SRI CHAITANYA IIT ACADEMY, INDIA 19-07-2025_Sr.

IPL-IC_Jee Main_WTM-32_Key & Sol's

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. IPL-IC JEE-MAIN Date: 19-07-2025
Time: 09.00Am to 12.00Pm WTM -32 Max. Marks: 300
KEY SHEET
MATHEMATICS
1) 4 2) 1 3) 1 4) 4 5) 2
6) 1 7) 1 8) 3 9) 1 10) 2
11) 2 12) 1 13) 4 14) 3 15) 2
16) 1 17) 4 18) 4 19) 4 20) 1
21) 12 22) 3 23) 4 24) 10 25) 272

PHYSICS
26 4 27 4 28 1 29 2 30 3
31 1 32 4 33 1 34 3 35 1
36 3 37 1 38 1 39 1 40 1
41 4 42 3 43 1 44 1 45 1
46 55 47 1200 48 4 49 1 50 70

CHEMISTRY
51 2 52 3 53 3 54 1 55 4
56 2 57 1 58 4 59 1 60 2
61 2 62 2 63 4 64 1 65 2
66 4 67 2 68 1 69 3 70 2
71 2 72 6 73 6 74 2 75 10

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SOLUTION
MATHEMATICS
1. Given S = (4, -3), A = (4, -1)
a = AS = 2
Equation of parabola is
( x  4)2  4(2)( y  1)
 x 2  8 x  8 y  24  0
2. 2a = Distance from (3,4) to 2x−3y+5 = 0 then L.L.R = 2(2a)
3. Given parabolas are,
y 2  32 x and x 2  256 y
We use a standard result to find equation of common tangent.
Equation of tangent common to y 2  4ax and x 2  4by is, xa1/3  yb1/3   ab   0
2/3

Here, 4a  32  a  8
4b  256  b  64
So, tangent is, (8)1/3 x  (64)1/3 y   8  64   0
2/3

 2 x  4 y  64  0
4. Given parabola
4 1
where 4 a   a 
3 3
Givenline x  3 y  k  0
Sin ce this is a tan gent then am 2  l.n
1
  9   k k  3
3
5. Let the general equation of the parabola is x = ay2+by+c
It passes through the points (-2,1),(1,2) and (-1,3)
Then
a  b  c  2  (1)
4a  2b  c  1  (2)
and 9a  3b  c  1  (3)
By solving (1), (2) and (3) we get
5 21
a   ,b  and c  10
2 2
Hence, the equation of parabola is
5 2 21
x y  y  10
2 2
 2 x  5 y 2  21 y  20
 5 y 2  2 x  21 y  20  0
6. Given parabola y2 = 4x ⇒ a = 1
1
Slope of given line x+3y+1= 0 is 
3
and slope of normal(m) = 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-07-2025_Sr.IPL-IC_Jee Main_WTM-32_Key & Sol's

Equation of normal with slope m is y  mx  2am  am3

y  mx  2.3  33  3 x  y  33  0
7.
I  e x x 2
 1
dx   e x x 2
 1  2
dx
(x  1) 2
(x  1)2
 x 1 2 
 ex   2
dx   e x  f  x   f   x   dx
 x  1 (x  1) 
x 1 2
 e x .f  x   c where f  x   then f   x  
x 1 (x  1) 2
8.  sin 3 x  cos 3 xdx

  sin 3 x  cos x 1  sin 2 x dx 
sin x  t
cos xdx  dt

  t 3 1  t 2 dt 

  t3  t5  dt
t4 t6
  c
4 6
sin x sin 6 x
4
  c
4 6
9.
1
 11 15
dx
(x  11) (x  15)13 13

1
 11
dx
 x  11 13
(x  15) 2  
 x  15 
 x  11 
put  t
 x  15 
diff w.r.to x on both sides
1 1
 dx  dt
(x  15) 2
26
11
1 13
G.I   t dt
26
2
1 t 13
 c
26 2
13
2
1  x  11 13
   c
4  x  15 
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10.

Let I  
x 2
 1 dx
 1
x
 3 x 2  1 tan 1  x  
4

 x
 1 
 1  2  dx
  x 
 2 1  1  1
 x  3  2  tan  x  
 x   x
 1 
 1  2  dx
  x 
 1
2
 1  1
  x    1 tan  x  
 x   x
1  1 
Put x   t  1  2  dx  dt
x  x 
dt
I  2
t  1 tan 1 t
Now put tan 1 t  u
dt
  du
1 t2
du
I
u
I  log u  C
 log tan 1 t  C
 1
 I  log tan 1  x    C
 x
1
x2 1
x4 x 4  1
 dx   dx
11. x7 x5
4
Put x  1  t
dx dt
Diff w.r.to x on both sides 
x5 4
 dt  1  2 3/ 2  1 4
 
3/ 2
 t     t c  x 1  c
 4  43  6

3
1  1  x4 
   c
6  x4 

1
  c
3
 1  x4
6.x 6
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on comparing we get
1
f ( x)  ,n  3
6 x6
12.
dx
 1
,
x 2026
x 2025
1  2025

Put x 2025  1  t
Diff w.r.to x on both sides
2025.x 2026 dx  dt
1
1 2025
G.I   t dt
2025
2024
1 t 2025
 . c
2025 2024
2025
1 2024

2024

x 2025  1 2025  c 
2024



 1  x 2025  2025
 c  m  n 1
2024 x 2024
13. Given vertex is (5, 4) and directrix 3x + y – 29 = 0
Let foot of perpendicular of (5, 4) on directrix is (x1, y1)
x1  5 y1  4 ( 10)
 
3 1 10
  x1 , y1   (8,5)
So, focus of parabola will be S = (2, 3)
Let P (x, y) be any point on parabola, then
(3x  y  29)2
( x  2)2  ( y  3)2 
10
 10  x  y  4 x  6 y  13
2 2

 9 x 2  y 2  841  6 xy  58 y  174 x
 x 2  9 y 2  6 xy  134 x  2 y  711  0
and given parabola
x 2  ay 2  bxy  cx  dy  k  0
 a  9, b  6, c  134, d  2, k  711
 a  b  c  d  k  576
5 x 6  7 x 8
14. f ( x)   dx
 1 1 
 7  5  2
x x 
1 1
put 7  5  2  t
x x
Diff w.r.to x on both sides

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7x 8

 5 x 6 dx   dt
1 1 x7
 f ( x)   (  dt )   c  c
t2 t x2  2x7  1
 f (0)  0  c  0
1
 f (1) 
4
 1  x  x  e x  x dx
1
1
15.
1
 1  x
  1  x   e x dx
 x
  1   x  1x
  1  x  1  2   e dx
  x 
 x 1 1
x  1 
  e x  xe x 1  2   dx
  x 
we knowthat  ( f  x   xf '  x ) dx  xf  x   c
1 1
x x
 xe x
 c  f ( x)  xe x

1
Now f (1)  f (1)  e 2 
e2
16. Given  f ( x)dx   ( x)  (1)
  x5 f x3 dx  
Put x  t  3 x 2 dx  dt
3

 dt  1
 tf (t )    t  f (t )dt    (1)  f (t )dt  dt 
3 3
1
 t (t )    (t ) dt 
3
1 3
 
  x  x3    x 3 3 x 2 dx 
3
  
1
 
  x 3 x3    x 2 x3 dx
3
 
17.
1  cos8x 1  cos 8x
 dx   dx
tan 2x  cot 2x sin 2x  cos 2 2x
2

sin 2 xcos 2x
1  cos8x.sin 2 xcos 2x
 dx
 cos 4 x
1
   sin 8 xdx
2
1
 cos8x  c
16

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1
By Comparison, f ( x)  , g ( x)  8 x
16
1 1 1 33
f   g   2 
4  4  16 16
18.
Given parabola y 2  8 x  1
where 4a  8  a  2
Let P   at12 , 2at1    2, 4 
 2at1  4 t1  1
If Normal at P(t1) meet the parabola again at Q(t2) then
2
t2  t1 
t1
 t2  3
 
 Q ( ,  )  at22 , 2at2  (18,12)
 (   )  18  12  30
19. Statement-2 is true. Equation in statement-1 can be written as (x−1)2 = −2(y − 3/2).
Which is a parabola with axis as the line x-1=0 and hence using statement-2, statement-1
is also correct.
20.

Equation of directrix is 3 x  4 y  1  0
2
 3x  4 y  1 
Given parabola ( x  2)  ( y  5)  
2 2

 25 
SP 2  PM 2
2a  perpendicular dis tan ce from focus (2, 5) to directrix
| 6  20  1|
 3
25
Now LLR  4a  2  2a  6

Let Z= Foot of the perpendicular from focus to directrix

h  2 k  5 (6  20  1)
 
3 4 25
19 13
h  ,k 
5 5
 19  13 
Z  , 
 5 5 
29 38 
Vertex is M.P of Z and S =  , 
 10 10 

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Equation of latus rectum which is parallel to directrix and passing through focus is
2 16 
3 x  4 y  14  0 By verification one end of L.R =  , 
 5 5 
  cos x  cos ec 2 xdx  2024   cos x 
2024 2024
dx
21.
I II
Apply by parts for first integral
  cos x   cotx     2024  cos x    sin x  cotx  dx  2024   cos x 
2024 2025 2024
dx
   cos x   cotx    2024    cos x  dx   2024    cos x  dx
2024 2024 2024

I  x     cos x   cotx   c
2024

2024

π π  1 
Sub x  onboth sides I        c 21012  21012  c  c  0
4 4  2
Now I  x     cos x   cotx 
2024

2024 2024
 3  2 
π
6
π
sub x   I     
6
  
3   3 
 2   3
22.
sec 2 x
I  dx
(2  tan x)(1  2 tan x )
put t  tan x
diff w.r.to x on both sides
dt  sec 2 x dx
put t  tan x
diff w.r .to x on both sides
dt  sec 2 x dx
dt
I 
 2  t 1  2t 
 1 2 
 3 
   3  dt
 2  t 1  2t 
 
2
log 1  2t
1
 log 2  t  3 c
3 2
1 1  2 tan x
 log c
3 2  tan x
1
p
3
 3p  2  3
23. sin10 x  cos8 x sin 2 x  sin 8 x cos 2 x  cos10 x
 sin 2 x  sin 8 x  cos8 x   cos 2 x  sin 8 x  cos8 x 

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 
 sin 2 x  cos 2 x sin 8 x  cos8 x 
  sin x  cos x  sin x  cos x  sin
2 2 2 2 4
x  cos 4 x 
  sin x  cos x 1  2sin x cos x 
2 2 2 2

  cos 2 x 1  2sin x cos x 

2 2

sin 2 x
I    cos 2 xdx   C
2
24. The equation of parabola whose axis parallel to y-axis is y  ax 2  bx  c
It is passes through the points (1,0),(0,2) and (-1,-1) then
a  b  c  0  1 ,c  0   2 and a  b  c  1   3
from 1 and  3 , a  b  2   4  , a  b  3   5 
5
 4    5  a  
2
1
from  4   b 
2
5 x
 Required parabola is y   x 2   2
2 2
 5x  x  2 y  4  0
2

By comparision we get a  5, b  1, c  2, d  4

ad
Now  10
bc
25. Equation of parabola is y2 = 32x
a=8
Given  x1 , y1  and  x2 , y2  are two points on parabola y2 = 32x
and focal distance =10
x1  8  10  x1  2
Now y12  32 x1
 x1 , y1   (2,8),  x2 , y2   (2, 8)
 
2 x12  x22  y12  y22  2(4  64  4  64)  272

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PHYSICS

26.
K0 A
Capacitance of “dx” element C  
dx
K 0 (1   x) 0 A
Capacitance of “dx” element C  
dx
All such elements are connected in series. Hence, net capacitance is given by,
1 dx
   0d
C K 0 0 A(1   x)
1 1  1 log ax 
  [ln(1   x)]b0   dx   c
C K 0 0 A  ax a 
1 1
  ln(1   d )
C K 0 0 A
Given  d  1
1 1   2d 2   x2 
   d   using ln(1  x)  x  
C K 0 0 A  2  2 
1 d  d 
  1
C K 0 0 A  2 
1
K 0 0 A   d 
C  1  
d  2 
K  A  ad 
 [using (1  x)  1  nx ]
n
 C  0 0 1 
d  2 
27.

 Ceq  2C
0 A
28. C0   180 pF ; Q0  C0V0  54  108 C
d
Q0 54 108
C1    540 pF
V1 1000
k A
 0  540  K  3
d

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and   k 0  27 1012 C2 N 1m 2

V 3000
E   3 105
d 102
29. 2500  250 y y  10
3  9 1012  500 104 9 1012  2000 104
C 2
 2
 63 1012 F
5 10 5 10
30. Electric displacement of dielectric medium filled between the plates of parallel plate
condenser is D=ε0E+P.
Here E is electric field in the medium and P is the dielectric polarisation.
Electric susceptibility of dielectric medium is non- zero, Electric susceptibility is zero
only for vaccum.
31. Two capacitors are connected in parallel to a battery. If a dielectric medium is inserted
between the plates of one of the capacitors then the energy stored in the system will
increase.
The effective capacitance will be (K+1)C. Capacity will increase.
So the energy stored will be increased.
0 A
32. C for conducting slab
d t
33.

16  4 16  4 16
Rab   , Rab   3.2Ω
16  4 20 5
34. R eq  4000Ω
4 1
i  A
4000 1000
1
V0  i.R   500  0.5V
1000
35. We are given:
Resistance at ice point R0  8Ω
Resistance at steam point (100°C) R100  10Ω
Temperature of hot bath t=400∘Ct = 400°C
We assume resistance of platinum wire varies linearly with temperature:
 R  R0 
Rt  R0   100  t
 100 

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Step-by-step calculation:
 10  8   2 
Rt  8     400  8    400   8  8  16Ω
 100   100 
36. For upper plate, we have T=Fe+m2g
For m1, we have T=m1g
On equating above two equations, we get
q2
m1 g   m2 g
2 A 0
q2
m1   m2
2 A 0 g

37. Let each capacity = C

C p  C  2C  3C  6C
1 1 1 1 6  3  2 11 6C
      C3 
Cs C 2C 3C 6c 6C 11
120 6C 120 120 (66  6)C
Given C p  C3   6C    
11 11 11 11 11
120
C  2 F , C1  2  F , C2  4  F .C3  6 F
60
38. Given Data: Two statements are given.
Concept Used: Dipole Moment due to electric field
Detailed Solution:
When an electric field is applied to a polar dielectric, it polarize the dielectric, it means all
the positive charge is on one side of the dielectric and the negative is on the other side.
And each molecule has a permanent dipole and in the absence of electric field, they are
just randomly distributed
0 A 0 A
39. C   C 
 1 d  2
d  t 1   d  1  
 k 2  3
6 A 6C 6
c  0   c   5  6  F
5d 5 5
40. Force on charge particles will be given by
F  qE
FE
  
E   2 0  F 10
F2  F1  2   F1    1   5N
 E1     2 2
 0 
 

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41. Change in energy of condenser,

1 1
ΔU  U 2  U1  C2V 2  C1V 2
2 2
V2 (100)2

2
 C2  C1  
2

10 106  2 106 )

 4  10 2 J
l
42. n
AeVd
10
n 6 19 3
 625  1025
5 10  1.6  10  2  10

43.
1 1 1
   Req  4Ω
Req 12 6
V 1
44. R 
I slope of I  V graph
At CD slope is negative, so resistance is negative.
45. As we know,
R T  R T 1    T  To   .
0

2
 60  20[1   (500  20)]   
480
Let the resistance of the wire be 25 ohms at temperature T'
 R T  R TO 1    T  To  
 2 
25  20 1 
 480

T   20 



 T  80 C
46. In C1  Q1  10 10 100  10000 C
(Q  KCV )
In C2  Q2  10 100  1000C  Q  C2V 
Now C1 and C2 kept in parallel
 KC1  KC2 V  (10000  1000)
10  C1  C2  V  11000
 C1  C2 V  1100
1100
V  55 volt
20

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47. Induced charge on Dielectric

Qi  ( K  1)CV
5 
   1  90  1012  20
3 
 40  30 1012 C
Qi  1200 pC
RR
48. S  R1  R2 , P  1 2
R1  R2
 R1 R2 
 R1  R2   n  
 R1  R2 
R 21  R 2 2  2 R1 R2  nR1R2
R 21 R2
 2 2n
R1 R2 R1R2
R1 R2
 2n
R2 R1
Maximum value of the above equation is 4.
49. The circuit can be drawn as follows

50. Resistance 50Ω and 20Ω are in a parallel.

1 1 1 20  50
   
R 50 20 1000
1000
R
70
So, equivalent resistance of circuit
1000
Req  10 
70
By voltage division rule
V  R10
V10 
Req
170  10
  70 : x  70
1000
10 
70

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CHEMISTRY
2
51. (I) Cr  H 2 O 6  Cr 2  [ Ar ]3d 4
H 2 O is a weak field ligand

4 unpaired electrons
Magnetic moment   24  4.89BM
(II)  Fe(CN ) 6  Fe 2  [ Ar ]3d 6
4

CN is a strong field ligand

Unpaired electrons = 0
magnetic moment = 0
3
(III)  Fe  C2 O 4 3  Fe3  [ Ar ]3d 5
As Δ 0  P

Number of unpaired electron = 1

Magnetic moment
  1(1  2)  1.732BM
( IV )( EtN )   CoCl4 
Co 2  [ Ar ]3d 7

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Number of unpaired electrons=3

Magnetic moment
  3(3  2)  3.87BM
52. Conceptual
1
53. The wavelength of the light absorbed by the complexes 
strength of ligands
Strength of ligand:en H2O Hence, order of wavelength:
2
  Ni2 H 2O  4 en  
2
 Ni  H 2 O 6    Ni (en)3 
2

 1   2   3 
54. No optical isomerism is exhibited by the given complex as there is a plane of symmetry.
Linkage isomers:
2
Co  NH 3 5  NO2  and Co  NH 3 5 (ON O )]2
Ionization isomers:
2 
Co  NH 3 5  NO2  and Co  NH 3 5  NO3  
For coordination isomerism, both cationic and anionic entities are required.
55. Δ 0  P  so no forced pairing.
CFSE  3   0.4Δ 0   1  0.6Δ 0 
 1.2Δ 0  0.6Δ 0  9480cm 1
56. CONCEPTUAL
57. In octahedral complexes
If Δ0<P (weal field, high spin situation).
The fourth electron enters one of the eg orbitals giving the configuration

t23g e1g metal ion: sp3d 2 
58. Here, P and Q both on heating will produce ether as major product.
C6 H5CH 2 Br  CH 3ONa  CH 3OCH 2C6 H5  NaBr
(10halide) Sodium
Benzyl bromide methoxide

C6 H5ONa  CH 3 Br  C6 H5OCH 3  NaBr

Sodium (1 halide) Methoxy benzene
phenoxide (Anisole)

Here, aryl halide and sodium alkanide cannot be used for preparing phenolic ethers
because of very less reactivity of aryl halides.
59. Bulkey base prefers elimination
60. Methyl vinyl ether under anhydrous conditions at room temperature undergoes addition
reaction.
CH 2  CH  OCH 3 HBr
  CH 3CHBrOCH 3

61.

62.

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63. i) SO42  Sulphate

ii) CrO42  Chromate
iii) BO33  Borate
iv) MnO4  Permanganate
64. In identification of group V cations i.e., Ba+2 and Ca+2 are precipitated as carbonates
65. Conceptual
66. Ni2+ and Cu2+ are produces blue coloured solutions.

67.

68.
69. Conceptual
70. Diethyl ketone (Pentone-3-one) and methyl (npropyl ketone Pentan-2-one) are a pair of
metamers.
71. Co 3 : 3d 6 t 2,2,2
2g e g
0,0

Unpaired e- = 0
2 ,1,1
Ni 2 : 3d8 e 2,2t 2
Unpaired e- = 2
72. Nesler’s reagent is K2[HgI4]

73.
74. aryl oxygens are not cleaved by HI

75.

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