Safety Data Sheet according to (EC) No 1907/2006

Page 1 of 13
SDS No. : 173122
V004.3
LOCTITE 407 Revision: 27.05.2015
printing date: 20.10.2016
Replaces version from: 02.02.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
LOCTITE 407

Contains:
Ethyl 2-cyanoacrylate

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Adhesive

1.3. Details of the supplier of the safety data sheet

Henkel Ltd
Wood Lane End
HP2 4RQ Hemel Hempstead

Great Britain

Phone: +44 1442 278000

Fax-no.: +44 1442 278071

[email protected]

1.4. Emergency telephone number

24 Hours Emergency Tel: +44 (0)1442 278497

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):
Skin irritation Category 2
H315 Causes skin irritation.
Serious eye irritation Category 2
H319 Causes serious eye irritation.
Specific target organ toxicity - single exposure Category 3
H335 May cause respiratory irritation.
Target organ: respiratory tract irritation

2.2. Label elements

Label elements (CLP):

Hazard pictogram:
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Signal word: Warning

Hazard statement: H315 Causes skin irritation.

H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of
children.
Contains Phthalic anhydride. May produce an allergic reaction.

Precautionary statement: P261 Avoid breathing vapours.

Prevention P280 Wear protective gloves/eye protection.

Precautionary statement: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
Response contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement: P501 Dispose of waste and residues in accordance with local authority requirements.
Disposal

2.3. Other hazards

None if used properly.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

General chemical description:

Cyanoacrylate Adhesive
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Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification

CAS-No. REACH-Reg No.
Ethyl 2-cyanoacrylate 230-391-5 50- 100 % Eye Irrit. 2
7085-85-0 01-2119527766-29 H319
STOT SE 3
H335
Skin Irrit. 2
H315

Phthalic anhydride 201-607-5 0,1- < 1 % Acute Tox. 4; Oral

85-44-9 01-2119457017-41 H302
STOT SE 3
H335
Skin Irrit. 2
H315
Eye Dam. 1
H318
Resp. Sens. 1
H334
Skin Sens. 1
H317

Hydroquinone 204-617-8 0,01- < 0,1 % Aquatic Acute 1

123-31-9 01-2119524016-51 H400
Aquatic Chronic 1
H410
Carc. 2
H351
Muta. 2
H341
Acute Tox. 4; Oral
H302
Eye Dam. 1
H318
Skin Sens. 1
H317
M factor: 10

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
Move to fresh air, consult doctor if complaint persists.

Skin contact:
Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in
warm soapy water.
Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn.
Burns should be treated normally after the adhesive has been removed from the skin.
If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva
inside the mouth.
Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action.

Eye contact:
If the eye is bonded closed, release eyelashes with warm water by covering with wet pad.
Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive.
Keep eye covered until debonding is complete, usually within 1-3 days.
Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause
any abrasive damage.
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Ingestion:
Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost
impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours).

4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.

SKIN: Redness, inflammation.

RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:
Foam, extinguishing powder, carbon dioxide.
Fine water spray

Extinguishing media which must not be used for safety reasons:

High pressure waterjet

5.2. Special hazards arising from the substance or mixture

In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released.
5.3. Advice for firefighters
Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation.

6.2. Environmental precautions

Do not let product enter drains.

6.3. Methods and material for containment and cleaning up

Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured material can be
disposed of as non-hazardous waste.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Ventilation (low level) is recommended when using large volumes
Use of dispensing equipment is recommended to minimise the risk of skin or eye contact

Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.
Good industrial hygiene practices should be observed.

7.2. Conditions for safe storage, including any incompatibilities

For optimum shelf life store in original containers under refrigerated conditions at 2 - 8°C (35.6 - 46.4 °F)

7.3. Specific end use(s)

Adhesive
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SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Great Britain

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Ethyl 2-cyanoacrylate 0,3 1,5 Short Term Exposure EH40 WEL
7085-85-0 Limit (STEL):
[ETHYL CYANOACRYLATE]
Phthalic anhydride 12 Short Term Exposure EH40 WEL
85-44-9 Limit (STEL):
[PHTHALIC ANHYDRIDE]
Phthalic anhydride 4 Time Weighted Average EH40 WEL
85-44-9 (TWA):
[PHTHALIC ANHYDRIDE]
Hydroquinone 0,5 Time Weighted Average EH40 WEL
123-31-9 (TWA):
[HYDROQUINONE]

Predicted No-Effect Concentration (PNEC):

Name on list Environmental Exposure Value Remarks

Compartment period
mg/l ppm mg/kg others
Phthalic anhydride soil 0,173
85-44-9 mg/kg
Phthalic anhydride STP 10 mg/L
85-44-9
Phthalic anhydride sediment 3,8 mg/kg
85-44-9 (freshwater)
Phthalic anhydride sediment 0,38 mg/kg
85-44-9 (marine water)
Phthalic anhydride aqua (marine 0,1 mg/L
85-44-9 water)
Phthalic anhydride aqua 5,6 mg/L
85-44-9 (intermittent
releases)
Phthalic anhydride aqua 1 mg/L
85-44-9 (freshwater)
Hydroquinone aqua 0,114 µg/L
123-31-9 (freshwater)
Hydroquinone aqua (marine 0,0114 µg/L
123-31-9 water)
Hydroquinone sediment 0,98 µg/kg
123-31-9 (freshwater)
Hydroquinone sediment 0,097 µg/kg
123-31-9 (marine water)
Hydroquinone aqua 0,00134 mg/L
123-31-9 (intermittent
releases)
Hydroquinone soil 0,129 µg/kg
123-31-9
Hydroquinone STP 0,71 mg/L
123-31-9
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Derived No-Effect Level (DNEL):

Name on list Application Route of Health Effect Exposure Value Remarks

Area Exposure Time
Ethyl 2-cyanoacrylate Workers Inhalation Long term 9,25 mg/m3
7085-85-0 exposure - local
effects
Ethyl 2-cyanoacrylate Workers Inhalation Long term 9,25 mg/m3
7085-85-0 exposure -
systemic effects
Ethyl 2-cyanoacrylate general Inhalation Long term 9,25 mg/m3
7085-85-0 population exposure - local
effects
Ethyl 2-cyanoacrylate general Inhalation Long term 9,25 mg/m3
7085-85-0 population exposure -
systemic effects
Phthalic anhydride Workers inhalation Long term 32,2 mg/m3
85-44-9 exposure -
systemic effects
Phthalic anhydride Workers Dermal Long term 10 mg/kg bw/day
85-44-9 exposure -
systemic effects
Phthalic anhydride general inhalation Long term 8,6 mg/m3
85-44-9 population exposure -
systemic effects
Phthalic anhydride general Dermal Long term 5 mg/kg bw/day
85-44-9 population exposure -
systemic effects
Phthalic anhydride general oral Long term 5 mg/kg bw/day
85-44-9 population exposure -
systemic effects
Hydroquinone Workers Dermal Long term 128 mg/kg bw/day
123-31-9 exposure -
systemic effects
Hydroquinone Workers Inhalation Long term 7 mg/m3
123-31-9 exposure -
systemic effects
Hydroquinone Workers Inhalation Long term 1 mg/m3
123-31-9 exposure - local
effects
Hydroquinone general Dermal Long term 64 mg/kg bw/day
123-31-9 population exposure -
systemic effects
Hydroquinone general Inhalation Long term 1,74 mg/m3
123-31-9 population exposure -
systemic effects
Hydroquinone general Inhalation Long term 0,5 mg/m3
123-31-9 population exposure - local
effects

Biological Exposure Indices:

None

8.2. Exposure controls:

Engineering controls:
Ensure good ventilation/extraction.

Respiratory protection:
Ensure adequate ventilation.
An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly
ventilated area
Filter type: A
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Hand protection:
The use of chemical resistant gloves such as Nitrile is recommended.
Polyethylene or polypropylene gloves are recommended when using large volumes.
Do not use PVC, rubber or nylon gloves.
Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many
influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear
are noticed then the gloves should be replaced.

Eye protection:
Wear protective glasses.

Skin protection:
Wear suitable protective clothing.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid
colourless
Odor irritating
Odour threshold No data available / Not applicable

pH No data available / Not applicable

Initial boiling point > 149 °C (> 300.2 °F)
Flash point 80 - 93,4 °C (176 - 200.12 °F)
Decomposition temperature No data available / Not applicable
Vapour pressure 0,6600000 mbar
(25,0 °C (77 °F))
Vapour pressure < 700 mbar
(50 °C (122 °F))
Density 1,0700 g/cm3
()
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) Polymerises in presence of water.
(Solvent: Water)
Solubility (qualitative) Miscible
(Solvent: Acetone)
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanol/water No data available / Not applicable
Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Oxidising properties No data available / Not applicable

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

See section reactivity
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10.4. Conditions to avoid

No decomposition if used according to specifications.

10.5. Incompatible materials

See section reactivity

10.6. Hazardous decomposition products

None known.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

General toxicological information:

The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological
information for the substances listed under Section 3 is provided in the following.

STOT-single exposure:
May cause respiratory irritation.
Oral toxicity:
Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to
swallow as it rapidly polymerises in the mouth.

Inhalative toxicity:
Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals
In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system

Skin irritation:
Causes skin irritation.
Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg
Due to polymerisation at the skin surface allergic reaction is unlikely to occur

Eye irritation:
Causes serious eye irritation.
Liquid product will bond eyelids. In a dry atmosphere (RH<50%) vapours may cause irritation and lachrymatory effect

Sensitizing:
May cause allergic reaction.

Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Ethyl 2-cyanoacrylate LD50 > 5.000 mg/kg oral rat OECD Guideline 401 (Acute
7085-85-0 Oral Toxicity)
Phthalic anhydride LD50 1.530 mg/kg oral rat
85-44-9
Hydroquinone LD50 367 mg/kg oral rat OECD Guideline 401 (Acute
123-31-9 Oral Toxicity)

Acute dermal toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Ethyl 2-cyanoacrylate LD50 > 2.000 mg/kg dermal rabbit OECD Guideline 402 (Acute
7085-85-0 Dermal Toxicity)
Phthalic anhydride LD50 > 10.000 mg/kg dermal rabbit
85-44-9

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Ethyl 2-cyanoacrylate slightly irritating 24 h rabbit OECD Guideline 404 (Acute
7085-85-0 Dermal Irritation / Corrosion)
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Serious eye damage/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Ethyl 2-cyanoacrylate irritating 72 h rabbit OECD Guideline 405 (Acute
7085-85-0 Eye Irritation / Corrosion)
Phthalic anhydride highly irritating rabbit
85-44-9

Respiratory or skin sensitization:

Hazardous components Result Test type Species Method

CAS-No.
Ethyl 2-cyanoacrylate not sensitising guinea pig
7085-85-0
Phthalic anhydride sensitising in vivo guinea pig
85-44-9
Phthalic anhydride sensitising Mouse mouse Mouse local lymphnode assay
85-44-9 local (LLNA)
lymphnod
e assay
(LLNA)
Hydroquinone sensitising Guinea pig guinea pig
123-31-9 maximisat
ion test

Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
Ethyl 2-cyanoacrylate negative bacterial reverse OECD Guideline 471
7085-85-0 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
negative mammalian cell with and without OECD Guideline 476 (In vitro
gene mutation assay Mammalian Cell Gene
Mutation Test)
negative in vitro mammalian with and without OECD Guideline 473 (In vitro
chromosome Mammalian Chromosome
aberration test Aberration Test)
Phthalic anhydride negative bacterial reverse with and without
85-44-9 mutation assay (e.g
Ames test)
Hydroquinone negative bacterial reverse with and without EU Method B.13/14
123-31-9 mutation assay (e.g (Mutagenicity)
Ames test)

Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method

CAS-No. application Frequency of
treatment
Hydroquinone NOAEL=>= 250 oral: gavage 14 days5 days/week. rat OECD Guideline 407
123-31-9 mg/kg 12 doses (Repeated Dose 28-Day Oral
Toxicity in Rodents)
Hydroquinone LOAEL=<= 500 oral: gavage 14 days5 days/week. rat OECD Guideline 407
123-31-9 mg/kg 12 doses (Repeated Dose 28-Day Oral
Toxicity in Rodents)

SECTION 12: Ecological information

General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological
information for the substances listed under Section 3 is provided in the following.

12.1. Toxicity

Ecotoxicity:
Do not empty into drains / surface water / ground water.
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Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
Phthalic anhydride LC50 313 mg/l Fish 48 h Leuciscus idus DIN 38412-15
85-44-9
Phthalic anhydride EC50 68 mg/l Algae 72 h Selenastrum sp. OECD Guideline
85-44-9 201 (Alga, Growth
Inhibition Test)
Hydroquinone LC50 0,638 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline
123-31-9 203 (Fish, Acute
Toxicity Test)
Hydroquinone EC50 0,134 mg/l Daphnia 48 h Daphnia magna OECD Guideline
123-31-9 202 (Daphnia sp.
Acute
Immobilisation
Test)
Hydroquinone EC50 0,335 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
123-31-9 (new name: Pseudokirchnerella 201 (Alga, Growth
subcapitata) Inhibition Test)
Hydroquinone NOEC 0,0057 mg/l chronic 21 d Daphnia magna OECD 211
123-31-9 Daphnia (Daphnia magna,
Reproduction Test)

12.2. Persistence and degradability

Persistence and Biodegradability:

The product is not biodegradable.

Hazardous components Result Route of Degradability Method

CAS-No. application
Ethyl 2-cyanoacrylate aerobic 57 % OECD Guideline 301 D (Ready
7085-85-0 Biodegradability: Closed Bottle
Test)
Phthalic anhydride aerobic 90 % OECD Guideline 301 D (Ready
85-44-9 Biodegradability: Closed Bottle
Test)
Hydroquinone readily biodegradable aerobic 75 - 81 % EU Method C.4-E (Determination
123-31-9 of the "Ready"
BiodegradabilityClosed Bottle
Test)

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Mobility:
Cured adhesives are immobile.

Bioaccumulative potential:
No data available.

Hazardous components LogKow Bioconcentration Exposure Species Temperature Method

CAS-No. factor (BCF) time
Ethyl 2-cyanoacrylate 0,776 22 °C EU Method A.8 (Partition
7085-85-0 Coefficient)
Phthalic anhydride 1,6
85-44-9
Hydroquinone 0,59 EU Method A.8 (Partition
123-31-9 Coefficient)

12.5. Results of PBT and vPvB assessment

Hazardous components PBT/vPvB

CAS-No.
Phthalic anhydride Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
85-44-9 Bioaccumulative (vPvB) criteria.
Hydroquinone Not fulfilling PBT (persistent/bioaccummulative/toxic) criteria
123-31-9

12.6. Other adverse effects

No data available.
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SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
Cured adhesive: Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled
conditions.
Dispose of in accordance with local and national regulations.
Contribution of this product to waste is very insignificant in comparison to article in which it is used

Disposal of uncleaned packages:

After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an
authorised legal land fill site or incinerated.
Disposal must be made according to official regulations.

Waste code
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances

SECTION 14: Transport information

14.1. UN number

ADR Not dangerous goods

RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA 3334

14.2. UN proper shipping name

ADR Not dangerous goods

RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)

14.3. Transport hazard class(es)

ADR Not dangerous goods

RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA 9

14.4. Packaging group

ADR Not dangerous goods

RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA III

14.5. Environmental hazards

ADR not applicable

RID not applicable
ADN not applicable
IMDG not applicable
IATA not applicable

14.6. Special precautions for user

ADR not applicable

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RID not applicable

ADN not applicable
IMDG not applicable
IATA Primary packs containing less than 500ml are unregulated by this mode of transport
and may be shipped unrestricted.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content < 3,00 %
(1999/13/EC)

15.2. Chemical safety assessment

A chemical safety assessment has been carried out.
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SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular
properties.

Label elements (DPD):

Xi - Irritant

Risk phrases:
R36/37/38 Irritating to eyes, respiratory system and skin.

Safety phrases:
S23 Do not breathe vapour.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Additional labeling:
Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.

Contains Phthalic anhydride. May produce an allergic reaction.

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.
Annex - Exposure Scenarios:
Exposure Scenarios for ethyl 2-cyanoacrylate can be downloaded under the following link:
http://mymsds.henkel.com/mymsds/.470833..en.ANNEX_DE.15743123.0.DE.pdf
Alternatively they can be accessed on the internet site www.mymsds.henkel.com by entering number 470833.