleum), hydrotreated heavy naphthenic

US. Massachusetts RTK - Substance List

Chemical Identity
Benzene

US. Pennsylvania RTK - Hazardous Substances

Chemical Identity
2-Propanone
Propane
Butane
Solvent naphtha (petroleum), light aliph.
Naphtha (petroleum), hydrotreated light
Heptane
Naphtha (petroleum), heavy alkylate

US. Rhode Island RTK

No ingredient regulated by RI Right-to-Know Law present.

International regulations

Montreal protocol
2-Propanone

Stockholm convention
2-Propanone

Rotterdam convention
2-Propanone

Kyoto protocol

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Inventory Status:
Australia AICS: Not in compliance with the inventory.

Canada DSL Inventory List: On or in compliance with the inventory

Canada NDSL Inventory: Not in compliance with the inventory.

Ontario Inventory: Not in compliance with the inventory.

China Inv. Existing Chemical Substances: On or in compliance with the inventory

Japan (ENCS) List: Not in compliance with the inventory.

Japan ISHL Listing: Not in compliance with the inventory.

Japan Pharmacopoeia Listing: Not in compliance with the inventory.

Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory.

Mexico INSQ: Not in compliance with the inventory.

New Zealand Inventory of Chemicals: Not in compliance with the inventory.

Philippines PICCS: Not in compliance with the inventory.

Taiwan Chemical Substance Inventory: Not in compliance with the inventory.

US TSCA Inventory: On or in compliance with the inventory

EINECS, ELINCS or NLP: Not in compliance with the inventory.

16.Other information, including date of preparation or last revision

Issue Date: 02/24/2020

Revision Information: No data available.

Version #: 1.0

Further Information: No data available.

Disclaimer: This information is provided without warranty. The information is believed to

be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

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